生物降解塑料的发展现状及应用前景
|
摘要
综述了生物降解塑料的种类,对几种重要的生物降解塑料(如聚己内酯、聚丁二酸丁二酯、聚乳酸、聚羟基烷酸酯、脂肪-芳香共聚酯、聚乙烯醇、二氧化碳共聚物等)的研究及发展现状进行了详细的阐述。生物降解塑料对环境无污染或无二次污染,但价格较传统塑料高,高性能、功能化产品的研究尚未成熟,应用范围较窄,有待进一步开发。
Biodegradable plastics are environmentally-friendly materials. In this paper,the types and several important biodegradable plastics are described,including polycaprolactone,polybutylene succinate,polylactic acid,polyhydroxyalkanoate,aliphatic-aromatic copolyester,polyvinyl alcohol,carbon dioxide copolymer. It is pointed out that biodegradable plastics have broad prospects for development because of their unique biodegradability and their non-pollution or non-secondary pollution to the environment. However,because of the higher price and lower performance than traditional plastics,the application of biodegradable plastics is limited.
Biodegradable plastics are environmentally-friendly materials. In this paper,the types and several important biodegradable plastics are described,including polycaprolactone,polybutylene succinate,polylactic acid,polyhydroxyalkanoate,aliphatic-aromatic copolyester,polyvinyl alcohol,carbon dioxide copolymer. It is pointed out that biodegradable plastics have broad prospects for development because of their unique biodegradability and their non-pollution or non-secondary pollution to the environment. However,because of the higher price and lower performance than traditional plastics,the application of biodegradable plastics is limited.
引文
[1]Narayan R.Degradable Polymers and Materials:Principles and Practice[M].Washington:American Chemical Society,2012:13-31.
[2]周磊,唐脱险,魏嵬,等.完全生物降解塑料的研究进展[J].安徽农业科学,2012,40(13):7867-7871.
[3]Khemani K,Scholz C.Degradable Polymers and Materials:Principles and Practice[M].2nd ed.Washington:American Chemical Society,2012:3-10.
[4]高炜丽,李建科,赵燕.可生物降解淀粉塑料研究进展[J].广东化工,2007,34(7):52-55.
[5]张蓉,兰文婷,邹倩,等.淀粉及纤维素基可降解塑料研究进展[J].塑料工业,2017,45(12):1-5.
[6]徐心昱.全生物降解塑料的类型与研究成果分析[J].科技展望,2016(23):287.
[7]Okada M.Chemical synthesis of biodegradable polymers[J].Prog Polym Sci,2002,27(1):87-133.
[8]卞士祥,王闻,周桂雄,等.生物合成聚羟基脂肪酸酯(PHA)的研究进展[J].新能源进展,2016,6(4):436-442.
[9]Mallek H,Jegat C,Mignard N,et al.Reversibly crosslinked self-healing PCL-based networks[J].J Appl Polym Sci,2013,129(3):954-964.
[10]葛祥军,田源,熊向源,等.聚己内酯在药物载体方面的研究进展[J].高分子通报,2017(3):11-18.
[11]谢文杰.PEG改性PBS聚合物的合成及性能研究[D].天津:天津科技大学,2016.
[12]Yeo J,Muiruri J K,Tan B H,et al.Biodegradable PHB-rubber copolymer toughened PLA green composites with ultrahigh extensibility[J].Chem Eng,2018,6(11):15517-15527.
[13]王跃,江洪波,陈大明,等.聚乳酸技术与市场现状及发展趋势分析[J].技术与市场,2017(6):17-22.
[14]范金钰.新型可降解塑料的研究及其应用[J].化工管理,2018(2):162.
[15]Roohi,Zaheer M R,Kuddus M,et al.PHB(poly-β-hydrobutyrate)and its enzymatic degradation[J].Polym Adv Technol,2018,29(1):30-40.
[16]黄险波,王伟伟,曾祥斌.生物基降解塑料行业现状[J].生物产业技术,2017(6):86-91.
[17]Han Ling,Zhu Guixiang,Zhang Wei,et al.Composition,thermal properties,and biodegradability of a new biodegradable aliphatic/aromatic copolyester[J].J Appl Polym Sci,2009,113(2):1298-1306.
