二维材料调控阻氢涂层研究进展
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摘要
在涉氢应用领域,氢及其同位素的渗透导致结构材料氢损伤、能源浪费及核污染等诸多问题,在结构材料表面覆盖阻氢涂层是解决氢渗透问题的重要技术手段。总结了传统阻氢涂层的特性及其阻氢效果,并阐明了传统阻氢涂层仍然存在的效率低及寿命短等问题。最新研究表明,石墨烯等二维材料薄膜具有很强的阻挡特性,多层堆垛结构效果尤其明显,可作为优异的阻氢材料,而传统阻氢涂层兼具有一定的吸附储氢性能。通过对氢渗透机理的分析提出引入二维材料作为阻氢层,并结合传统阻氢涂层的储氢特性构建新型阻氢结构模型,阐述了阻氢层的制备应用现状及储氢层的储氢机理,同时探讨了针对不同应用背景下新型阻氢结构的不同形式与应用效果,最后展望了新型阻氢结构涂层在不同应用领域下的应用前景。
The permeation of hydrogen and its isotope lead to many problems in hydrogen related field,such as hydrogen damage of structural materials,energy waste and environmental pollution etc.Hydrogen permeation barriers prepared on structural materials has become the most promising techniques to prevent the hydrogen penetration.In this paper,the properties of various types of conventional coatings are summarized,furthermore,the existing issues of low efficiency and short lifetime are expounded.Latest research show that two-dimensional(2D)materials membranes,such as grapheme,possess strong impermeability,especially in multi-layer stacking structures,while the conventional coatings also possess definite property of hydrogen adsorption storage.By the analyze of hydrogen penetrate mechanism,the novel hydrogen permeation barrier structure model is proposed,which suggests2 D materials as hydrogen barrier layer combined with the hydrogen storage character of the conventional coatings,the present preparation and application status of the hydrogen barrier layers together with the storage mechanism of the hydrogen storage layers are elucidated,and the application effects of different structure styles for various environments are discussed simultaneously.Finally,the potential applications of the novel structure of hydrogen barriers are prospected.
The permeation of hydrogen and its isotope lead to many problems in hydrogen related field,such as hydrogen damage of structural materials,energy waste and environmental pollution etc.Hydrogen permeation barriers prepared on structural materials has become the most promising techniques to prevent the hydrogen penetration.In this paper,the properties of various types of conventional coatings are summarized,furthermore,the existing issues of low efficiency and short lifetime are expounded.Latest research show that two-dimensional(2D)materials membranes,such as grapheme,possess strong impermeability,especially in multi-layer stacking structures,while the conventional coatings also possess definite property of hydrogen adsorption storage.By the analyze of hydrogen penetrate mechanism,the novel hydrogen permeation barrier structure model is proposed,which suggests2 D materials as hydrogen barrier layer combined with the hydrogen storage character of the conventional coatings,the present preparation and application status of the hydrogen barrier layers together with the storage mechanism of the hydrogen storage layers are elucidated,and the application effects of different structure styles for various environments are discussed simultaneously.Finally,the potential applications of the novel structure of hydrogen barriers are prospected.
引文
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[10]WANG P,LIU J,WANG J,et al.Investigation of SiC films deposited onto stainless steel and their retarding effects on tritium permeation interaction of hydrogen plasma with SiC/SiC composite[J].Surface and Coating Technology,2000,128/129:99-104.
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[12]CHIKADA T,SUZUKI A,TERAI T.Deuterium permeation and thermal behaviors of amorphous silicon carbide coatings on steels[J].Fusion Engineering and Design,2011,86:2192-2195.
[13]NEMANIC V,MCGUINESS P,DANEU N,et al.Hydrogen permeation through silicon nitride films[J].Journal of Alloys and Compounds,2012,539:184-189.
[14]ZHANG R Q,LIU Y G,HUANG N K.Effects of hydrogen ion implantation on TiC-C coating of stainless steel[J].Journal of Iron&Steel Research International,2008,15(4):77-81.
[15]CHIKADA T,NAITOH S,SUZUKI A,et al.Deuterium permeation through erbium oxide coatings on RAFM steels by a dip-coating technique[J].Journal of Nuclear Materials,2013,442:533-537.
[16]SUBANOVIC M,NAUMENKO D,KAMRUDDIN M,et al.Blistering of MCrAlY-coatings in H2/H2Oatmospheres[J].Corrosion Science,2009,51(3):446-450.
[17]XIE D G,WANG Z G,SUN J,et al.In situ study of the initiation of hydrogen bubbles at the aluminium metal/oxide interface[J].Nature Materials,2015,14(9):899-903.
[18]PRICE H,FORRISTALL R,WENDELIN T,et al.Field survey of parabolic trough receiver thermal performance[C]∥Proceedings of the ASME International Solar Energy Conference.Denver,2006:109-116.
[19]http://www.spaceman.com.cn/i.php?id=156.
[20]http://www.cspplaza.com/article-2513-1.html.
[21]NAIR R R,BLAKE P,GRIGORENKO A N,et al.Fine structure constant defines visual transparency of graphene[J].Science,2008,320(5881):1308.
