国内电解精炼法制备高纯金综述
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摘要
介绍了高纯金的研究意义及电解精炼法制备高纯金的基本原理。从电解电源、阴极板的设计、电解环境、电解工艺、标准状况及主要生产厂家等方面,综述了国内电解精炼法制备高纯金的生产研究现状,并提出了制备满足新国标要求的5N高纯金的研究方向。
The significance and the basic principle of high-purity gold prepared by electro-refining were introduced.The domestic production status of high-purity gold by electro-refining were reviewed from the aspects of electrolysis power,cathode plate design,electrolysis environment,electrolysis process,standard condition and main manufactures.In the meantime,the research prospect of developing 5 N high-purity gold process was also forecasted.
The significance and the basic principle of high-purity gold prepared by electro-refining were introduced.The domestic production status of high-purity gold by electro-refining were reviewed from the aspects of electrolysis power,cathode plate design,electrolysis environment,electrolysis process,standard condition and main manufactures.In the meantime,the research prospect of developing 5 N high-purity gold process was also forecasted.
引文
[1]郭学益,田庆华.高纯金属材料[M].北京:冶金工业出版社,2011:178-179.GUO X Y,TIAN Q H.High-pure metallic materials[M].Beijing:Metallurgical Industry Press,2011,178-179.
[2]胡建华.一种高纯金的制备方法:CN102925679A[P].2013-02-13.HU J H.A method of high-purity gold preparation:CN102925679A[P].2013-02-13.
[3]胡秋芬.固相萃取技术在金提取和分析中的应用研究[D].昆明:昆明理工大学,2008.HU Q F.Study on the application of solid phase extraction technology in the gold extraction and gold determination[D].Kunming:Kunming University of Technology,2008.
[4]巩海娟.99.99%黄金提纯工艺的研究[D].长春:吉林大学,2006.GONG H J.An experimental study of 99.99%gold refining[D].Changchun:Jinlin University,2006.
[5]刘勇,阳振球,杨天足.金电解与溶剂萃取精炼工艺比较分析[J].黄金,2007,28(6):42-45.LIU Y,YANG Z Q,YANG T Z.The comparison between gold electrolysis and solvent extraction refining process[J].Gold,2007,28(6):42-45.
[6]魏莉,汪丹,郭平.黄金精炼提纯工艺研究与生产实践[J].黄金,2000,21(3):37-39.WEI L,WANG D,GUO P.Study and operation practice of the technology of gold refining[J].Gold,2000,21(3):37-39.
[7]霍松龄.黄金精炼工艺综述[J].黄金,2014,35(8):65-68.HUO S L.Overview on gold-refining technology[J].Gold,2014,35(8):65-68.
[8]张济祥,谢宏潮,阳岸恒,等.高纯金制备技术研究现状与展望[J].贵金属,2015,36(3):81-86.ZHANG J X,XIE H C,YANG A H,et al.Status and prospect of preparative methods for high-purity gold[J].Precious metals,2015,36(3):81-86.
[9]吴玉.金的电解精炼技术条件的控制[J].中国有色冶金,1984(11):24-25.WU Y.Control of technology conditions of gold electrorefining[J].China nonferrous metallurgy,1984(11):24-25.
[10]孙戬.金银冶金[M].北京:冶金工业出版社,1986:376-37.SUN J.Gold and silver metallurgy[M].Beijing:Metallurgical Industry Press,1986:376-379.
[11]盛枝,张墨霞.黄金电解电源[J].白银科技,1995(2):50-53.SHENG Z,ZHANG M X.Gold electrolysis power supply[J].Silver technology,1995(2):50-53.
[12]郑勇,常占河,李德俊.周期自动换向金电解新工艺[J].黄金,1996,17(4):35-3ZHENG Y,CHANG Z H,LI D J.New technology of gold electrolysis with the installation of changing direction automatically at regular intervals[J].Gold,1996,17(4):35-38.
[13]郑勇.周期(2π)换向金电解电源[J].黄金,1999,20(12):29-33.ZHENG Y.Power supply of cyclic(2π)change over electrorefining of gold[J].Gold,1999,20(12):29-33
[14]付国民.非对称交流电源在金电解生产中的应用[J].黄金,2000,21(5):37-39.FU G M.The application of non-symmetrical AC power supply in the operation of gold electrolysis[J].Gold,2000,21(5):37-39.
[15]赵忱.金电解电源装置的优化设计与应用[J].矿冶,2002,11(3):77-79.ZHAO C.Optimum desing and application of power supply for gold electrolysis[J].Mining and metallurgy,2002,11(3):77-79.
