湖南瑶岗仙石英脉型钨矿床成矿系统
|
摘要
湖南瑶岗仙石英脉型钨矿床是南岭成矿带具有代表性的矿床。长期以来,对脉型钨矿床的成矿岩体特征及各种不同类型矿化的空间与演化关系一直存在争论。文章以瑶岗仙石英脉型钨矿床为研究对象,在野外地质调查的基础上,针对成矿岩体、含钨石英脉及与之相关的矿化开展地质地球化学研究工作,探讨了岩浆-热液演化过程中形成的各类矿化现象,从而建立了脉型钨矿床成矿系统。在瑶岗仙钨矿床中,成矿地质体即成矿花岗岩为碱长花岗岩,主要矿化类型包括岩浆岩型、云英岩析离体、云英岩脉、石英脉和毒砂黄玉层等,分布于岩体顶部接触带附近。成矿作用可划分为岩浆晚期阶段、岩浆热液过渡阶段、岩浆期后热液阶段,岩浆岩型矿石形成于岩浆晚期,云英岩析离体和云英岩脉等形成于岩浆-热液过渡阶段,石英脉和毒砂黄玉层主要形成于热液阶段,岩浆阶段→热液阶段的演化是连续的。成矿花岗岩侵位深度约为2~3 km,提供了主要成矿物质与成矿流体。成矿系统相对封闭,外来成矿物质和流体较少,含钨石英脉主要以快速充填的形式形成于岩浆固结之后。瑶岗仙矿床含钨石英脉控制垂深达1300 m,"五层楼"垂向分带不明显,顶部未出现细脉带和线脉带,而在石英大脉的顶部出现横向交代形成的毒砂黄玉层。研究表明,瑶岗仙矿区脉型钨矿床成矿系统保存较完整,代表系统顶部的毒砂黄玉层保存完好,剥蚀水平正好达到岩体顶部。
The Yaogangxian quartz vein type tungsten deposit of Hunan Province is a typical deposit in the Nanling metallogenic belt.There long exists controversy over such problems as the granite,a variety of different types of mineralization and the evolution of the deposit.Based on the study of the geology and geochemistry of the oreforming granite,veins,and other mineralization forms,the authors investigated the metallogenic evolution from magma to hydrothermal solution,and established the metallogenic system of the vein-type tungsten deposit.In the Yaogangxian deposit,the metallogenic intrusion is alkali feldspar granite,the main mineralization forms include magmatic ore,greisen inclusion,greisen veins,W-bearing quartz veins and arsenopyrite topaz layers.The mineralization mainly occurs at the top of the contact zone of the granite.Three ore forming stages were recognized:the late magmatic stage,the magma-hydrothermal transition stage and the postmagmatic hydrothermal stage.The magmatic W-Sn ore was formed at the late magmatic stage;the greisen inclusions and greisen veins were formed at the magma-hydrothermal transition stage;the quartz vein and arsenopyrite topaz were formed mainly at the postmagmatic hydrothermal stage.The mineralization continued from the late magmatic stage to the hydrothermal stage.The alkali feldspar granite was emplaced at the depth of about 2~3 km,and provided the ore-forming metals and fluid.W-bearing quartz veins were formed by rapid filling during the hydrothermal stage after magma solidification.The controlled depth of the W-bearing quartz vein in Yaogangxian deposit can be more than 1300 m.Unlike "the!five floor" model,the vertical mineral zoning of the vein are not clear.There is an altered arsenopyrite topaz layer rather than a narrow quartz vein(veinlet) zone at the top of the vein system in the deposit.It is considered that the metallogenic system of the W-bearing quartz vein in the Yaogangxian deposit is well preserved,and the arsenopyrite topaz layer is the top of the system.
The Yaogangxian quartz vein type tungsten deposit of Hunan Province is a typical deposit in the Nanling metallogenic belt.There long exists controversy over such problems as the granite,a variety of different types of mineralization and the evolution of the deposit.Based on the study of the geology and geochemistry of the oreforming granite,veins,and other mineralization forms,the authors investigated the metallogenic evolution from magma to hydrothermal solution,and established the metallogenic system of the vein-type tungsten deposit.In the Yaogangxian deposit,the metallogenic intrusion is alkali feldspar granite,the main mineralization forms include magmatic ore,greisen inclusion,greisen veins,W-bearing quartz veins and arsenopyrite topaz layers.The mineralization mainly occurs at the top of the contact zone of the granite.Three ore forming stages were recognized:the late magmatic stage,the magma-hydrothermal transition stage and the postmagmatic hydrothermal stage.The magmatic W-Sn ore was formed at the late magmatic stage;the greisen inclusions and greisen veins were formed at the magma-hydrothermal transition stage;the quartz vein and arsenopyrite topaz were formed mainly at the postmagmatic hydrothermal stage.The mineralization continued from the late magmatic stage to the hydrothermal stage.The alkali feldspar granite was emplaced at the depth of about 2~3 km,and provided the ore-forming metals and fluid.W-bearing quartz veins were formed by rapid filling during the hydrothermal stage after magma solidification.The controlled depth of the W-bearing quartz vein in Yaogangxian deposit can be more than 1300 m.Unlike "the!five floor" model,the vertical mineral zoning of the vein are not clear.There is an altered arsenopyrite topaz layer rather than a narrow quartz vein(veinlet) zone at the top of the vein system in the deposit.It is considered that the metallogenic system of the W-bearing quartz vein in the Yaogangxian deposit is well preserved,and the arsenopyrite topaz layer is the top of the system.
