摘要
对延长石油集团煤油共炼装置产生的共炼残渣进行原料特性分析,并对其理化性质及危害性进行了评价。基于煤油共炼残渣的特性,提出了煤油共炼残渣与多元料浆气化技术相结合,实现煤油共炼残渣的资源化高效清洁利用的思路,并详细介绍了技术路线和研究情况。多元料浆气化技术能使煤油共炼残渣中的有机物在高温下得到有效分解,实现污染物消减;能使无机物在熔融条件下与原料煤的灰渣形成安全稳定的玻璃化产物,有利于最终的处置利用。结果表明将煤油共炼残渣作为部分原料进行多元料浆气化反应,能够实现对残渣的资源化处理,气化指标良好。
The characteristics of the coal-oil coprocessing residue produced in the coal-oil coprocessing unit of Yanchang Petroleum Group were analyzed, and its physical and chemical properties and harmfulness were evaluated.Based on the characteristics of coal-oil coprocessing residue, the idea of combining coal-oil coprocessing residue with multi-component slurry gasification technology to realize efficient and clean utilization of coal-oil coprocessing residue was put forward, and the technical route and research situation were introduced in detail. The multi-component slurry gasification technology can effectively decompose organic matter in coal-oil coprocessing residue at high temperature to realize pollutant reduction. It can also make inorganic matter form a safe and stable vitrification product with the ash of raw coal under the melting condition, which is beneficial to the final disposal and utilization. The results show that using coal-oil coprocessing residue as part of the raw material to carry out multi-component slurry gasification can realize the resource processing of residue, and the gasification index is good.
引文
[1]朱豫飞.煤油共炼技术的现状与发展[J].洁净煤技术,2013(4):68-72.
[2]钱伯章.我国煤油共炼工业化技术世界领先[J].石油炼制与化工,2015(12):9.
[3]杨东元,扈广法,齐永红,等.煤油共炼残渣掺配水煤浆气化评价研究[J].应用化工,2016,45(12):2248-2251.
[4]董子平,闫大海,何洁,等.煤直接液化残渣掺烧的燃烧特性及其苯系物的排放特征[J].环境科学研究,2015,20(8):1253-1258.
[5]Makadia T H,Adetutu E M,Simons K L,et al.Re-use of remediated soils for the bioremediation of waste oil sludge[J].Journal of Environmental Management,2011,92(3):866-871.
[6]王志刚,白进,马晓贝,等.不同可磨性原煤的煤粉颗粒组成分布规律[J].煤炭技术,2017,36(7):272-274.
[7]谢欣馨.工业废水制水煤浆气化特性研究[D].西安石油大学,2013.
[8]谢欣馨,朱玉琴.工业废水和煤液化残渣制取水煤浆的研究[J].应用化工,2013,42(8):1448-1450.