静电纺丝法制备的纳米纤维在环境污染治理中的应用研究进展
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摘要
静电纺丝法可实现多种材料一维纳米结构的构筑,对纳米纤维的粗糙结构、直径、比表面积、堆积密度和连通性精准可控,在环境领域具有广阔的应用前景。系统介绍了静电纺丝法制备的纳米纤维在过滤、催化氧化、吸附、固定酶及物理性污染等领域的应用,并指出了目前研究存在的问题和今后研究的方向,旨在为进一步扩宽纳米纤维在环境污染治理领域中的应用。
Electrospinning method can build up one-dimension nano-structure,especially for achieving precise control of nanofibers in the rough nanostructure,fiber diameter,specific surface area,bulk density and connectivity,which has a spacious application foreground in the field of environment.This paper introduced the progress of nanofiber applications in filtration,catalytic oxidation,adsorption,enzyme immobilization and physical pollution.The problems and the prospects of research were also discussed,aiming to expand the nanofiber applications in the field of environmental pollution control.
Electrospinning method can build up one-dimension nano-structure,especially for achieving precise control of nanofibers in the rough nanostructure,fiber diameter,specific surface area,bulk density and connectivity,which has a spacious application foreground in the field of environment.This paper introduced the progress of nanofiber applications in filtration,catalytic oxidation,adsorption,enzyme immobilization and physical pollution.The problems and the prospects of research were also discussed,aiming to expand the nanofiber applications in the field of environmental pollution control.
引文
[1]张宏忠,秦小青,王明花.石墨烯/TiO2复合物的制备及其光催化性能[J].环境工程学报,2016,10(1):169-174.
[2]于亚琴,成杰民.醋酸改性纳米黑碳对Cu2+、Cd2+吸附能力的研究[J].环境污染与防治,2015,37(5):22-26.
[3]周旭健,李晓东,徐帅玺,等.多孔碳材料对二噁英吸附性能的研究评述及展望[J].环境污染与防治,2016,38(1):76-81.
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[5]王文帝,徐化云,刘金华,等.MoO3纳米纤维电极材料的水热合成和电化学表征[J].功能材料,2006,37(3):434-436.
[6]钱海生.碳、硅基功能纳米纤维的模板合成与性能研究[D].合肥:中国科学技术大学,2006.
[7]董宪君,魏取福.原位聚合法制备PANI-TSA/PA6核壳纳米纤维[J].化工新型材料,2012,40(6):42-44.
[8]宣宗伟.含N化合物、聚合物及CdS纳米材料的合成及自组装研究[D].南京:南京理工大学,2012.
[9]姜艳.高温硅基陶瓷分离膜材料的制备与表征[D].合肥:合肥工业大学,2015.
[10]覃小红,王善元.静电纺丝纳米纤维的工艺原理、现状及应用前景[J].高科技纤维与应用,2004,29(2):28-32.
[11]丁彬,斯阳,俞建勇.静电纺纳米纤维材料在环境领域中的应用研究进展[J].中国材料进展,2013,32(8).
[12]李雄,王雪芬.静电纺纳米纤维材料在膜分离领域的应用研究进展[J].中国材料进展,2014,33(8):475-483.
[13]李山山,何素文,胡祖明,等.静电纺丝的研究进展[J].合成纤维工业,2009,32(4):44-47.
[14]曹鼎,付志峰,李从举.静电纺丝技术在过滤中的应用进展[J].化工新型材料,2011,39(8):15-18.
[15]丁彬,余建勇.静电纺丝与纳米纤维[M].北京:中国纺织出版社,2011.
[16]NICOSIA A,GIEPARDA W,FOKSOWICZ FLACZYK J,et al.Air filtration and antimicrobial capabilities of electrospun PLA/PHB,containing ionic liquid[J].Separation&Purification Technology,2015,154(9):154-160.
[17]赵文敏,蒋国军,李方,等.静电纺PVDF/PAN共混纳米纤维膜对含油污水的过滤性能[J].东华大学学报(自然科学版),2015,41(5):565-571.
[18]娄莉华.高效低阻PAN静电纺微纳米滤膜制备与性能研究[D].上海:东华大学,2016.
[19]马利婵,王娇娜,李丽,等.静电纺空气过滤用PET/CTS抗菌复合纳米纤维膜的制备[J].高分子学报,2015(2):221-227.
[20]徐国荣.基于纳米纤维的反渗透复合膜的制备及性能研究[D].北京:北京化工大学,2014.
[21]刘波文.尼龙56纳米蛛网纤维膜的可控制备及其空气过滤应用研究[D].上海:东华大学,2016.
