含氮杂环添加剂抗腐防锈性能的研究进展
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摘要
对近年来苯并三氮唑类、苯并咪唑类、苯并噻唑类和噻二唑类等含氮杂环添加剂的抗腐防锈性能研究进行了概述,分析了其抗腐防锈机理及研究中存在的问题,并指出其未来发展应基础与应用研究并重,积极开展环境友好、综合性能良好的含氮杂环添加剂的研究。
The recent research progress in anti-corrosion/rust properties of nitrogen-containing heterocyclic lubricating additives,such as benzotriazole,benzimidazole,benzothiazol and thiadiazole,was reviewed and their mechanisms and existed problems in the current study were analyzed in this paper.And it was pointed out that both basic and applied study shoud be equally concerned and the research of environment-friendly nitrogen-containing lubricating addtives with good comprehensive performances should be actively carried out in the future.
The recent research progress in anti-corrosion/rust properties of nitrogen-containing heterocyclic lubricating additives,such as benzotriazole,benzimidazole,benzothiazol and thiadiazole,was reviewed and their mechanisms and existed problems in the current study were analyzed in this paper.And it was pointed out that both basic and applied study shoud be equally concerned and the research of environment-friendly nitrogen-containing lubricating addtives with good comprehensive performances should be actively carried out in the future.
引文
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[2]薛卫国,徐宁.我国防锈油的现状[J].润滑油与燃料,2006,16(72):15-20.
[3]欧阳平,陈严华.硼化含氮杂环润滑材料的研究进展[J].材料科学与工程学报,2014,32(1):135-141.
[4]张进,肖国民.含氮杂环化合物的研究进展[J].石油化工,2011,40(6):579-584.
[5]欧阳平,张贤明,郭豫川,等.一种新型含氮杂环润滑添加剂的摩擦学特性研究[J].机械科学与技术,2013,32(5):57-60.
[6]Wang Y L,Hong J H,Wei C C.Tribological properties and nanomechanics of Cu-BTA composite nanooils[J].Key Eng Mat,2015,642:147-151.
[7]Zhou G D,Ma Z C,Tong R L,et al.Corrsion inhibition of copper with benzotriazole and tolyltriazole in a 3%Na Cl solution[J].Bull Electrochem,1991,7(2):60-71.
[8]Peng S S,Zhao W J,Li H,et al.The enhancement of benzotriazole on epoxy functionalized silica sol-gel coating for copper protection[J].Appl Surf Sci,2013,276:284-290.
[9]Florina B,Viorel Branzoi.Corrsion inhibition of carbon steel by using some benzotrizaole derivatives in 0.5M H2SO4medium[J].Rev Roum Chim,2015,60(1):85-96
[10]Zhao D,Wang M Z,Xu Y F,et al.The fabrication and corrosion resistance of benzotriazole-loaded raspberry-like hollow polymeric microspheres[J].Surf Coat Tech,2014,238:15-26.
[11]曹佩根,姚建林,顾仁敖,等.苯并三氮唑对铜和铁缓蚀作用的拉曼光谱研究[J].光散射学报,1999,(1):3-8.
[12]Statake M.Structure of benzotriazole films on metals[J].Jpn Res Inst Adv Copper-Base Mater Technol,2003,42:253-260.
[13]徐群杰,周国定.BTA系列缓蚀剂对铜缓蚀作用的光电化学比较[J].太阳能学报,2005,(5):665-670.
[14]黄勇,秦技强,杨万生.苯骈三氮唑酰基衍生物的缓蚀性能[J].材料保护,2002,35(9):27-28.
[15]Khaled K F.The inhibition of benzimidazole derivatives on corrosion of iron in 1MHC1 solutions[J].Electrochim Acta.2003,48(4):2493-2503.
[16]李杰兰,梁成浩,黄乃宝,等.苯并咪唑衍生物缓蚀剂研究进展[J].腐蚀科学与防护技术,2011,23(2):191-195.
[17]Fatma B E,Melis K,Fulya E K,et al.A benzimidazolebased conducting polymer and a PMMA-clay nanocomposite containing biosensor platform for glucose sensing[J].Synthetic Met,2015,207:102-109.
[18]张军,赵卫民,郭文跃,等.苯并咪唑类缓蚀剂缓蚀性能的理论评价[J].物理化学学报,2008,24(7):1239-1244.
[19]Nassar A M,Hassan A M,Shoeib M A,et al.Synthesis,characterization and anticorrosion studies of new homobimetallic Co(II),Ni(II),Cu(II),and Zn(II)schiff base complexes[J].J Bio Tribo Corros,2015,19(1):1-16.
[20]钱建华.油溶性缓蚀剂ω,ω'-双(1-辛基苯并咪唑-2-基)烷烃的合成及缓蚀性能研究[J].化学通报,2012,75(1):88-91.
