制备方法对HNIW撞击感度影响研究进展
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摘要
2,4,6,8,10,12-六硝基-2,4,6,8,10,12-六氮杂异伍兹烷(HNIW)是一种高能新型材料,目前已广泛应用于军事领域。由于HNIW在受到碰撞时容易发生剧烈化学反应,因此需要通过采用合适的材料制备方法来调控其撞击感度。综述了溶剂-非溶剂法、机械分散法及超临界流体法等多种方法制备得到的HNIW撞击感度研究进展,指出微观形貌和粒径尺寸是影响HNIW撞击感度的关键因素,小尺度球形化的HNIW具有更低的撞击感度。
HNIW,an abbreviation of Hexanitrohexaazaisowurtzitane,was a new kind high energy material and had been widely used in the military application fields.Hence a violent chemical reaction would take place easily when HNIW suffering accident mechanical impact loading,it was necessary to modulate its impact sensitivity by material preparation methods.In this work,the influence on the impact sensitivity of HNIW prepared by different methods are summarized.Moreover,it is suggested that the morphology and average particle size play key roles in the impact sensitivity of HNIW and samples with small particles and high spherical shape exhibit lower impact sensitivity.
HNIW,an abbreviation of Hexanitrohexaazaisowurtzitane,was a new kind high energy material and had been widely used in the military application fields.Hence a violent chemical reaction would take place easily when HNIW suffering accident mechanical impact loading,it was necessary to modulate its impact sensitivity by material preparation methods.In this work,the influence on the impact sensitivity of HNIW prepared by different methods are summarized.Moreover,it is suggested that the morphology and average particle size play key roles in the impact sensitivity of HNIW and samples with small particles and high spherical shape exhibit lower impact sensitivity.
引文
[1] 王昕,彭翠枝.国外六硝基六氮杂异伍兹烷的发展现状[J].火炸药学报,2007,30(5):45-48.
[2] Nair U R,Sivabalan R,Gore G M,et al.Hexanitrohexaazaisowurtzitane(CL-20)and CL-20-based formulations(review)[J].Combustion,Explosion,and Shock Waves,2005,41(2):121-132.
[3] 宋振伟,李笑江.高能量密度化合物HNIW的最新研究进展及其应用前景[J].化学推进剂与高分子材料,2011,9(1):40-45.
[4] 欧育湘,贾会平,陈博仁,等.六硝基六氮杂异伍兹烷的研究进展[J].含能材料,1999,7(2):49-52.
[5] 陈鲁英,杨培进,张林军,等.CL-20炸药性能研究[J].火炸药学报,2003,26(3):65-67.
[6] 解瑞珍,卢斌,赵久宏,等.超细HNIW机械感度的研究[J].火工品,2006,5:24-26.
[7] 郑孟菊,云主惠.炸药性能及测试技术[M].北京:机械工业出版社,1986.
[8] 王鼎,曹端林,王建龙,等.Span类表面活性剂对CL-20重结晶的影响[J].火炸药学报,2010,33(5):48-51.
[9] 郭学永,姜夏冰,于兰,等.粒径和晶形对ε-HNIW感度的影响[J].火炸药学报,2013,36(2):29-33.
[10] Yadollah Bayat,Vida Zeynali.Preparation and characterization of Nano CL-20explosive[J].Journal of Energetic Materials,2011,29(4):281-291.
[11] 王培勇,史春红,贺清彦,等.超细CL-20的制备与测试[J].火工品,2009,1:19-21.
[12] 任晓婷,孙忠祥,曹一林.细粒度ε-CL-20的制备基钝化[J].火炸药学报,2011,34(4):21-25.
[13] Joanna Szczygielska,Sandra Chlebna,Pawel Maksimowski,et al.Friction sensitivity of theε-CL-20 crystals obtained in precipitation process[J].Central European Journal of Energetic Materials,2011,8(2):117-130.
[14] Chen H X,Li L J,Jin S H,et al.Effects of additives on ε-HNIW crystal morphology and impact[J].Propellant,Explosives,Pyrotechnics,2012,37:77-82.
[15] 张朴,郭学永,张静元,等.机械研磨制备球形超细CL-20[J].含能材料,2013,21(6):738-742.
[16] 王彩玲,赵省向,戴致鑫,等.CL-20晶体粒度和形貌对其机械感度及火焰感度的影响[J].爆破器材,2010,43(5):1-5.
[17] 张静元,郭学永,张朴,等.球形超细ε-HNIW的球磨制备工艺[J].固体火箭技术,2015,38(6):837-841.
[18] Gao H,Liu J,Hao G Z,et al.Study on preparation,characterization and comminution mechanism of nano-sized CL-20[J].Chinese Journal of Explosives and Propellants,2015,38(2):46-49.
[19] 王保国,陈亚芳,张景林,等.亚微米级ε型CL-20的制备、表征与性能[J].爆炸与冲击,2009,29(5):550-554.
[20] 尚菲菲,张景林,张小连,等.超临界流体增强溶液扩散技术制备纳米CL-20及表征[J].火炸药学报,2012,35(6):37-40.
