复合锂基润滑脂的研究进展
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摘要
复合锂基润滑脂具有良好的高温多效性能,自发明以来持续受到广泛研究和应用。同时复合锂皂良好的基础油稠化能力和添加剂感受性,使其可以制备满足各种工况要求的润滑脂。综述了复合锂基脂组成和制备工艺对其性能及结极的影响,探讨了复合锂基脂成脂机理,幵对复合锂基润滑脂的未来发展进行了展望。
Lithium complex grease has good high temperature and multi-effect performance,and has been widely studied and applied since the invention.At the same time,compound lithium soap has good base oil thickening ability and additive sensitivity,so that it can be used to prepare various types of grease.In this paper,the impact of composition and preparation process on properties and structure of complex lithium grease was summarized,the lipid formation mechanism of complex lithium grease was discussed.Finally,the future development trend of complex lithium based grease was prospected.
Lithium complex grease has good high temperature and multi-effect performance,and has been widely studied and applied since the invention.At the same time,compound lithium soap has good base oil thickening ability and additive sensitivity,so that it can be used to prepare various types of grease.In this paper,the impact of composition and preparation process on properties and structure of complex lithium grease was summarized,the lipid formation mechanism of complex lithium grease was discussed.Finally,the future development trend of complex lithium based grease was prospected.
引文
[1]孙全淑.润滑脂性能及应用[M].北京:烃加工业出版社,1988.
[2]EHRLISH M.MUSIL1 T GThe development of lithium complex grease[J].NLGI SPOKESMAN,1980,12(6):87-100.
[3]Tanaka N,Tajiri H,Okamoto T.HIGH DROPPING-POINTLITHIUM-COMPLEX GREASE HAVING IMPROVED ANTI-NOISEPROPERTIES:EP,EP 0084910 B1[P].1989.
[4]蒋明俊,郭小川.复合锂基脂的研究[J].润滑与密封,2000(5):25-28.
[5]Kholijah A M S,Yeung S L C,Sazwani S,et al.Production of High Temperature Grease from Waste Lubricant Sludge and Silicone Oil[J].Journal of Applied Sciences,2012,12(11):1171-1175.
[6]王伟军,田松柏,孙洪伟.基础油与添加剂对润滑脂微观结极的影响[J].石油商技,2015(5):26-34.
[7]蒋明俊,郭小川,付洪瑞.复合锂基润滑脂的制备及性能研究[C].中国石油学会石油炼制学术年会,2010.
[8]赵军,张亮,席瀛,等.多用途航空复合锂基润滑脂的研制[J].合成润滑材料,2016,43(3):3-5.
[9]曾晖,陈哲,纪红兵,等.基于硅油的复合锂基润滑脂的极效关系研究[J].润滑与密封,2012,37(2):20-24.
[10]曾晖,李辉华,纪红兵,等.邻苯二甲酸二辛酯复合锂基润滑脂的研制及其性能表征[J].塑料工业,2012,40(5):123-125.
[11]刘志颖,刘庆廉,孙洪伟,等.基础油对复合锂基润滑脂性能及稠化剂结极的影响[J].石油商技,2008,26(4):46-53.
[12]孙元碧,付玉娥.一种新型复合锂基润滑脂的制备[J].山东化工,2013,42(7)15-16
[13]郭阳,胡萍,骆旎,等.基础油复配复合锂基脂的制备及性能研究[J].润滑与密封,2016,41(9):32-36.
[14]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[15]Mao D H,Hao F,Sun X Y.Preparation of hyperthermal lithium complex grease[J].中国有色金属学报(英文版),2005,15(6):1361-1366.
[16]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[17]Ischuk Y L,Bulgak V B,STALCHURSKY A D.Composition of lithium complex soap and its role in the formation of grease properties[J].NLGIspokesman,1995,59(1):21-24.
[18]Luo R,Wang P,Liu F.A Study of Composition and Technology of Complex Lithium Grease[R].Nlgi Spokesman,1998.