[16]赵忱.交直流叠加在金电解中的应用[J].设备管理与维修,2003(3):19.ZHAO C.Application of AC/DC technology in gold electrolysis[J].Plant maintencence engineering,2003(3):19.
[17]孙敬韬,邓成虎,王日,等.一步法高纯金生产工艺开发与产业化[J].有色金属(冶炼部分),2014(7):45-48.SUN J T,DENG C H,WANG R,et al.Process development and industrialization for production of high purity gold with one-step process[J].Nonferrous metals(extractive metallurgy),2014(7):45-48.
[18]叶跃威.高纯金的电解工艺[J].贵金属,2014,35(1):23-16.YE Y W.Electrolysis process of high purity gold[J].Precious metals,2014,35(1):23-16.
[19]胡建辉,夏兴旺,王日,等.一步法高纯金生产工艺:CN101122032A[P].2008-02-13.HU J J,XIA X W,WANG R,et al.One-step high pure gold production process:CN101122032A[P].2008-02-13.
[20]王日,黄绍勇,熊超,等.一种阴极金电解精炼工艺:CN102978658[P].2013-03-20.WANG R,HUANG S Y,XIONG C,et al.A cathode gold electrolysis refining process,CN102978658[P].2013-03-20.
[21]王银祥,冯治兵,周俊涛,等.一种提高金电解精炼工艺中金析出品位的方法:CN 103590071A[P].2014-02-19.WANG Y X,FENG Z B,ZHOU J T,et al.A method to improve gold precipitation grade in gold electrolysis refining process:CN103590071A[P].2014-02-19.
[22]文书毕.用电解精炼制备高纯金[J].有色金属与稀土应用,1993(4):1-3.WEN S B.Preparation of high purity gold by electrolytic refining[J].Application of nonferrous metals and rare earth,1993(4):1-3.
[23]肖金娥,毛仕杰.钛材阴极在我厂金电解的应用[J].株冶科技,1995(3):40-42.XIAO J E,MAO S J.Application of titanium cathode in gold electrolysis in our plant[J].Zhuzhou science and technology,1995(3):40-42.
[24]熊超.金线用高纯金生产关键设备的研发实践[J].铜业工程,2012(3):18-20.XIONG C.Research practice on production equipment of high pure gold for gold wire[J].Copper engineering,2012(3):18-20.
[25]孙敬韬,邓成虎,王日,等.一步法高纯金生产工艺开发与产业化[J].有色金属(冶炼部分),2014(7):45-48.SUN J T,DENG C H,WANG R,et al.Process development and industrialization for production of high purity gold with one-step process[J].Nonferrous metals(extractive metallurgy),2014(7):45-48.
[26]卢宜源,宾万达.贵金属冶金学[M].湖南:中南大学出版社,2006.LU Y Y,BIN W D.Precious metal metallurgy[M].Hunan:Central South University Press,2006.
[27]撒应福,郑焕荣,曹海祥.均质阴离子交换膜在电解提纯金中的应用[J].贵金属,1998,19(3):38-39.SA Y F,ZHENG H Y,CAO H X.An application of homogeneous anion exchange membrane to gold refining by electrolysis[J].Precious metals,1998,19(3):38-39.
[28]宋裕华,张基娟.阴离子交换膜在金电解中的应用[J].黄金,2007,28(12):47-48.SONG Y H,ZHANG J J.Application of anion exchange membrane in gold electrolysis[J].Gold,2007,28(12):47-48.
[29]张兴仁.金的电解精炼法[J].国外黄金参考,2000(7):28-31.ZHANG X R.Electrorefining of gold[J].Foreign gold reference,2000(7):28-31.
[30]王定良,毛仕杰.沃耳维尔法电解金的生产实践[J].湖南冶金,1989(2):24-26.WANG D L,MAO S J.Production practice of Wohlwill process in gold electrolysis[J].Hunan metallurgy,1989(2):24-26.
[31]陈东.黑金粉直接连续金电解[J].黄金,1987,8(1):64.CHEN D.Direct continuous electrolysis of black gold powder[J].Gold,1987,8(1):64.
[32]全国黄金标准化技术委员会.高纯金:GB/T 25933-2010[S].北京:中国标准出版社,2011.SAC/TC 379.High-purity gold:GB/T 25933-2010[S].Beijing:Standards Press of China,2011.
