生物质模板剂制备介孔材料研究进展
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摘要
介孔材料的制备通常采用模板法,所用模板剂多为石油衍生的表面活性剂,属于不可再生资源,这种模板剂的使用不符合可持续发展的理念。生物质模板剂具有原料来源广、毒性低、绿色环保等优点,因此受到了研究人员的广泛关注。本文综述了近年来国内外利用生物质模板剂制备介孔材料的研究进展,阐述了脂肪酸及其衍生物、氨基酸类、糖类、脂类等生物质衍生物作为模板剂应用于介孔材料制备的现状,其中糖类作为模板剂用于介孔材料的制备研究较多,简要介绍了利用不同种类生物质模板剂制备介孔材料的条件以及生物质模板剂的去除方法,得出生物质模板剂制备介孔材料操作简单、模板剂容易去除的结论,同时列表总结了所得介孔材料的结构及性质特点和应用情况,并对该领域的研究方向进行了展望。指出采用低成本的方法提纯生物质模板剂,绿色的方法去除生物质模板剂以及构建生物质模板剂的结构、组成与介孔材料的结构、性质之间的对应关系是未来发展的主要方向。
Mesoporous materials are usually prepared with the petroleum derived surfactants as templates,which are non-renewable resources;the adoption of these templates does not match the concept of sustainable development. The biomass templates have been extensively investigated owing to its wide availability of raw materials,low toxicity,environmental friendlines,and other advantages. This work reviewed the recent research progresses in synthesizing the mesoporous materials with biomass templates,such as fatty acids and their derivatives,amino acids,sugars,lipids and so on. The studies on the application of sugars as template in the preparation of mesoporous materials were more than other biomass templates. The conditions of preparing the mesoporous materials with different kinds of biomass templates and the removal methods of biomass templates were briefly introduced. It was concluded that the operations of synthesizing the mesoporous materials with biomass templates were simple and the biomass templates could be easily removed. At the same time,the characteristics of structures and properties of mesoporous material obtained and their applications were summarized. It was pointed out that the purification of the biomass template at the low cost,the green method to remove the biomass templates,and more studies on the relationship between the structure and composition of biomass templates and the structure and properties of mesoporous materials are the main directions of future development.
Mesoporous materials are usually prepared with the petroleum derived surfactants as templates,which are non-renewable resources;the adoption of these templates does not match the concept of sustainable development. The biomass templates have been extensively investigated owing to its wide availability of raw materials,low toxicity,environmental friendlines,and other advantages. This work reviewed the recent research progresses in synthesizing the mesoporous materials with biomass templates,such as fatty acids and their derivatives,amino acids,sugars,lipids and so on. The studies on the application of sugars as template in the preparation of mesoporous materials were more than other biomass templates. The conditions of preparing the mesoporous materials with different kinds of biomass templates and the removal methods of biomass templates were briefly introduced. It was concluded that the operations of synthesizing the mesoporous materials with biomass templates were simple and the biomass templates could be easily removed. At the same time,the characteristics of structures and properties of mesoporous material obtained and their applications were summarized. It was pointed out that the purification of the biomass template at the low cost,the green method to remove the biomass templates,and more studies on the relationship between the structure and composition of biomass templates and the structure and properties of mesoporous materials are the main directions of future development.
引文
[1]PING E W,WALLACE R,PIERSON J,et al.Highly dispersed palladium nanoparticles on ultra-porous silica mesocellular foam for the catalytic decarboxylation of stearic acid[J].Microporous and Mesoporous Materials,2010,132(1):174-180.
[2]GUPTA G,PATEL M N,FERRER D,et al.Stable ordered Fe Pt mesoporous silica catalysts with high loadings[J].Chemistry of Materials,2015,15(20):5005-5015.
[3]PEI S T,LIN H Y,RUI C O,et al.Carbon molecular sieve membranes for biofuel separation[J].Carbon,2011,2(49):369-375.
[4]HEYDARIGORJI A,BELMABKHOUT Y,SAYARI A.Polyethylenimine-impregnated mesoporous silica:effect of amine loading and surface alkyl chains on CO2 adsorption[J].Langmuir,2011,27(20):12411-12416.