引文
Bettencourt J S,Leite Jr W B,Goraieb C L,Sparrenberger I,Bello R M S,Payolla B L.2005.Sn-polymetallic greisen-type deposits associated with late-stage rapakivi granites.Brazil-fluid inclusion and stable isotope characteristics[J].Lithos,363-386.
Bureau of Geology and Mineral Resources of Hunan Province.1988.Regional geology of Hunan Province[M].Beijing:Geologioal Publishing House.1-719(in Chinese with English abstract).
Chen H W,Hu R Z,Peng J T and Bi X W.2011.Helium and argon isotopic compositions of ore-forming fluid from the Yaogangxian tungsten deposit and their geological implications[J].Acta Mineralogica Sinica,31(3):597-603(in Chinese with English abstract).
Chen W.1981.Veins width change,mineralization zoning and orebody forecast of Huangsha tungsten deposit[J].Geology and Prospecting.17(6):19-22(in Chinese).
Chen Y C,Pei R F,Zhang H L,et al.1989.The geology of nonferrous and rare metal deposits related to mesozoic granitoids in the Nanling region.China[M].Beijing:Geological Publishing House.414-463(in Chinese with English abstract).
Chen Y R.1981.Geological characteristics and prospecting criteria of Yaogangxian vein-tungsten deposit[J].Geology and Prospecting.17(1):25-30(in Chinese).
Chen Y R.1988.Geological and geochemical characteristics and diagenetic-mineralgenetic processes of Yaogangxian granite[J].Mineral Resource and Geology,2(1):62-72(in Chinese with English abstract).
Chen Z H,et al.2012.Summing research on metallogenic law of resource crisis mines-Research report of typical ore deposit(Dajishan,Kuimeishan,Pangushan and Xihuashan)[R].(in Chinese).
China Non-ferrous Metals Resource Geological Survey.2009.Exploration report of Yiaogangxian tungsten deposit,Yizhang,Hunan Province[R].1-146(in Chinese).
Cuo W K.1983.Metallization of Xihuashan tungsten deposit—an example linking magmatic deuteric infiltration with hydrothermal lodes[J].Mineral Deposits,2:1-12(in Chinese with English abstract).
Department of Geology,Nanjing University.1984.The characteristics of granite and its relationship with mineralization[M].Beijing:Science Press.1-395(in Chinese).
Gu J Y.1984.The morphological zonation of vein tungsten deposits in Southern China[A].In:Yu H Z,ed.Proceedings of symposium on tungsten geology,Nanchang,1981[C].Beijing:Geological Publishing House.35-45(in Chinese).
Guangdong Nonferrous Metal Geological Exploration Company No.932Team.1966.How did we explore and study the quartz vein type tungsten deposit with"the five floor"model[J].Geology and Prospecting,(5):15-19(in Chinese).
Guo W G,Jiang J Z and Gan X P.2010.Research on the ore deposit geologic characteristics and metallogenic model of Yaogangxian tungsten deposit.Hunan Province[J].Mineral Resources and Geology,24(4):309-313(in Chinese with English abstract).
Heinrich C A.1990.The chemistry of tin(-tungsten)ore deposition[J].Econ.Geol.,85:529-550.
Hsu Ke-chin.1957.Discovery of pyrometasometic scheelite deposits near a wolframite-producing district in southern China,and a discussion about the origin of these two classes of deposits[J].Acta Geologica Sinaca,37(2):117-151(in Chinese with English abstract).
Huang H L,Wang W Y,and Feng H Q.1984.Studies on the origin of wolframite quartz vein in limestone[A].In:Yu H Z.ed.Proceedings of symposium on tungsten geology,Nanchang 1981[C].Beijing:Geological Publishing House.47-54(in Chinese).
Huang H L,Chang H L,Li F,Zhang C H,Tan J and Zhou Y.2012.A comparative study of fluid inclusions from coexisting transparent mineral sand opaque minerals in Xihuashan tungsten deposit[J].Mineral Deposits,31(6):1171-1183(in Chinese with English abstract)
Institute of Regional Geological Survey(Hunan Bureau of Geology and Mineral Resources).1990.1/50000 regional geological survey report,G49-35-B[R].l-113(in Chinese).
Landis G P and Rye R O.1974.Geologic,fluid inclusion,and stable isotope studies of the Pasto Buena tungsten-base metal ore deposit,Northern Peru[J].Econ.Geol.,69:1025-1059.
Li S T,Wang J B,Zhu X Y,Wang Y L,Han Ying and Guo L L.2011a.Chronological characteristics of the Yaogangxian composite pluton in Hunan Province[J].Geology and Exploration,47(2):143-150(in Chinese with English abstract).
Li S T,Wang J B,Zhu X Y and Li C.2011b.Re-Os dating of molybdenite and sulfur isotope analysis of the Yaogangxian tungsten polymetallic deposits in Hunan Province and their geological significance[J].Geoscience.25(2):228-235(in Chinese with English abstract).
Li T.1959.The study on the pulse-precipitation zone in the sulfide-type tungsten deposit[J].Chinese Journal of Geology,2(10):300-305(in Chinese).
Lin X D,Zhang D H and Zhang C L.1986.A discussion on the property of ore-forming fluid of the wolframite quartz-vein in the Yaogangxian tungsten deposit,Yizhang County,Hunan Province[J].Earth Science-Journal of China University of Geosciences,11(2):153-160(in Chinese with English abstract).
Lin X D,Zhang C L and Zhang D H.1987.Vertical zonation of tungsten-bearing quartz veins and mineralization in Yaogangxian,Hunan[J].Geological Review,33(6):539-546(in Chinese with English abstract).
Liu K H.1989.Primary geochemical zoning of the Shanhu W-Sn deposit and its prospecting significance[J].Journal of Guilin College of Geology,9(4):421-430(in Chinese with English abstract).
