钝感推进剂配方研究及发展趋势
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摘要
从钝感黏合剂、钝感增塑剂、钝感高能填料以及新型复合材料等方面综述了国内外钝感固体推进剂配方及钝感方法进展。结果表明,HTPE黏合剂、BDNPF/A增塑剂、FOX-7高能填料以及HMX-TATB核-壳微粒等均可有效降低推进剂感度。今后钝感推进剂的重点研究方向主要为推进剂钝感机理、钝感推进剂能量与感度关系、钝感材料的匹配技术以及影响感度的综合因素等。
The progresses in formulations and insensitive ways for solid propellants at home and abroad were reviewed including insensitive binder,insensitive plasticizer,insensitive high energetic substance and new composite material,etc.The results show that the sensitivity of propellant can be decreased by using HTPE binder,BDNPF/A plasticizer,FOX-7high energetic substance and HMX-TATB core-shell microparticles,ect.The important research aspects for insensitive propellants are proposed,which will be the study of insensitive mechanism for propellant,relationship between energy and sensitivity of propellant,well-matched composite insensitive substances,the effects of various factors on the sensitivity of the propellant,etc.
The progresses in formulations and insensitive ways for solid propellants at home and abroad were reviewed including insensitive binder,insensitive plasticizer,insensitive high energetic substance and new composite material,etc.The results show that the sensitivity of propellant can be decreased by using HTPE binder,BDNPF/A plasticizer,FOX-7high energetic substance and HMX-TATB core-shell microparticles,ect.The important research aspects for insensitive propellants are proposed,which will be the study of insensitive mechanism for propellant,relationship between energy and sensitivity of propellant,well-matched composite insensitive substances,the effects of various factors on the sensitivity of the propellant,etc.
引文
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[15]Li Jun,Zhao Xiao-bin,Wang Chen-xue,et al.Fuzzy evaluation method for synthesis sensitivity of solid propellant[J].Journal of Solid Rocket Technology,2007,30(4):324-327.
[16]Walsh M R,Walsh M E,Hewitt A D.Energetic residues from field disposal of gun propellants[J].Journal of Hazardous Materials,2009,173(1):115-122.
[17]Chu Hung-Ta,Chou Jung-Hua.Effect of cooling load on the safety factor of propellant grains[J].Journal of Propulsion and Power,2013,29:27-33.
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[22]Parthiban S,Ibrahim E M,Smyth Hugh D C.Swellable hydrogel particles for controlled release pulmonary administration using propellant-driven metered dose inhalers[J].Journal of Aerosol Medicine and Pulmonary Drug Delivery,2010,24(1):25-34.
[23]Paul K,AmtoW II.Propellant formulation and projectiles and munitions employing same:US,2007/0251615A1[P].2007.
[24]Yi Jian-hua,Zhao Feng-qi,Hong Wei-liang,et al.Effects of Bi-NTO complex on thermal behaviors,non-isothermal reaction kinetics and burning rates of NG/TEGDN/NC propellant[J].Journal of Hazardous Materials,2009,176(1):257-261.
[25]Kadiresh P N,Sridhar B T N.Experimental study on ballistic behavior of an aluminised AP/HTPB propellant during accelerated aging[J].Journal of Thermal Analysis and Calorimetry,2010,100(1):331-335.
[26]Wei Wen-xian,Jiang Xiao-hong,Lu Lu-de,et al.Study on the catalytic effect of NiO nanoparticles on the thermal decomposition of TEGDN/NC propellant[J].Journal of Hazardous Materials,2009,168(2):838-842.
[27]Li Yan-chun,Kou Chen-xia,Chuan Huang,et al.Effect of MnC2O4nanoparticles on the thermal decomposition of TEGDN/NC propellant[J].Journal of Thermal Analysis and Calorimetry,2012,109(1):171-176.
[28]Huang Zhi-ping,Nie Hai-ying,Zhang Yuan-yuan,et al.Migration kinetics and mechanisms of plasticizers,stabilizers at interfaces of NEPE propellant/HTPB liner/EDPM insulation[J].Journal of Hazardous Materials,2012,229:251-257.