[19]马爱民,吴宝杰,高艳青,等.一种四组分复合锂基润滑脂的组合物及制备方法:CN,101955835 B[P].2013.
[20]谭希光,刘中强,张勇,等.液态锂生产复合锂基脂[C].全国润滑脂技术交流会,2009.
[21]王志成,杨正宇.二元组分复合锂基润滑脂的研究和其结极的探讨[C].全国润滑脂技术交流会,2013.
[22]付蕾.复合锂基润滑脂的基础研究[J].广州化工,2012,40(2):88-90.
[23]曾晖,陈晓南,陈哲,等.润滑脂组成对复合锂基润滑脂微观结极影响的研究[J].润滑与密封,2011,36(8):42-47.
[24]I.Couronné,P.Vergne,D.Mazuyer,et al.Effects of Grease Composition and Structure on Film Thickness in Rolling Contact[J].Tribology Transactions,2003,46(1):31-36.
[25]刘志颖,孙洪伟,刘庆廉,等.二元酸对复合锂基润滑脂滴点的影响及其分子机理[J].石油商技,2016(2):38-43.
[26]Michael E.Brooks,Chin-Shia Chang,Mark Durchholz.微动磨损研究:复合锂基润滑脂添加壬二酸-A和壬二酸-B的效果[C].全国润滑脂技术交流会,2015.
[27]Okaniwa T,Kimura H.Effects of various factors on properties of lithium complex grease[R].Nlgi Spokesman,1997.
[28]Kimura H,Shibayama A,Yamamoto Y.Study on Hybrid Lithium Soap Greases[J].Japanese Journal of Tribology,2001,46(4):237-238.
[29]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[30]朱廷彬.润滑脂技术大全[M].北京:中国石化出版社,2015.
[31]王伟,张群敏,唐广秋.高滴点三组分复合锂基润滑脂的研制[C].全国润滑脂技术交流会,1997.
[32]蒋明俊,郭小川,付洪瑞.影响复合锂基润滑脂性能的因素探讨[J].石油炼制与化工,2011,42(2):73-77.
[33]益廸国,杨舒虹.复合锂基润滑脂的性能及应用[J].合成润滑材料,2003(1):4-6.
[34]William J.Mertz,Eric Ndegwa,Wade Flemming.多种新二元酸混合剂作复合锂基润滑脂复合剂的评价[C].全国润滑脂技术交流会,2013.
[35]蒋明俊,郭小川,董浚修,等.添加剂在复合锂基脂中的应用[J].合成润滑材料,2000(3):1-7.
[36]俸颢,毛大恒,刘巧红,等.枀压抗磨添加剂在复合锂基润滑脂中作用的研究[J].润滑与密封,2006(9):55-57.
[37]于唯,董元虎,许自立,等.枀压抗磨剂对高温复合锂基润滑脂性能的影响[J].甘肃农大学报,2013(6):174-180.
[38]杨海宁,姚立丹,孙洪伟,等.添加剂在复合锂基润滑脂中抗磨性能的研究[J].石油学报(石油加工),2011,27(s1):71-75.
[39]赵勤.新型离子型润滑油脂添加剂的分子设计与合成制备及其性能研究[R].固体润滑国家重点实验室,2014.
[40]马丼,周园.一种耐轴承腐蚀和磨损的复合锂基润滑脂的研制[J].汽车零部件,2014(6):64-67.
[41]Cron A,Fatkin J.Graphite in lubrication:fundamental parameters and selection guide[J].NLGI spokesman,1989,53(4):137-147.
[42]Albert V.The effect of graphite type,purity,and concentration on the performance of a clay filled polyalphaolefin grease,based on four ball wear(ASTM D2266)with coefficient of friction,and load wear index(ASTM D2596)[J].NLGI Spokesman,2002,65(12):10-25.
[43]程嘉兴,谢凤,李斌,等.不同粒径纳米石墨在锂基脂中的抗磨减摩性能研究[J].石油化工应用,2016,35(6):150-154.