Lu Z C,Lu G X,Li Y S,Yan T J and Zhang Z.2011.New progress on deep prospecting for the meaning of metallogenic model research[J].Geological Bulletin of China,30(4):532-537(in Chinese with English abstract).
McDonough W F and Sun S S.1995.The composition of the Earth[J].Chemical Geology,120:223-253.
Pollard P J and Taylor R G.1986.Progressive evolution of alteration and tin mineralization:Controls by interstitial permeability and fracture-related tapping of magmatic fluid reservoirs in tin granites[J].Econ.Geol.,81:1795-1800.
Ren Y C,Chen M X and Wang C C.1986.Characteristics and vertical zoning of tungsten-bismuth minerals in the Pangushan quartz-vein type tungsten deposit of Jiangxi Province[J].Mineral Deposits.5(2):63-74(in Chinese with English abstract).
Roberts S,Sanderson D J and Gumiel P.1998.Fractal analysis of Sn-W mineralization from Central Iberia:Insights into the role of fracture connectivity in the formation of an ore deposit[J].Econ.Geol.,93:360-365.
Sanderson D J,Roberts S,Gumiel P and Greenfield C.2008.Quantitative analysis of tin-and tungsten-bearing sheeted vein systems[J].Econ.Geol.,103:1043-1056.
Shi C Y,Yan M C,Liu C M,Chi Q H,Hu S Q,Gu T X,Bu W and Yan W D.2005.Abundances of chemical elements in granitiods of China and their characteristics[J].Geochemica,34(5):470-482(in Chinese with English abstract).
Tang Y F,Miao S P,Li S Z,Gu J Y,Li Y D and Wu Y L.1989.Tungsten deposits of China[M].Beijing:Geological Publishing House.1-104(in Chinese).
Wang D S,Lu S M,Hu B Y,Zhang S B.Ruan Y Y and Cheng D S.2011.The geological characteristics and mineralization model of a tungsten-tin deposit[J].China Tungsten Industry.26(2):6-ll(in Chinese with English abstract).
Wang J B.1990.Features and origin of the Xiangyuan tin deposit[J].Geology and Prospecting.26(9):17-20(in Chinese with English abstract).
Wang R C,Zhu J C,Zhang W L,Xie L,Yu A P and Che X D.2008.Ore-forming mineralogy of W-Sn granites in the Nanling range:Concept and case study[J].Geological Journal of China Universities,14(4):485-495(in Chinese with English abstract).
Wei X L.2012.The Metallogenic features and ore-finding potentiality of the tungsten deposits in south Jiangxi Province[J].China Tungsten Industry.27(1):14-21(in Chinese with English abstract).
Wu Y L,Mei Y W,Liu P C,et al.1987.Xihuashan tungsten ore geology[M].Beijing:Geological Publishing House.1-317(in Chinese).
Xia H Y,Liang S Y,Shuai D Q and Xie W X.1982.The existing form and enrichment regularity of Huangsha wolframite-quartz vein type deposit.Jiangxi Province[J].Chinese Science Bulletin.(3):164-167(in Chinese).
Xia W H,Zhang J T,Feng Z W,et al.1989.Geology of the granitetype rare metal deposit in Nanling[M].Wuhan:China University of Geosciences Press.1-112(in Chinese with English abstract).
Xiao G M and Di W.2011.Metallogenic regularity of tungsten deposits in northern Guangdong Province[J].Geology and Mineral Resources of South China,27(2):132-140(in Chinese with English abstract).
Xing S J,Chen D S and Li G L.2010.Analysis on the vertical zonal law of"tungsten upon and molybdenum down"in the Zhangdongkeng WMo deposit of Jiangxi[J].China Tungsten Industry,25(5):8-12(in Chinese with English abstract).
Yaogangxian Mining Co.1988.Mining annals of Yaogangxian tungsten deposit.Hunan Province[R].l-22(in Chinese).
Yu Z F,Xu H,Zhu X Y,Wang Y L and Cheng X Y.2015.Characteristics and evolution of ore-forming fluids in Yaogangxian tungsten deposit.Hunan[J].Mineral Deposits,34(2):309-320(in Chinese with English abstract).
Zhai Y S.1999.On the metallogenic system[J].Earth Science Frontiers,6(1):13-27(in Chinese).
Zhang D H.1984.Geological characteristics and metallogenic mechanism of the Yaogangxian wolframite deposit.Hunan Province[D].Wuhan:Master degree thesis of Wuhan College of Geology(in Chinese).
Zhang D H.1988.On the liquid fractionation origin of wolframite quartz veins[J].Geology and Prospecting,24(4):15-20(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,He P,Fu Q B and Li S T.2012.Characteristics of alkali feldspar granite in tungsten(tin)deposits of Nanling region[J].Geology in China.39(2):359-381(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,He P,Fu Q B and Li S T.2013.Characteristics of greisen inclusions in alkali feldspar granite of Yaogangxian tungsten deposit[J].Mineral Deposits,32(3):533-544(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y and Fu Q B.2014a.Relative closed ore-forming in the Tungsten-Bearing quartz Vein:A case study of the Yaogangxian,Hunan Province[J].Acta Geologica Sinica,88(5):825-835(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,Fu Q B,Fu M and Yu Z F.2014b.The characteristics of the S,Pb,O,H isotope of Yaogangxian tungsten deposits,Hunan Province[J].Geology and Exploration,50(5):947-960(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L and Cheng X Y.2015a.The role of magma-hydrothermal transition fluid in the skarn-type tungsten mineralization process:A case study from the Shizhuyuan tungsten and tin polymetallic ore deposit[J].Acta Petrologica Sinica,31(3):891-905(in Chinese with English abstract).