[21]茌方,周桃玉.2-(3-甲氧基-4-羟基苯基)苯并咪唑的碳钢海水缓蚀性能[J].全面腐蚀控制,2014,28(9):68-71.
[22]黄炎俊.2-(苄硫基)苯并咪唑与2-(对氯苄硫基)苯并咪唑的合成及缓蚀性能研究[J].化学世界,2011,(5):306-309,316.
[23]钱建华,张月,郑艳秋,等.新型双苯并咪唑润滑油添加剂的合成及其多效性能研究[J].石油化工,2011,40(12):1 321-1 324.
[24]Cai M R,Liang Y M,Zhou F,et al.A novel imidazolium salt with antioxidation and anticorrosion dual functionalities as the additive in poly(ethylene glycol)for steel/steel contacts[J].Wear,2013,306:197-208.
[25]贾明子,张哲,阮乐,等.咪唑类化合物自组装膜对316不锈钢的缓蚀作用[J].表面技术,2013,42(3):23-27,41.
[26]Obot I B,Madhankumar A,Umoren S A,et al.Surface protection of mild steel using benzimidazole derivativesexperimental and theoretical approach[J].J Adhes Sci,2015,29(19):2130-2152.
[27]钱建华,张月,阴翔宇,等.1,3-双(2-苯并咪唑基)-2-氧杂丙烷对N80钢的缓蚀性能[J].石油炼制与化工,2012,43(3):75-77.
[28]王清云,佟永纯,曹成,等.HCl溶液中苯并咪唑类化合物对低碳钢的缓蚀性能研究[J].化学通报,2012,75(10):930-934.
[29]Javier I,Juan J S,Sergio G,et al.Scanning microelectrochemical characterization of the anti-corrosion performance of inhibitor films formed by 2-mercaptobenzimidazole on copper[J].Prog Org Coat,2012,74:526-533.
[30]Qiao D,Wang H Z,Feng D P.Benzimidazolyl phosphates as anti-wear additives in poly(ethylene glycol)for steelsteel contacts[J].Lubr Sci,2014,26(1):1-11.
[31]胡莲跃,张胜涛,黄小红,等.苯并咪唑在KOH溶液中对锌材的缓蚀性能[J].材料保护,2011,44(8):14-17,88.
[32]岳松涛,户贵华,刘电力,等.KY-2型缓蚀剂在中原油田卫22块的研究应用[J].化学研究与应用,2012,24(4):653-656.
[33]欧阳平,陈严华,张贤明,等.苯并噻唑(啉)类润滑油添加剂的研究进展[J].化学研究与应用,2014,26(10):1521-1526.
[34]Rajeev P,Surendranathan A O,Murhty C S.Corrosion mitigation of the oil well steels using organic inhibitors-a review[J].J Mater Environ Sci,2012,3(5):856-859.
[35]Li Z P,Li X F,Zhang Y W,et al.Tribological study of a highly hydrolytically stable phenylboronic acidester containing benzothiazolyl in mineral oil[J].Appl Surf Sci,2014,308:91-99.
[36]张军平,张秋禹,范晓东,等.3-(苯胺基甲基)-苯并噻唑-2-硫酮的缓蚀性能及吸附作用[J].材料保护,2010,43(6):21-23,78,91.
[37]朱传方.2-膦酰亚甲硫基1,3-苯并噻唑的合成及其对金属缓蚀的研究[J].华中师范大学学报(自然科学版),1989,23(4):46-49.
[38]He Z Y,Xiong L P,Qian Liang,et al.Tribological properties and hydrolysis stability study of benzothiazole borate derivative[J].Lubr Sci,2014,26(2):81-94.
[39]刘琳,郑艳秋,邢锦娟,等.2-巯基苯并噻唑衍生物自组装分子膜对45#钢的缓蚀性能[J].科学技术与工程,2012,12(4):89-91.
[40]刘琳,郑艳秋,钱建华,等.2-苯并噻唑基-4-甲氧基苯腙自组装膜对45#钢的缓蚀性能研究[J].材料导报,2012,26(24):85-87.
[41]张军.2-巯基苯并咪唑缓蚀剂对Q235钢的缓蚀性能研究[J].青岛大学学报(工程技术版),2010,25(1):76-80.
[42]Nessim M I,Ahmed M H M,Ali A M,et al.The effect of some benzothiazole derivatives as antioxidants for base stock[J].Int J Curr Res,2013,5(5):1 111-1 117.
[43]钟文英,郑朝华.光谱电化学研究T-巯基苯并噻唑对铜的缓蚀机理[J].无机化学学报,1999,15(6):7 56-760.
[44]张大全,俞路,陆柱.苯并噻唑衍生物的缓蚀作用及PPP量子化学研究[J].中国腐蚀与防护学报,1998,18(4):69-72.
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