[44]胡耀娟,金娟,张卉,吴萍,蔡称心.石墨烯的制备、功能化及在化学中的应用[J].物理化学学报,2010(08):2073-2086.
[45]Zheng D,Cai Z B,Shen M X,et al.Investigation of the tribology behaviour of the graphene nanosheets as oil additives on textured alloy cast iron surface[J].Applied Surface Science,2016,387:66-75.
[46]王晶,郭小川,何燕,等.石墨烯作为锂基润滑脂添加剂的摩擦学性能研究[J].中国炼油与石油化工.2017,19(1):46-54.
[47]Barry H F,Risdon T J,Sargent D J.Comparison of commercially available U.S.greases with and without molybdenum disulfide[J].Wear,1970,15(2):154-154.
[48]胡献国,程亚洲,孙晓军,等.纳米Mo S2空间润滑脂的真空高温摩擦学特性研究[C].摩擦、减摩、耐磨材料和技术学术年会,2013.
[49]范海粉,王瑞兴,等.固体添加剂和摩擦改进剂对锂基润滑脂性能的影响[J].润滑与密封,2016,41(12):136-140.
[50]张哲,陈国需,程鹏,等.润滑脂中层状二硅酸钠对二硫化钼的替代作用[J].石油学报(石油加工),2015,31(3):790-795.
[51]张哲,陈国需,赵立涛,等.石墨和层状二硅酸钠的复配体系作为润滑脂添加剂的摩擦学性能[J].润滑与密封,2014,39(1):17-23.
[52]杜鹏飞,陈国需,宋世远,等.白云母微粉作为润滑脂添加剂的摩擦学性能[J].硅酸盐学报,2016,44(5):748-753.
[53]陈力,陈国需,李华峰,等.二氧化硅在锂基脂中的摩擦学性能[J].润滑与密封,2014,39(2):9-14.
[54]俸颢,毛大恒,刘巧红,等.二硫化钨超细粉末对高温复合锂基润滑脂性能的影响[J].四川大学学报(工程科学版),2006,38(3):119-123.
[55]陈汉林,陈国需,杜鹏飞,等.二硫化钨纳米粉体作为锂基润滑脂添加剂的摩擦学研究[J].摩擦学学报,2015,35(6):651-657.
[56]毛大恒,石琛,俸颢,等.高温润滑脂中WS2亚微米粒子的摩擦学性能研究[J].摩擦学学报,2010,30(1):68-74.
[57]乔鹏.导电润滑脂的摩擦学性能研究及电--热耦合分析[D].华北电力大学,2014.
[58]刘椿,夏延秋,曹正锋.碳纳米管在润滑脂中的导电性和摩擦学性能研究[J].摩擦学学报,2015,35(4):393-397.
[59]曹正锋,夏延秋,陈俊寰.气相生长碳纤维作为润滑脂导电填料的摩擦学性能研究[J].摩擦学学报,2016,36(2):137-144.
[60]王骏遥,夏延秋.导电复合锂基润滑脂润滑的制备及性能研究[J].润滑与密封,2015,40(3):79-83.
[61]潘正华.应用压力釜生产复合锂基润滑脂的研究[C].中国石油炼制技术大会,2013.
[62]刘晓波.冷却方式对锂基润滑脂性能的影响简述[J].合成润滑材料,2013,40(3):29-30.
[63]林成钦,李集周.复合锂基脂的制备工艺研究[J].山东化工,2015,(13):18-19-21.
[64]赵宍斐,谷红宽.后处理方式对锂基润滑脂机械安定性的影响[J].石油商技,2016(4):34-36.
[65]于唯,董元虎,贾文,等.复合锂基润滑脂实验室制备工艺研究[J].润滑与密封,2013,38(1):92-95.
[66]许俊,徐楠,王晓波,等.冰水浴和自然冷却条件下锂基润滑脂的流变学性能[J].摩擦学学报,2013,33(4):406-412.
[67]席瀛,杨文毅.硼酸和12-羟基硬脂酸复合锂基润滑脂及其预制皂的结极探讨及性能研究[C].全国润滑脂技术交流会,1997.