Zhu X Y,Wang Y L,Cheng X Y and Li S T.2015b.Characteristics of layer alteration at the top of quartz vein,Yaogangxian tungsten deposit,Hunan province[J].Geology in China,42(2):621-630(in Chinese with English abstract).
Zhu Y L,Li C Y and Zhu Y H.1981.Tungsten ggeology in southern Jiangxi[M].Nanchang:Jiangxi People's Press.1-270(in Chinese with English abstract).
陈宏伟,胡瑞忠,彭建堂,毕献武.2011.湖南瑶岗仙钨矿床成矿流体的氦、氩同位素组成及其意义[J].矿物学报,31(3):597-603.
陈微.1981.黄沙钨矿脉幅变化、矿化分带与矿体预测[J].地质与勘探,17(6):19-22.
陈依壤.1981.瑶岗仙脉钨矿床地质特征与找矿标志[J].地质与勘探,17(2)25-30.
陈依壤.1988.瑶岗仙花岗岩地质地球化学特征与成岩成矿作用[J].矿产与地质,2(1):62-72.
陈毓川,裴荣富,张宏良等.1989.南岭地区与中生代花岗岩类有关的有色及稀有金属矿床地质[M].北京:地质出版社,414-463.
陈振辉,等.2012.全国危机矿山成矿规律总结研究——典型矿床研究报告(大吉山、岿美山、盘古山和西华山)[R].
古菊云.1984.华南脉钨矿床的形态分带[A].见:余鸿彰,主编.钨矿地质讨论会论文集(中文版),南昌1981[M].北京:地质出版社.35-45
广东有色金属地质勘探公司932队.1966.我们是怎样用“五层楼”规律寻找、评价和勘探黑钨石英脉矿床的[J].地质与勘探,(5):15-19.
郭伟革,蒋加燥,甘先平.2010.湖南瑶岗仙钨矿床地质特征及成矿模式探讨[J].矿产与地质,24(4):309-313.
郭文魁.1983.西华山钨矿床的金属矿化作用一个与岩浆后期渗浸相联系的热液脉矿的实例[J].矿床地质,2:1-12.
湖南省地质矿产局.1988.湖南省区域地质志[M].北京:地质出版社.1-719.
湖南省地质矿产局区域地质调查所.1990.1/50000区域地质调查报告,瑶岗仙幅[R].G49-35-B,1-113.
黄汉烈,王韦玉,冯海清.1984.关于石灰岩中脉钨矿床黑钨矿的成因问题[A].见:余鸿彰,主编.钨矿地质讨论会论文集(中文版),南昌1981[M].北京:地质出版社.47-54.
黄惠兰,常海亮,李芳,张春红,谭靖,周云.2012.西华山钨矿床共生透明矿物与不透明矿物中流体包裹体的对比研究[J].矿床地质,31(6):1171-1183.
康永孚,苗树屏,李崇佑,古菊云,李亿斗,吴永乐.1989.中国钨矿床[M].北京:地质出版社.1-104.
黎彤.1959.论硫化物型钨矿床的脉动-沉淀分带[J].地质科学,2(10):300-305.
李顺庭,王京彬,祝新友,王艳丽,韩英,郭宁宁.2011a.湖南瑶岗仙复式岩体的年代学特征[J].地质与勘探,47(2):143-150.
李顺庭,王京彬,祝新友,李超.2011b.湖南瑶岗仙钨多金属矿床辉钼矿Re-Os同位素定年和硫同位素分析及其地质意义[J].现代地质,25(2):228-235.
林新多,张德会,章传玲.1986.湖南宜章瑶岗仙黑钨矿石英脉成矿流体性质的探讨[J].地球科学,11(2):153-160.
林新多,章传玲,张德会.1987.初论湖南瑶岗仙含钨矿脉及矿化的垂直分带[J].地质论评,33(6):539-546.
刘慷怀.1989.广西珊瑚钨锡矿床原生地球化学分带及其找矿意义[J].桂林冶金地质学院学报,9(4):421-430.
吕志成,吕古贤,李永胜,颜廷杰,张志.2011.深部找矿新进展对矿床成矿模式研究的意义[J].地质通报,30(4):532-537.
南京大学地质系.1984.华南不同时代花岗岩及其与成矿关系研究[M].北京:科学出版社.1-395.
任英忱,程敏清,王存昌.1986.江西盘古山石英脉型钨矿床钨秘矿物特征及矿物的垂直分带[J].矿床地质,5(2):63-74.
史长义,鄢明才,刘崇民,迟清华,胡树起,顾铁新,卜维,鄢卫东.2005.中国花岗岩类化学元素丰度及特征[J].地球化学,34(5):470-482.
王定生,陆思明,胡本语,张声波,阮瑜瑜,陈冬生.2011.江西茅坪钨锡矿床地质特征及成矿模式[J].中国钨业,26(2):6-11.
王京彬.1990.湘源锡矿床的特征及其成因探讨[J].地质与勘探,26(9):17-20.
王汝成,朱金初,张文兰,谢磊,于阿朋,车旭东.2008.南岭地区钨锡花岗岩的成矿矿物学:概念与实例[J].高校地质学报,14(4):485-495.
韦星林.2012.赣南钨矿成矿特征与找矿前景[J].中国钨业,27(1):14-21.
吴永乐,梅勇文,刘鹏程,蔡常良,卢同衍.1987.西华山钨矿地质[M].北京:地质出版社.1-317.
夏宏远,梁书艺,帅德权,谢为鑫.1982.江西黄沙黑钨矿石英脉中银的存在形式和富集规律[J].科学通报,(3):164-167.
