离子液体在燃料油脱硫中的研究进展
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摘要
在简单对比了催化加氢和非催化加氢技术在燃料油脱硫方面应用的基础上,分析了非催化加氢技术的研究状况,论述了几种离子液体在直接萃取、氧化脱硫和烷基化脱硫等非催化加氢中的研究进展,并对几种离子液体的脱硫效果做了一定量的汇总。针对氧化脱硫过程中双氧水消耗量多、成本高等问题,对功能化离子液体在氧气氧化脱硫过程中的应用做了介绍,并对其今后的研究方向和内容做了展望。
Based on a simple comparison of the applications of non-catalytic hydrogenation and catalytic hydrogenation technology in fuel oil desulfurization,the research status of non-catalytic hydrogenation technology was reviewed.Then the research progress in applications of several ionic liquids in non-catalytic hydrogenation desulfurizations,such as direct extraction,oxidative desulfurization,and alkylation desulfurization,was discussed.A certain amount of summary for the desulfurization effect of such ionic liquids was made.Then,for the problems of more H2O2′s consumption and high cost etc.,the application of the functionalized ionic liquids in oxygen oxidative desulfurization process was introduced.The research direction and contents in future were also prospected.
Based on a simple comparison of the applications of non-catalytic hydrogenation and catalytic hydrogenation technology in fuel oil desulfurization,the research status of non-catalytic hydrogenation technology was reviewed.Then the research progress in applications of several ionic liquids in non-catalytic hydrogenation desulfurizations,such as direct extraction,oxidative desulfurization,and alkylation desulfurization,was discussed.A certain amount of summary for the desulfurization effect of such ionic liquids was made.Then,for the problems of more H2O2′s consumption and high cost etc.,the application of the functionalized ionic liquids in oxygen oxidative desulfurization process was introduced.The research direction and contents in future were also prospected.
引文
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[18]张薇,李阳,吴琼,等.酸性离子液体[BMIm]HSO4催化噻吩氧化脱硫[J].化学通报,2013,76(12):1137-1140.
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[21]Yu Guangren,Zhao Jingjing,Song Dandan,et al.Deep oxidative desulfurization of diesel fuels by acidic ionic liquids[J].Ind.Eng.Chem.Res.,2011,50(20):11690-11697.
[22]Li Fangtang,Kou Chengguang,Sun Zhimin,et al.Deep extractive and oxidative desulfurization of dibenzothiophene with C5H9NO·Sn Cl2coordinated ionic liquid[J].J.Hazard.Mater.,2012,205/206:164-170.
[23]李蕊,王景芸,周明东,等.有机钼多金属氧酸盐在柴油氧化脱硫中的应用[J].石油化工高等学校学报,2014,27(4):6-10.
[24]王浩杰,贺建勋,郑栓辰,等.磷钼杂多酸离子液体在FCC汽油催化氧化脱硫中的应用[J].石油炼制与化工,2014(9):16-19.
[25]Zhang W,Xu K,Zhang Q,et al.Oxidative desulfurization of dibenzothiophene catalyzed by ionic liquid[BMIM]HSO4[J].Ind.Eng.Chem.Res.,2010,49(22):11760-11763.
[26]黎俊波,曹灿灿,余响林,等.酸性离子液体萃取催化氧化脱除模拟油中噻吩[J].武汉工程大学学报,2013,35(2):32-36.
[27]朱文帅,巢艳红,李华明,等.离子液体中过氧钨配合物催化氧化燃油脱硫[J].化学研究与应用,2011,23(10):1309-1312.
[28]杨志杰,张全,张岩.离子液体中FCC模拟汽油相转移催化氧化脱硫研究[J].化工新型材料,2015(9):179-182.
[29]Huang Wangli,Zhu Wenshuai,Li Huaming.Polyoxometalate-based ionic liquids as catalysts for deep desulfurization of fuels[J].Fuel Processing Technology,2011,92(10):1842-1848.
