典型稀土精矿及废渣中清洁提钍工艺研究进展
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  • 英文篇名:Research Progress in Clean Extraction Technology of Thorium from Typical Rare Earth Concentrate and Waste Slag
  • 作者:侯晓志 ; 杨占峰
  • 英文作者:Hou Xiaozhi;Yang Zhanfeng;Institute of Mining Engineering,Inner Mongolia University of Science and Technology;Baotou Rare Earth Research Institute,Rare Earth Resources Research and the Comprehensive Utilization State Key Laboratory of Bayan Obo;
  • 关键词: ; 稀土精矿 ; 废渣 ; 提钍工艺
  • 英文关键词:thorium;;rare earth concentrate;;waste residue;;thorium extraction technology
  • 中文刊名:XTXB
  • 英文刊名:Journal of the Chinese Society of Rare Earths
  • 机构:内蒙古科技大学矿业研究院;包头稀土研究院白云鄂博稀土资源研究与综合利用国家重点实验室;
  • 出版日期:2018-11-26 16:59
  • 出版单位:中国稀土学报
  • 年:2019
  • 期:v.37;No.178
  • 语种:中文;
  • 页:XTXB201902003
  • 页数:14
  • CN:02
  • ISSN:11-2365/TG
  • 分类号:29-42
摘要
随着中国不可再生能源的日益紧缺,开发核电新能源对中国可持续发展具有重要意义,钍作为未来核电发展的重要原料,必将成为今后能源发展的新方向,建立钍反应堆可以很大程度上缓解中国对不可再生能源的依赖。中国钍资源储量巨大,在现行的稀土选冶工艺中,钍主要赋存于稀土精矿中或最终进入冶炼废渣,处理不当,不仅对环境造成了放射性污染,同时也造成了钍资源的严重浪费。本文主要对中国近年来典型稀土精矿及废渣中清洁提钍工艺研究进展以及高纯钍的制备进行了综述,并提出了相关建议与意见。
        With the decreasing of nonrenewable resources in our country, developing new energy sources of nuclear power is of great significance to the sustainable development of our country. As an important raw material for the future development of nuclear power, thorium will become the new direction of energy development in the future, and the establishment of thorium reactor can greatly ease our country′s dependence on non-renewable energy. China has huge reserves of thorium, in the current rare earth processing and smelting process, thorium mainly occurs in the rare earth concentrate or eventually enters the smelting waste residue, the improper treatment not only causes radioactive pollution, but also causes serious waste of thorium resource. This article mainly summarized the research progresses on the clean extraction of thorium from typical rare earth concentrates and waste residues and the preparation of high purity thorium was reviewed, and some suggestions and measures were puts forward.
引文
[1] 张书成, 刘平, 仉宝聚. 钍资源及其利用 [J]. 世界核地质科学, 2005, 22(2): 98.Zhang S C, Liu P, Zhang B J. Thorium resources and their availability [J]. World Nuclear Geoscience, 2005, 22(2): 98.
    [2] 程建忠, 侯运炳. 白云鄂博矿钍资源及综合利用 [A]. 2007年中国稀土资源综合利用与环境保护研讨会论文集 [C]. 海口: 中国稀土学会地采选专业委员会, 2007. 22.Cheng J Z, Hou Y B. Thorium resources and comprehensive utilization of Baiyunebo mine [A]. Proceedings of 2007 Symposium on Comprehensive Utilization of Rare Earth Resources and Environmental Protection in China [C]. Haikou: China Rare Earth Society of Geology, Mining and Mineral Processing Professional Committee, 2007. 22.
    [3] Timothy A, Steven K, Allen C. Thorium fuel cycle research and literature: Trends and insights from eight decades of diverse projects and evolving priorities [J]. Ann. Nucl. Energy, 2017, 110: 726.
    [4] 林双幸, 张铁岭. 加快钍资源开发促进我国核能可持续发展 [J]. 中国核工业, 2016, (1): 32.Lin S X, Zhang T L. Accelerating the development of thorium resources to promote the sustainable development of nuclear energy in China[J]. China Nuclear Industry, 2016, (1): 32.