夏卫华,章绵统,冯志文等.1989.南岭花岗岩型稀有金属矿床地质[M].武汉:中国地质大学出版社.14-115.
肖光铭,邸文.2011.粤北地区钨成矿规律研究[J].华南地质与矿产,27(2):132-140.
幸世军,陈冬生,李光来.2010.江西樟东坑钨钼矿床“上钨下钼”垂向分带规律浅析[J].中国钨业,25(5):8-12.
徐克勤.1957.湘南钨铁锰矿矿区矽卡岩型钙钨矿的发现,并论两类矿床在成因上的联系[J].地质学报,37(2):117-151.
瑶岗仙钨矿.1988.瑶岗仙矿山志[R].1-22.有色金属矿产地质调查中心.2009.湖南省宜章县瑶岗仙钨矿接替资源勘查报告[R].1-146.
于志峰,许虹,祝新友,王艳丽,程细音.2015.湖南瑶岗仙钨矿床成矿流体演化特征研究[J].矿床地质,34(2):309-320
翟裕生.1999.论成矿系统[J].地学前缘,6(1):14-28
张德会.1984.湖南瑶岗仙黑钨矿矿床地质特征及其成矿机制[D].武汉:武汉地质学院硕士学位论文.
张德会.1988.试论石英脉型黑钨矿床的液态分离成因[J].地质与勘探,24(7):15-20.
朱焱岭,李崇佑,林运淮.1981.赣南钨矿地质[M].南昌:江西人民出版社.1-270.
祝新友,王京彬,王艳丽,程细音,何鹏,傅其斌,李顺庭.2012.南岭锡钨多金属矿区碱长花岗岩的厘定及其意义[J].中国地质,39(2):359-381.
祝新友,王京彬,王艳丽,程细音,何鹏,傅其斌,李顺庭.2013.黑钨矿矿床中云英岩包体及岩浆液态分异成矿研究——以湖南瑶岗仙钨矿为例[J].矿床地质,32(3):533-544.
祝新友,王京彬,王艳丽,陈细音,傅其斌.2014a.论石英脉型钨矿成矿系统的相对封闭性--以湖南瑶岗仙脉型钨矿床为例[J].地质学报,88(5):825-835.
祝新友,王京彬,王艳丽,程细音,傅其斌,傅迷,于志峰.2014b.湖南瑶岗仙钨矿稳定同位素地球化学研究[J].地质与勘探,50(5):947-960.
祝新友,王京彬,王艳丽,陈细音.2015a.浆液过渡态流体在矽卡岩型钨矿成矿过程中的作用——以湖南柿竹园钨锡多金属矿为例[J].岩石学报,31(3):891-905.
祝新友,王艳丽,程细音,李顺庭.2015b.湖南瑶岗仙石英脉型钨矿床顶部的横向交代作用[J].中国地质,42(2):621-630.
Bureau of Geology and Mineral Resources of Hunan Province.1988.Regional geology of Hunan Province[M].Beijing:Geologioal Publishing House.1-719(in Chinese with English abstract).
Chen H W,Hu R Z,Peng J T and Bi X W.2011.Helium and argon isotopic compositions of ore-forming fluid from the Yaogangxian tungsten deposit and their geological implications[J].Acta Mineralogica Sinica,31(3):597-603(in Chinese with English abstract).
Chen W.1981.Veins width change,mineralization zoning and orebody forecast of Huangsha tungsten deposit[J].Geology and Prospecting.17(6):19-22(in Chinese).
Chen Y C,Pei R F,Zhang H L,et al.1989.The geology of nonferrous and rare metal deposits related to mesozoic granitoids in the Nanling region.China[M].Beijing:Geological Publishing House.414-463(in Chinese with English abstract).
Chen Y R.1981.Geological characteristics and prospecting criteria of Yaogangxian vein-tungsten deposit[J].Geology and Prospecting.17(1):25-30(in Chinese).
Chen Y R.1988.Geological and geochemical characteristics and diagenetic-mineralgenetic processes of Yaogangxian granite[J].Mineral Resource and Geology,2(1):62-72(in Chinese with English abstract).
Chen Z H,et al.2012.Summing research on metallogenic law of resource crisis mines-Research report of typical ore deposit(Dajishan,Kuimeishan,Pangushan and Xihuashan)[R].(in Chinese).
China Non-ferrous Metals Resource Geological Survey.2009.Exploration report of Yiaogangxian tungsten deposit,Yizhang,Hunan Province[R].1-146(in Chinese).
Cuo W K.1983.Metallization of Xihuashan tungsten deposit—an example linking magmatic deuteric infiltration with hydrothermal lodes[J].Mineral Deposits,2:1-12(in Chinese with English abstract).
Department of Geology,Nanjing University.1984.The characteristics of granite and its relationship with mineralization[M].Beijing:Science Press.1-395(in Chinese).
Gu J Y.1984.The morphological zonation of vein tungsten deposits in Southern China[A].In:Yu H Z,ed.Proceedings of symposium on tungsten geology,Nanchang,1981[C].Beijing:Geological Publishing House.35-45(in Chinese).
Guangdong Nonferrous Metal Geological Exploration Company No.932Team.1966.How did we explore and study the quartz vein type tungsten deposit with"the five floor"model[J].Geology and Prospecting,(5):15-19(in Chinese).
Guo W G,Jiang J Z and Gan X P.2010.Research on the ore deposit geologic characteristics and metallogenic model of Yaogangxian tungsten deposit.Hunan Province[J].Mineral Resources and Geology,24(4):309-313(in Chinese with English abstract).