[22]李小虎.熔体静电纺丝制备高效过滤微纳膜及其水过滤性能研究[D].北京:北京化工大学,2015.
[23]汪小亮.双喷静电纺PA6/66纳米蛛网纤维膜的制备及其过滤性能[D].苏州:苏州大学,2015.
[24]CHEN Yuecheng,MAO Xue,SHAN Haoru,et al.Free-standing zirconia nanofibrous membranes with robust flexibility for corrosive liquid filtration[J].RSC Advances,2013,4(6):2756-2763.
[25]CHOI J,YANG B J,BAE G N,et al.Herbal extract incorporated nanofiber fabricated by an electrospinning technique and its application to antimicrobial air filtration[J].ACS Applied Materials&Interfaces,2015,7(45):25313-25320.
[26]KIANI S,MOUSAVI S M,SHAHTAHMASSEBI N,et al.Preparation and characterization of polyphenylsulfone nanofibrous membranes for the potential use in liquid filtration[J].Desalination&Water Treatment,2015,69(6):1-10.
[27]王成,姚理荣,陈宇岳.芳纶纳米纤维毡/聚苯硫醚高温超过滤材料的制备及其性能[J].纺织学报,2013,34(7):1-4.
[28]简绍菊,杨为森,林维晟,等.Ag掺杂ZnO纳米纤维的制备及其光催化性能[J].现代化工,2015(10):84-86.
[29]陈仁忠,胡毅,袁菁红,等.静电纺MnO2/PAN纳米纤维膜的制备及其催化氧化甲醛性能[J].纺织学报,2015,36(5):1-6.
[30]王芳芳,郝露,徐山青,等.CNTs/La3+掺杂TiO2纳米纤维对Cr(Ⅵ)的催化性能研究[J].纺织导报,2015(12):72-75.
[31]NIE Longhui,YU Jiaguo,FU Junwei.Complete decomposition of formaldehyde at room temperature over a platinum-decorated hierarchically porous electrospun titania nanofiber mat[J].ChemCatChem,2014,6(7):1983-1989.
[32]胡明江.CeO2-TiO2复合纳米纤维光催化降解醛酮类污染物的研究[J].环境科学学报,2015,35(1):215-221.
[33]TAI M H,TAN B Y L,JUAY J,et al.A self-assembled superhydrophobic electrospun carbon-silica nanofiber sponge for selective removal and recovery of oils and organic solvents[J].Chemistry,2015,21(14):5395-5402.
[34]曾良滨,何雪涛,谭晶,等.熔体微分静电纺丝聚丙烯纤维的吸油性能研究[J].北京化工大学学报(自然科学版),2015,42(6):66-71.
[35]GUAN Jipeng,LI Jingye,LI Yongjin.Electrospun nanofibers with both surface nanopores and internal interpenetrated nanochannels for oil absorption[J].RSC Advances,2016,6(40):33781-33788.
[36]SHAHRAM FOROUZ F,RAVANDI S A,ALLAFCHIAN A R.Removal of Ag and Cr heavy metals using nanofiber membranes functionalized with aminopropyltriethoxysilane(APTES)[J].Current Nanoscience,2016,12(2):266-274.
[37]张慧敏,阮弦,胡勇有,等.静电纺壳聚糖/聚乙烯醇纳米纤维膜对Cu2+、Ni 2+及Cd2+的吸附特性[J].环境科学学报,2015,35(1):184-193.
[38]LI Xin,LIN Huiming,CHEN Xiang,et al.Fabrication of TiO2/porous carbon nanofibers with superior visible photocatalytic activity[J].New Journal of Chemistry,2015,39(10):7863-7872.
[39]MA Yao,ZHANG Bowu,MA Hongjuan,et al.Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution[J].Science China Materials,2016,59(1):38-50.
[40]LI Changlong,ZHOU Lei,WANG Cuie,et al.Electrospinning of a PMA-co-PAA/FP biopolymer nanofiber:enhanced capability for immobilized horseradish peroxidase and its consequence for p-nitrophenol disposal[J].RSC Advances,2015,5(52):41994-41998.
[41]崔静,张平,魏取福.金属配合纳米纤维固定漆酶及其应用[J].化工新型材料,2015,43(5):258-260.
[42]代云容,袁钰,于彩虹,等.静电纺丝纤维膜固定化漆酶对水中双酚A的降解性能[J].环境科学学报,2015,35(7):2107-2113.
[43]贾巍,覃小红.聚氨酯静电纺纳米纤维膜的吸声性能[J].东华大学学报(自然科学版),2014,40(5):509-514.
