广东梅子冲铅锌钨多金属矿床流体包裹体特征及成矿作用
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摘要
梅子冲铅锌钨多金属矿床位于广东省韶关市一六矿区。野外调查和室内显微镜鉴定表明,梅子冲矿床成矿作用分为两期五阶段,第一期为矽卡岩期,可以分为早期矽卡岩阶段(A1)、晚期矽卡岩阶段(A2)和钾长石白钨矿阶段(A3);第二期为热液期,可以分为石英硫化物阶段(B1)和石英碳酸盐阶段(B2)。矿体的石英和白钨矿中含有富液相的气液两相流体包裹体,地质特征结合包裹体测温资料表明,成矿温度介于207℃~449℃,盐度为1.16%~12.4%,反映矿床形成于中-高温环境。成矿流体特征及成矿温度的演化表明,A1+A2至A3阶段的流体混合作用可能导致了白钨矿的形成,A3至B1阶段的流体混合作用可能促进了铅锌矿的形成。
The Meizichong Pb-Zn-W polymetallic deposit is located in the Yiliu mining area,Shaoguan,Guangdong Province.Field geological investigations and microscope characteristics suggest that the mineralization of this deposit can be divided into 2 episodes,namely skarn episode(A)and hydrothermal episode(B).The former can be subdivided into early skarn stage(A1),late skarn stage(A2)and K-feldspar-tungsten stage(A3),while the latter is subdivided into quartz-sulfide stage(B1)and quartz-carbonate stage(B2).Liquid-rich inclusions were observed in quartz and tungsten from ores.Geological characteristics and micro-thermometric data show that ore-forming temperatures range from 207℃to 449℃,while salinities range from 1.16%to 12.4%,indicating that the deposit was formed in a medium-high temperature environment.The fluid mixing from A1+A2 stage to A3stage might lead to the W precipitation and the fluid mixing from A3 stage to B1 stage might result in the Pb-Zn precipitation.
The Meizichong Pb-Zn-W polymetallic deposit is located in the Yiliu mining area,Shaoguan,Guangdong Province.Field geological investigations and microscope characteristics suggest that the mineralization of this deposit can be divided into 2 episodes,namely skarn episode(A)and hydrothermal episode(B).The former can be subdivided into early skarn stage(A1),late skarn stage(A2)and K-feldspar-tungsten stage(A3),while the latter is subdivided into quartz-sulfide stage(B1)and quartz-carbonate stage(B2).Liquid-rich inclusions were observed in quartz and tungsten from ores.Geological characteristics and micro-thermometric data show that ore-forming temperatures range from 207℃to 449℃,while salinities range from 1.16%to 12.4%,indicating that the deposit was formed in a medium-high temperature environment.The fluid mixing from A1+A2 stage to A3stage might lead to the W precipitation and the fluid mixing from A3 stage to B1 stage might result in the Pb-Zn precipitation.
引文
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Duan Shi-gang,Xue Chun-ji,Liu Guo-yin,Yan Chang-hai,Feng Qiwei,Song Yao-wu.2010.Geology,fluid inclusions and stable isotopic geochemistry of Bailugou Pb-Zn deposit in Luanchuan area,Henan Province[J].Mineral Deposits,29(5):810-826(in Chinese with English abstract)
Gong Qing-jie,Han Dong-Yu,Wang Yu-rong.2006.Experimental determination of scheelite solubilities in 4.0%Na Cl solution in critical region[J].Acta Petrologica Sinica,22(12):3052-3058(in Chinese with English abstract)
Heinrich C A.1990.The chemistry of hydrothermal tin(-tungsten)ore deposition[J].Economic Geology,85(3):457-481
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Nan Yi,Zhou Guo-qiang.2008.Guangdong Province rock strata[M].Wuhan:China University of Geosciences Press:52-149(in Chinese)
Ouyang Hai-Tao,Sun Xiang,Zheng You-ye,Wu song,You Zhi-min,Gen Rui-rui,Wang Xuan.2015.Characteristics of metallogenic fluid in the Lubuzhen Pb-Zn deposit of the Gangdese Belt,Southern Tibet[J].Geology and Exploration,51(5):0816-0827(in Chinese with English abstract)
Pei Tai-chang.1990.Preliminary analysis to metallotects and minerogenetic regularity of endogenic metal mineral resource in ShaoguanRuyuan area[J].Mineral Resources and Geology,4(17):1-10(in Chinese)
Potter R W.1977.Pressure corrections for fluid-inclusion homogenization temperatures based on the volumetric properties of the system Na Cl-H2O[J].J.Res.US Geol.Surv.;(United states),5(5):603-607
Ramboz C,Schnapper D,Dubessy J.1985.The P-Vˉ-T-X-f O2evolution of H2O-CO2-CH4-bearing fluid in a wolframite vein:Reconstruction from fluid inclusion studies[J].Geochimica et Cosmochimica Acta,49(1):205-219