Heinrich C A.1990.The chemistry of tin(-tungsten)ore deposition[J].Econ.Geol.,85:529-550.
Hsu Ke-chin.1957.Discovery of pyrometasometic scheelite deposits near a wolframite-producing district in southern China,and a discussion about the origin of these two classes of deposits[J].Acta Geologica Sinaca,37(2):117-151(in Chinese with English abstract).
Huang H L,Wang W Y,and Feng H Q.1984.Studies on the origin of wolframite quartz vein in limestone[A].In:Yu H Z.ed.Proceedings of symposium on tungsten geology,Nanchang 1981[C].Beijing:Geological Publishing House.47-54(in Chinese).
Huang H L,Chang H L,Li F,Zhang C H,Tan J and Zhou Y.2012.A comparative study of fluid inclusions from coexisting transparent mineral sand opaque minerals in Xihuashan tungsten deposit[J].Mineral Deposits,31(6):1171-1183(in Chinese with English abstract)
Institute of Regional Geological Survey(Hunan Bureau of Geology and Mineral Resources).1990.1/50000 regional geological survey report,G49-35-B[R].l-113(in Chinese).
Landis G P and Rye R O.1974.Geologic,fluid inclusion,and stable isotope studies of the Pasto Buena tungsten-base metal ore deposit,Northern Peru[J].Econ.Geol.,69:1025-1059.
Li S T,Wang J B,Zhu X Y,Wang Y L,Han Ying and Guo L L.2011a.Chronological characteristics of the Yaogangxian composite pluton in Hunan Province[J].Geology and Exploration,47(2):143-150(in Chinese with English abstract).
Li S T,Wang J B,Zhu X Y and Li C.2011b.Re-Os dating of molybdenite and sulfur isotope analysis of the Yaogangxian tungsten polymetallic deposits in Hunan Province and their geological significance[J].Geoscience.25(2):228-235(in Chinese with English abstract).
Li T.1959.The study on the pulse-precipitation zone in the sulfide-type tungsten deposit[J].Chinese Journal of Geology,2(10):300-305(in Chinese).
Lin X D,Zhang D H and Zhang C L.1986.A discussion on the property of ore-forming fluid of the wolframite quartz-vein in the Yaogangxian tungsten deposit,Yizhang County,Hunan Province[J].Earth Science-Journal of China University of Geosciences,11(2):153-160(in Chinese with English abstract).
Lin X D,Zhang C L and Zhang D H.1987.Vertical zonation of tungsten-bearing quartz veins and mineralization in Yaogangxian,Hunan[J].Geological Review,33(6):539-546(in Chinese with English abstract).
Liu K H.1989.Primary geochemical zoning of the Shanhu W-Sn deposit and its prospecting significance[J].Journal of Guilin College of Geology,9(4):421-430(in Chinese with English abstract).
Lu Z C,Lu G X,Li Y S,Yan T J and Zhang Z.2011.New progress on deep prospecting for the meaning of metallogenic model research[J].Geological Bulletin of China,30(4):532-537(in Chinese with English abstract).
McDonough W F and Sun S S.1995.The composition of the Earth[J].Chemical Geology,120:223-253.
Pollard P J and Taylor R G.1986.Progressive evolution of alteration and tin mineralization:Controls by interstitial permeability and fracture-related tapping of magmatic fluid reservoirs in tin granites[J].Econ.Geol.,81:1795-1800.
Ren Y C,Chen M X and Wang C C.1986.Characteristics and vertical zoning of tungsten-bismuth minerals in the Pangushan quartz-vein type tungsten deposit of Jiangxi Province[J].Mineral Deposits.5(2):63-74(in Chinese with English abstract).
Roberts S,Sanderson D J and Gumiel P.1998.Fractal analysis of Sn-W mineralization from Central Iberia:Insights into the role of fracture connectivity in the formation of an ore deposit[J].Econ.Geol.,93:360-365.
Sanderson D J,Roberts S,Gumiel P and Greenfield C.2008.Quantitative analysis of tin-and tungsten-bearing sheeted vein systems[J].Econ.Geol.,103:1043-1056.
Shi C Y,Yan M C,Liu C M,Chi Q H,Hu S Q,Gu T X,Bu W and Yan W D.2005.Abundances of chemical elements in granitiods of China and their characteristics[J].Geochemica,34(5):470-482(in Chinese with English abstract).
Tang Y F,Miao S P,Li S Z,Gu J Y,Li Y D and Wu Y L.1989.Tungsten deposits of China[M].Beijing:Geological Publishing House.1-104(in Chinese).
Wang D S,Lu S M,Hu B Y,Zhang S B.Ruan Y Y and Cheng D S.2011.The geological characteristics and mineralization model of a tungsten-tin deposit[J].China Tungsten Industry.26(2):6-ll(in Chinese with English abstract).
Wang J B.1990.Features and origin of the Xiangyuan tin deposit[J].Geology and Prospecting.26(9):17-20(in Chinese with English abstract).
Wang R C,Zhu J C,Zhang W L,Xie L,Yu A P and Che X D.2008.Ore-forming mineralogy of W-Sn granites in the Nanling range:Concept and case study[J].Geological Journal of China Universities,14(4):485-495(in Chinese with English abstract).
Wei X L.2012.The Metallogenic features and ore-finding potentiality of the tungsten deposits in south Jiangxi Province[J].China Tungsten Industry.27(1):14-21(in Chinese with English abstract).
Wu Y L,Mei Y W,Liu P C,et al.1987.Xihuashan tungsten ore geology[M].Beijing:Geological Publishing House.1-317(in Chinese).