[44]WU Changmou,CHOU Minhui.Sound absorption of electrospun polyvinylidene fluoride/graphene membranes[J].European Polymer Journal,2016,82:35-45.
[45]WANG Zhihua,ZHAO Lin,WANG Puhong,et al.Low material density and high microwave-absorption performance of hollow strontium ferrite nanofibers prepared via coaxial electrospinning[J].Journal of Alloys and Compounds,2016,687:541-547.
[46]WANG Tao,WANG Haoda,CHI Xiao,et al.Synthesis and microwave absorption properties of Fe-C nanofibers by electrospinning with disperse Fe nanoparticles parceled by carbon[J].Carbon,2014,74:312-318.
[2]于亚琴,成杰民.醋酸改性纳米黑碳对Cu2+、Cd2+吸附能力的研究[J].环境污染与防治,2015,37(5):22-26.
[3]周旭健,李晓东,徐帅玺,等.多孔碳材料对二噁英吸附性能的研究评述及展望[J].环境污染与防治,2016,38(1):76-81.
[4]ANGAMMANA C J,JAYARAM S H.Fundamentals of electrospinning and processing technologies[J].Particulate Science and Technology,2016,34(1):72-82.
[5]王文帝,徐化云,刘金华,等.MoO3纳米纤维电极材料的水热合成和电化学表征[J].功能材料,2006,37(3):434-436.
[6]钱海生.碳、硅基功能纳米纤维的模板合成与性能研究[D].合肥:中国科学技术大学,2006.
[7]董宪君,魏取福.原位聚合法制备PANI-TSA/PA6核壳纳米纤维[J].化工新型材料,2012,40(6):42-44.
[8]宣宗伟.含N化合物、聚合物及CdS纳米材料的合成及自组装研究[D].南京:南京理工大学,2012.
[9]姜艳.高温硅基陶瓷分离膜材料的制备与表征[D].合肥:合肥工业大学,2015.
[10]覃小红,王善元.静电纺丝纳米纤维的工艺原理、现状及应用前景[J].高科技纤维与应用,2004,29(2):28-32.
[11]丁彬,斯阳,俞建勇.静电纺纳米纤维材料在环境领域中的应用研究进展[J].中国材料进展,2013,32(8).
[12]李雄,王雪芬.静电纺纳米纤维材料在膜分离领域的应用研究进展[J].中国材料进展,2014,33(8):475-483.
[13]李山山,何素文,胡祖明,等.静电纺丝的研究进展[J].合成纤维工业,2009,32(4):44-47.
[14]曹鼎,付志峰,李从举.静电纺丝技术在过滤中的应用进展[J].化工新型材料,2011,39(8):15-18.
[15]丁彬,余建勇.静电纺丝与纳米纤维[M].北京:中国纺织出版社,2011.
[16]NICOSIA A,GIEPARDA W,FOKSOWICZ FLACZYK J,et al.Air filtration and antimicrobial capabilities of electrospun PLA/PHB,containing ionic liquid[J].Separation&Purification Technology,2015,154(9):154-160.
[17]赵文敏,蒋国军,李方,等.静电纺PVDF/PAN共混纳米纤维膜对含油污水的过滤性能[J].东华大学学报(自然科学版),2015,41(5):565-571.
[18]娄莉华.高效低阻PAN静电纺微纳米滤膜制备与性能研究[D].上海:东华大学,2016.
[19]马利婵,王娇娜,李丽,等.静电纺空气过滤用PET/CTS抗菌复合纳米纤维膜的制备[J].高分子学报,2015(2):221-227.
[20]徐国荣.基于纳米纤维的反渗透复合膜的制备及性能研究[D].北京:北京化工大学,2014.
[21]刘波文.尼龙56纳米蛛网纤维膜的可控制备及其空气过滤应用研究[D].上海:东华大学,2016.
[22]李小虎.熔体静电纺丝制备高效过滤微纳膜及其水过滤性能研究[D].北京:北京化工大学,2015.
[23]汪小亮.双喷静电纺PA6/66纳米蛛网纤维膜的制备及其过滤性能[D].苏州:苏州大学,2015.
[24]CHEN Yuecheng,MAO Xue,SHAN Haoru,et al.Free-standing zirconia nanofibrous membranes with robust flexibility for corrosive liquid filtration[J].RSC Advances,2013,4(6):2756-2763.
[25]CHOI J,YANG B J,BAE G N,et al.Herbal extract incorporated nanofiber fabricated by an electrospinning technique and its application to antimicrobial air filtration[J].ACS Applied Materials&Interfaces,2015,7(45):25313-25320.
