微波法合成金属-有机骨架材料研究应用进展
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摘要
微波加热是一种简单、高效、低成本的加热方式,近年来在新材料合成方面得到广泛应用。作为新型多孔材料,金属-有机骨架(MOF)材料在吸附、催化等领域的应用备受关注。由于传统加热法合成MOF材料存在反应时间长等缺点,微波法作为一种新的加热方式被越来越多地用于合成MOF材料。与传统加热法相比,微波法合成MOF具有反应速度快、合成的晶体尺寸小等特点。综述了微波法合成MOF材料的研究进展,介绍了该方法合成的MOF材料在气相吸附、液相吸附方面的应用。
Microwave(MW)irradiation is a simple,inexpensive and efficient nonconventional heating methods which has been widely used in the preparation of new material.Metal-organic framework(MOF)is a new kind of porous materials,which is attracting more and more attention in the fields of adsorption and catalysis.Because conventional heating method has some disadvantages,such as long reaction time,MW irradiation as a new heating method has been more and more applied in MOF synthesis.Compared with the traditional heating method,MOF synthesis by microwave method has the characteristics of fast reaction speed and small size crystal that can be got.The investigations on the preparation of MOF using MW method were reviewed.The recent applications of MOF materials prepared by MW method in the field of gas and liquid adsorption were introduced.
Microwave(MW)irradiation is a simple,inexpensive and efficient nonconventional heating methods which has been widely used in the preparation of new material.Metal-organic framework(MOF)is a new kind of porous materials,which is attracting more and more attention in the fields of adsorption and catalysis.Because conventional heating method has some disadvantages,such as long reaction time,MW irradiation as a new heating method has been more and more applied in MOF synthesis.Compared with the traditional heating method,MOF synthesis by microwave method has the characteristics of fast reaction speed and small size crystal that can be got.The investigations on the preparation of MOF using MW method were reviewed.The recent applications of MOF materials prepared by MW method in the field of gas and liquid adsorption were introduced.
引文
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[33]Bao Z B,Yu L,Ren Q L,et al.Adsorption of CO2and CH4on a magnesium-based metal organic framework[J].J Colloid Interf Sci,2011,353(2):549-556.
[34]Li Z Q,Yang J C,Sui K E,et al.Facile synthesis of metal-organic framework MOF-808for arsenic removal[J].Mater Lett,2015,160:412-414.
[35]Ge J L,Liu L L,Shen Y H.Facile synthesis of amine-functionalized UiO-66 by microwave method and application for methylene blue adsorption[J].J Porous Mat,2016,23(4):857-865.
[36]Zou F,Yu R H,Li R,et al.Microwave-assisted synthesis of HKUST-1and functionalized HKUST-1-@H3PW12O40:selective adsorption of heavy metal ions in water analyzed with synchrotron radiation[J].Chem Phys Chem,2013,14(12):2825-2832.
[37]Liu B T,He Y P,Han L P,et al.Microwave-assisted rapid synthesis ofγ-cyclodextrin metal-organic frameworks for size control and efficient drug loading[J].Cryst Growth Des,2017,17(4):1654-1660.
[38]Yin N,Wang K,Li Z Q.Rapid microwave-promoted synthesis of Zr-MOFs:an efficient adsorbent for Pb(Ⅱ)removal[J].Chem Lett,2016,45(6):625-627.
[2]张中,蒙延双,韩旺庆,等.微波辅助加热法合成LiFePO4/C正极材料[J].化工新型材料,2016,44(3):56-58.
[3]徐龙泉,杨敏,汪德祥,等.微波辐照合成固载咪唑离子液体中间体:1-甲基-3-(3-三乙氧硅基丙基)咪唑氯[J].化工新型材料,2014,42(6):132-134.
[4]Batten S R,Champness N R,Chen X,et al.Terminology of metal-organic frameworks and coordination polymers[J].Pure Appl Chem,2013,85(8):1715-1724.
[5]Batten S R,Champness N R,Chen X,et al.Coordination polymers metal-organic frameworks and the need for terminology guidelines[J].Crystengcomm,2012,14(9):3001-3004.
[6]Li H L,Eddaoud M,Keffe M O,et al.Design and synthesis of an exceptionally stable and highly porousmetal-organic framework[J].Nature,1999,402(1):276-279.
[7]Wang Z X,Zheng B S,Liu H T,et al.High-capacity gas storage by a microporous oxalamide-functionalized NbO-type metal-organic framework[J].Cryst Growth Des,2013,13(11):5001-5006.
[8]Gutov O V,Bury W,Gomezgualdron D A,et al.Water-stable zirconium-based metal-organic framework material with highsurface area and gas-storage capacities[J].Chem,2014,20(39):12389-12393.
[9]张伊,顾奕奕,陈云琳,等.掺杂金属离子对MOF-5吸附甲烷分子的影响[J].化工新型材料,2015,43(2):93-96.
[10]郑琴琴,刘心中,林松烨,等.金属-有机骨架材料的合成及CO2吸附分离研究进展[J].化工新型材料,2017,45(2):25-27.
[11]符瞰,黄思思,赵祯霞,等.MOFs材料合成及其对有机气体吸附研究进展[J].化工新型材料,2013,41(8):4-6.
[12]刘艳凤,张天永,吴武斌,等.水处理提高MOF-199催化苯羟基化反应性能[J].化工进展,2016,35(4):1113-1120.
[13]Yi X L,Dong W F,Zhang X D,et al.MIL-53(Fe)MOF-mediated catalytic chemilum inescence for sensitive detection of glucose[J].Anal Bioanal Chem,2016,408(30):8805-8812.
