尖晶石结构的钴基金属氧化物超级电容器电极材料的研究进展
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摘要
超级电容器作为一种新型储能转化设备,以其充放电时间短、循环寿命长以及功率大等优点,引起了广泛的关注。超级电容器电极材料是影响其性能的重要因素。具有尖晶石结构的钴基金属氧化物以其优异的电化学性能作为超级电容器的电极材料使用获得了极大的成功。概述了各种钴基金属氧化物的最新进展,如钴酸锌、钴酸锰、钴酸镍等,并对其未来的发展进行了展望。
As a novel device for energy storage, the supercapacitor has attracts a wide attention due to its unique advantages, such as the short charge-discharge time, the long cycle life, and the high power. The electrode material of supercapacitor is an important factor to affect its performance. Cobalt based metal oxides with spinel structure have been greatly developed in the field of electrode materials with excellent properties. The latest research progress of electrode materials for supercapacitor are introduced and several electrode materials currently used are discussed, including zinc cobaltate, manganese cobaltate, nickel cobaltate, etc. And its development is prospected.
As a novel device for energy storage, the supercapacitor has attracts a wide attention due to its unique advantages, such as the short charge-discharge time, the long cycle life, and the high power. The electrode material of supercapacitor is an important factor to affect its performance. Cobalt based metal oxides with spinel structure have been greatly developed in the field of electrode materials with excellent properties. The latest research progress of electrode materials for supercapacitor are introduced and several electrode materials currently used are discussed, including zinc cobaltate, manganese cobaltate, nickel cobaltate, etc. And its development is prospected.
引文
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[30]LIU B,TAN D,WANG X,et al.Flexible,planar-integrated,all-solid-state fiber supercapacitors with an enhanced distributed-capacitance effect[J].Small,2013,9(11):1998-2004.
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[32]BAO F,WANG X,ZHAO X,et al.Controlled growth of mesoporous Zn Co2O4 nanosheet arrays on Ni foam as high-rate electrodes for supercapacitors[J].RSC Adv,2014(4):2393-2397.
[33]ZOU R,XU K,WANG T,et al.Chain-like Ni Co2O4 nanowires with different exposed reactive planes for high-performance supercapacitors[J].J Mater Chem A,2013,30(1):8560-8566.
[34]WANG H,GAO Q,JIANG L.Facile approach to prepare nickel cobaltite nanowire materials for supercapacitors[J].Small,2011,17(7):2454-2459.
[35]ZHANG G,LOU X W.Controlled growth of Ni Co2O4 nanorods and ultrathin nanosheets on carbon nanofibers for high-performance supercapacitors[J].Sci Rep,2013(3):1470.
[36]WANG Q,WANG X,LIU B,et al.Ni Co2O4 nanowire arrays supported on Ni foam for high-performance flexible all-solid-state supercapacitors[J].J Mater Chem A,2013,7(1):2468-2473.
[37]WEI T Y,CHEN C H,CHIEN H C,et al.A cost-effective supercapacitor material of ultrahigh specific capacitances:spinel nickel cobaltite aerogels from an epoxide-driven sol-gel process[J].Adv Mater,2010,22(3):347-351.
[38]PU J,WANG J,JIN X,et al.Porous hexagonal Ni Co2O4 nanoplates as electrode materials for supercapacitors[J].Electrochim Acta,2013,106:226-234.
[39]LU Q,CHEN Y,LI W,et al.Ordered mesoporous nickel cobaltite spinel with ultra-high supercapacitance[J].J Mater Chem A,2013,6(1):2331-2336.
[40]LIU X Y,ZHANG Y Q,XIA X H,et al.Self-assembled porous Ni Co2O4hetero-structure array for electrochemical capacitor[J].J Power Sources,2013,239:157-163.
[41]WANG Q F,WANG X F,XU J,et al.Flexible coaxial-type fiber supercapacitor based on Ni Co2O4 nanosheets electrodes[J].Nano Energy,2014,8:44-51.
[42]AN C,WANG Y,HUANG Y,et al.Novel three-dimensional Ni Co2O4hierarchitectures:solvothermal synthesis and electrochemical properties[J].Crystengcomm,2014,16(3):385-392.
[43]LAVELA P,TIRADO J L.Co Fe2O4 and Ni Fe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries[J].Power Sources,2007,172(1):379-387.
[44]LU C,KONG L B.The synthesis and electrochemical study of MCo2O4(M=Ni,Mn)[D].兰州:兰州理工大学,2013.
