问荆提取物页岩水化膨胀抑制剂性能及防膨机理
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摘要
提出将问荆提取物作为页岩水化膨胀抑制剂,通过室内实验研究了其抑制页岩水化膨胀的性能,与氯化钾和聚胺进行了对比,并分析了其防膨机理。膨润土水化抑制实验、膨润土沉淀实验、动态线性膨胀实验、滚动回收实验和吸附量测定实验结果表明:问荆提取物可以抑制膨润土的水化,阻止黏土矿物在溶液中均匀分散,减小膨润土的膨胀,抑制钻屑在水中破碎和分散,且与氯化钾和聚胺性能相当。对问荆提取物的防膨机理进行分析后发现:其成分中具有活性烃基的物质与膨润土颗粒表面间氢键缔合,降低了膨润土颗粒表面的吸水率,从而抑制膨润土膨胀。除了具有良好的防膨能力,问荆提取物获取容易、价格低廉,且不会破坏生态环境,是一种理想的页岩水化膨胀抑制剂。
The Horsetail extract was used as shale stabilizer, its inhibition performance was stuided by laboratory experiments and compared with potassium chloride and polyamine, and its anti-swelling mechanism was analyzed. Bentonite inhibition test, sodium bentonite sedimentation test, dynamic linear swelling test, and hot rolling cutting dispersion test were employed. The results show that: the bentonite is not capable of being hydrated or dispersed in solution with the Horsetail extract; the Horsetail extract can resuce the swelling of the bentonite and prevent disintegration and dispersion of cuttings in aqueous medium; the extract is well comparable and competitive with potassium chloride and polyamine in inhibition performance. The constituents of the Horsetail extract have active hydroxyls which are capable of forming hydrogen bounding with surfaces of bentonite particles, leading to decrease of the water absorption on bentonite particles' surfaces which results in bentonite swelling reduction. Besides having good anti-swelling ability, Horsetail extract is ecofriendly, readily available and inexpensive.
The Horsetail extract was used as shale stabilizer, its inhibition performance was stuided by laboratory experiments and compared with potassium chloride and polyamine, and its anti-swelling mechanism was analyzed. Bentonite inhibition test, sodium bentonite sedimentation test, dynamic linear swelling test, and hot rolling cutting dispersion test were employed. The results show that: the bentonite is not capable of being hydrated or dispersed in solution with the Horsetail extract; the Horsetail extract can resuce the swelling of the bentonite and prevent disintegration and dispersion of cuttings in aqueous medium; the extract is well comparable and competitive with potassium chloride and polyamine in inhibition performance. The constituents of the Horsetail extract have active hydroxyls which are capable of forming hydrogen bounding with surfaces of bentonite particles, leading to decrease of the water absorption on bentonite particles' surfaces which results in bentonite swelling reduction. Besides having good anti-swelling ability, Horsetail extract is ecofriendly, readily available and inexpensive.
引文
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[9]XUAN Yang,JIANG Guancheng,LI Yingying,et al.Inhibiting effect of dopamine adsorption and polymerization on hydrated swelling of montmorillonite[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,422:50-60.
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[15]RAZI M M,MAZIDI M,RAZI F M,et al.Artificial neural network modeling of plastic viscosity,yield point,and apparent viscosity for water-based drilling fluids[J].Journal of Dispersion Science and Technology,2013,34(6):822-827.
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[17]AATON M S,ELLIOTT G P.Water-based glycol drilling muds:Shale inhibition mechanisms[R].SPE 28818,2007.
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[19]ROEHL E A,HACKETT J L.A laboratory technique for screening shale swelling inhibitors[R].SPE 11117,1982.
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[23]李建成,杨鹏,关键,等.新型全油基钻井液体系[J].石油勘探与开发,2014,41(4):490-496.LI Jiancheng,YANG Peng,GUAN Jian,et al.A new type of whole oil-based drilling fluid[J].Petroleum Exploration and Development,2014,41(4):490-496.
