无机纳米粒子协同无卤阻燃聚丙烯的研究进展
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摘要
卤系阻燃剂对生态环境和人体健康有较大的危害,因此绿色环保的无卤阻燃剂得到了较为快速的发展。无卤阻燃剂主要包括无机阻燃剂、有机硅阻燃剂和无卤膨胀型阻燃剂等。用于聚丙烯无卤阻燃的主要有铝、镁等无机金属化合物类阻燃剂,以及利用聚磷酸铵为主体复配而成的一类无卤膨胀型阻燃剂。卤系阻燃剂存在阻燃效果低、添加量大等缺陷,严重损害基体的力学性能,而添加某些无机纳米粒子可在一定程度上提升其阻燃效果。本文围绕无机纳米粒子与聚丙烯这两大类阻燃剂的阻燃协同效应,概述了改善无机纳米粒子与聚丙烯基体分散性的表面改性方法,并阐述了无机纳米粒子协同阻燃聚丙烯的机理与发展现状。主要介绍了蒙脱土、海泡石、碳基填料等无机纳米粒子协同聚丙烯无卤阻燃复合材料的研究进展,并展望了无机纳米粒子无卤阻燃剂填充改性阻燃聚丙烯的发展趋势。
The use of halogen-based flame retardants has caused great damage to the ecological environment and human health,so the green halogen-free flame retardant has developed rapidly. Halogen-free flame retardants mainly include inorganic flame retardants,silicone flame retardants and halogen-free intumescent flame retardants. The halogen-free flame retardant for polypropylene mainly includes inorganic metal compound flame retardants such as aluminum and magnesium,and a type of halogen-free intumescent flame retardant which is compounded by ammonium polyphosphate. However,the flame retardant effect of the halogen-based flame retardant is low,and the addition amount and the like seriously impair the mechanical properties of the matrix. The addition of certain inorganic nanoparticles can enhance the flame retardant effect to some extent.This paper summarizes the improvement of the dispersion of inorganic nanoparticles and polypropylene matrix by the flame retardant synergistic effect of inorganic nanoparticles and polypropylene. The surface modification method and the synergistic mechanism and development status of the inorganic nanoparticle flame retardant polypropylene. It mainly introduces the non-halogen flame retardant of inorganic nanoparticle synergistic polypropylene such as montmorillonite,sepiolite,and carbon-based filler. The research progress of composite materials and the development trend of inorganic nanoparticle halogen-free flame retardant filled modified flame retardant polypropylene.
The use of halogen-based flame retardants has caused great damage to the ecological environment and human health,so the green halogen-free flame retardant has developed rapidly. Halogen-free flame retardants mainly include inorganic flame retardants,silicone flame retardants and halogen-free intumescent flame retardants. The halogen-free flame retardant for polypropylene mainly includes inorganic metal compound flame retardants such as aluminum and magnesium,and a type of halogen-free intumescent flame retardant which is compounded by ammonium polyphosphate. However,the flame retardant effect of the halogen-based flame retardant is low,and the addition amount and the like seriously impair the mechanical properties of the matrix. The addition of certain inorganic nanoparticles can enhance the flame retardant effect to some extent.This paper summarizes the improvement of the dispersion of inorganic nanoparticles and polypropylene matrix by the flame retardant synergistic effect of inorganic nanoparticles and polypropylene. The surface modification method and the synergistic mechanism and development status of the inorganic nanoparticle flame retardant polypropylene. It mainly introduces the non-halogen flame retardant of inorganic nanoparticle synergistic polypropylene such as montmorillonite,sepiolite,and carbon-based filler. The research progress of composite materials and the development trend of inorganic nanoparticle halogen-free flame retardant filled modified flame retardant polypropylene.
引文
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4 Bai C,Liu M.Angewandte Chemie International Edition,2013,52(10),2678.
5 Kango S,Kalia S,Celli A,et al.Progress in Polymer Science,2013,38(8),1232.
6 Mallakpour S,Khadem E.Progress in Polymer Science,2015,51,74.
7 孟庆捷.河南化工,2017,34(4),11.
8 Wang H,Shi X,Zhao S.Journal of Macromolecular Science Part B,2014,53(5),769.
9 Sheng Y,Li P,Chen Y.Advances in Polymer Technology,2014,33(S1),1.
10 于娜娜,陈东方,秦兵杰,等.精细与专用化学品,2013,21(1),51.
11 虞鑫海,吴冯.绝缘材料,2014(4),6.
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13 刘国胜.协同膨胀阻燃聚丙烯研究,博士学位论文.北京理工大学,2014.
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19 Younis A A.Egyptian Journal of Petroleum,2016,26(1),1.
20 Navarchian A H,Joulazadeh M,Mousazadeh S.Journal of Vinyl & Additive Technology,2013,19(4),276.
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22 Kooshki R M,Ghasemi I,Karrabi M,et al.Journal of Vinyl & Additive Technology,2013,19(3),203.
23 Zhu H ,Li J ,Zhu Y ,et al.Polymers for Advanced Technologies,2014,25(8),872.
24 Tian Qin,Qin Shuhao,Wu Fuzhong,et al.Journal of Thermoplastic Composite Materials,2017,30(3),341.
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26 白卯娟,金杨,王勇,等.现代塑料加工应用,2015,27(1),60.
27 郭义,申明霞,韩永芹.粘接,2015(2),73.
28 Xiao D,Li Z,Zhao X,et al.Applied Clay Science,2017,143,192.
29 Liu H,Zhong Q,Kong Q,et al.Journal of Thermal Analysis & Calorimetry,2014,117(2),693.
30 郭妍婷,黄雪,陈曼,等.化工新型材料,2017(3),37.
31 王明义,韩强,纪莲清,等.广东化工,2016,43(6),3.
32 Jin J ,Wang H ,Shu Z ,et al.Journal of Materials Science,2017,52(6),3269.
33 Qinghong Kong,Ting Wu,Hongkai Zhang,et al.Applied Clay Science,2017,146,230.
34 Wen P,Wang D,Liu J J,et al.Polymers for Advanced Technologies,2016,28(6),1.
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42 He M,Cao W C,Wang L J,et al.Polymers for Advanced Technologies,2013,24(12),1081.
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46 Huang G,Wang S,Song P A,et al.Composites Part A Applied Science and Manufacturing,2014,59(2),18.