Xia H Y,Liang S Y,Shuai D Q and Xie W X.1982.The existing form and enrichment regularity of Huangsha wolframite-quartz vein type deposit.Jiangxi Province[J].Chinese Science Bulletin.(3):164-167(in Chinese).
Xia W H,Zhang J T,Feng Z W,et al.1989.Geology of the granitetype rare metal deposit in Nanling[M].Wuhan:China University of Geosciences Press.1-112(in Chinese with English abstract).
Xiao G M and Di W.2011.Metallogenic regularity of tungsten deposits in northern Guangdong Province[J].Geology and Mineral Resources of South China,27(2):132-140(in Chinese with English abstract).
Xing S J,Chen D S and Li G L.2010.Analysis on the vertical zonal law of"tungsten upon and molybdenum down"in the Zhangdongkeng WMo deposit of Jiangxi[J].China Tungsten Industry,25(5):8-12(in Chinese with English abstract).
Yaogangxian Mining Co.1988.Mining annals of Yaogangxian tungsten deposit.Hunan Province[R].l-22(in Chinese).
Yu Z F,Xu H,Zhu X Y,Wang Y L and Cheng X Y.2015.Characteristics and evolution of ore-forming fluids in Yaogangxian tungsten deposit.Hunan[J].Mineral Deposits,34(2):309-320(in Chinese with English abstract).
Zhai Y S.1999.On the metallogenic system[J].Earth Science Frontiers,6(1):13-27(in Chinese).
Zhang D H.1984.Geological characteristics and metallogenic mechanism of the Yaogangxian wolframite deposit.Hunan Province[D].Wuhan:Master degree thesis of Wuhan College of Geology(in Chinese).
Zhang D H.1988.On the liquid fractionation origin of wolframite quartz veins[J].Geology and Prospecting,24(4):15-20(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,He P,Fu Q B and Li S T.2012.Characteristics of alkali feldspar granite in tungsten(tin)deposits of Nanling region[J].Geology in China.39(2):359-381(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,He P,Fu Q B and Li S T.2013.Characteristics of greisen inclusions in alkali feldspar granite of Yaogangxian tungsten deposit[J].Mineral Deposits,32(3):533-544(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y and Fu Q B.2014a.Relative closed ore-forming in the Tungsten-Bearing quartz Vein:A case study of the Yaogangxian,Hunan Province[J].Acta Geologica Sinica,88(5):825-835(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L,Cheng X Y,Fu Q B,Fu M and Yu Z F.2014b.The characteristics of the S,Pb,O,H isotope of Yaogangxian tungsten deposits,Hunan Province[J].Geology and Exploration,50(5):947-960(in Chinese with English abstract).
Zhu X Y,Wang J B,Wang Y L and Cheng X Y.2015a.The role of magma-hydrothermal transition fluid in the skarn-type tungsten mineralization process:A case study from the Shizhuyuan tungsten and tin polymetallic ore deposit[J].Acta Petrologica Sinica,31(3):891-905(in Chinese with English abstract).
Zhu X Y,Wang Y L,Cheng X Y and Li S T.2015b.Characteristics of layer alteration at the top of quartz vein,Yaogangxian tungsten deposit,Hunan province[J].Geology in China,42(2):621-630(in Chinese with English abstract).
Zhu Y L,Li C Y and Zhu Y H.1981.Tungsten ggeology in southern Jiangxi[M].Nanchang:Jiangxi People's Press.1-270(in Chinese with English abstract).
陈宏伟,胡瑞忠,彭建堂,毕献武.2011.湖南瑶岗仙钨矿床成矿流体的氦、氩同位素组成及其意义[J].矿物学报,31(3):597-603.
陈微.1981.黄沙钨矿脉幅变化、矿化分带与矿体预测[J].地质与勘探,17(6):19-22.
陈依壤.1981.瑶岗仙脉钨矿床地质特征与找矿标志[J].地质与勘探,17(2)25-30.
陈依壤.1988.瑶岗仙花岗岩地质地球化学特征与成岩成矿作用[J].矿产与地质,2(1):62-72.
陈毓川,裴荣富,张宏良等.1989.南岭地区与中生代花岗岩类有关的有色及稀有金属矿床地质[M].北京:地质出版社,414-463.
陈振辉,等.2012.全国危机矿山成矿规律总结研究——典型矿床研究报告(大吉山、岿美山、盘古山和西华山)[R].
古菊云.1984.华南脉钨矿床的形态分带[A].见:余鸿彰,主编.钨矿地质讨论会论文集(中文版),南昌1981[M].北京:地质出版社.35-45
广东有色金属地质勘探公司932队.1966.我们是怎样用“五层楼”规律寻找、评价和勘探黑钨石英脉矿床的[J].地质与勘探,(5):15-19.
郭伟革,蒋加燥,甘先平.2010.湖南瑶岗仙钨矿床地质特征及成矿模式探讨[J].矿产与地质,24(4):309-313.
郭文魁.1983.西华山钨矿床的金属矿化作用一个与岩浆后期渗浸相联系的热液脉矿的实例[J].矿床地质,2:1-12.
湖南省地质矿产局.1988.湖南省区域地质志[M].北京:地质出版社.1-719.
湖南省地质矿产局区域地质调查所.1990.1/50000区域地质调查报告,瑶岗仙幅[R].G49-35-B,1-113.
黄汉烈,王韦玉,冯海清.1984.关于石灰岩中脉钨矿床黑钨矿的成因问题[A].见:余鸿彰,主编.钨矿地质讨论会论文集(中文版),南昌1981[M].北京:地质出版社.47-54.
黄惠兰,常海亮,李芳,张春红,谭靖,周云.2012.西华山钨矿床共生透明矿物与不透明矿物中流体包裹体的对比研究[J].矿床地质,31(6):1171-1183.