[5]CROISSANT J G,QI C,MONGIN O,et al.Disulfide-gated mesoporous silica nanoparticles designed for two-photon-triggered drug release and imaging[J].Journal of Materials Chemistry B,2015,31(3):6456-6461.
[6]KRESGE C T,LEONOWICZ M E,ROTH W J,et al.Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J].Nature,1992,6397(359):710-712.
[7]BECK J S,VARTULI J C,SCHMITT K D,et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates[J].Journal of the American Chemical Society,1992,114(27):10834-10843.
[8]田军,乔秀丽,迟彩霞,等.介孔材料制备中模板剂脱除的研究进展[J].化学世界,2013,54(1):59-62.TIAN J,QIAO X L,CHI C X,et al.Progress of template removal methods in synthesis of mesoporous material[J].Chemical World,2013,54(1):59-62.
[9]TIAN B,LUI X,YU C,et al.Microwave assisted template removal of siliceous porous materials[J].Chemical Communications,2002,11(11):1186-1187.
[10]SOTIROPOULOU S,SIERRASASTRE Y,MARK S S,et al.Biotemplated nanostructured materials[J].Chemistry of Materials,2008,20(3):821-834.
[11]GALLOWAY J M,STANILAND S S.Protein and peptide biotemplated metal and metal oxide nanoparticles and their patterning onto surfaces[J].Journal of Materials Chemistry,2012,22(25):12423-12434.
[12]南海明,蔡强,孙乾耀,等.不饱和脂肪酸为模板制备高水热稳定性介孔材料[C]//第29届中国洗涤用品行业年会.上海,2009:129-131NAN H M,CAI Q,SUN Q Y,et al.Preparation of high hydrothermal stability mesoporous materials by using unsaturated fatty acids as template[C]//The 29th Anuual Meeting of China Surfactant Soap and Detergent Industries.Shanghai,2009:129-131.
[13]CANLAS C P,PINNAVAIA T J.Bio-derived oleyl surfactants as porogens for the sustainable synthesis of micelle-templated mesoporous silica[J].RSC Advances,2012,2(19):7449-7455.
[14]THOMAS B,BACCILE N,MASSE S,et al.Mesostructured silica from amino acid-based surfactant formulations and sodium silicate at neutral p H[J].Journal of Sol-Gel Science and Technology,2011,58(1):170-174.
[15]蔡琳.阴离子氨基酸表面活性剂调控介孔硅材料的合成及应用[D].大连:大连理工大学,2010.CAI L.The synthesis and application of mesoporous silica meterial by anionic amino acid surfactant[D].Dalian:Dalian University of Technology,2010.
[16]YANG Y,HUANG Z,DENG W,et al.Synthesis of mesoporous silica templated by sodium N-dodecyl glycine[J].Microporous Mesoporous Materials,2008,116(1/2/3):267-276.
[17]XIANG W D,YANG Y X,CHEN J,et al.Preparation of mesoporous silica using amphoteric surfactant potassium and sodium N-dodecyl glycine template[J].Journal of the American Ceramic Society,2008,91(5):1517-1521.
[18]陈馥,庞敏,吴柯颖,等.C10~C14烷基糖苷的合成及其作为乳化剂的应用[J].化工进展,2015,34(7):1998-2002.CHEN F,PANG M,WU K Y,et al.Synthesis of C10—C14 alkyl polyglycoside and their application as emulsifiers[J].Chemical Industry and Engineering Progress,2015,34(7):1998-2002.
[19]?TANGAR U L,HüSING N.Alkyl-glycoside surfactants in the synthesis of mesoporous silica films[J].Silicon Chemistry,2003,2(3/4):157-165.
[20]BOTELLA P,CORMA A,QUESADA M.Synthesis of ordered mesoporous silica templated with biocompatible surfactants and applications in controlled release of drugs[J].Journal of Materials Chemistry,2012,22(13):6394-6401.
[21]WANG H,YIN X,LONG Y,et al.Discussion on one step synthesis of mesoporous carbon materials[J].Experimental Technology&Management,2014,31(6):47-50.
[22]KONG A G,WANG H W,HE Z,et al.Cation alkyl polyglycoside for preparation of mesoporous silica and direct synthesis of mesoporous carbon[J].Materials Letters,2008,62(17):2973-2976.