[24]?ANADANOVI?-BRUNET J M,?ETKOVI?G S,DJILAS S M,et al.Radical scavenging and antimicrobial activity of horsetail(Equisetum arvense L.)extracts[J].International Journal of Food Science&Technology,2009,44(2):269-278.
[25]MIMICA-DUKIC N,SIMIN N,CVEJIC J,et al.Phenolic compounds in field horsetail(Equisetum arvense L.)as natural antioxidants[J].Molecules,2008,13(7):1455-1464.
[26]MILOVANOVI?V,RADULOVI?N,TODOROVI?Z,et al.Antioxidant,antimicrobial and genotoxicity screening of hydro-alcoholic extracts of five Serbian Equisetum species[J].Plant Foods for Human Nutrition,2007,62(3):113-119.
[27]DANIELSKI L,MICHIELIN E M Z,FERREIRA S R S.Horsetail(Equisetum giganteum L.)oleoresin and supercritical CO2:Experimental solubility and empirical data correlation[J].Journal of Food Engineering,2007,78(3):1054-1059.
[28]HEIM K E,TAGLIAFERRO A R,BOBILYA D J.Flavonoid antioxidants:chemistry,metabolism and structure-activity relationships[J].The Journal of nutritional biochemistry,2002,13(10):572-584.
[29]HARBORNE J B,WILLIAMS C A.Advances in flavonoid research since 1992[J].Phytochemistry,2000,55(6):481-504.
[30]GüDER A,KORKMAZ H.Evaluation of in-vitro antioxidant properties of hydroalcoholic solution extracts Urtica dioica L.,Malva neglecta Wallr.and their mixture[J].Iranian Journal of Pharmaceutical Research:IJPR,2012,11(3):913.
[2]ZHONG Hanyi,QIU Zhengsong,HUANG Weian,et al.Poly(oxypropylene)-amidoamine modified bentonite as potential shale inhibitor in water-based drilling fluids[J].Applied Clay Science,2012,67/68:36-43.
[3]SERRA O.Fundamentals of well-log interpretation[M].Amsterdam:Elsevier,1984.
[4]ZHONG Hanyi,QIU Zhengsong,HUANG Weian,et al.Shale inhibitive properties of polyether diamine in water-based drilling fluid[J].Journal of Petroleum Science and Engineering,2011,78(2):510-515.
[5]ZHONG H Y,QIU Z S,HUANG W A,et al.The development and application of a novel polyamine water-based drilling fluid[J].Petroleum Science and Technology,2014,32(4):497-504.
[6]WANG Lei,LIU Shangying,WANG Tian,et al.Effect of poly(oxypropylene)diamine adsorption on hydration and dispersion of montmorillonite particles in aqueous solution[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2011,381(1):41-47.
[7]CHESSER B G.Design considerations for an inhibitive,stable water-based mud system[R].SPE 14757,1987.
[8]ZHONG Hanyi,QIU Zhengsong,HUANG Weian,et al.Bis(hexamethylene)triamine as potential shale inhibitor in water-based drilling fluid[J].Open Petroleum Engineering Journal,2013,6(1):49-56.
[9]XUAN Yang,JIANG Guancheng,LI Yingying,et al.Inhibiting effect of dopamine adsorption and polymerization on hydrated swelling of montmorillonite[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,422:50-60.
[10]YILMAZ Semih,EKINCI Sernur,YILMAZ Bilal.Determination of bioactive compounds of equistum arvense by gas chromatography-mass spectrometry method[J].International Journal of Pharmacognosy,2014,1(3):184-188.
[11]SANDHU N S,KAUR S,CHOPRA D.Equisetum arvense:Pharmacology and phytochemistry:A review[J].Asian J Pharm Clin Res,2010,3(3):146-150.
[12]American Petroleum Institute.Recommended practice standard procedure for laboratory testing of drilling fluids:API Specifications13I[S].Dallas:American Petroleum Institute,2000.