[33]全国有色金属标准化技术委员会.金锭:GB/T 4134-2015[S].北京:中国标准出版社,2015.SAC/TC 243.Gold ingot:GB/T 4134-2015[S].Beijing:Standards Press of China,2011.
[34]杨国祥,邓志明.键合金丝用高纯金的制备[J].贵金属,2010,31(2):54-56.YANG G X,DENG Z M.Preparation of high pure gold used for gold bonding wires[J].Precious metals,2010,31(2):54-56.
[35]佚名.紫金矿业具备年产5 t“五九”高纯金能力[J].黄金科学技术,2012,20(2):85.Anon.Zijin Mining have a 5 ton production capacity of high purity gold[J].Gold science and technology,2012,20(2):85.
[2]胡建华.一种高纯金的制备方法:CN102925679A[P].2013-02-13.HU J H.A method of high-purity gold preparation:CN102925679A[P].2013-02-13.
[3]胡秋芬.固相萃取技术在金提取和分析中的应用研究[D].昆明:昆明理工大学,2008.HU Q F.Study on the application of solid phase extraction technology in the gold extraction and gold determination[D].Kunming:Kunming University of Technology,2008.
[4]巩海娟.99.99%黄金提纯工艺的研究[D].长春:吉林大学,2006.GONG H J.An experimental study of 99.99%gold refining[D].Changchun:Jinlin University,2006.
[5]刘勇,阳振球,杨天足.金电解与溶剂萃取精炼工艺比较分析[J].黄金,2007,28(6):42-45.LIU Y,YANG Z Q,YANG T Z.The comparison between gold electrolysis and solvent extraction refining process[J].Gold,2007,28(6):42-45.
[6]魏莉,汪丹,郭平.黄金精炼提纯工艺研究与生产实践[J].黄金,2000,21(3):37-39.WEI L,WANG D,GUO P.Study and operation practice of the technology of gold refining[J].Gold,2000,21(3):37-39.
[7]霍松龄.黄金精炼工艺综述[J].黄金,2014,35(8):65-68.HUO S L.Overview on gold-refining technology[J].Gold,2014,35(8):65-68.
[8]张济祥,谢宏潮,阳岸恒,等.高纯金制备技术研究现状与展望[J].贵金属,2015,36(3):81-86.ZHANG J X,XIE H C,YANG A H,et al.Status and prospect of preparative methods for high-purity gold[J].Precious metals,2015,36(3):81-86.
[9]吴玉.金的电解精炼技术条件的控制[J].中国有色冶金,1984(11):24-25.WU Y.Control of technology conditions of gold electrorefining[J].China nonferrous metallurgy,1984(11):24-25.
[10]孙戬.金银冶金[M].北京:冶金工业出版社,1986:376-37.SUN J.Gold and silver metallurgy[M].Beijing:Metallurgical Industry Press,1986:376-379.
[11]盛枝,张墨霞.黄金电解电源[J].白银科技,1995(2):50-53.SHENG Z,ZHANG M X.Gold electrolysis power supply[J].Silver technology,1995(2):50-53.
[12]郑勇,常占河,李德俊.周期自动换向金电解新工艺[J].黄金,1996,17(4):35-3ZHENG Y,CHANG Z H,LI D J.New technology of gold electrolysis with the installation of changing direction automatically at regular intervals[J].Gold,1996,17(4):35-38.
[13]郑勇.周期(2π)换向金电解电源[J].黄金,1999,20(12):29-33.ZHENG Y.Power supply of cyclic(2π)change over electrorefining of gold[J].Gold,1999,20(12):29-33
[14]付国民.非对称交流电源在金电解生产中的应用[J].黄金,2000,21(5):37-39.FU G M.The application of non-symmetrical AC power supply in the operation of gold electrolysis[J].Gold,2000,21(5):37-39.
[15]赵忱.金电解电源装置的优化设计与应用[J].矿冶,2002,11(3):77-79.ZHAO C.Optimum desing and application of power supply for gold electrolysis[J].Mining and metallurgy,2002,11(3):77-79.
[16]赵忱.交直流叠加在金电解中的应用[J].设备管理与维修,2003(3):19.ZHAO C.Application of AC/DC technology in gold electrolysis[J].Plant maintencence engineering,2003(3):19.
[17]孙敬韬,邓成虎,王日,等.一步法高纯金生产工艺开发与产业化[J].有色金属(冶炼部分),2014(7):45-48.SUN J T,DENG C H,WANG R,et al.Process development and industrialization for production of high purity gold with one-step process[J].Nonferrous metals(extractive metallurgy),2014(7):45-48.