[23]WITOON T,CHAREONPANICH M.Effect of acidity on the formation of silica-chitosan hybrid materials and thermal conductive property[J].Journal of Sol-Gel Science and Technology,2009,51(2):146-152.
[24]EL K A,BOUSMINA M.Chitosan bio-based organic-inorganic hybrid aerogel microspheres[J].Chemistry:A European Journal,2012,18(27):8264-8277.
[25]ALONSO B,BELAMIE E.Chitin-silica nanocomposites by self-assembly[J].Angewandte Chemie(International Edition),2010,49(44):8201-8204.
[26]MOON R J,MARTINI A,NAIRN J,et al.Cellulose nanomaterials review:structure,properties and nanocomposites[J].Chemical Society Reviews,2011,40(7):3941-3994.
[27]康宏亮,刘瑞刚,黄勇.纤维素基功能材料的研究进展[J].高分子通报,2016(9):87-98.KANG H L,LIU R G,HUANG Y.Research progress of cellulose-based functional materials[J].Chinese Polymer Bulletin,2016(9):87-98.
[28]CAI J,ZHANG L,ZHOU J,et al.Multifilament fibers based on dissolution of cellulose in Na OH/urea aqueous solution:structure and properties[J].Advanced Materials,2007,19(6):821-825.
[29]LUTERBACHER J S,RAND J M,ALONSO D M,et al.Nonenzymatic sugar production from biomass using biomass-derivedγ-valerolactone[J].Science,2014,6168(343):277-280.
[30]TINGAUT P,ZIMMERMANN T,SèBE G.Cellulose nanocrystals and microfibrillated cellulose as building blocks for the design of hierarchical functional materials[J].Journal of Materials Chemistry,2012,22(38):20105-20111.
[31]ZHANG L,YAN Z F,QIAO S Z,et al.Facile synthesis of stable mesoporous silica MCM-41 via a dual templating of CMC and CTAB[J].Journal of Molecular Catalysis,2008,22(4):315-319.
[32]ZHANG Z,YANG L,WANG Y,et al.Morphology controlling of micrometer-sized mesoporous silica spheres assisted by polymers of polyethylene glycol and methyl cellulose[J].Microporous and Mesoporous Materials,2008,115(3):447-453.
[33]DUJARDIN E,BLASEBY M,MANN S.Synthesis of mesoporous silica by sol-gel mineralisation of cellulose nanorod nematic suspensions[J].Journal of Materials Chemistry,2003,13(4):696-699.
[34]THOMAS A,ANTONIETTI M.Silica nanocasting of simple cellulose derivatives:towards chiral pore systems with long-range order and chiral optical coatings[J].Advanced Functional Materials,2003,13(10):763-766.
[35]BRINCHI L,COTANA F,FORTUNATI E,et al.Production of nanocrystalline cellulose from lignocellulosic biomass:technology and applications[J].Carbohydrate Polymers,2013,94(1):154-169.
[36]SHOPSOWITZ K E,QI H,HAMAD W Y,et al.Free-standing mesoporous silica films with tunable chiral nematic structures[J].Nature,2010,468(7322):422-425.
[37]ZHANG B,LI X,WU Q,et al.Synthesis of Ni/mesoporous ZSM-5for direct catalytic conversion of cellulose to hexitols:modulating the pore structure and acidic sites via a nanocrystalline cellulose template[J].Green Chemistry,2016,18(11):3315-3323.
[38]程传英.利用纤维素制备多级孔道TS-1[D].大连:大连理工大学,2013.CHENG C Y.Sythesie of hierarchical TS-1 using cellulose[D].Dalian:Dalian University of Technology,2013.
[39]陈孝云,陆东芳,陈彦,等.酸法纳米纤维素模板剂合成介孔Ti O2及光催化活性[J].无机化学学报,2013,29(3):528-536.CHEN X Y,LU D F,CHEN Y,et al.Synthesis and photocatalytic activity of mesoporous Ti O2 using nano-cellulose template prepared by acid method[J].Chinese Journal of Inorganic Chemistry,2013,29(3):528-536.
[40]SLEIMAN J N,KOHLHOFF S A,ROBLIN P M,et al.Sophorolipids as antibacterial agents[J].Annals of Clinical&Laboratory Science,2009,39(1):60-63.