[45]GU S,LOU Z,MA X,et al.Cu Co2O4 nanowires grown on a Ni wire for high performance,flexible fiber supercapacitors[J].Chem Electro Chem,2015,7(2):1042-1047.
[2]CHU S,MAJUMDAR A.Opportunities and challenges for a sustainable energy future[J].Nature,2012,488(7411):294-303.
[3]WANG G,ZHANG L,ZHANG J.A review of electrode materials for electrochemical supercapacitors[J].Chem Soc Rev,2012,41(2):797-828.
[4]LIU C,LI F,MA L P,et al.Advanced materials for energy storage[J].Adv Mater,2010,22(8):28-62.
[5]YUAN C,WU H B,XIE Y,et al.Mixed transition-metal oxides:design,synthesis,and energy-related applications[J].Angew Chem Int Ed,2014,53(6):1488-1504.
[6]SIMON P,GOGOTSI Y.Materials for electrochemical capacitors[J].Nat Mater,2008,7(11):845-854.
[7]MILLER J R,SIMON P.Electrochemical capacitors for energy management[J].Science,2008,321(5889):651-652.
[8]TANG Z,TANG C,GONG H.A high energy density asymmetric supercapacitor from nano-architectured Ni(OH)2/carbon nanotube electrodes[J].Adv Funct Mater,2012,22(6):1272-1278.
[9]GUO Y,HU J,WAN L.Nanostructured materials for electrochemical energy conversion and storage devices[J].Adv Mater,2008,20(15):2878-2887.
[10]WANG K,WU H P,MENG Y N,et al.Conducting polymer nanowire arrays for high performance supercapacitors[J].Small,2014,10(1):14-31.
[11]JIANG J,LI Y,LIU J,et al.Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage[J].Adv Mater,2012,24(38):5166-5180.
[12]刘俊,雷跃荣,陈希明,等.尖晶石结构材料的最新研究进展[J].材料导报,2008,22(11):26-29.
[13]CESTEROS Y,SALAGRE P,MEDINA F,et al.Preparation and characterization of several high-area Ni Al2O4 spinels[J].Chem Mater,2000,12(2):331-335.
[14]ZHOU G,ZHU J,CHEN Y.Simple method for the preparation of highly porous Zn Co2O4 nanotubes withenhanced electrochemical property for supercapacitor[J].Electrochim Acta,2014,123:450-455.
[15]KARTHIKEYAN K,KALPANA D,RENGANATHAN N G.Synthesis and characterizationof Zn Co2O4 nanomaterial for symmetric supercapacitor applications[J].Ionics,2009,15(1):107-110.
[16]BAO F X,LIU X Y.Synthesis of cobalt-based metal oxides and the investigation of their pseudocapacitive performance[D].长春:吉林大学,2014.
[17]LEI Y,LI J,WANG Y,et al.Rapid microwave-assisted green synthesis of3D hierarchical flower-shaped Ni Co2O4 microsphere for high-performance supercapacitor[J].ACS Appl Mater Int,2014,6(3):1773-1780.
[18]ZHU Y,JI X,WU Z,et al.Spinel Ni Co2O4 for use as a high-performance supercapacitor electrode material:understanding of its electrochemical properties[J].J Power Sources,2014,267:888-900.
[19]ZHOU Q,XING J,GAO Y,et al.Ordered assembly of Ni Co2O4 multiple hierarchical structures for high-performance pseudocapacitors[J].ACS Appl Mater Int,2014,14(6):11394-11402.
[20]PENDASHTEH A,RAHMANIFAR M S,KANER R B,et al.Facile synthesis of nanostructured Cu Co2O4 as a novel electrode material for high-rate supercapacitors[J].Chem Commun,2014,50(16):1972-1975.
[21]LI L,ZHANG Y Q,LIU X Y,et al.One-dimension Mn Co2O4 nanowire arrays for electrochemicalenergy storage[J].Electrochim Acta,2014,116:467-474.
[22]KONG L B,LU C,LIU M C,et al.The specificcapacitance of sol-gel synthesised spinel Mn Co2O4 in an alkaline electrolyte[J].Electrochim Acta,2014,115:22-27.
[23]GOMEZ J,KALU E E.High-performance binder-free Co-Mn composite oxidesupercapacitor electrode[J].J Power Sources,2013,230:218-224.
[24]KRISHNAN S G,REDDY M V,HARILAL M,et al.Characterization of Mg Co2O4 as an electrode for high performance supercapacitors[J].Electrochim Acta,2015,161:312-321.
