无机抗菌剂在抗菌涂料中的研究进展
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摘要
无机抗菌剂可赋予材料和加工制品持久、长效的抗菌、杀菌性能,而抗菌涂料是涂料工业重要发展方向之一。本文介绍了无机抗菌剂的分类和作用机理,论述了无机抗菌剂在抗菌涂料中应用的研究进展,阐述了抗菌涂料的检测方法,并针对现行方法提出了一些见解。预测了抗菌涂料和无机抗菌剂的发展趋势。
The materials and products involved inorganic antibacterial agents presented permanent antibacterial and bactericidal properties.It is well known that antibacterial coatings were a typical direction in coatings industry.The classification and action mechanism of inorganic antibacterial agents were introduced herein,then their application in antibacterial coatings were described as well.Subsequently,testing techniques of antimicrobial performance were discussed,and the development of antibacterial coatings and antibacterial agents were predicted.
The materials and products involved inorganic antibacterial agents presented permanent antibacterial and bactericidal properties.It is well known that antibacterial coatings were a typical direction in coatings industry.The classification and action mechanism of inorganic antibacterial agents were introduced herein,then their application in antibacterial coatings were described as well.Subsequently,testing techniques of antimicrobial performance were discussed,and the development of antibacterial coatings and antibacterial agents were predicted.
引文
[1]苏学军,王建军.抗菌剂在抗菌涂料中的应用进展[J].天津化工,2007,21(4):4.
[2]董加胜,陈四红,吕曼祺,等.抗菌材料发展和现状[J].材料导报,2004,18(3):41.
[3]蔡晓峰.无机抗菌剂及其应用[J].陶瓷科学与艺术,2004(2):40.
[4]肖清华,李博文,王宁.载银无机抗菌剂的研究现状和发展趋势[J].中国非金属矿导报,1999(6):5.
[5]Trapalis C C,Kokkoris M,Perdikakis G,et al.Study of antibacterial composite Cu/Si O2 thin coatings[J].Sol Gel Science and Technology.2003,26(3):1213.
[6]胡占江,赵忠,王雪梅.纳米氧化锌抗菌性能及机制[J].中国组织工程研究,2012,16(3):527.
[7]陈美婉,彭新生,吴琳娜,等.纳米银抗菌剂的研究和应用[J].中国消毒学杂志,2009,26(4):424.
[8]秦嘉旭,张亚涛,陈义丰,等.无机纳米抗菌剂及其载体[J].材料导报,2011,25,专辑18:67.
[9]陆露.纳米银的合成及其抗菌机制研究[D].兰州大学,2015.
[10]Qiu Y J,Yu J.synthesis of titanium dioxide nanotubes from electrospun fiber templates[J].Solid State Commun,2008,148:556.
[11]Chen Y S,Crittenden J C,Hackney S,et al.Preparation of a novel Ti O2-based p-n junction nanotube photocatalyst[J].Environ Sci Techn,2005,39(5):1201.
[12]徐瑞芬,许秀艳,付国柱.纳米Ti O2在涂料中的抗菌性能研究[J].北京化工大学学报(自然科学版),2002,29(5):45.
[13]徐丽丽,綦晓峰,陈玉清.纳米二氧化钛抗菌材料的研究与应用进展[J].山东陶瓷,2007,30(5):26.
[14]胡创,李沪萍,罗康碧,等.四针状Zn O晶须制备及应用的研究现状[J].化工科技,2009,17(5):69.
[15]唐楠楠.纳米氧化锌颗粒抗菌修饰及在光固化涂料中的应用研究[D].北京化工大学,2014.
[16]Chang C C,Lin C K,Chan C C,et al.Photocatalytic properties of nanocrystalline Ti O2 thin film with Ag additions[J].Thin Solid Films,2006,494:274.
[17]Lim S K,Lee S K,Hwang S H,et al.Photocatalytic deposition of silver nanoparticles onto organic/inorganic composite nanofibers[J].Macromol Mater Eng,2006,291:1265.
[18]崔学军,刘春海,杨瑞嵩等.水性抗菌耐污氟碳涂料的研究[J].四川理工学院学报(自然科学版).2012,25(1):31.
[19]杜杰辉.银离子抗菌涂料性能特点剂应用浅析[J].中国医院建筑与装备,2010(4):81。
[20]Mahltig B,Gutmann E,Meyer DC,et al.Solvothermal preparationof metallized titania sols for photocatalytic and antimicrobialcoatings[J].Journal of Materials Chemistry,2007,17(22):2367.
[21]Diego Meseguer Yebra,SΦren Kiil,et al.Dissolution ratemeasurements of sea water soluble pigments for antifoulingpaints:Zn O[J].Progress in Organic Coatings,2006,(56):327.