    [5] 苏文清, 贺海钧, 宋洪芳, 李振宏. 包头白云鄂博矿钍资源的回收及用于核电燃料的研究现状 [J]. 稀有金属, 2005, 29(6): 914.Su W Q, He H J, Song H F, Li Z H. Research status of recovery of thorium resource of Baotou Baiyun Obo ore and application of thorium in nuclear power fuels [J]. Chinese Journal of Rare Metals, 2005, 29(6): 914.
    [6] 罗明标. 钍的资源化学 [M]. 北京: 中国科学技术出版社, 2013.Luo M B. The Resource Chemistry of Thorium [M]. Beijing: Science and Technology of China Press, 2013.
    [7] Yanis Miezitis. Australia′s Identified Mineral Resources 2012 [DB/OL]. http: //www.ga.gov.ou/data-pubs/data-and-publications-search/publications/aimr/thorium.
    [8] 侯晓志, 杨占峰, 王振江, 王文才. 白云鄂博矿萤石型铁矿石中钍的赋存状态及分布规律研究 [J]. 中国稀土学报, 2018, 36(3): 365.Hou X Z, Yang Z F, Wang Z J, Wang W C. Occurrence and distribution of thorium in fluorite-type iron ore in Bayan Obo mine [J]. Journal of the Chinese Society of Rare Earths, 2018, 36(3): 365.
    [9] 黄小卫, 李红卫, 王彩凤, 王国珍, 薛向欣, 张国成. 我国稀土工业发展现状及进展 [J]. 稀有金属, 2007, 31(3): 279.Huang X W, Li H W, Wang C F, Wang G Z, Xue X X, Zhang G C. Development status and research progress in rare earth Industry in China [J]. Chinese Journal of Rare Metals, 2007, 31(3): 279.
    [10] Zhu Z W, PranoloY, Cheng C Y. Separation of uranium and thorium from rare earths for rare earth production——A review[J]. Miner Eng., 2015, 77: 185.
    [11] 郑强, 边雪, 吴文远. 白云鄂博稀土尾矿的工艺矿物学研究 [J]. 东北大学学报(自然科学版), 2017, 38(8): 1107.Zheng Q, Bian X, Wu W Y. Study on technological mineralogy of rare earth tailings from Bayan Obo [J]. Journal of Northeastern University (Natural Science), 2017,38(8): 1107.
    [12] 刘建亮, 罗明标, 平爱东, 蒋小辉, 袁自遵. 稀土精矿中钍的提取工艺研究进展 [J]. 稀有金属, 2012, 36(4): 651.Liu J L, Luo M B, Ping A D, Jiang X H, Yuan Z Z. Progress in extraction technology of thorium from rare earth concentrate [J]. Chinese Journal of Rare Metals, 2012, 36(4): 651.
    [13] 马莹, 张丽萍, 许延辉, 王秀艳, 乔军, 白彦, 常叔, 张军. 稀土精矿浓硫酸低温焙烧分解工艺 [P]. 中国专利: 02144405.6, 2003.Ma Y, Zhang L P, Xu Y H, Wang X Y, Qiao J, Bai Y, Chang S, Zhang J. Low-temperature roasting and decomposing process of rare earth heading concentrated sulfuric acid [P]. China Patent: CN02144405, 2003.
    [14] 李国民, 胡克强, 刘金山, 徐庆新, 王文惠, 郭玲弟, 胡天润, 陈鹏, 曾天元, 王国珍, 于俊霞, 肖荣辉. 一种混合型稀土精矿分解方法 [P]. 中国专利: ZL200410006443.8, 2005. Li G M, Hu K Q, Liu J S, Xu Q X, Wang W H, Guo L D, Hu T R, Chen B, Zeng T Y, Wang G Z, Yu J X, Xiao R H. Mixed rare earth concentrate decomposition method [P]. China Patent: ZL200410006443.8, 2005.