[30]黄蔚霞,李云龙,汪燮卿.离子液体在催化裂化汽油脱硫中的应用[J].化工进展,2004,23(3):297-299.
[31]刘植昌,胡建茹,高金森.离子液体用于催化裂化汽油烷基化脱硫的实验室研究[J].石油炼制与化工,2006,37(10):22-26.
[32]曾丹林,胡义,舒大凡,等.利用离子液体烷基化脱除汽油中噻吩硫的研究[J].湖北大学学报:自然科学版,2012,34(1):77-80.
[33]时雪.氧气氧化脱除噻吩类硫化物[D].大连:大连理工大学,2010.
[34]宋鹏俊,闫锋,张影,等.FCC柴油氧气氧化萃取法脱硫研究[J].化工科技,2010,18(1):43-47.
[35]侯付国.氧化-温控相分离离子液体的合成及其在催化汽油氧气氧化脱硫中的应用研究[D].青岛:青岛科技大学,2014.
[36]于凤丽,唐会宝,柳春玉,等.氧化-温控双功能离子液体催化O2氧化模拟柴油脱硫[J].化学学报,2014,72(11):1152-1156.
[2]胡松青,张军,刘冰,等.离子液体萃取脱硫的探索性研究[J].石油学报:石油加工,2007,23(1):100-103.
[3]冯婕,李春喜,孟洪,等.磷酸酯类离子液体在燃油深度脱硫中的应用[J].石油化工,2006,35(3):272-276.
[4]Huang Chongpin,Chen Biaohua,Zhang Jie,et al.Desulfurization of gasoline by extraction with new ionic liquids[J].Energy&Fuels2004,18(6):1862-1864.
[5]张傑,黄崇品,陈标华,等.用[BMIM][Cu2Cl3]离子液体萃取脱除汽油中的硫化物[J].燃料化学学报,2005,33(4):431-434.
[6]田景芝,荆涛,邓启刚.离子液体在汽油脱硫中的应用[J].化学工程师,2012,26(3):64-66.
[7]姚文生,邱瀟杨,钱建华,等.氯化亚锡低共熔离子液体萃取油品脱硫研究[J].科学技术与工程,2013,13(16):4671-4675.
[8]颜文超,王强,周明东,等.烷基咪唑氯酸盐离子液体的萃取脱硫研究[J].石油化工高等学校学报,2012,25(6):1-4.
[9]Zhang S G,Zhang Q L,Zhang Z C.Extractive desulfurization and denitrogenation of fuels using ionic liquids[J].Ind.Eng.Chem.Res.,2004,43(2):614-622.
[10]Liu D,Gui J Z,Song L,et al.Deep desulfurization of diesel fuel by extraction with task-specific ionic liq uids[J].Pet.Sci.Technol.,2008,26(7/8/9):973-982.
[11]于颖敏.亲水性离子液体在油品脱硫中的应用[J].曲阜师范大学学报:自然科学版,2009,35(3):64-68.
[12]Wang Xiaomeng,Han Mingjuan,Wan Hui,et al.Study on extraction of thiophene from model gasoline with bronsted acidic ionic liquids[J].Front.Chem.SCi.Eng.,2011,5(1):107-112.
[13]张航,贺建勋,杨彩茸,等.[BMIM]BF4氧化萃取脱除模拟汽油中噻吩的研究[J].西北大学学报:自然科学版,2013,43(1):60-63.
[14]韩兴华,李翔,王安杰,等.[BMIM][BF4]离子液体萃取脱除氧化柴油中砜类化合物[J].石油学报:石油加工,2013,29(6):1062-1066.
[15]张存,王峰,潘小玉,等.酸性离子液体萃取-氧化模拟油品脱硫研究[J].燃料化学学报,2011,39(9):689-693.
[16]肖晶,王强,周明东,等.硫酸氢盐离子液体萃取氧化脱硫研究[J].石油化工高等学校学报,2013,26(1):21-24,28.