康永孚,苗树屏,李崇佑,古菊云,李亿斗,吴永乐.1989.中国钨矿床[M].北京:地质出版社.1-104.
黎彤.1959.论硫化物型钨矿床的脉动-沉淀分带[J].地质科学,2(10):300-305.
李顺庭,王京彬,祝新友,王艳丽,韩英,郭宁宁.2011a.湖南瑶岗仙复式岩体的年代学特征[J].地质与勘探,47(2):143-150.
李顺庭,王京彬,祝新友,李超.2011b.湖南瑶岗仙钨多金属矿床辉钼矿Re-Os同位素定年和硫同位素分析及其地质意义[J].现代地质,25(2):228-235.
林新多,张德会,章传玲.1986.湖南宜章瑶岗仙黑钨矿石英脉成矿流体性质的探讨[J].地球科学,11(2):153-160.
林新多,章传玲,张德会.1987.初论湖南瑶岗仙含钨矿脉及矿化的垂直分带[J].地质论评,33(6):539-546.
刘慷怀.1989.广西珊瑚钨锡矿床原生地球化学分带及其找矿意义[J].桂林冶金地质学院学报,9(4):421-430.
吕志成,吕古贤,李永胜,颜廷杰,张志.2011.深部找矿新进展对矿床成矿模式研究的意义[J].地质通报,30(4):532-537.
南京大学地质系.1984.华南不同时代花岗岩及其与成矿关系研究[M].北京:科学出版社.1-395.
任英忱,程敏清,王存昌.1986.江西盘古山石英脉型钨矿床钨秘矿物特征及矿物的垂直分带[J].矿床地质,5(2):63-74.
史长义,鄢明才,刘崇民,迟清华,胡树起,顾铁新,卜维,鄢卫东.2005.中国花岗岩类化学元素丰度及特征[J].地球化学,34(5):470-482.
王定生,陆思明,胡本语,张声波,阮瑜瑜,陈冬生.2011.江西茅坪钨锡矿床地质特征及成矿模式[J].中国钨业,26(2):6-11.
王京彬.1990.湘源锡矿床的特征及其成因探讨[J].地质与勘探,26(9):17-20.
王汝成,朱金初,张文兰,谢磊,于阿朋,车旭东.2008.南岭地区钨锡花岗岩的成矿矿物学:概念与实例[J].高校地质学报,14(4):485-495.
韦星林.2012.赣南钨矿成矿特征与找矿前景[J].中国钨业,27(1):14-21.
吴永乐,梅勇文,刘鹏程,蔡常良,卢同衍.1987.西华山钨矿地质[M].北京:地质出版社.1-317.
夏宏远,梁书艺,帅德权,谢为鑫.1982.江西黄沙黑钨矿石英脉中银的存在形式和富集规律[J].科学通报,(3):164-167.
夏卫华,章绵统,冯志文等.1989.南岭花岗岩型稀有金属矿床地质[M].武汉:中国地质大学出版社.14-115.
肖光铭,邸文.2011.粤北地区钨成矿规律研究[J].华南地质与矿产,27(2):132-140.
幸世军,陈冬生,李光来.2010.江西樟东坑钨钼矿床“上钨下钼”垂向分带规律浅析[J].中国钨业,25(5):8-12.
徐克勤.1957.湘南钨铁锰矿矿区矽卡岩型钙钨矿的发现,并论两类矿床在成因上的联系[J].地质学报,37(2):117-151.
瑶岗仙钨矿.1988.瑶岗仙矿山志[R].1-22.有色金属矿产地质调查中心.2009.湖南省宜章县瑶岗仙钨矿接替资源勘查报告[R].1-146.
于志峰,许虹,祝新友,王艳丽,程细音.2015.湖南瑶岗仙钨矿床成矿流体演化特征研究[J].矿床地质,34(2):309-320
翟裕生.1999.论成矿系统[J].地学前缘,6(1):14-28
张德会.1984.湖南瑶岗仙黑钨矿矿床地质特征及其成矿机制[D].武汉:武汉地质学院硕士学位论文.
张德会.1988.试论石英脉型黑钨矿床的液态分离成因[J].地质与勘探,24(7):15-20.
朱焱岭,李崇佑,林运淮.1981.赣南钨矿地质[M].南昌:江西人民出版社.1-270.
祝新友,王京彬,王艳丽,程细音,何鹏,傅其斌,李顺庭.2012.南岭锡钨多金属矿区碱长花岗岩的厘定及其意义[J].中国地质,39(2):359-381.
祝新友,王京彬,王艳丽,程细音,何鹏,傅其斌,李顺庭.2013.黑钨矿矿床中云英岩包体及岩浆液态分异成矿研究——以湖南瑶岗仙钨矿为例[J].矿床地质,32(3):533-544.
祝新友,王京彬,王艳丽,陈细音,傅其斌.2014a.论石英脉型钨矿成矿系统的相对封闭性--以湖南瑶岗仙脉型钨矿床为例[J].地质学报,88(5):825-835.
祝新友,王京彬,王艳丽,程细音,傅其斌,傅迷,于志峰.2014b.湖南瑶岗仙钨矿稳定同位素地球化学研究[J].地质与勘探,50(5):947-960.
祝新友,王京彬,王艳丽,陈细音.2015a.浆液过渡态流体在矽卡岩型钨矿成矿过程中的作用——以湖南柿竹园钨锡多金属矿为例[J].岩石学报,31(3):891-905.
祝新友,王艳丽,程细音,李顺庭.2015b.湖南瑶岗仙石英脉型钨矿床顶部的横向交代作用[J].中国地质,42(2):621-630.