箭推法在高价金属(Cr,Mn,Fe)含氧酸盐氧化还原反应机理中的应用
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摘要
讨论了箭推法在解释无机高价过渡金属(Cr~(Ⅵ)、Mn~(Ⅶ)和Fe~(Ⅵ))化合物有关反应机理中的应用。文中引入了若干反应实例,探讨了箭推法的应用。
In this paper, we try to use the arrow-pushing method to explain the reaction mechanisms of some highvalence transition-metallic oxysalts. Some typical examples are introduced to demonstrate the method.
In this paper, we try to use the arrow-pushing method to explain the reaction mechanisms of some highvalence transition-metallic oxysalts. Some typical examples are introduced to demonstrate the method.
引文
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[2]Ghosh,A.;Berg,S.Arrow Pushing in Inorganic Chemistry:A Logical Approach to the Chemistry of the Main-Group Elements;John Wiley&Sons,Inc.:Hoboken,New Jersey,USA,2014;pp 13-16.
[3]Bae,C.H.;Roberts,E.P.L.;Dryfe,R.A.W.Electrochimica Acta 2002,48,279.
[4]Sharma,V.K.J.Environ.Manage 2011,92,1051.
[5]Rbbai,G.;Beck,M.T.J.Chem.Soc.1985,4,1669.
[6]Latunji,M.A.;McAuley,A.J.Am.Chem.Soc.1974,4,1292.
[7]Lin,C.T.;Beattie,J.K.J.Am.Chem.Soc.1972,94,3011.
[8]Olatunji,M.A.;Ayoko,G.A.Polyhedron.1988,7,11.
[9]Sharma,V.K.;Rivera,W.;Joshi,V.N.;Millero,F.J.;O’Connor,D.Environ.Sci.Technol.1999,33,2645.
[10]Dozsa,L.;Beck,M.T.Inorg.Chim.Acta 1970,4,219.
[11]Dash.S.;Patel,S.;Mishra,B.K.Tetrahedron 2009,65,707.
[12]SimPandi,L.I.;Miklos,J.;Savage,C.R.;Schelly,Z.A.J.Am.Chem.Soc.1985,107,4220.
[13]Goff,H.;Murmann,R.K.J.Am.Chem.Soc.1971,93,6058.