[25]SONG X,RU Q,ZHANG B,et al.Flake-by-flake Zn Co2O4 as a high capacity anode material for lithium-ion battery[J].J Alloys Comp,2014,585:518-522.
[26]LIU H,WANG J.One-pot synthesis of Zn Co2O4 nanorod anodes for high power lithium ions batteries[J].Electrochim Acta,2013,92:371-375.
[27]LIU B,ZHANG J,WANG X,et al.Hierarchical three-dimensional Zn Co2O4 nanowire arrays/carbon cloth anodes for a novel class of high-performance flexible lithium-ion batteries[J].Nano Lett,2012,12(6):3005-3011.
[28]DAVIS M,GUEMECI C,BLACK B,et al.Tailoring cobalt doped zinc oxide nanocrystals with high capacitance activity:factors affecting structure and surface morphology[J].Rsc Adv,2012(2):2061-2066.
[29]KARTHIKEYAN K,KALPANA D,RENGANATHAN N G.Synthesis and characterization of Zn Co2O4 nanomaterial for symmetric supercapacitor applications[J].Ionics,2009,15(1):107-110.
[30]LIU B,TAN D,WANG X,et al.Flexible,planar-integrated,all-solid-state fiber supercapacitors with an enhanced distributed-capacitance effect[J].Small,2013,9(11):1998-2004.
[31]LIU B,LIU B,WANG Q,et al.New energy storage option:toward Zn Co2O4 nanorods/nickel foam architectures for high-performance supercapacitors[J].ACS Appl Mater Int,2013,20(5):10011-10017.
[32]BAO F,WANG X,ZHAO X,et al.Controlled growth of mesoporous Zn Co2O4 nanosheet arrays on Ni foam as high-rate electrodes for supercapacitors[J].RSC Adv,2014(4):2393-2397.
[33]ZOU R,XU K,WANG T,et al.Chain-like Ni Co2O4 nanowires with different exposed reactive planes for high-performance supercapacitors[J].J Mater Chem A,2013,30(1):8560-8566.
[34]WANG H,GAO Q,JIANG L.Facile approach to prepare nickel cobaltite nanowire materials for supercapacitors[J].Small,2011,17(7):2454-2459.
[35]ZHANG G,LOU X W.Controlled growth of Ni Co2O4 nanorods and ultrathin nanosheets on carbon nanofibers for high-performance supercapacitors[J].Sci Rep,2013(3):1470.
[36]WANG Q,WANG X,LIU B,et al.Ni Co2O4 nanowire arrays supported on Ni foam for high-performance flexible all-solid-state supercapacitors[J].J Mater Chem A,2013,7(1):2468-2473.
[37]WEI T Y,CHEN C H,CHIEN H C,et al.A cost-effective supercapacitor material of ultrahigh specific capacitances:spinel nickel cobaltite aerogels from an epoxide-driven sol-gel process[J].Adv Mater,2010,22(3):347-351.
[38]PU J,WANG J,JIN X,et al.Porous hexagonal Ni Co2O4 nanoplates as electrode materials for supercapacitors[J].Electrochim Acta,2013,106:226-234.
[39]LU Q,CHEN Y,LI W,et al.Ordered mesoporous nickel cobaltite spinel with ultra-high supercapacitance[J].J Mater Chem A,2013,6(1):2331-2336.
[40]LIU X Y,ZHANG Y Q,XIA X H,et al.Self-assembled porous Ni Co2O4hetero-structure array for electrochemical capacitor[J].J Power Sources,2013,239:157-163.
[41]WANG Q F,WANG X F,XU J,et al.Flexible coaxial-type fiber supercapacitor based on Ni Co2O4 nanosheets electrodes[J].Nano Energy,2014,8:44-51.
[42]AN C,WANG Y,HUANG Y,et al.Novel three-dimensional Ni Co2O4hierarchitectures:solvothermal synthesis and electrochemical properties[J].Crystengcomm,2014,16(3):385-392.
[43]LAVELA P,TIRADO J L.Co Fe2O4 and Ni Fe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries[J].Power Sources,2007,172(1):379-387.
[44]LU C,KONG L B.The synthesis and electrochemical study of MCo2O4(M=Ni,Mn)[D].兰州:兰州理工大学,2013.
[45]GU S,LOU Z,MA X,et al.Cu Co2O4 nanowires grown on a Ni wire for high performance,flexible fiber supercapacitors[J].Chem Electro Chem,2015,7(2):1042-1047.