    [15] 黄小卫, 张国成, 龙志奇, 朱兆武, 李红卫, 彭新林, 李建宁, 崔大立, 赵娜. 从稀土矿中综合回收稀土和钍工艺方法 [P]. 中国专利: ZL200510085230.3, 2006.Huang X W, Zhang G C, Long Z Q, Zhu Z W, Li H W, Peng X L, Li J N, Cui D L, Zhao N. Process for comprehensive recovery of rare earth and thorium from rare earth ore [P]. China Patent: ZL200510085230.3, 2006.
    [16] 许延辉, 李良才, 孟志军, 刘海娇, 崔建国, 张旭霞, 王英杰, 胡卫红. 一种混合稀土精矿液碱低温焙烧分解工艺 [P]. 中国专利: CN201010145796.1, 2010.Xu Y H , Li L C, Meng Z J, Liu H J, Cui J G, Zhang X X, Wang Y J, Hu W H. A kind of mixed rare earth concentrate liquid caustic soda roasting decomposition process [P]. China Patent: CN201010145796.1, 2010.
    [17] 许延辉, 孟志军, 周建鹏, 赵文怡, 马升峰, 王英杰, 张旭霞, 田皓, 刘铃声, 胡卫红. 一种液碱焙烧分解稀土精矿超声波强化酸浸出稀土的方法 [P]. 中国专利: 201410173709.1, 2014.Xu Y H, Meng Z J, Zhou J P, Zhao W Y, Ma S F, Wang Y J, Zhang X X, Tian H, Liu L S, Hu W H. A method of decomposition of rare earth concentrate by liquid alkali roasting and ultrasonic enhanced acid leaching of rare earth [P]. China Patent: 201410173709.1, 2014.
    [18] 赵君梅, 潘峰, 霍芳, 刘会洲. 一种氟碳铈矿和独居石混合稀土精矿的清洁冶炼工艺 [P]. 中国专利: CN201410073432.5, 2015.Zhao J M, Pan F, Huo F, Liu H Z. A clean smelting process of bastnaesite and monazite mixed rare earth concentrate [P]. China Patent: CN201410073432.5, 2015.
    [19] Zhao J M, Pan F, Liu H Z. An environmental friendly Na2CO3-roasting decomposition strategy for the mixed rare earth concentrate [J]. Sep. Purif. Technol., 2016, 168: 161.
    [20] 崔建国, 王哲, 侯睿恩, 张丽, 郝肖丽, 高婷. 酸碱联合分解混合型稀土精矿的方法 [P]. 中国专利: 201710152283.5, 2017.Cui J G, Wang Z, Hou R E, Zhang L, Hao X L, Gao T. A method of acid-basecombined decomposition of mixed rare earth concentrate [P]. China Patent: 201710152283.5, 2017.
    [21] Lu Y C, Zhang Z F , Li Y L, Liao W P. Extraction and recovery of cerium(IV) and thorium(IV) from sulphate medium by an α-aminophosphonate extractant [J]. J. Rare Earths, 2017, 35(1): 34.
    [22] Wei H Q, Li Y L, Zhang Z F, Xue T Y, Kuang S T, Liao W P. Selective extraction and separation of Ce(IV) and Th(IV) from RE(III) in sulfate medium using Di(2-ethylhexyl)-N-heptylaminomethyl phosphonate [J]. Solvent Extr. Ion Exc., 2017, 35(2): 117.
    [23] 廖伍平, 卢有彩, 张志峰, 李艳玲, 吴国龙. 一种分离四价铈、 钍和稀土的方法 [P]. 中国专利: ZL201410764931.9, 2016.Liao W P, Lu Y C, Zhang Z F, Li Y L, Wu G L. A method for separation of tetravalent cerium, thorium and rare earth [P]. China Patent: ZL201410764931.9, 2016.