[41]KASTURE M,SINGH S,PATEL P,et al.Multiutility sophorolipids as nanoparticle capping agents:synthesis of stable and water dispersible Co nanoparticles[J].Langmuir,2007,23(23):11409-11412.
[42]DESAI J D,BANAT I B.Microbial production of surfactants and their commercial potential[J].Microbiology and Molecular Biology Reviews,1997,61(1):47-64.
[43]BACCILE N,NASSIF N,MALFATTI L,et al.Sophorolipids:a yeast-derived glycolipid as greener structure directing agents for self-assembled nanomaterials[J].Green Chemistry,2010,12(9):1564-1567.
[44]THOMAS B,BABONNEAU F,CORADIN T,et al.One-step introduction of broad-band mesoporosity in silica particles using a stimuli-responsive bioderived glycolipid[J].ACS Sustainable Chemistry&Engineering,2013,2(3):512-522.
[45]DHASAIYAN P,LE G P,ROELANTS S,et al.Micelles versus ribbons:how congeners drive the self-assembly of acidic sophorolipid biosurfactants[J].Chemphyschem,2017,18(6):643-652.
[46]DUNPHY D R,ALAM T M,TATE M P,et al.Characterization of lipid-templated silica and hybrid thin film mesophases by grazing incidence small-angle X-ray scattering[J].Langmuir Article,2009,25(16):9500-9509.
[47]GALARNEAU A,RENARD G,MURESEANU M,et al.Synthesis of sponge mesoporous silicas from lecithin/dodecylamine mixed-micelles in ethanol/water media:a route towards efficient biocatalysts[J].Microporous and Mesoporous Materials,2007,104(1):103-114.
[2]GUPTA G,PATEL M N,FERRER D,et al.Stable ordered Fe Pt mesoporous silica catalysts with high loadings[J].Chemistry of Materials,2015,15(20):5005-5015.
[3]PEI S T,LIN H Y,RUI C O,et al.Carbon molecular sieve membranes for biofuel separation[J].Carbon,2011,2(49):369-375.
[4]HEYDARIGORJI A,BELMABKHOUT Y,SAYARI A.Polyethylenimine-impregnated mesoporous silica:effect of amine loading and surface alkyl chains on CO2 adsorption[J].Langmuir,2011,27(20):12411-12416.
[5]CROISSANT J G,QI C,MONGIN O,et al.Disulfide-gated mesoporous silica nanoparticles designed for two-photon-triggered drug release and imaging[J].Journal of Materials Chemistry B,2015,31(3):6456-6461.
[6]KRESGE C T,LEONOWICZ M E,ROTH W J,et al.Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J].Nature,1992,6397(359):710-712.
[7]BECK J S,VARTULI J C,SCHMITT K D,et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates[J].Journal of the American Chemical Society,1992,114(27):10834-10843.
[8]田军,乔秀丽,迟彩霞,等.介孔材料制备中模板剂脱除的研究进展[J].化学世界,2013,54(1):59-62.TIAN J,QIAO X L,CHI C X,et al.Progress of template removal methods in synthesis of mesoporous material[J].Chemical World,2013,54(1):59-62.
[9]TIAN B,LUI X,YU C,et al.Microwave assisted template removal of siliceous porous materials[J].Chemical Communications,2002,11(11):1186-1187.
[10]SOTIROPOULOU S,SIERRASASTRE Y,MARK S S,et al.Biotemplated nanostructured materials[J].Chemistry of Materials,2008,20(3):821-834.
[11]GALLOWAY J M,STANILAND S S.Protein and peptide biotemplated metal and metal oxide nanoparticles and their patterning onto surfaces[J].Journal of Materials Chemistry,2012,22(25):12423-12434.
[12]南海明,蔡强,孙乾耀,等.不饱和脂肪酸为模板制备高水热稳定性介孔材料[C]//第29届中国洗涤用品行业年会.上海,2009:129-131NAN H M,CAI Q,SUN Q Y,et al.Preparation of high hydrothermal stability mesoporous materials by using unsaturated fatty acids as template[C]//The 29th Anuual Meeting of China Surfactant Soap and Detergent Industries.Shanghai,2009:129-131.
