Nb在现代铁素体不锈钢中的应用研究进展
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摘要
Nb元素越来越多地被应用于铁素体不锈钢中以提高其性能。本文综述了Nb对铁素体不锈钢强度、韧性、耐腐蚀、抗高温氧化等性能影响的研究进展,以及国内外含Nb铁素体不锈钢在汽车、建筑、家用电器等领域中的应用现状。分析了目前我国含Nb高性能铁素体不锈钢研发中存在的主要问题,认为我国未来应重点研究新型超临界温度的含Nb耐热不锈钢等高端装备制造材料,以促进含Nb高性能铁素体不锈钢的研发和生产,改善我国不锈钢的品种结构。
Nb element is more and more used in ferritic stainless steel to improve its properties. The latest research advances on the influence of Nb on the strength, toughness, corrosion resistance and high-temperature oxidation resistance of ferritic stainless steels were reviewed in this paper,as well as the application status quo of Nb ferritic stainless steels in automobile, building, household appliances and other fields. The main problems in the research and development of Nb-containing high performance ferritic stainless steel in China were analyzed. It is considered that in the future,high-end equipment manufacturing materials such as new supercritical temperature Nb-containing heat-resistant stainless steel should be studied to promote the development and production of Nb-containing high-performance ferritic stainless steel and improve the variety structure of stainless steel in China.
Nb element is more and more used in ferritic stainless steel to improve its properties. The latest research advances on the influence of Nb on the strength, toughness, corrosion resistance and high-temperature oxidation resistance of ferritic stainless steels were reviewed in this paper,as well as the application status quo of Nb ferritic stainless steels in automobile, building, household appliances and other fields. The main problems in the research and development of Nb-containing high performance ferritic stainless steel in China were analyzed. It is considered that in the future,high-end equipment manufacturing materials such as new supercritical temperature Nb-containing heat-resistant stainless steel should be studied to promote the development and production of Nb-containing high-performance ferritic stainless steel and improve the variety structure of stainless steel in China.
引文
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[4]付俊岩,侯豁然.现代新型铁素体不锈钢技术进步及其应用与市场[EB/OL].[2018-03-20]. http://www. wanfangdata. com.cn/details/detail. do?_type=conference&id=5303312.
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[7]孟繁茂,傅俊岩.现代含铌不锈钢[M].北京:冶金工业出版社,2004:3-4.
[8]中信微合金化技术中心.铌·科学与技术[M].北京:冶金工业出版社,2003:456-472.
[9]李尚诣,周渝生,杜华云,等.铌资源开发应用技术[M].北京:冶金工业出版社,1992:433-436.
[10]王俊琴,刘云霞.铌在不锈钢中的应用[J].大型铸锻件,2004(2):51-54.
[11]刘涛,曹建春,赵宝禄,等.铌在不锈钢中的应用[J].中国材料科技与设备,2008(3):20-23.
[12]MARTINEZ L G,IMAKUMA K,PADILHA A F,et al. Influence of niobium on stacking-fault energy of all-austenite stainless steels[J]. Steel Research,1992,63(5):221-223.
[13]孟繁茂,傅俊岩.铌在现代不锈钢中的应用[EB/OL].[2018-03-18]. http://www. doc88. com/p-758222014195. html.
[14]中信微合金化技术中心.铌·科学与技术[M].北京:冶金工业出版社,2003:611-618.
[15]STORMS E K,KRIKORIAN N H. The niobium-niobium carbide system[J]. J Phys&Chem,1960,64(10):1471-1477.
[16]雍岐龙,马鸣图,吴宝榕.微合金钢——物理和力学冶金[M].北京:机械工业出版社,1989.
[17]冶金工业部钢铁研究总院.钢和铁、镍基合金的物理化学相分析[M].上海:上海科学技术出版社,1981,29-33.
[18]萨姆索诺夫.难熔化合物手册[M].北京:中国工业出版社,1965:51.
[19]BARIN I,KNACKE O,KUBASCHEWSKI O. Thermochemical Properties of Inorganic Substances[M]. Berlin,GER:Springer Verlag. 1977.
[20]谭静.铌的碳氮化物对奥氏体静态再结晶的影响[D].武汉:武汉科技大学,2006.
[21]LIFSHITZ I M,SLYOZOV V V. The kinetics of precipitation from supersaturated solid solutions[J]. J Phys&Chem Solids,1961,19(1/2):35-50.
[22]雍岐龙,吴宝榕,白埃民,等.铌微合金钢中碳氮化铌化学组成的计算与分析[J].钢铁研究学报,1990,(2):37-42.
[23]雍岐龙,李永福,孙珍宝,等.微合金碳氮化物与奥氏体之间的半共格界面比界面能的理论计算[J].科学通报,1988(6):467-470.
[24]东涛,孟繁茂,王祖滨,等.神奇的Nb-铌在钢铁中的应用[M].北京:中信美国钢铁公司,1999.
[25]YAN H T,BI H Y,LI X,et al. Precipitation and mechanical properties of Nb-modified ferritic stainless steel during isothermal aging[J]. Materials Characterization,2009,60(3):204-209.