    [24] 廖伍平, 张志峰, 李艳玲, 吴国龙, 卢有彩. 分离铈-氟和钍的方法 [P]. 中国专利: ZL201410764960.5, 2016.Liao W P, Zhang Z F, Li Y L, Wu G L, Lu Y C. Separation of cerium-fluoride and thorium [P]. China Patent: ZL201410764960.5, 2016.
    [25] 廖伍平, 邝圣庭, 薛天宇, 张志峰, 李艳玲, 吴国龙. 中性膦萃取剂用于萃取分离铈(IV)或钍(IV)的用途和方法 [P]. 中国专利: ZL 201610227923.X, 2017. Liao W P, Kuang S T, Xue T Y, Zhang Z F, Li Y L, Wu G L. Extraction and separation of cerium(IV) or thorium(IV) by neutral phosphine extractant and its application [P]. China Patent: ZL 201610227923.X, 2017.
    [26] 张廷安, 豆志河, 吕国志, 牛丽萍, 刘燕, 赫冀成. 一种钙化转型-浸出分解氟碳铈矿的方法 [P]. 中国专利: ZL201310125757.9, 2013.Zhang T A, Dou Z H, Lü G Z, Niu L P, Liu Y, He J C. A method of calcification transformation-leaching for decomposition of bastnaesite [P]. China Patent: ZL201310125757.9, 2013.
    [27] 李德谦, 陆军, 魏正贵, 王忠怀, 孟淑兰, 马根祥. 一种从氟碳铈矿浸出液中萃取分离铈、 钍的工艺 [P]. 中国专利: ZL98122348.6, 2000.Li D Q, Lu J, Wei Z G, Wang Z H, Meng S L, Ma G X. Process for extracting and separating cerium and thorium from hamartite leachate [P]. China Patent: ZL98122348.6, 2000.
    [28] 刘营, 廖春生, 张玻, 贾江涛, 王嵩龄, 严纯华. 硫酸法处理氟碳铈矿和分离提纯铈的方法 [P]. 中国专利: 200410031179.3, 2005.Liu Y, Liao C S, Zhang B, Jia J T, Wang S L, Yan C H. Sulfuric acid process for treating bastnaesite and separating and purifying cerium [P]. China Patent: 200410031179.3, 2005.
    [29] 四川省冕宁方兴稀土有限公司. 四川氟碳铈镧矿湿法冶炼稀土生产工艺和产污环节 [J]. 四川稀土, 2007, (3): 15.Sichuan Mianning Fangxing Rare Earth Co.,Ltd. Hydrometallurgy rare earth productive technology and link producing pollution for Sichun bastnasite [J]. Sichuan Rare Earth, 2007, (3):15.
    [30] 黄小卫, 朱兆武, 刘营, 龙志奇, 彭新林, 张顺利, 韩业斌, 罗兴华. 从硫酸稀土溶液中萃取分离四价铈、 钍、 氟及少铈三价稀土的工艺方法 [P]. 中国专利: 200710098733.3, 2008.Huang X W, Zhu Z W, Liu Y, Long Z Q, Peng X L, Zhang S L, Han Y B, Luo X H. Extraction and separation of tetravalence cerium, thorium, fluorine and less cerium trivalent rare earths from sulfate rare earth solution [P]. China Patent: 200710098733.3, 2008.
    [31] Wang L S, Huang X W, Yu Y, Zhao L S, Wang C M, Feng Z Y, Cui D L, Long Z Q. Towards cleaner production of rare earth elements from bastnaesite in China [J]. J. Clean Prod., 2017, 165: 231.
    [32] Huang Y K, Zhang T A, Dou Z H, Liu J, Tang F F. Study on leaching rare earths from bastnaesite treated by calcification transition [J]. J. Rare Earths, 2014, 32(11): 1043.
    [33] 覃波, 王国珍, 韩连敬, 颜豪威, 邱爽, 唐建文, 陈云, 周文龙, 刘国, 邱雪明. 氟碳铈精矿的处理方法 [P].中国专利: 201510434228.6, 2015.Qin B, Wang G Z, Han L J, Yan H W, Qiu S, Tang J W, Chen Y, Zhou W L, Liu G, Qiu X M. Treatment of bastnaesite concentrate [P]. China Patent: 201510434228.6, 2015.