[13]CANLAS C P,PINNAVAIA T J.Bio-derived oleyl surfactants as porogens for the sustainable synthesis of micelle-templated mesoporous silica[J].RSC Advances,2012,2(19):7449-7455.
[14]THOMAS B,BACCILE N,MASSE S,et al.Mesostructured silica from amino acid-based surfactant formulations and sodium silicate at neutral p H[J].Journal of Sol-Gel Science and Technology,2011,58(1):170-174.
[15]蔡琳.阴离子氨基酸表面活性剂调控介孔硅材料的合成及应用[D].大连:大连理工大学,2010.CAI L.The synthesis and application of mesoporous silica meterial by anionic amino acid surfactant[D].Dalian:Dalian University of Technology,2010.
[16]YANG Y,HUANG Z,DENG W,et al.Synthesis of mesoporous silica templated by sodium N-dodecyl glycine[J].Microporous Mesoporous Materials,2008,116(1/2/3):267-276.
[17]XIANG W D,YANG Y X,CHEN J,et al.Preparation of mesoporous silica using amphoteric surfactant potassium and sodium N-dodecyl glycine template[J].Journal of the American Ceramic Society,2008,91(5):1517-1521.
[18]陈馥,庞敏,吴柯颖,等.C10~C14烷基糖苷的合成及其作为乳化剂的应用[J].化工进展,2015,34(7):1998-2002.CHEN F,PANG M,WU K Y,et al.Synthesis of C10—C14 alkyl polyglycoside and their application as emulsifiers[J].Chemical Industry and Engineering Progress,2015,34(7):1998-2002.
[19]?TANGAR U L,HüSING N.Alkyl-glycoside surfactants in the synthesis of mesoporous silica films[J].Silicon Chemistry,2003,2(3/4):157-165.
[20]BOTELLA P,CORMA A,QUESADA M.Synthesis of ordered mesoporous silica templated with biocompatible surfactants and applications in controlled release of drugs[J].Journal of Materials Chemistry,2012,22(13):6394-6401.
[21]WANG H,YIN X,LONG Y,et al.Discussion on one step synthesis of mesoporous carbon materials[J].Experimental Technology&Management,2014,31(6):47-50.
[22]KONG A G,WANG H W,HE Z,et al.Cation alkyl polyglycoside for preparation of mesoporous silica and direct synthesis of mesoporous carbon[J].Materials Letters,2008,62(17):2973-2976.
[23]WITOON T,CHAREONPANICH M.Effect of acidity on the formation of silica-chitosan hybrid materials and thermal conductive property[J].Journal of Sol-Gel Science and Technology,2009,51(2):146-152.
[24]EL K A,BOUSMINA M.Chitosan bio-based organic-inorganic hybrid aerogel microspheres[J].Chemistry:A European Journal,2012,18(27):8264-8277.
[25]ALONSO B,BELAMIE E.Chitin-silica nanocomposites by self-assembly[J].Angewandte Chemie(International Edition),2010,49(44):8201-8204.
[26]MOON R J,MARTINI A,NAIRN J,et al.Cellulose nanomaterials review:structure,properties and nanocomposites[J].Chemical Society Reviews,2011,40(7):3941-3994.
[27]康宏亮,刘瑞刚,黄勇.纤维素基功能材料的研究进展[J].高分子通报,2016(9):87-98.KANG H L,LIU R G,HUANG Y.Research progress of cellulose-based functional materials[J].Chinese Polymer Bulletin,2016(9):87-98.
[28]CAI J,ZHANG L,ZHOU J,et al.Multifilament fibers based on dissolution of cellulose in Na OH/urea aqueous solution:structure and properties[J].Advanced Materials,2007,19(6):821-825.
[29]LUTERBACHER J S,RAND J M,ALONSO D M,et al.Nonenzymatic sugar production from biomass using biomass-derivedγ-valerolactone[J].Science,2014,6168(343):277-280.
[30]TINGAUT P,ZIMMERMANN T,SèBE G.Cellulose nanocrystals and microfibrillated cellulose as building blocks for the design of hierarchical functional materials[J].Journal of Materials Chemistry,2012,22(38):20105-20111.
