通过棒状金属羧酸/羟基次级结构单元形成的锌金属有机骨架的低温余晖性质（英文）
|
摘要
通过一个含3个羧基基团的多功能配体2-羟基-1,3,5-苯基三羧酸(HO-H3BTC)与锌盐构筑了一个三维多孔锌骨架结构配合物,{[Zn4(O-BTC)2(H2O)5]·2DMF·0.5H2O}n(1)。通过单晶X射线衍射、粉末X射线衍射、元素分析、红外光谱、热重分析以及固体紫外吸收光谱对该配合物进行了表征。配合物1是通过棒状金属锌-羧酸/羟基次级结构单元构筑的一个三维骨架结构,其在室温下显示强烈的蓝色荧光。此外,在低温条件下(10 K)配合物1显示余晖性质。
A three-dimensional(3 D) porous Zn (Ⅱ)-based framework, {[Zn4(O-BTC)2(H2 O)5]·2 DMF·0.5 H2 O}n(1),which is constructed from a multifunctional tricarboxylate ligand, 2-hydroxyl-1,3,5-benzenetricarboxylic acid(HOH3 BTC) and Zn (Ⅱ) salts was prepared. Complex 1 has been characterized by X-ray single-crystal diffraction,PXRD, elemental analysis, infrared spectroscopy, thermogravimetric analysis, and solid-state UV-Vis absorption spectra. Complex 1 exhibits a three-dimensional(3 D) framework structure based on the rod-shaped Zncarboxylate/hydroxyl secondary building unit(SBU). Solid-state luminescence studies showed that 1 exhibits intense blue emission at room temperature. Interestingly, 1 could exhibit afterglow property only under low temperature(10 K) condition.
A three-dimensional(3 D) porous Zn (Ⅱ)-based framework, {[Zn4(O-BTC)2(H2 O)5]·2 DMF·0.5 H2 O}n(1),which is constructed from a multifunctional tricarboxylate ligand, 2-hydroxyl-1,3,5-benzenetricarboxylic acid(HOH3 BTC) and Zn (Ⅱ) salts was prepared. Complex 1 has been characterized by X-ray single-crystal diffraction,PXRD, elemental analysis, infrared spectroscopy, thermogravimetric analysis, and solid-state UV-Vis absorption spectra. Complex 1 exhibits a three-dimensional(3 D) framework structure based on the rod-shaped Zncarboxylate/hydroxyl secondary building unit(SBU). Solid-state luminescence studies showed that 1 exhibits intense blue emission at room temperature. Interestingly, 1 could exhibit afterglow property only under low temperature(10 K) condition.
引文
[1] Eddaoudi M, Kim J, Yaghi O M. et al. Science, 2002,295:469-472
[2] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004,43:2334-2375
[3] Li B Y, Leng K Y, Ma S Q, et al. J. Am. Chem. Soc., 2015,137:4243-4248
[4] Chen B L, Xiang S C, Qian G D. Acc. Chem. Res., 2010,43:1115-1124
[5] Huang X D, Xu Y, Zheng L M, et al. Angew. Chem. Int. Ed.,2018,58:8577-8581
[6] Weng D F, Wang Z M, Gao S. Chem. Soc. Rev., 2011,40:3157-3181
[7] Liu F L, Li D, Tao J, et al. Dalton Trans., 2018,47:1407-1411
[8] Cui Y J, Chen B L, Qian G D, et al. Acc. Chem. Res., 2016,49:483-493
[9] Sun C Y, Wang X L, Li J, et al. Nat. Commun., 2013,4:2717-2723
[10]Chorazy S, Kumar K, Ohkoshi S, et al. Inorg. Chem., 2017,56:5239-5252
[11]Wang H, Lusting W P, Li J. Chem. Soc. Rev., 2018,47:4729-4756
[12]Cepeda J, Sebastian E S, Seco J M, et al. Chem. Commun.,2016,52:8671-8674
[13]Yuan S, Deng Y K, Sun D. Chem. Eur. J., 2014,20:10093-10098
[14]Yang X G, Yan D P. Chem. Sci., 2016,7:4519-4526
[15]LIU Ying-Liang(刘应亮), LEI Bing-Fu(雷炳富), KUANG Jin-Yong(邝金勇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(8):1323-1329
[16]Matsuzawa T, Aoko Y, Takeuchi N, et al. J. Electrochem.Soc., 1996,143:2670-2673
[17]Maragani R, Thomas M B, Misra R, et al. J. Phys. Chem. A,2018,122:4829-4837
[18]Howarth A J, Davies D L, Wolf M O, et al. Inorg. Chem.,2014,53:11882-11889
[19]Han L, Qin L, Xu L P, et al. Inorg. Chem., 2013,52:1667-1669
[20]Luo F, Sun G M, Zheng A M, et al. Dalton Trans., 2012,41:13280-13283
[21]Gao M J, Yang P, Wu J Z, et al. CrystEngComm, 2012,14:1264-1270
[22]SADABS and SAINT, Program for Data Extraction and Reduction, Bruker AXS Inc., Madison, WI, USA, 2003.