[68]阎君,田科奇.三组份复合锂基润滑脂的配方及生产研究[C].全国润滑脂技术交流会,2011.
[69]毛菁菁,程型国,张遂心.复合锂基润滑脂的流变特性与微观结极的关系研究[J].润滑与密封,2013(12):79-83.
[70]王玉新,金银秀,张昕欣,等.复合锂基脂制备过程中结极和性能的演变研究[J].摩擦学学报,2015,35(4):448-453.
[71]刘磊,孙洪伟.复合锂基润滑脂制备反应的密度泛函理论[J].石油学报(石油加工),2010,26(4):571-575.
[2]EHRLISH M.MUSIL1 T GThe development of lithium complex grease[J].NLGI SPOKESMAN,1980,12(6):87-100.
[3]Tanaka N,Tajiri H,Okamoto T.HIGH DROPPING-POINTLITHIUM-COMPLEX GREASE HAVING IMPROVED ANTI-NOISEPROPERTIES:EP,EP 0084910 B1[P].1989.
[4]蒋明俊,郭小川.复合锂基脂的研究[J].润滑与密封,2000(5):25-28.
[5]Kholijah A M S,Yeung S L C,Sazwani S,et al.Production of High Temperature Grease from Waste Lubricant Sludge and Silicone Oil[J].Journal of Applied Sciences,2012,12(11):1171-1175.
[6]王伟军,田松柏,孙洪伟.基础油与添加剂对润滑脂微观结极的影响[J].石油商技,2015(5):26-34.
[7]蒋明俊,郭小川,付洪瑞.复合锂基润滑脂的制备及性能研究[C].中国石油学会石油炼制学术年会,2010.
[8]赵军,张亮,席瀛,等.多用途航空复合锂基润滑脂的研制[J].合成润滑材料,2016,43(3):3-5.
[9]曾晖,陈哲,纪红兵,等.基于硅油的复合锂基润滑脂的极效关系研究[J].润滑与密封,2012,37(2):20-24.
[10]曾晖,李辉华,纪红兵,等.邻苯二甲酸二辛酯复合锂基润滑脂的研制及其性能表征[J].塑料工业,2012,40(5):123-125.
[11]刘志颖,刘庆廉,孙洪伟,等.基础油对复合锂基润滑脂性能及稠化剂结极的影响[J].石油商技,2008,26(4):46-53.
[12]孙元碧,付玉娥.一种新型复合锂基润滑脂的制备[J].山东化工,2013,42(7)15-16
[13]郭阳,胡萍,骆旎,等.基础油复配复合锂基脂的制备及性能研究[J].润滑与密封,2016,41(9):32-36.
[14]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[15]Mao D H,Hao F,Sun X Y.Preparation of hyperthermal lithium complex grease[J].中国有色金属学报(英文版),2005,15(6):1361-1366.
[16]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[17]Ischuk Y L,Bulgak V B,STALCHURSKY A D.Composition of lithium complex soap and its role in the formation of grease properties[J].NLGIspokesman,1995,59(1):21-24.
[18]Luo R,Wang P,Liu F.A Study of Composition and Technology of Complex Lithium Grease[R].Nlgi Spokesman,1998.
[19]马爱民,吴宝杰,高艳青,等.一种四组分复合锂基润滑脂的组合物及制备方法:CN,101955835 B[P].2013.
[20]谭希光,刘中强,张勇,等.液态锂生产复合锂基脂[C].全国润滑脂技术交流会,2009.
[21]王志成,杨正宇.二元组分复合锂基润滑脂的研究和其结极的探讨[C].全国润滑脂技术交流会,2013.
[22]付蕾.复合锂基润滑脂的基础研究[J].广州化工,2012,40(2):88-90.
[23]曾晖,陈晓南,陈哲,等.润滑脂组成对复合锂基润滑脂微观结极影响的研究[J].润滑与密封,2011,36(8):42-47.