Song Xue-xin,Zhang Jing-kai.1990.Study of fluid inclusions of the Shizhuyuan-Yejiwei W-Sn-Mo-Bi-polymetallic deposit in southern Hunan[J].Mineral Deposits,9(4):332-338(in Chinese)
Tang Yi-ang.2016.Microthermometric study of fluid inclusions and mineralization analysis of Meizichong Pb-Zn-W polymetallic deposit in Guangdong Province[D].Changsha:Central South University:20-21(in Chinese)
Vinogradov A P.1962.Average content of chemical elements in the chief types of igneous rocks of the crust of the Earth[J].Geokhimiy,(7):555-571
Wang Qiao-yun,Hu Rui-zhong,Peng Jian-tang,Bi Xian-wu,Wu Liyan,Li Hua,Su Ben-xun.2007.Characterristics of the fluid inclusions from Yaogangxian tungsten deposit in south of Hunan[J].Acta Petrologica Sinica,23(9):2263-2273(in Chinese with English abstract)
Wang Tian-gang,Ni Pei,Shen Kun,Wang Guo-guang,Zhao Chao,Ding Jun-ying.2011.Characteristic and genetic significance of fluid inclusions in the Changba Zn-Pb deposit,Qinling orogen,China[J].Journal of Nanjing University(Nature Science),47(6):731-743(in Chinese with English abstract)
Wang Xu-dong,Ni Pei,Jiang Shao-yong,Zhao Kui-dong,Wang Tiangang.2010.Origin of ore-forming fluids in the Piaotang tungsten deposit in Jiangxi Province:Evidence from helium and argon isotopes[J].Chinese Science Bulletin,55(7):628-634
Wang Xu-dong,Ni Pei,Yuan Shun-da,Wu Sheng-hua.2012.Fluid inclusion studies of the Huangsha quartz-vein type tungsten deposit,Jiangxi Province[J].Acta Petrologica Sinica,28(1):122-132(in Chineset with English abstract)
Wood S A,Samson I M.2000.The hydrothermal geochemistry of tungsten in granitoid environments:I.Relative solubilities of ferberite and scheelite as a function of T,P,p H,and m Na Cl[J].Economic Geology,95(1):143-182
Wood S A.1992.Experimental determination of the solubility of WO3(s)and the thermodynamic properties of H2WO4(aq)in the range300~600℃at 1 kbar:Calculation of scheelite solubility[J].Geochimica et Cosmochimica Acta,56(5):1827-1836
Wu Gui-jie,Yu Jin-xiang,Wang Chong-jie.1994.Tections and zoning of ore deposits in Yiliu orefield,Qujiang,Guangdong Province[A].Yichang Institute of Geology and Mineral Resources,CAGS(19)[C].Yichang:Yichang Institute of Geology and Mineral Resources:100-110(in Chinese)
Wu Sheng-hua,Liu Lan-ming,Yin Bing,Guo Chun-li,Li Tie-gang,Le Guo-liang,Liu Xiao-fei.2012.Fluid inclusion study of Pb-Zn deposits in Chaishan-Shexingping area of Dongpo,Hunan Province[J].Mineral Deposits,31(2):216-228(in Chinese with English abstract)
Yao Jun-ming,Zhao Tai-ping,Wei Qing-guo,Yuan Zhen-lei.2008.Fluid inclusion features and genetic type of the Wangpingxigou PbZn deposit,Henan Province[J].Acta Petologica Sinica,24(9):2113-2123(in Chinese with English abstract)
Zhang Chang-qing,Mao Jing-wen,Yu Jin-jie,Li Hou-min.2007.Study on fluid inclusion and the metallogenetic mechanism of Chipu PbZn deposit in Sichuan,China[J].Acta Petrologica Sinica,23(10):2541-2552(in Chinese with English abstract)
Zhu Xin-you,Wang Jing-bin,Wang Yan-li,Cheng Xi-yin,Fu Qi-bin,Tian Ye.2015a.The differences of the ore-forming fluid between the vein-type and skarn type tungsten deposits[J].Acta Petrologica Sinica,31(4):941-953(in Chinese with English abstract)
Zhu Xin-you,Wang Jing-bin,Wang Yan-li,Cheng Xi-yin.2015b.The role of magma-hydrothermal transition fluid in the skarn-type tungsten mineralization process:A case study from the Shizhuyuan tungsten and tin polymetallic ore deposit[J].Acta Petrologica Sinica,31(3):891-905(in Chinese with English abstract)
池国祥,赖健清.2009.流体包裹体在矿床研究中的作用[J].矿床地质,28(6):850-855
迟清华,焉明才.2007.应用地球化学元素丰度手册[M].北京:地质出版社:147-188
段世刚,薛春纪,刘国印,燕长海,冯启伟,宋要武.2010.河南栾川百炉沟铅锌矿床地质、流体包裹体和稳定同位素地球化学[J].矿床地质,29(5):810-826
龚庆杰,韩东昱,王玉荣.2006.4.0%Na Cl水溶液临界区域内白钨矿溶解度实验测定[J].岩石学报,22(12):3052-3058
华仁民.1994.成矿过程中由流体混合而导致金属沉淀的研究[J].地球科学进展,9(4):15-22
刘英俊.1982.论钨的成矿地球化学[J].地质与勘探,18(01):15-23
卢焕章.1986.华南钨矿成因[M].重庆:重庆出版社:172-184
南颐,周国强.2008.广东省岩石地层[M].武汉:中国地质大学出版社:52-149
欧阳海涛,孙祥,郑有业,吴松,游智敏,耿瑞瑞,王烜.2015.西藏冈底斯罗布真铅锌矿床成矿流体特征[J].地质与勘探,51(5):816-827
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