[23]Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of G觟ttingen, Germany, 1997.
[24]Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of G觟ttingen, Germany, 1997.
[25]Yu M H, Hu T L, Bu X H. Inorg. Chem. Front., 2017,4:256-260
[26]WANG Peng-Fei(汪鹏飞). Chinese J. Inorg. Chem.(无机化学学报), 2018,34(9):1747-1752
[27]Rosi N L, Kim J, Yaghi O M, et al. J. Am. Chem. Soc.,2005,127:1504-1518
[28]Wang Y L, Jiang Y L, Liu Q Y, et al. Dalton Trans., 2012,41:11428-11437
[29]Spek A L. PLATON:A Multipurpose Crystallographic Tool,Utrecht University, The Netherlands, 2001.
[30]Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th Ed. New Jersey:John Wiley&Sons, Inc., 2009:61-67
[31]Liu L, Dai J C. Cryst. Growth Des., 2018,18:4460-4469
[32]Cui Y J, Qian G D, Chen B L, et al. Chem. Rev., 2012,112:1126-1162
[33]Seco J M, Briones D, Cepeda J, et al. Cryst. Growth Des.,2017,17:3893-3906
[2] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004,43:2334-2375
[3] Li B Y, Leng K Y, Ma S Q, et al. J. Am. Chem. Soc., 2015,137:4243-4248
[4] Chen B L, Xiang S C, Qian G D. Acc. Chem. Res., 2010,43:1115-1124
[5] Huang X D, Xu Y, Zheng L M, et al. Angew. Chem. Int. Ed.,2018,58:8577-8581
[6] Weng D F, Wang Z M, Gao S. Chem. Soc. Rev., 2011,40:3157-3181
[7] Liu F L, Li D, Tao J, et al. Dalton Trans., 2018,47:1407-1411
[8] Cui Y J, Chen B L, Qian G D, et al. Acc. Chem. Res., 2016,49:483-493
[9] Sun C Y, Wang X L, Li J, et al. Nat. Commun., 2013,4:2717-2723
[10]Chorazy S, Kumar K, Ohkoshi S, et al. Inorg. Chem., 2017,56:5239-5252
[11]Wang H, Lusting W P, Li J. Chem. Soc. Rev., 2018,47:4729-4756
[12]Cepeda J, Sebastian E S, Seco J M, et al. Chem. Commun.,2016,52:8671-8674
[13]Yuan S, Deng Y K, Sun D. Chem. Eur. J., 2014,20:10093-10098
[14]Yang X G, Yan D P. Chem. Sci., 2016,7:4519-4526
[15]LIU Ying-Liang(刘应亮), LEI Bing-Fu(雷炳富), KUANG Jin-Yong(邝金勇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(8):1323-1329
[16]Matsuzawa T, Aoko Y, Takeuchi N, et al. J. Electrochem.Soc., 1996,143:2670-2673
[17]Maragani R, Thomas M B, Misra R, et al. J. Phys. Chem. A,2018,122:4829-4837
[18]Howarth A J, Davies D L, Wolf M O, et al. Inorg. Chem.,2014,53:11882-11889
[19]Han L, Qin L, Xu L P, et al. Inorg. Chem., 2013,52:1667-1669
[20]Luo F, Sun G M, Zheng A M, et al. Dalton Trans., 2012,41:13280-13283
[21]Gao M J, Yang P, Wu J Z, et al. CrystEngComm, 2012,14:1264-1270
[22]SADABS and SAINT, Program for Data Extraction and Reduction, Bruker AXS Inc., Madison, WI, USA, 2003.
[23]Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of G觟ttingen, Germany, 1997.
[24]Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of G觟ttingen, Germany, 1997.
[25]Yu M H, Hu T L, Bu X H. Inorg. Chem. Front., 2017,4:256-260
[26]WANG Peng-Fei(汪鹏飞). Chinese J. Inorg. Chem.(无机化学学报), 2018,34(9):1747-1752
[27]Rosi N L, Kim J, Yaghi O M, et al. J. Am. Chem. Soc.,2005,127:1504-1518
[28]Wang Y L, Jiang Y L, Liu Q Y, et al. Dalton Trans., 2012,41:11428-11437
[29]Spek A L. PLATON:A Multipurpose Crystallographic Tool,Utrecht University, The Netherlands, 2001.
[30]Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th Ed. New Jersey:John Wiley&Sons, Inc., 2009:61-67
[31]Liu L, Dai J C. Cryst. Growth Des., 2018,18:4460-4469
[32]Cui Y J, Qian G D, Chen B L, et al. Chem. Rev., 2012,112:1126-1162
[33]Seco J M, Briones D, Cepeda J, et al. Cryst. Growth Des.,2017,17:3893-3906