某工程橡胶生产废水处理工艺改造实践
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摘要
针对某工程橡胶公司生产废水处理工艺缺乏有效预处理,导致废水中难降解有机物不能有效生物降解,出水COD超标的问题,分析了问题原因,通过试验比较了Fenton和臭氧两种预处理工艺的效果和成本,确定了在原有处理工艺流程的基础上,增加臭氧氧化预处理工艺,形成臭氧-生物接触氧化处理工艺的改造方案,经改造后,出水达到GB 27632-2011《橡胶制品工业污染物排放标准》的水质标准。
There was no effective pretreatment for the wastewater treatment process of a rubber company. The degradation of refractory organics in wastewater could not be effectively biodegraded, and the effluent COD exceeded the standard. The causes of the problem were analyzed, and the effects and costs of two pretreatment processes, Fenton and ozone, were compared by experiments. On the basis of the original treatment process, the ozone oxidation pretreatment process was added, and then the ozone biological contact oxidation treatment process was constructed. After modification, the effluent quality reaches Emission Standard of Pollutants for Rubber Products Industry(GB 27632-2011).
There was no effective pretreatment for the wastewater treatment process of a rubber company. The degradation of refractory organics in wastewater could not be effectively biodegraded, and the effluent COD exceeded the standard. The causes of the problem were analyzed, and the effects and costs of two pretreatment processes, Fenton and ozone, were compared by experiments. On the basis of the original treatment process, the ozone oxidation pretreatment process was added, and then the ozone biological contact oxidation treatment process was constructed. After modification, the effluent quality reaches Emission Standard of Pollutants for Rubber Products Industry(GB 27632-2011).
引文
[1]尚海英,席宏波,周岳溪,等.丁苯橡胶生产废水的生物降解特性[J].环境科学研究,2016,29(6):887-893.
[2]薛念涛,曹明利,纪玉琨,等.水解酸化工艺的研究现状与发展趋势[J].环境工程,2013,31(5):50-54.
[3]程凯英,黄石峰,邓耀杰.水解(酸化)反应器在工程应用中的研究与展望[J].工业水处理,2005,25(3):39-42.
[4]张伟军,高雅,马士龙,等.不同来源高浓度有机废水的集中处理[J].环境工程学报,2013,7(4):1213-1218.
[5]Deng Y,Englehardt J D.Treatment of landfill leachate by the Fenton process[J].Water Research,2006,40(20):3683-3694.
[6]徐苏云,何品晶,唐琼瑶,等.Fenton法处理类长填龄渗滤液的氧化和絮凝作用[J].环境科学研究,2008,21(4):20-24.
[7]陈诚,章诗芳,董玉莲,等.臭氧工艺对水中有机物分布影响情况研究[J].广州化工,2006,34(6):29-31.
[8]Baird R,Smith R K.Third century of biochemical oxygen demand[M].Water Environment Federation,2002.
[2]薛念涛,曹明利,纪玉琨,等.水解酸化工艺的研究现状与发展趋势[J].环境工程,2013,31(5):50-54.
[3]程凯英,黄石峰,邓耀杰.水解(酸化)反应器在工程应用中的研究与展望[J].工业水处理,2005,25(3):39-42.
[4]张伟军,高雅,马士龙,等.不同来源高浓度有机废水的集中处理[J].环境工程学报,2013,7(4):1213-1218.
[5]Deng Y,Englehardt J D.Treatment of landfill leachate by the Fenton process[J].Water Research,2006,40(20):3683-3694.
[6]徐苏云,何品晶,唐琼瑶,等.Fenton法处理类长填龄渗滤液的氧化和絮凝作用[J].环境科学研究,2008,21(4):20-24.
[7]陈诚,章诗芳,董玉莲,等.臭氧工艺对水中有机物分布影响情况研究[J].广州化工,2006,34(6):29-31.
[8]Baird R,Smith R K.Third century of biochemical oxygen demand[M].Water Environment Federation,2002.