[14]Albuquerque G H,Herman G S.Chemically modulated microwave-assisted synthesis of MOF-74(Ni)and preparation of MOF-matrix based membranes for removal of metal ions from a queous media[J].Cryst Growth Des,2017,17(1):156-172.
[15]Dreischarf A C,Lammert M,Stock N,et al.Green synthesis of Zr-CAU-28:structure and properties of the first Zr-MOFbased on 2,5-furandicarboxylic acid[J].Inorg Chem,2017,56(4):2270-2277.
[16]张晓东,李红欣,侯扶林,等.金属有机骨架材料MOF-5的制备及其吸附CO2性能研究[J].功能材料,2016,8(47):178-181.
[17]Laybourn A,Katrib J,Ferrari-john R S,et al.Metal-organic frameworks in seconds via selective microwave heating[J].JMater Chem A,2017,5(16):7333-7338.
[18]Haque E,Khan N A,Park J H,et al.Synthesis of a metal-organic framework material,iron terephthalate,by ultrasound,microwave,and conventional electric heating:a kinetic study[J].Chem,2010,16(3):1046-52.
[19]Haque E,Jhung S H.Synthesis of isostructural metal-organic frameworks,CPO-27s,with ultrasound,microwave,and conventional heating:effect of synthesis methods and metal ions[J].Chem Eng J,2011,173(3):866-872.
[20]Haque E,Khan N A,Kim C M,et al.Syntheses of metal organic frameworks and aluminophosphates under microwave heating:quantitative analysis of accelerations[J].Crystal Growth and Design,2011,11(10):4413-4421.
[21]Khan A N,Haque E,Jhung S H.Rapid syntheses of a metalorganic framework material Cu3(BTC)2(H2O)3under microwave:aquantitative analysis of accelerated syntheses[J].Phys Chem Chem Phys,2010,12(11):2625-2631.
[22]Gordon J,Kazemian H,Rohani S.Rapid and efficient crystallization of MIL-53(Fe)by ultrasound and microwave irradiation[J].Micropor Mesopor Mat,2012,162(6):36-43.
[23]Jung D W,Yang D A,Kim J,et al.Facile synthesis of MOF-177by a sonochemical method using 1-methyl-2-pyrrolidinone as a solvent[J].Dalton T,2010,39(11):2883-2887.
[24]Chalatl T,Horcajada P,Gref R,et al.Optimisation of the synthesis of MOF nanoparticles made of flexible porous iron fumarate MIL-88A[J].J Mater Chem,2011,21(7):2220-2227.
[25]Wu X F,Bao Z B,Yuan B,et al.Microwave synthesis and characterization of MOF-74(M=Ni,Mg)for gas separation[J].Micropor Mesopor Mat,2013,180(9):114-122.
[26]Khan N A,Lee J S,Jeon J,et al.Phase-selective synthesis and phase-conversion of porousaluminum-benzenetricarboxylates with microwave irradiation[J].Micropor Mesopor Mat,2012,152(2):235-239.
[27]Dr S H J,Lee J H,Dr P M F,et al.Microwave synthesis of hybrid in organic-organic porous materials:phase-selective and rapid crystallization[J].Chem,2006,12(30):7899-7905.
[28]Tari N E,Tadjarodi A,Tamnanloo J,et al.Facile and fast,one pot microwave synthesis of metal organic framework copper terephthalate and study CO2and CH4adsorption on it[J].JPorous Mat,2015,22(5):1161-1169.
[29]Yang T B,Sun L X,Xu F,et al.Microwave synthesis of MOFs/graphene oxide composites and hydrogen storage properties[C].第七届中国储能与动力电池及其关键材料学术研讨与技术交流会.桂林:2015.
[30]Cho H Y,Yanga D A,Kima J,et al.CO2adsorption and catalytic application of Co-MOF-74 synthesized by microwave heating[J].Catal Today,2012,185(1):35-40.
[31]Palomino C C,Arean C O,Parra J B,et al.A rapid microwaveassisted synthesis of a sodium-cadmium metal-organic framework having improved performance as a CO2 adsorbent for CCS[J].Dalton T,2015,44(21):9955-9965.
[32]Sarawade P,Tan H,Polshettiwar V.Shape-and morphologycontrolled sustainable synthesis of Cu,Co,and in metal organic frameworks with high CO2capture capacity[J].ACS Sustain Chem Eng,2013,1(1):66-74.
[33]Bao Z B,Yu L,Ren Q L,et al.Adsorption of CO2and CH4on a magnesium-based metal organic framework[J].J Colloid Interf Sci,2011,353(2):549-556.
[34]Li Z Q,Yang J C,Sui K E,et al.Facile synthesis of metal-organic framework MOF-808for arsenic removal[J].Mater Lett,2015,160:412-414.
[35]Ge J L,Liu L L,Shen Y H.Facile synthesis of amine-functionalized UiO-66 by microwave method and application for methylene blue adsorption[J].J Porous Mat,2016,23(4):857-865.
[36]Zou F,Yu R H,Li R,et al.Microwave-assisted synthesis of HKUST-1and functionalized HKUST-1-@H3PW12O40:selective adsorption of heavy metal ions in water analyzed with synchrotron radiation[J].Chem Phys Chem,2013,14(12):2825-2832.
[37]Liu B T,He Y P,Han L P,et al.Microwave-assisted rapid synthesis ofγ-cyclodextrin metal-organic frameworks for size control and efficient drug loading[J].Cryst Growth Des,2017,17(4):1654-1660.
[38]Yin N,Wang K,Li Z Q.Rapid microwave-promoted synthesis of Zr-MOFs:an efficient adsorbent for Pb(Ⅱ)removal[J].Chem Lett,2016,45(6):625-627.