[21] 朱康,李国平,罗运军.超临界CO2反溶剂法制备CL-20超细微粒[J].含能材料,2012,20(4):445-449.
[22] Sivabalan R,Gore G M,Nair U R,et al.Study on ultrasound assisted precipitation of CL-20and its effect on morphology and sensitivity[J].Journal of Hazardous Materials,2007,A139:199-203.
[23] Yang Z J,Li J S,H B,et al.Preparation and properties study of core-shell CL-20/TATB composites[J].Propellants,Explosives,Pyrotechnics,2014,39,51-58.
[24] 王保国,陈亚芳,张景林,等.超细CL-20/Cr2O3复合物的制备、表征与性能[J].火工品,2013,3,26-29.
[25] 姜夏冰,焦清介,任慧,等.高聚物粘结ε-HNIW混合炸药的制备及其感度[J].火炸药学报,2011,34(3):21-24.
[2] Nair U R,Sivabalan R,Gore G M,et al.Hexanitrohexaazaisowurtzitane(CL-20)and CL-20-based formulations(review)[J].Combustion,Explosion,and Shock Waves,2005,41(2):121-132.
[3] 宋振伟,李笑江.高能量密度化合物HNIW的最新研究进展及其应用前景[J].化学推进剂与高分子材料,2011,9(1):40-45.
[4] 欧育湘,贾会平,陈博仁,等.六硝基六氮杂异伍兹烷的研究进展[J].含能材料,1999,7(2):49-52.
[5] 陈鲁英,杨培进,张林军,等.CL-20炸药性能研究[J].火炸药学报,2003,26(3):65-67.
[6] 解瑞珍,卢斌,赵久宏,等.超细HNIW机械感度的研究[J].火工品,2006,5:24-26.
[7] 郑孟菊,云主惠.炸药性能及测试技术[M].北京:机械工业出版社,1986.
[8] 王鼎,曹端林,王建龙,等.Span类表面活性剂对CL-20重结晶的影响[J].火炸药学报,2010,33(5):48-51.
[9] 郭学永,姜夏冰,于兰,等.粒径和晶形对ε-HNIW感度的影响[J].火炸药学报,2013,36(2):29-33.
[10] Yadollah Bayat,Vida Zeynali.Preparation and characterization of Nano CL-20explosive[J].Journal of Energetic Materials,2011,29(4):281-291.
[11] 王培勇,史春红,贺清彦,等.超细CL-20的制备与测试[J].火工品,2009,1:19-21.
[12] 任晓婷,孙忠祥,曹一林.细粒度ε-CL-20的制备基钝化[J].火炸药学报,2011,34(4):21-25.
[13] Joanna Szczygielska,Sandra Chlebna,Pawel Maksimowski,et al.Friction sensitivity of theε-CL-20 crystals obtained in precipitation process[J].Central European Journal of Energetic Materials,2011,8(2):117-130.
[14] Chen H X,Li L J,Jin S H,et al.Effects of additives on ε-HNIW crystal morphology and impact[J].Propellant,Explosives,Pyrotechnics,2012,37:77-82.
[15] 张朴,郭学永,张静元,等.机械研磨制备球形超细CL-20[J].含能材料,2013,21(6):738-742.
[16] 王彩玲,赵省向,戴致鑫,等.CL-20晶体粒度和形貌对其机械感度及火焰感度的影响[J].爆破器材,2010,43(5):1-5.
[17] 张静元,郭学永,张朴,等.球形超细ε-HNIW的球磨制备工艺[J].固体火箭技术,2015,38(6):837-841.
[18] Gao H,Liu J,Hao G Z,et al.Study on preparation,characterization and comminution mechanism of nano-sized CL-20[J].Chinese Journal of Explosives and Propellants,2015,38(2):46-49.
[19] 王保国,陈亚芳,张景林,等.亚微米级ε型CL-20的制备、表征与性能[J].爆炸与冲击,2009,29(5):550-554.
[20] 尚菲菲,张景林,张小连,等.超临界流体增强溶液扩散技术制备纳米CL-20及表征[J].火炸药学报,2012,35(6):37-40.
[21] 朱康,李国平,罗运军.超临界CO2反溶剂法制备CL-20超细微粒[J].含能材料,2012,20(4):445-449.
[22] Sivabalan R,Gore G M,Nair U R,et al.Study on ultrasound assisted precipitation of CL-20and its effect on morphology and sensitivity[J].Journal of Hazardous Materials,2007,A139:199-203.
[23] Yang Z J,Li J S,H B,et al.Preparation and properties study of core-shell CL-20/TATB composites[J].Propellants,Explosives,Pyrotechnics,2014,39,51-58.
[24] 王保国,陈亚芳,张景林,等.超细CL-20/Cr2O3复合物的制备、表征与性能[J].火工品,2013,3,26-29.
[25] 姜夏冰,焦清介,任慧,等.高聚物粘结ε-HNIW混合炸药的制备及其感度[J].火炸药学报,2011,34(3):21-24.