    [34] 魏志雄, 田寿同, 邵朱强. 新型LH-01萃取剂在四川氟碳铈矿萃取分离中的应用研究 [J]. 中国稀土学报, 2015, 33(6): 705.Wei Z X, Tian S T, Shao Z Q. Solvent extraction of Sichuan bastnasite with a novel LH-01 extractant [J]. Journal of the Chinese Society of Rare Earths, 2015, 33(6): 705.
    [35] 李良才. 稀土提取及分离 [M]. 赤峰: 内蒙古科学技术出版社, 2011.Li L C. Extraction and Separation of Rare earth [M]. Chifeng: Inner Mongolia Science and Technology Press, 2011.
    [36] 黄小卫, 李红卫, 龙志奇, 刘营, 赵娜, 张国成. 一种富铁独居石稀土矿的冶炼方法 [P]. 中国专利: CN200710146235.1, 2007.Huang X W, Li H W, Long Z Q, Liu Y, Zhao N, Zhang G C. A smelting method of iron-rich monazite rare earth mine [P]. China Patent: CN200710146235.1, 2007.
    [37] 肖勇, 陈月华. 独居石与独居石渣利用研究进展 [J]. 稀土, 2016, 37(4): 129.Xiao Y, Chen Y H. Research progress on the utilization of monazite and monazite slag [J]. Chinese Rare Earths, 2016, 37(4): 129.
    [38] Amer T E, Abdella W M, Abdel Wahab G M, El-Sheikh E M. A suggested alternative procedure for processing of monazite mineral concentrate [J]. Int. J. Miner Process, 2013, 125: 106.
    [39] Sadri F, Rashchi F, Amini A. Hydrometallurgical digestion and leaching of Iranian monazite concentrate containing rare earth elements Th, Ce, La and Nd [J]. Int. J. Miner Process, 2017, 159: 7.
    [40] Lapidus G T, Doyle F M. Selective thorium and uranium extraction from monazite: I. Single-stage oxalate leaching [J]. Hydrometallurgy, 2015, 154: 102.
    [41] 吴文远, 陈旭东, 陈杰, 孙树臣, 涂赣峰. CaO-NaCl焙烧分解独居石的研究 [J]. 稀土, 2004, 25(2): 16.Wu W Y, Chen X D, Chen J, Sun S C, Tu G F. Study of roasting decomposition of monazite in CaO-NaCl [J]. Chinese Rare Earths, 2004, 25(2): 16.
    [42] 孙树臣, 吴志颖, 边雪, 高波, 吴文远, 涂赣峰. NaCl-CaCl2对氧化钙分解独居石的影响 [J]. 稀土, 2007, 28(5): 6.Sun S C, Wu Z Y, Bian X, Gao B, Wu W Y, Tu G F. Influence of NaCl-CaCl2 on decomposing monazite with CaO [J]. Chinese Rare Earths, 2007, 28(5): 6.
    [43] 李解, 李成元, 李保卫, 王少炳, 韩继铖, 王介良. 微波加热低品位稀土精矿酸浸实验研究 [J]. 稀有金属, 2014, 38(5): 839.Li J, Li C Y, Li B W, Wang S B, Han J C, Wang J L. Acid leaching of low grade rare earth concentrate by microwave heating [J]. Chinese Journal of Rare Metals, 2014, 38(5): 839.
    [44] 李永绣. 离子吸附型稀土资源与绿色提取 [M]. 北京: 化学工业出版社, 2014.Li Y X. Ion Adsorption Type Rare Earth Resources and Green Extraction [M]. Beijing: Chemical Industry Press, 2014.
    [45] 张选旭, 张洁. 一种稀有金属冶炼伴生放射性元素的去除方法 [J]. 中国钨业, 2015, 30(3): 28.Zhang X X, Zhang J. Removing radioactive elements associated with rare metals in the smelting process [J]. China Tungsten Industry, 2015, 30(3): 28.