[17]Zhao D S,Wang J L,Zhou E P.Oxidative desulfurization of diesel fuel using a Bronsted acid room temperature ionic liquid in the presence of H2O2[J].Green Chem.,2007,9(11):1219-1222.
[18]张薇,李阳,吴琼,等.酸性离子液体[BMIm]HSO4催化噻吩氧化脱硫[J].化学通报,2013,76(12):1137-1140.
[19]Lo W H,Yang H Y,Wei G T.One-pot desulfurization of light oils by chemical oxidation and solvent extraction with room temperature ionic liquids[J].Green Chem.,2003,(5):639-642.
[20]Zhu Wenshuai,Zhu Guopeng,Li Huaming,et al.Oxidative desulfurization of fuel catalyzed by metal-based surfactant-type ionic liquids[J].J.Mol.Catal.A:Chem.,2011,347(1/2):8-14.
[21]Yu Guangren,Zhao Jingjing,Song Dandan,et al.Deep oxidative desulfurization of diesel fuels by acidic ionic liquids[J].Ind.Eng.Chem.Res.,2011,50(20):11690-11697.
[22]Li Fangtang,Kou Chengguang,Sun Zhimin,et al.Deep extractive and oxidative desulfurization of dibenzothiophene with C5H9NO·Sn Cl2coordinated ionic liquid[J].J.Hazard.Mater.,2012,205/206:164-170.
[23]李蕊,王景芸,周明东,等.有机钼多金属氧酸盐在柴油氧化脱硫中的应用[J].石油化工高等学校学报,2014,27(4):6-10.
[24]王浩杰,贺建勋,郑栓辰,等.磷钼杂多酸离子液体在FCC汽油催化氧化脱硫中的应用[J].石油炼制与化工,2014(9):16-19.
[25]Zhang W,Xu K,Zhang Q,et al.Oxidative desulfurization of dibenzothiophene catalyzed by ionic liquid[BMIM]HSO4[J].Ind.Eng.Chem.Res.,2010,49(22):11760-11763.
[26]黎俊波,曹灿灿,余响林,等.酸性离子液体萃取催化氧化脱除模拟油中噻吩[J].武汉工程大学学报,2013,35(2):32-36.
[27]朱文帅,巢艳红,李华明,等.离子液体中过氧钨配合物催化氧化燃油脱硫[J].化学研究与应用,2011,23(10):1309-1312.
[28]杨志杰,张全,张岩.离子液体中FCC模拟汽油相转移催化氧化脱硫研究[J].化工新型材料,2015(9):179-182.
[29]Huang Wangli,Zhu Wenshuai,Li Huaming.Polyoxometalate-based ionic liquids as catalysts for deep desulfurization of fuels[J].Fuel Processing Technology,2011,92(10):1842-1848.
[30]黄蔚霞,李云龙,汪燮卿.离子液体在催化裂化汽油脱硫中的应用[J].化工进展,2004,23(3):297-299.
[31]刘植昌,胡建茹,高金森.离子液体用于催化裂化汽油烷基化脱硫的实验室研究[J].石油炼制与化工,2006,37(10):22-26.
[32]曾丹林,胡义,舒大凡,等.利用离子液体烷基化脱除汽油中噻吩硫的研究[J].湖北大学学报:自然科学版,2012,34(1):77-80.
[33]时雪.氧气氧化脱除噻吩类硫化物[D].大连:大连理工大学,2010.
[34]宋鹏俊,闫锋,张影,等.FCC柴油氧气氧化萃取法脱硫研究[J].化工科技,2010,18(1):43-47.
[35]侯付国.氧化-温控相分离离子液体的合成及其在催化汽油氧气氧化脱硫中的应用研究[D].青岛:青岛科技大学,2014.
[36]于凤丽,唐会宝,柳春玉,等.氧化-温控双功能离子液体催化O2氧化模拟柴油脱硫[J].化学学报,2014,72(11):1152-1156.