[24]I.Couronné,P.Vergne,D.Mazuyer,et al.Effects of Grease Composition and Structure on Film Thickness in Rolling Contact[J].Tribology Transactions,2003,46(1):31-36.
[25]刘志颖,孙洪伟,刘庆廉,等.二元酸对复合锂基润滑脂滴点的影响及其分子机理[J].石油商技,2016(2):38-43.
[26]Michael E.Brooks,Chin-Shia Chang,Mark Durchholz.微动磨损研究:复合锂基润滑脂添加壬二酸-A和壬二酸-B的效果[C].全国润滑脂技术交流会,2015.
[27]Okaniwa T,Kimura H.Effects of various factors on properties of lithium complex grease[R].Nlgi Spokesman,1997.
[28]Kimura H,Shibayama A,Yamamoto Y.Study on Hybrid Lithium Soap Greases[J].Japanese Journal of Tribology,2001,46(4):237-238.
[29]毛大恒,孙晓亚.提高高温复合锂基脂滴点的机理研究[J].南方金属,2006(2):21-24.
[30]朱廷彬.润滑脂技术大全[M].北京:中国石化出版社,2015.
[31]王伟,张群敏,唐广秋.高滴点三组分复合锂基润滑脂的研制[C].全国润滑脂技术交流会,1997.
[32]蒋明俊,郭小川,付洪瑞.影响复合锂基润滑脂性能的因素探讨[J].石油炼制与化工,2011,42(2):73-77.
[33]益廸国,杨舒虹.复合锂基润滑脂的性能及应用[J].合成润滑材料,2003(1):4-6.
[34]William J.Mertz,Eric Ndegwa,Wade Flemming.多种新二元酸混合剂作复合锂基润滑脂复合剂的评价[C].全国润滑脂技术交流会,2013.
[35]蒋明俊,郭小川,董浚修,等.添加剂在复合锂基脂中的应用[J].合成润滑材料,2000(3):1-7.
[36]俸颢,毛大恒,刘巧红,等.枀压抗磨添加剂在复合锂基润滑脂中作用的研究[J].润滑与密封,2006(9):55-57.
[37]于唯,董元虎,许自立,等.枀压抗磨剂对高温复合锂基润滑脂性能的影响[J].甘肃农大学报,2013(6):174-180.
[38]杨海宁,姚立丹,孙洪伟,等.添加剂在复合锂基润滑脂中抗磨性能的研究[J].石油学报(石油加工),2011,27(s1):71-75.
[39]赵勤.新型离子型润滑油脂添加剂的分子设计与合成制备及其性能研究[R].固体润滑国家重点实验室,2014.
[40]马丼,周园.一种耐轴承腐蚀和磨损的复合锂基润滑脂的研制[J].汽车零部件,2014(6):64-67.
[41]Cron A,Fatkin J.Graphite in lubrication:fundamental parameters and selection guide[J].NLGI spokesman,1989,53(4):137-147.
[42]Albert V.The effect of graphite type,purity,and concentration on the performance of a clay filled polyalphaolefin grease,based on four ball wear(ASTM D2266)with coefficient of friction,and load wear index(ASTM D2596)[J].NLGI Spokesman,2002,65(12):10-25.
[43]程嘉兴,谢凤,李斌,等.不同粒径纳米石墨在锂基脂中的抗磨减摩性能研究[J].石油化工应用,2016,35(6):150-154.
[44]胡耀娟,金娟,张卉,吴萍,蔡称心.石墨烯的制备、功能化及在化学中的应用[J].物理化学学报,2010(08):2073-2086.
[45]Zheng D,Cai Z B,Shen M X,et al.Investigation of the tribology behaviour of the graphene nanosheets as oil additives on textured alloy cast iron surface[J].Applied Surface Science,2016,387:66-75.
[46]王晶,郭小川,何燕,等.石墨烯作为锂基润滑脂添加剂的摩擦学性能研究[J].中国炼油与石油化工.2017,19(1):46-54.
[47]Barry H F,Risdon T J,Sargent D J.Comparison of commercially available U.S.greases with and without molybdenum disulfide[J].Wear,1970,15(2):154-154.