    [46] 刘志强, 邱显扬, 朱薇, 郭秋松. 一种从南方离子型稀土浸出液中萃取铀和钍的方法 [P]. 中国专利: ZL201210509685.3, 2013.Liu Z Q, Qiu X Y, Zhu W, Guo Q S. A method for extracting uranium and thorium from southern ionic rare-earth leachate [P]. China Patent: ZL201210509685.3, 2013.
    [47] 崔建国, 马莹, 张春新, 琚建勇, 于晓丽, 张赟馨, 曹鸿璋. 一种对稀土酸法工艺废渣中稀土、 钍和铁的回收方法 [P]. 中国专利: CN201310074514.7, 2013.Cui J G, Ma Y, Zhang C X, Ju J Y, Yu X L, Zhang Y X, Cao H Z. A method for recovering rare earth, thorium and iron from waste residue of rare earth acid process [P]. China Patent: CN201310074514.7, 2013.
    [48] 许文林, 王雅琼, 魏晓延, 朱金玉, 魏巍, 丁培兴, 徐珊, 周玲. 一种从优溶渣中分离富集铀、 钍混合物和稀土的方法 [P]. 中国专利: ZL200710019939.2, 2007.Xu W L, Wang Y Q, Wei X T, Zhu J Y, Wei W, Ding P X, Xu S, Zhou L. A method for separating enriched uranium, thorium mixture and rare earth from preferred slag [P]. China Patent: ZL200710019939.2, 2007.
    [49] 黄辉, 王峰. 一种从优溶渣中分离提取铀和钍的方法 [P]. 中国专利: CN201110138142.0, 2011. Huang H, Wang F. The method of separating and extracting uranium and thorium from preferred molten slag [P]. China Patent: CN201110138142.0, 2011.
    [50] 王琦, 任萍, 陈月华, 崔小震, 许鸽鸣. 独居石渣中铀、 钍、 稀土的分离回收方法 [P]. 中国专利: ZL201210489697.4, 2013. Wang Q, Ren P, Chen Y H, Cui X Z, Xu G M. The separation and recovery method of uranium, thorium and rare earth from monazite slag [P]. China Patent: ZL201210489697.4, 2013.
    [51] 花榕, 曹新波, 刘云海, 刘峙嵘, 张志宾, 汪大伟, 朱建夫, 陈军, 吴旬. 一种从优溶渣中提取高纯铀、 钍和混合稀土的方法 [P]. 中国专利: CN201510148009.1, 2015.Hua R, Cao X B, Liu Y H, Liu Z R, Zhang Z B, Wang D W, Zhu J F, Chen J, Wu X. A method for extracting high purity uranium, thorium and mixed rare earth from molten slag [P]. China Patent: CN201510148009.1, 2015.
    [52] 罗宏, 王志坚, 翁国庆, 兰石琨. 从独居石冶炼酸不溶渣中回收钍、 铀和稀土 [P].中国专利: CN201310285220.9, 2015.Luo H, Wang Z J, Weng G Q, Lan S K. Recovery of uranium, thorium and rare earth from acid insoluble slag of monazite [P]. China Patent: CN201310285220.9, 2015.
    [53] 崔小震, 陈月华, 任萍, 朱焱, 许鸽鸣. 独居石酸溶渣资源综合回收绿色循环工艺 [J]. 稀土, 2015, 36(3): 61.Cui X Z, Chen Y H, Ren P, Zhu Y, Xu G M. Recycling of residual slag from monazite processing [J]. Chinese Rare Earths, 2015, 36(3): 61.
    [54] 崔小震, 陈月华, 郭卫权, 任萍, 许鸽鸣, 朱焱, 曾志平. 一种稀土矿分解余渣中铀、 钍、 稀土的分离回收方法 [P]. 中国专利: ZL201410716752.8, 2015.Cui X Z, Chen Y H, Guo W Q, Ren P, Xu G M, Zhu Y, Zeng Z P. Separation and recovery of uranium, thorium and rare earth from residual residue of rare earth ore [P]. China Patent: ZL201410716752.8, 2015.