[26]上海艾荔艾金属材料有限公司.含铌铁素体不锈钢430LX钢F14Nb在汽车排气系统中的应用[EB/OL].[2018-03-18].https://club. 1688. com/article/29606344. htm.
[27]付俊岩.汽车工业用含铌钢的技术与发展[EB/OL].[2018-03-18]. http://www. docin. com/p-5514501. html.
[28]DUW,JIANG L Z,SUN Q S,et al. Microstructure,texture,and formability of Nb+Ti stabilized high purity ferritic stainless steel[J]. Journal of Iron and Steel Research,International,2010,17(6):47-52.
[29]DAVISON R M. Texture and anisotropy of low-interstitial 18 Pct Cr-2 Pct Mo ferritic stainless steel[J]. Metallurgical&Materials Transactions A,1975,6(12):2243-2248.
[30]李晓林,肖宝亮,崔阳,等. Nb、Ti微合金钢中碳氮化物固溶与再析出的研究[J].材料导报,2017,31(1):105-111.
[31]YAN H T,BI H Y,LI X,et al. Influence of Nb on microstructure and mechanical properties of 0Cr11 ferritic stainless steel[J].Iron&Steel,2009,44(1):59-62.
[32]PERTULLA J,KANTANEN P,KARJALAINEN L P. Effect of precipitation on flow stess and recrystallization in Nb and Ti bearing austenite[J]. Scandinavian Journal of Metallurgy,1998,27(3):128-132.
[33]HANSEN S S,SANDE J B V,COHEN M. Niobium carbonitride precipitation and austenite recrystallization in hot-rolled microalloyed steels[J]. Metallurgical Transactions A,1980,11(3):387-402.
[34]JORGE-BADIOLA D,GUTIERREZ I. Study of the strain reversal effect on the recrystallization and strain-induced precipitation in a Nb-microalloyed steel[J]. Acta Materialia,2004,52(2):333-341.
[35]KWON O,DEARDO A J. Interactions between recrystallization and precipitation in hot-deformed microalloyed steels[J]. Acta Metallurgica Et Materialia,1991,39(4):529-538.
[36]ISLAM M A,BEPARI M M A. Effects of niobium additions on the structure,depth,and austenite grain size of the case of carburized 0. 07%C steels[J]. Journal of Materials Engineering&Performance,1996,5(5):593-597.
[37]HELD J F.美国对微合金钢的研究及应用[J].失效分析与预防,1989(2):61-63.
[38]康喜范.铁素体不锈钢[M].北京:冶金工业出版社,2012:88-97.
[39]FUJITA N,OHMURA K,KIKUCHI M,et al. Effect of Nb on high-temperature properties for ferritic stainless steel[J]. Scripta Materialia,1996,35(6):705-710.
[40]HIRAIDE N.含铌铁素体不锈钢在汽车零部件上的应用[J].世界钢铁,2004(6):33-36.
[41]TAKAHASHI J,KAWAKAMI K,HAMADA J I,et al. Direct observation of niobium segregation to dislocations in steel[J]. Acta Materialia,2016,107:415-422.
[42]黄训增,杨弋涛.铌钛对铁素体不锈钢第二相高温析出行为的影响[J].金属热处理,2015,40(10):7-12.
[43]JUUTI T,ROVATTI L,PORTER D,et al. Factors controlling ambient and high temperature yield strength of ferritic stainless steel susceptible to intermetallic phase formation[J]. Materials Science&Engineering A,2018,726:45-55.
[44]FUJITA N,OHMURA K,YAMAMOTO A. Changes of microstructures and high temperature properties during high temperature service of Niobium added ferritic stainless steels[J]. Materials Science&Engineering:A,2003,351(1/2):272-281.
[45]FUJITA N,BHADESHIA H,KIKUCHI M. Modeling M6C precipitation in niobium-alloyed ferritic stainless steel[J]. Metallurgical and Materials Transactions A,2002,33(11):3339-3347.
[46]FUJITA N,OHMURA K,SATO E,et al. Development of ferritic steel YUS450 with high heat resistance for automotive exhaust system components[J]. Nippon Steel Technical Report,1996(71):25-30.
[47]HIRAMATSU N.铌在铁素体不锈钢和马氏体不锈钢中的应用[M]//科技与技术.北京:冶金工业出版社,2003:603-610.
[48]DEARDO A J.北美IF钢和铁素体不锈钢的最新进展[EB/OL].[2018-03-20]. http://www. wanfangdata. com. cn/details/detail. do?_type=conference&id=5810720.
[49]李鑫,刘后龙,毕洪运,等.中铬铁素体不锈钢18CrNb高温氧化行为[J].材料研究学报,2016,30(4):263-268.
[50]陈海涛,郎宇平,屈华鹏.现代铁素体不锈钢的研究现状及发展趋势[C]//全国耐蚀金属材料第十三届学术年会论文集.九江:中国腐蚀与防护学会耐蚀金属材料专业委员会,2014:32-41.
[51]孟繁茂,付俊岩.现代含铌不锈钢[M].北京:冶金工业出版社,2004.
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