[22]Kawahara K,Tsuruda K,Morishita M,et al.Antibacterial effect of silver-zeolite on oral bacteria under anaerobic conditions[J].Dentmater.2000,16(6):452.
[23]严建华,冯乃谦,等.载银天然沸石抗菌耐久性的研究[J].硅酸盐通报,2002,(3):7.
[24]GB/T21866-2008,抗菌涂料(漆膜)抗菌性测定法和抗菌效果[S].
[25]GB/T23763-2009,光催化抗菌材料及制品抗菌性能的评价[S].
[26]GB/T1741-2007,漆膜耐霉菌性测定法[S].
[27]GB/T3950-2007,抗菌涂料[S].
[2]董加胜,陈四红,吕曼祺,等.抗菌材料发展和现状[J].材料导报,2004,18(3):41.
[3]蔡晓峰.无机抗菌剂及其应用[J].陶瓷科学与艺术,2004(2):40.
[4]肖清华,李博文,王宁.载银无机抗菌剂的研究现状和发展趋势[J].中国非金属矿导报,1999(6):5.
[5]Trapalis C C,Kokkoris M,Perdikakis G,et al.Study of antibacterial composite Cu/Si O2 thin coatings[J].Sol Gel Science and Technology.2003,26(3):1213.
[6]胡占江,赵忠,王雪梅.纳米氧化锌抗菌性能及机制[J].中国组织工程研究,2012,16(3):527.
[7]陈美婉,彭新生,吴琳娜,等.纳米银抗菌剂的研究和应用[J].中国消毒学杂志,2009,26(4):424.
[8]秦嘉旭,张亚涛,陈义丰,等.无机纳米抗菌剂及其载体[J].材料导报,2011,25,专辑18:67.
[9]陆露.纳米银的合成及其抗菌机制研究[D].兰州大学,2015.
[10]Qiu Y J,Yu J.synthesis of titanium dioxide nanotubes from electrospun fiber templates[J].Solid State Commun,2008,148:556.
[11]Chen Y S,Crittenden J C,Hackney S,et al.Preparation of a novel Ti O2-based p-n junction nanotube photocatalyst[J].Environ Sci Techn,2005,39(5):1201.
[12]徐瑞芬,许秀艳,付国柱.纳米Ti O2在涂料中的抗菌性能研究[J].北京化工大学学报(自然科学版),2002,29(5):45.
[13]徐丽丽,綦晓峰,陈玉清.纳米二氧化钛抗菌材料的研究与应用进展[J].山东陶瓷,2007,30(5):26.
[14]胡创,李沪萍,罗康碧,等.四针状Zn O晶须制备及应用的研究现状[J].化工科技,2009,17(5):69.
[15]唐楠楠.纳米氧化锌颗粒抗菌修饰及在光固化涂料中的应用研究[D].北京化工大学,2014.
[16]Chang C C,Lin C K,Chan C C,et al.Photocatalytic properties of nanocrystalline Ti O2 thin film with Ag additions[J].Thin Solid Films,2006,494:274.
[17]Lim S K,Lee S K,Hwang S H,et al.Photocatalytic deposition of silver nanoparticles onto organic/inorganic composite nanofibers[J].Macromol Mater Eng,2006,291:1265.
[18]崔学军,刘春海,杨瑞嵩等.水性抗菌耐污氟碳涂料的研究[J].四川理工学院学报(自然科学版).2012,25(1):31.
[19]杜杰辉.银离子抗菌涂料性能特点剂应用浅析[J].中国医院建筑与装备,2010(4):81。
[20]Mahltig B,Gutmann E,Meyer DC,et al.Solvothermal preparationof metallized titania sols for photocatalytic and antimicrobialcoatings[J].Journal of Materials Chemistry,2007,17(22):2367.
[21]Diego Meseguer Yebra,SΦren Kiil,et al.Dissolution ratemeasurements of sea water soluble pigments for antifoulingpaints:Zn O[J].Progress in Organic Coatings,2006,(56):327.
[22]Kawahara K,Tsuruda K,Morishita M,et al.Antibacterial effect of silver-zeolite on oral bacteria under anaerobic conditions[J].Dentmater.2000,16(6):452.
[23]严建华,冯乃谦,等.载银天然沸石抗菌耐久性的研究[J].硅酸盐通报,2002,(3):7.
[24]GB/T21866-2008,抗菌涂料(漆膜)抗菌性测定法和抗菌效果[S].
[25]GB/T23763-2009,光催化抗菌材料及制品抗菌性能的评价[S].
[26]GB/T1741-2007,漆膜耐霉菌性测定法[S].
[27]GB/T3950-2007,抗菌涂料[S].