[18]叶跃威.高纯金的电解工艺[J].贵金属,2014,35(1):23-16.YE Y W.Electrolysis process of high purity gold[J].Precious metals,2014,35(1):23-16.
[19]胡建辉,夏兴旺,王日,等.一步法高纯金生产工艺:CN101122032A[P].2008-02-13.HU J J,XIA X W,WANG R,et al.One-step high pure gold production process:CN101122032A[P].2008-02-13.
[20]王日,黄绍勇,熊超,等.一种阴极金电解精炼工艺:CN102978658[P].2013-03-20.WANG R,HUANG S Y,XIONG C,et al.A cathode gold electrolysis refining process,CN102978658[P].2013-03-20.
[21]王银祥,冯治兵,周俊涛,等.一种提高金电解精炼工艺中金析出品位的方法:CN 103590071A[P].2014-02-19.WANG Y X,FENG Z B,ZHOU J T,et al.A method to improve gold precipitation grade in gold electrolysis refining process:CN103590071A[P].2014-02-19.
[22]文书毕.用电解精炼制备高纯金[J].有色金属与稀土应用,1993(4):1-3.WEN S B.Preparation of high purity gold by electrolytic refining[J].Application of nonferrous metals and rare earth,1993(4):1-3.
[23]肖金娥,毛仕杰.钛材阴极在我厂金电解的应用[J].株冶科技,1995(3):40-42.XIAO J E,MAO S J.Application of titanium cathode in gold electrolysis in our plant[J].Zhuzhou science and technology,1995(3):40-42.
[24]熊超.金线用高纯金生产关键设备的研发实践[J].铜业工程,2012(3):18-20.XIONG C.Research practice on production equipment of high pure gold for gold wire[J].Copper engineering,2012(3):18-20.
[25]孙敬韬,邓成虎,王日,等.一步法高纯金生产工艺开发与产业化[J].有色金属(冶炼部分),2014(7):45-48.SUN J T,DENG C H,WANG R,et al.Process development and industrialization for production of high purity gold with one-step process[J].Nonferrous metals(extractive metallurgy),2014(7):45-48.
[26]卢宜源,宾万达.贵金属冶金学[M].湖南:中南大学出版社,2006.LU Y Y,BIN W D.Precious metal metallurgy[M].Hunan:Central South University Press,2006.
[27]撒应福,郑焕荣,曹海祥.均质阴离子交换膜在电解提纯金中的应用[J].贵金属,1998,19(3):38-39.SA Y F,ZHENG H Y,CAO H X.An application of homogeneous anion exchange membrane to gold refining by electrolysis[J].Precious metals,1998,19(3):38-39.
[28]宋裕华,张基娟.阴离子交换膜在金电解中的应用[J].黄金,2007,28(12):47-48.SONG Y H,ZHANG J J.Application of anion exchange membrane in gold electrolysis[J].Gold,2007,28(12):47-48.
[29]张兴仁.金的电解精炼法[J].国外黄金参考,2000(7):28-31.ZHANG X R.Electrorefining of gold[J].Foreign gold reference,2000(7):28-31.
[30]王定良,毛仕杰.沃耳维尔法电解金的生产实践[J].湖南冶金,1989(2):24-26.WANG D L,MAO S J.Production practice of Wohlwill process in gold electrolysis[J].Hunan metallurgy,1989(2):24-26.
[31]陈东.黑金粉直接连续金电解[J].黄金,1987,8(1):64.CHEN D.Direct continuous electrolysis of black gold powder[J].Gold,1987,8(1):64.
[32]全国黄金标准化技术委员会.高纯金:GB/T 25933-2010[S].北京:中国标准出版社,2011.SAC/TC 379.High-purity gold:GB/T 25933-2010[S].Beijing:Standards Press of China,2011.
[33]全国有色金属标准化技术委员会.金锭:GB/T 4134-2015[S].北京:中国标准出版社,2015.SAC/TC 243.Gold ingot:GB/T 4134-2015[S].Beijing:Standards Press of China,2011.
[34]杨国祥,邓志明.键合金丝用高纯金的制备[J].贵金属,2010,31(2):54-56.YANG G X,DENG Z M.Preparation of high pure gold used for gold bonding wires[J].Precious metals,2010,31(2):54-56.
[35]佚名.紫金矿业具备年产5 t“五九”高纯金能力[J].黄金科学技术,2012,20(2):85.Anon.Zijin Mining have a 5 ton production capacity of high purity gold[J].Gold science and technology,2012,20(2):85.