[13]RAZI M M,RAZI F M.An experimental study of influence of salt concentration,mixing time,and p H on the rheological properties of pre-hydrated bentonite slurries treated by polymers[J].Journal of Dispersion Science and Technology,2013,34(6):764-770.
[14]American Petroleum Institute.Recommended practice on the rheology and hydraulics of oil-well drilling fluids:API Specifications13D[S].Dallas:American Petroleum Institute,1995.
[15]RAZI M M,MAZIDI M,RAZI F M,et al.Artificial neural network modeling of plastic viscosity,yield point,and apparent viscosity for water-based drilling fluids[J].Journal of Dispersion Science and Technology,2013,34(6):822-827.
[16]AHMADI M A,SHADIZADEH S R.Experimental investigation of adsorption of a new nonionic surfactant on carbonate minerals[J].Fuel,2013,104:462-467.
[17]AATON M S,ELLIOTT G P.Water-based glycol drilling muds:Shale inhibition mechanisms[R].SPE 28818,2007.
[18]Ava Drilling Fluids&Services.Drilling fluid manual[M]Rome:Ava Drilling Fluids&Services,2004.
[19]ROEHL E A,HACKETT J L.A laboratory technique for screening shale swelling inhibitors[R].SPE 11117,1982.
[20]EWY R T,MORTON E K.Wellbore-stability performance of water-based mud additives[R].SPE 116139,2009.
[21]LIU Shangying,MO Xiaogang,ZHANG Chunguang,et al.Swelling inhibition by polyglycols in montmorillonite dispersions[J].Journal of Dispersion Science and Technology,2004,25(1):63-66.
[22]DE SOUZA C E C,LIMA A S,NASCIMENTO R S V.Hydrophobically modified poly(ethylene glycol)as reactive clays inhibitor additive in water-based drilling fluids[J].Journal of Applied Polymer Science,2010,117(2):857-864.
[23]李建成,杨鹏,关键,等.新型全油基钻井液体系[J].石油勘探与开发,2014,41(4):490-496.LI Jiancheng,YANG Peng,GUAN Jian,et al.A new type of whole oil-based drilling fluid[J].Petroleum Exploration and Development,2014,41(4):490-496.
[24]?ANADANOVI?-BRUNET J M,?ETKOVI?G S,DJILAS S M,et al.Radical scavenging and antimicrobial activity of horsetail(Equisetum arvense L.)extracts[J].International Journal of Food Science&Technology,2009,44(2):269-278.
[25]MIMICA-DUKIC N,SIMIN N,CVEJIC J,et al.Phenolic compounds in field horsetail(Equisetum arvense L.)as natural antioxidants[J].Molecules,2008,13(7):1455-1464.
[26]MILOVANOVI?V,RADULOVI?N,TODOROVI?Z,et al.Antioxidant,antimicrobial and genotoxicity screening of hydro-alcoholic extracts of five Serbian Equisetum species[J].Plant Foods for Human Nutrition,2007,62(3):113-119.
[27]DANIELSKI L,MICHIELIN E M Z,FERREIRA S R S.Horsetail(Equisetum giganteum L.)oleoresin and supercritical CO2:Experimental solubility and empirical data correlation[J].Journal of Food Engineering,2007,78(3):1054-1059.
[28]HEIM K E,TAGLIAFERRO A R,BOBILYA D J.Flavonoid antioxidants:chemistry,metabolism and structure-activity relationships[J].The Journal of nutritional biochemistry,2002,13(10):572-584.
[29]HARBORNE J B,WILLIAMS C A.Advances in flavonoid research since 1992[J].Phytochemistry,2000,55(6):481-504.
[30]GüDER A,KORKMAZ H.Evaluation of in-vitro antioxidant properties of hydroalcoholic solution extracts Urtica dioica L.,Malva neglecta Wallr.and their mixture[J].Iranian Journal of Pharmaceutical Research:IJPR,2012,11(3):913.