    [55] 俞正明, 李效平, 王凯, 严炳深, 陈伯华, 李金叶, 徐学道. 一种萃取分离钍与稀土工艺 [P]. 中国专利: CN201510450060.8, 2017.Yu Z M, Li X P, Wang K, Yan B S, Chen B H, Li J Y, Xu X D. A process of extraction separation of thorium and rare earth [P]. China Patent: CN201510450060.8, 2017.
    [56] Wang Y L, Huang C, Li F J, Dong Y M, Sun X Q. Process for the separation of thorium and rare earth elements from radioactive waste residues using Cyanex? 572 as a new extractant [J]. Hydrometallurgy, 2017, 169: 158.
    [57] Ma L, Zhao Z Y, Dong Y M, Sun X Q. A synergistic extraction strategy by Cyanex572 and Cyanex923 for Th(IV) separation[J]. Sep. Purif. Technol., 2018,191: 307.
    [58] 王艳良, 董亚敏, 孙晓琦. 离子型稀土矿放射性废渣处理的应用基础研究 [A]. 中国稀土学会2017学术年会摘要集 [C]. 北京: 中国稀土学会, 2017. 39.Wang Y L, Dong Y M, Sun X Q. Basic research on the application of radioactive waste residue in ionic rare earth ore [A]. Summary of the 2017 Annual Conference of the Chinese rare Earth Society [C]. Beijing: China Rare Earth Society, 2017. 39.
    [59] 吴华武. 核燃料化学工艺学 [M]. 北京: 原子能出版社,1989.Wu H W. Nuclear Fuel Chemical Technology [M]. Beijing: Atomic Energy Publishing House, 1989.
    [60] 李德谦, 王艳良, 廖伍平. 一种钍的纯化方法 [P]. 中国专利: ZL201110074345.8, 2012.Li D Q, Wang Y L, Liao W P. A purification method for thorium [P]. China Patent: ZL201110074345.8, 2012.
    [61] 李德谦, 王艳良, 廖伍平. 一种钍的分离纯化方法 [P]. 中国专利: ZL201210552752.X, 2013.Li D Q, Wang Y L, Liao W P. A method for separation and purification of thorium [P]. China Patent: ZL201210552752.X, 2013.
    [62] Wang Y L, Li Y L, Liao W P, Li D Q. Preparation of high-purity thorium by solventextraction with di-(2-ethylhexyl) 2-ethylhexyl phosphonate [J]. J. Radioanal. Nucl. Chem., 2013, 298(3): 1651.
    [63] 廖伍平, 李艳玲, 张志峰, 卢有彩. 中性磷酰胺萃取剂用于萃取分离钍的用途和方法 [P]. 中国专利: ZL201410409451.0, 2014.Liao W P, Li Y L, Zhang Z F, Lu Y C. Use and method of neutral phosphamide extractant for extraction and separation of thorium [P]. China Patent: ZL201410409451.0, 2014.
    [64] 廖伍平, 李艳玲, 张志峰, 吴国龙, 卢有彩. 含氨基中性膦萃取剂用于萃取分离钍的用途和方法 [P]. 中国专利: ZL201410765062.1, 2016.Liao W P, Li Y L, Zhang Z F, Wu G L, Lu Y C. Use and method of extraction of thorium with amino-neutral phosphine extractant [P]. China Patent: ZL201410765062.1, 2016.
    [65] 廖伍平, 王小飞, 孙玉丽, 卢有彩, 李艳玲. 一种杯芳烃及其分离纯化钍的方法 [P]. 中国专利: ZL201210453853.1, 2013.Liao W P, Wang X F, Sun Y L, Lu Y C, Li Y L. A method of calixarene and its separation and purification of thorium [P]. China Patent: ZL201210453853.1, 2013.

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