[22]BALANDIN A A,GHOSH S,BAO W,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[23]LEE C,WEI X D,KYSAR J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[24]MIAO M,NARDELLI M B,WANG Q,et al.First principles study of the permeability of graphene to hydrogen atoms[J].Chysical Chemistry Chemical Physics,2013,15(38):16132-16137.
[25]BUNCH J S,VERBRIDGE S S,ALDEN J S,et al.Impermeable atomic membranes from graphene sheets[J].Nano Letters,2008,8(8):2458-2462.
[26]TSETSERIS L,PANTELIDES S T.Graphene:an impermeable or selectively permeable membrane for atomic species?[J].Carbon,2014,67:58-63.
[27]NOVOSELOV K S,JIANG D,SCHEDIN F,et al.Twodimensional atomic crystals[J].Proc.Natl.Acad.Sci.,2005,102(30):10451-10453.
[28]GEIM A K,GRIGORIEVA I V.Van der Waals heterostructures[J].Nature,2013,499(25):419-425.
[29]MIURA Y,KASAI H,DINO W A,et al.Effective pathway for hydrogen atom adsorption on graphene[J].Journal of the Physical Society of Japan,2003,72(5):995-997.
[30]VIKAS B.Impermeability of graphene and its applications[J].Carbon,2013,62:1-10.
[31]HU S.Proton transport through two-dimensional materials[D].Manchester:University of Manchester,2014.
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[33]SEEL M,PANDEY R.Proton and hydrogen transport through two-dimensional monolayers[J].2D Materials,2016,3(2):025004.
[34]ACHTYL J L,UNOCIC R R,XU L J,et al.Aqueous proton transfer across single-layer graphene[J].Nature Communications,2015,6:6539.
[35]LOZADA-HIDALGO M,HU S,MARSHALL O,et al.Sieving hydrogen isotopes through two-dimensional crystals[J].Science,2016,351(6268):68-70.
[36]CELEBI K,BUCHHEIM J,WYSS R M,et al.Ultimate permeation across atomically thin porous graphene[J].Science,2014,344(6181):289-292.
[37]O’HERN S C,JANG D,BOSE S,et al.Nanofiltration across defect-sealed nanoporous monolayer graphene[J].Nano Letters,2015,15(5):3254-3260.
[38]BOUTILIER MICHAEL S H,SUN C Z,O’HERN S C,et al.Implications of permeation through intrinsic defects in graphene on the design of defect-tolerant membranes for gas separation[J].ACS Nano,2014,8(1):841-849.
[39]YANG X W,QIU L,CHENG C,et al.Ordered gelation of chemically converted graphene for next-generation electroconductive hydrogel films[J].Angewandte ChemieInternational Edition,2011,50(32):7325-7328.
[40]YANG X,CHENG C,WANG Y,et al.Liquid-mediated dense integration of graphene materials for compact capacitive energy storage[J].Science,2013,341(6145):534-537.
[41]宋文海,杜家驹.陶瓷-金属复合体系氢同位素渗透模型[J].核聚变与等离子体物理,1998,18(3):9-16.SONG W H,DU J J.A model for hydrogen isotope permeation through metals with ceramic film barriers[J].Nuclear Fusion and Plasma Physics,1998,18(3):9-16.
[42]李勇峰.氢在钢中的渗透特性及镀层阻氢渗透机理的研究[D].上海:华东理工大学,2012.LI Y F.Research on hydrogen permeation characteristic in steels and hydrogen permeation resistance mechanism of plating[D].Shanghai:East China University of Science and Technology,2012.
[43]GU P C,ZHANG K L,FENG Y L,et al.Recent progress of two-dimensional layered molybdenum disulfide[J].Acta Physica Sinica,2016,65(1):018102.
[44]KIRKLAND N T,SCHILLER T,MEDHEKAR N,et al.Exploring graphene as a corrosion protection barrier[J].Corros.Sci.,2012,56:1-4.
[45]LEENAERTS O,PARTOENS B,PEETERS F M.Graphene:a perfect nanoballoon[J].Applied Physics Letters,2008,93(19):193107.
[46]GEORGIOU T,BRITNELL L,BLAKE P,et al.Graphene bubbles with controllable curvature[J].Appl.Phys.Lett.,2011,99(9):093103.
[47]JOHN R.ASHOKREDDY A,VIJAYAN C,et al.Singleand few-layer graphene growth on stainless steel substrates by direct thermal chemical vapor deposition[J].Nanotechnology,2011,22(16):165701.
[48]YUAN G D,ZHANG W J,YANG Y,et al.Graphene sheets via microwave chemical vapor deposition[J].Chem.Phys.Lett.,2009,467(4):361-364.
[49]LI X S,ZHU Y W,CAI W W,et al.Transfer of large-area graphene films for high-performance transparent conductive electrodes[J].Nano Letters,2009,9(12):4259-4363.
[50]HU B,AGO H,ITO Y,et al.Epitaxial growth of largearea single-layer graphene over Cu(111)/sapphire by atmospheric pressure CVD[J].Carbon,2012,50:57-65.
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