[26]KIANI S,MOUSAVI S M,SHAHTAHMASSEBI N,et al.Preparation and characterization of polyphenylsulfone nanofibrous membranes for the potential use in liquid filtration[J].Desalination&Water Treatment,2015,69(6):1-10.
[27]王成,姚理荣,陈宇岳.芳纶纳米纤维毡/聚苯硫醚高温超过滤材料的制备及其性能[J].纺织学报,2013,34(7):1-4.
[28]简绍菊,杨为森,林维晟,等.Ag掺杂ZnO纳米纤维的制备及其光催化性能[J].现代化工,2015(10):84-86.
[29]陈仁忠,胡毅,袁菁红,等.静电纺MnO2/PAN纳米纤维膜的制备及其催化氧化甲醛性能[J].纺织学报,2015,36(5):1-6.
[30]王芳芳,郝露,徐山青,等.CNTs/La3+掺杂TiO2纳米纤维对Cr(Ⅵ)的催化性能研究[J].纺织导报,2015(12):72-75.
[31]NIE Longhui,YU Jiaguo,FU Junwei.Complete decomposition of formaldehyde at room temperature over a platinum-decorated hierarchically porous electrospun titania nanofiber mat[J].ChemCatChem,2014,6(7):1983-1989.
[32]胡明江.CeO2-TiO2复合纳米纤维光催化降解醛酮类污染物的研究[J].环境科学学报,2015,35(1):215-221.
[33]TAI M H,TAN B Y L,JUAY J,et al.A self-assembled superhydrophobic electrospun carbon-silica nanofiber sponge for selective removal and recovery of oils and organic solvents[J].Chemistry,2015,21(14):5395-5402.
[34]曾良滨,何雪涛,谭晶,等.熔体微分静电纺丝聚丙烯纤维的吸油性能研究[J].北京化工大学学报(自然科学版),2015,42(6):66-71.
[35]GUAN Jipeng,LI Jingye,LI Yongjin.Electrospun nanofibers with both surface nanopores and internal interpenetrated nanochannels for oil absorption[J].RSC Advances,2016,6(40):33781-33788.
[36]SHAHRAM FOROUZ F,RAVANDI S A,ALLAFCHIAN A R.Removal of Ag and Cr heavy metals using nanofiber membranes functionalized with aminopropyltriethoxysilane(APTES)[J].Current Nanoscience,2016,12(2):266-274.
[37]张慧敏,阮弦,胡勇有,等.静电纺壳聚糖/聚乙烯醇纳米纤维膜对Cu2+、Ni 2+及Cd2+的吸附特性[J].环境科学学报,2015,35(1):184-193.
[38]LI Xin,LIN Huiming,CHEN Xiang,et al.Fabrication of TiO2/porous carbon nanofibers with superior visible photocatalytic activity[J].New Journal of Chemistry,2015,39(10):7863-7872.
[39]MA Yao,ZHANG Bowu,MA Hongjuan,et al.Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution[J].Science China Materials,2016,59(1):38-50.
[40]LI Changlong,ZHOU Lei,WANG Cuie,et al.Electrospinning of a PMA-co-PAA/FP biopolymer nanofiber:enhanced capability for immobilized horseradish peroxidase and its consequence for p-nitrophenol disposal[J].RSC Advances,2015,5(52):41994-41998.
[41]崔静,张平,魏取福.金属配合纳米纤维固定漆酶及其应用[J].化工新型材料,2015,43(5):258-260.
[42]代云容,袁钰,于彩虹,等.静电纺丝纤维膜固定化漆酶对水中双酚A的降解性能[J].环境科学学报,2015,35(7):2107-2113.
[43]贾巍,覃小红.聚氨酯静电纺纳米纤维膜的吸声性能[J].东华大学学报(自然科学版),2014,40(5):509-514.
[44]WU Changmou,CHOU Minhui.Sound absorption of electrospun polyvinylidene fluoride/graphene membranes[J].European Polymer Journal,2016,82:35-45.
[45]WANG Zhihua,ZHAO Lin,WANG Puhong,et al.Low material density and high microwave-absorption performance of hollow strontium ferrite nanofibers prepared via coaxial electrospinning[J].Journal of Alloys and Compounds,2016,687:541-547.
[46]WANG Tao,WANG Haoda,CHI Xiao,et al.Synthesis and microwave absorption properties of Fe-C nanofibers by electrospinning with disperse Fe nanoparticles parceled by carbon[J].Carbon,2014,74:312-318.