[18]Wang Bingtao,Zhang Yan,Zhang Ping,et al.Preparation,characterization,and properties of novel biodegradable aliphatic-aromatic copolyester nanohybrids with polyhedral oligomeric silsesquioxanes moieties[J].J Polym Sci,Part B:Polym Phys,2012,50(19):1374-1382.
[19]Chen Xirong,Chen Wei,Zhu Guixiang,et al.Synthesis,1H-NMR characterization,and biodegradation behavior of aliphatic-aromatic random copolyester[J].J Appl Polym Sci,2007,104(4):2643-2649.
[20]彭荣诚,陈为丰.二氧化碳共聚脂肪族聚碳酸酯的研究与工业发展及应用[J].山东化工,2016,45(20):77-80.
[21]郭智臣.二氧化碳基新型生物降解塑料量产[J].化学推进剂与高分子材料,2019,17(1):16.
[2]周磊,唐脱险,魏嵬,等.完全生物降解塑料的研究进展[J].安徽农业科学,2012,40(13):7867-7871.
[3]Khemani K,Scholz C.Degradable Polymers and Materials:Principles and Practice[M].2nd ed.Washington:American Chemical Society,2012:3-10.
[4]高炜丽,李建科,赵燕.可生物降解淀粉塑料研究进展[J].广东化工,2007,34(7):52-55.
[5]张蓉,兰文婷,邹倩,等.淀粉及纤维素基可降解塑料研究进展[J].塑料工业,2017,45(12):1-5.
[6]徐心昱.全生物降解塑料的类型与研究成果分析[J].科技展望,2016(23):287.
[7]Okada M.Chemical synthesis of biodegradable polymers[J].Prog Polym Sci,2002,27(1):87-133.
[8]卞士祥,王闻,周桂雄,等.生物合成聚羟基脂肪酸酯(PHA)的研究进展[J].新能源进展,2016,6(4):436-442.
[9]Mallek H,Jegat C,Mignard N,et al.Reversibly crosslinked self-healing PCL-based networks[J].J Appl Polym Sci,2013,129(3):954-964.
[10]葛祥军,田源,熊向源,等.聚己内酯在药物载体方面的研究进展[J].高分子通报,2017(3):11-18.
[11]谢文杰.PEG改性PBS聚合物的合成及性能研究[D].天津:天津科技大学,2016.
[12]Yeo J,Muiruri J K,Tan B H,et al.Biodegradable PHB-rubber copolymer toughened PLA green composites with ultrahigh extensibility[J].Chem Eng,2018,6(11):15517-15527.
[13]王跃,江洪波,陈大明,等.聚乳酸技术与市场现状及发展趋势分析[J].技术与市场,2017(6):17-22.
[14]范金钰.新型可降解塑料的研究及其应用[J].化工管理,2018(2):162.
[15]Roohi,Zaheer M R,Kuddus M,et al.PHB(poly-β-hydrobutyrate)and its enzymatic degradation[J].Polym Adv Technol,2018,29(1):30-40.
[16]黄险波,王伟伟,曾祥斌.生物基降解塑料行业现状[J].生物产业技术,2017(6):86-91.
[17]Han Ling,Zhu Guixiang,Zhang Wei,et al.Composition,thermal properties,and biodegradability of a new biodegradable aliphatic/aromatic copolyester[J].J Appl Polym Sci,2009,113(2):1298-1306.
[18]Wang Bingtao,Zhang Yan,Zhang Ping,et al.Preparation,characterization,and properties of novel biodegradable aliphatic-aromatic copolyester nanohybrids with polyhedral oligomeric silsesquioxanes moieties[J].J Polym Sci,Part B:Polym Phys,2012,50(19):1374-1382.
[19]Chen Xirong,Chen Wei,Zhu Guixiang,et al.Synthesis,1H-NMR characterization,and biodegradation behavior of aliphatic-aromatic random copolyester[J].J Appl Polym Sci,2007,104(4):2643-2649.
[20]彭荣诚,陈为丰.二氧化碳共聚脂肪族聚碳酸酯的研究与工业发展及应用[J].山东化工,2016,45(20):77-80.
[21]郭智臣.二氧化碳基新型生物降解塑料量产[J].化学推进剂与高分子材料,2019,17(1):16.