[29]Sun B,Min H,Soo H.Study on combustion characteristics of HTPB/AP propellants containing zirconium[J].Journal of Propulsion and Power,2012,28(1):211-213.
[30]Kim C K,Yoo J C,Min B S,et al.Insensitive propellant composition:US,2012/0227875[P].2012.
[31]Goleniewski J R,Roberts J A.Solid propellant with non-crystalline polyether/inert plasticizer binder:US,5348596[P].1994.
[32]翟进贤,杨荣杰.BAMO-THF复合推进剂催化燃烧特性分析[J].推进技术,2010(2):226-229.ZHAI Jin-xian,YANG Rong-jie.Analysis on properties of catalytic combustion of composite BAMO-THF propellants[J].Journal of Propulsion Technology,2010(2):226-229.
[33]张弛,张向飞,翟滨,等.P(BAMO-r-AMMO)在推进剂中的应用[J].火炸药学报,2013,36(4):61-64.ZHANG Chi,ZHANG Xiang-fei,ZHAI Bin,et al.Application of P(BAMO-r-AMMO)in propellant[J].Chinese Journal of Explosives and Propellants,2013,36(4):61-64.
[34]蔚红建,付小龙,邓重清,等.星型GAP与固体推进剂填料的表界面性能[J].固体火箭技术,2011,34(2):211-213.WEI Hong-jian,FU Xiao-long,DENG Chong-qing,et al.Surface and interfacial properties between S-GAP and other ingredients in solid propellant[J].Journal of Solid Rocket Technology,2011,34(2):211-213.
[35]Yi Jian-hua,Zhao Feng-qi,Xu Si-yu,et al.Effects of pressure and TEGDN content on decomposition reaction mechanism and kinetics of DB gun propellant containing the mixed ester of TEGDN and NG[J].Journal of Hazardous Materials,2008,165(1):853-859.
[36]Zhang Chao-yang.Review of the establishment of nitro group charge method and its applications[J].Journal of Hazardous Materials,2009,161:21-28.
[37]Damse R S,Omprakash B,Tope B G,et al.Study of N-n-butyl-N-(2-nitroxyethyl)nitramine in RDX based gun propellant[J].Journal of Hazardous Materials,2009,167(1):1222-1225.
[38]Li S,Liu Y,Tuo X,et al.Mesoscale dynamic simulation on phase separation between plasticizer and binder in NEPE propellants[J].Polymer,2008,49(11):2775-2780.
[39]Libardi J,Ravagnani S P,Morais A M F,et al.Diffusion of plasticizer in a solid propellant based on hydroxyl-terminated polybutadiene[J].Polimeros,2010,20(4):241-245.
[40]Hildebrandt F J,Hildebrandt S,Simmons R L,et al.Single-base propellant composition using Bu-NENA as energetic plasticizer:US,7862668B1[P].2011.
[41]Chan M L,Turner A D.Insensitive high energy booster propellant:US,6576072[P].2003.
[42]Cerri S,Bohn M A,Menke K,et al.Characterization of ADN/GAP‐based and ADN/Desmophen‐based propellant formulations and comparison with AP analogues[J].Propellants,Explosives,Pyrotechnics,2014,39(2):192-204.
[43]Massa L,Jackson T L,Buckmaster J.Optimization of global kinetics parameters for heterogeneous propellant combustion using agenetic algorithm[J].Combust.Theory Model,2007,11(4):553-568.
[44]Walsh M R,Walsh M E,Hewitt A D.Energetic residues from field disposal of gun propellants[J].Journal of Hazardous Materials,2009,173(1):115-122.
[45]Liu Bo,Wang Qiong-lin,Liu Shao-wu,et al.Study on the performance of the modified single base gun propellant[J].Advanced Materials Research,2012,1583(415):1656-1661.
[46]Rauch R B,Behrens R.Vapor pressures,mass spectra and thermal decomposition processes of bis(2,2‐dintropropyl)acetal(BDNPA)and bis(2,2‐dinitropropyl)formal(BDNPF)[J].Propellants,Explosives,Pyrotechnics,2007,32(2):97-116.
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