[31]ZHANG L,YAN Z F,QIAO S Z,et al.Facile synthesis of stable mesoporous silica MCM-41 via a dual templating of CMC and CTAB[J].Journal of Molecular Catalysis,2008,22(4):315-319.
[32]ZHANG Z,YANG L,WANG Y,et al.Morphology controlling of micrometer-sized mesoporous silica spheres assisted by polymers of polyethylene glycol and methyl cellulose[J].Microporous and Mesoporous Materials,2008,115(3):447-453.
[33]DUJARDIN E,BLASEBY M,MANN S.Synthesis of mesoporous silica by sol-gel mineralisation of cellulose nanorod nematic suspensions[J].Journal of Materials Chemistry,2003,13(4):696-699.
[34]THOMAS A,ANTONIETTI M.Silica nanocasting of simple cellulose derivatives:towards chiral pore systems with long-range order and chiral optical coatings[J].Advanced Functional Materials,2003,13(10):763-766.
[35]BRINCHI L,COTANA F,FORTUNATI E,et al.Production of nanocrystalline cellulose from lignocellulosic biomass:technology and applications[J].Carbohydrate Polymers,2013,94(1):154-169.
[36]SHOPSOWITZ K E,QI H,HAMAD W Y,et al.Free-standing mesoporous silica films with tunable chiral nematic structures[J].Nature,2010,468(7322):422-425.
[37]ZHANG B,LI X,WU Q,et al.Synthesis of Ni/mesoporous ZSM-5for direct catalytic conversion of cellulose to hexitols:modulating the pore structure and acidic sites via a nanocrystalline cellulose template[J].Green Chemistry,2016,18(11):3315-3323.
[38]程传英.利用纤维素制备多级孔道TS-1[D].大连:大连理工大学,2013.CHENG C Y.Sythesie of hierarchical TS-1 using cellulose[D].Dalian:Dalian University of Technology,2013.
[39]陈孝云,陆东芳,陈彦,等.酸法纳米纤维素模板剂合成介孔Ti O2及光催化活性[J].无机化学学报,2013,29(3):528-536.CHEN X Y,LU D F,CHEN Y,et al.Synthesis and photocatalytic activity of mesoporous Ti O2 using nano-cellulose template prepared by acid method[J].Chinese Journal of Inorganic Chemistry,2013,29(3):528-536.
[40]SLEIMAN J N,KOHLHOFF S A,ROBLIN P M,et al.Sophorolipids as antibacterial agents[J].Annals of Clinical&Laboratory Science,2009,39(1):60-63.
[41]KASTURE M,SINGH S,PATEL P,et al.Multiutility sophorolipids as nanoparticle capping agents:synthesis of stable and water dispersible Co nanoparticles[J].Langmuir,2007,23(23):11409-11412.
[42]DESAI J D,BANAT I B.Microbial production of surfactants and their commercial potential[J].Microbiology and Molecular Biology Reviews,1997,61(1):47-64.
[43]BACCILE N,NASSIF N,MALFATTI L,et al.Sophorolipids:a yeast-derived glycolipid as greener structure directing agents for self-assembled nanomaterials[J].Green Chemistry,2010,12(9):1564-1567.
[44]THOMAS B,BABONNEAU F,CORADIN T,et al.One-step introduction of broad-band mesoporosity in silica particles using a stimuli-responsive bioderived glycolipid[J].ACS Sustainable Chemistry&Engineering,2013,2(3):512-522.
[45]DHASAIYAN P,LE G P,ROELANTS S,et al.Micelles versus ribbons:how congeners drive the self-assembly of acidic sophorolipid biosurfactants[J].Chemphyschem,2017,18(6):643-652.
[46]DUNPHY D R,ALAM T M,TATE M P,et al.Characterization of lipid-templated silica and hybrid thin film mesophases by grazing incidence small-angle X-ray scattering[J].Langmuir Article,2009,25(16):9500-9509.
[47]GALARNEAU A,RENARD G,MURESEANU M,et al.Synthesis of sponge mesoporous silicas from lecithin/dodecylamine mixed-micelles in ethanol/water media:a route towards efficient biocatalysts[J].Microporous and Mesoporous Materials,2007,104(1):103-114.