[48]胡献国,程亚洲,孙晓军,等.纳米Mo S2空间润滑脂的真空高温摩擦学特性研究[C].摩擦、减摩、耐磨材料和技术学术年会,2013.
[49]范海粉,王瑞兴,等.固体添加剂和摩擦改进剂对锂基润滑脂性能的影响[J].润滑与密封,2016,41(12):136-140.
[50]张哲,陈国需,程鹏,等.润滑脂中层状二硅酸钠对二硫化钼的替代作用[J].石油学报(石油加工),2015,31(3):790-795.
[51]张哲,陈国需,赵立涛,等.石墨和层状二硅酸钠的复配体系作为润滑脂添加剂的摩擦学性能[J].润滑与密封,2014,39(1):17-23.
[52]杜鹏飞,陈国需,宋世远,等.白云母微粉作为润滑脂添加剂的摩擦学性能[J].硅酸盐学报,2016,44(5):748-753.
[53]陈力,陈国需,李华峰,等.二氧化硅在锂基脂中的摩擦学性能[J].润滑与密封,2014,39(2):9-14.
[54]俸颢,毛大恒,刘巧红,等.二硫化钨超细粉末对高温复合锂基润滑脂性能的影响[J].四川大学学报(工程科学版),2006,38(3):119-123.
[55]陈汉林,陈国需,杜鹏飞,等.二硫化钨纳米粉体作为锂基润滑脂添加剂的摩擦学研究[J].摩擦学学报,2015,35(6):651-657.
[56]毛大恒,石琛,俸颢,等.高温润滑脂中WS2亚微米粒子的摩擦学性能研究[J].摩擦学学报,2010,30(1):68-74.
[57]乔鹏.导电润滑脂的摩擦学性能研究及电--热耦合分析[D].华北电力大学,2014.
[58]刘椿,夏延秋,曹正锋.碳纳米管在润滑脂中的导电性和摩擦学性能研究[J].摩擦学学报,2015,35(4):393-397.
[59]曹正锋,夏延秋,陈俊寰.气相生长碳纤维作为润滑脂导电填料的摩擦学性能研究[J].摩擦学学报,2016,36(2):137-144.
[60]王骏遥,夏延秋.导电复合锂基润滑脂润滑的制备及性能研究[J].润滑与密封,2015,40(3):79-83.
[61]潘正华.应用压力釜生产复合锂基润滑脂的研究[C].中国石油炼制技术大会,2013.
[62]刘晓波.冷却方式对锂基润滑脂性能的影响简述[J].合成润滑材料,2013,40(3):29-30.
[63]林成钦,李集周.复合锂基脂的制备工艺研究[J].山东化工,2015,(13):18-19-21.
[64]赵宍斐,谷红宽.后处理方式对锂基润滑脂机械安定性的影响[J].石油商技,2016(4):34-36.
[65]于唯,董元虎,贾文,等.复合锂基润滑脂实验室制备工艺研究[J].润滑与密封,2013,38(1):92-95.
[66]许俊,徐楠,王晓波,等.冰水浴和自然冷却条件下锂基润滑脂的流变学性能[J].摩擦学学报,2013,33(4):406-412.
[67]席瀛,杨文毅.硼酸和12-羟基硬脂酸复合锂基润滑脂及其预制皂的结极探讨及性能研究[C].全国润滑脂技术交流会,1997.
[68]阎君,田科奇.三组份复合锂基润滑脂的配方及生产研究[C].全国润滑脂技术交流会,2011.
[69]毛菁菁,程型国,张遂心.复合锂基润滑脂的流变特性与微观结极的关系研究[J].润滑与密封,2013(12):79-83.
[70]王玉新,金银秀,张昕欣,等.复合锂基脂制备过程中结极和性能的演变研究[J].摩擦学学报,2015,35(4):448-453.
[71]刘磊,孙洪伟.复合锂基润滑脂制备反应的密度泛函理论[J].石油学报(石油加工),2010,26(4):571-575.