生物柴油的研究进展及发展方向
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摘要
为了减少温室气体排放,减轻环境污染,加速发展生物燃料产业已引起国内外许多国家的关注。本文着重从生物柴油的制备技术、化学反应、反应机理、使用的催化剂和工业化工艺出发,探究不同工艺生物柴油的特点,总结不同工艺的优缺点,对未来生物柴油的现状和发展趋势进行了综述和分析。
order to reduce greenhouse gas emissions and environmental pollution,accelerating the development of biofuel industry has attracted the attention of many countries at home and abroad.This paper focuses on the preparation technology,chemical reaction,reaction mechanism,catalyst and industrial process of biodiesel,explores the characteristics of different processes of biodiesel.The advantages and disadvantages of different processes were summarized,and the status quo and development trend of biodiesel in the future were reviewed and analyzed.
order to reduce greenhouse gas emissions and environmental pollution,accelerating the development of biofuel industry has attracted the attention of many countries at home and abroad.This paper focuses on the preparation technology,chemical reaction,reaction mechanism,catalyst and industrial process of biodiesel,explores the characteristics of different processes of biodiesel.The advantages and disadvantages of different processes were summarized,and the status quo and development trend of biodiesel in the future were reviewed and analyzed.
引文
[1] Connemann J,Krallmann A,Fischer E.Process for the continuous production of lower alkyl esters of higher fatty acids:US,5354878[P].1994-10-11.
[2] 忻耀年.现代生物柴油的生产工艺及产品质量[J].中国油脂,2003,28(11):62-64.
[3] Arkansas.Biodiesel plant increasing production[J].Land line magazine,2006,9:311-322.
[4] 曾广溯,我国基础油脂化学品的生产工艺水平[J].日用化学工业,2001,12(6):37-40.
[5] Ma F,Clements L D,Hanna M A.The effect of mixing on transesterification of beef tallow[J].Bioresource Tcnology,1999,69:289-293.
[6] 盛梅,邬国英,徐鸽,等.生物柴油的制备[J].高校化学工程学报,2004,18(2):231-236.
[7] 杨振强,谢文磊,左玉.固体碱催化剂在油脂酯交换反应中的应用[J].粮食与油脂,2006.7:13-15.
[8] 张高勇,李天栋.脂肪酸烷基酯的生产方法:CN,1810761[P].2006-08-02.
[9] Stern R,Hillion G,Gateau P,et al.Process for manufacturing a composition of fatty acid esters useful as gas oil substitute motor fuel with hydrated ethyl alcoholand the resultant esters composition:US,4695411[P].1987-09-22.
[10] 岳娟,王兴国,金青哲,等.固体酸性催化剂催化生物柴油合成反应性能的比较[J].中国油脂,2006,31(7):63-65.
[11] Martin M,Claudia R.Biodiesel:the comprehensive handbook[M].Graz (Austria):Karl-Franzens University,2004.
[2] 忻耀年.现代生物柴油的生产工艺及产品质量[J].中国油脂,2003,28(11):62-64.
[3] Arkansas.Biodiesel plant increasing production[J].Land line magazine,2006,9:311-322.
[4] 曾广溯,我国基础油脂化学品的生产工艺水平[J].日用化学工业,2001,12(6):37-40.
[5] Ma F,Clements L D,Hanna M A.The effect of mixing on transesterification of beef tallow[J].Bioresource Tcnology,1999,69:289-293.
[6] 盛梅,邬国英,徐鸽,等.生物柴油的制备[J].高校化学工程学报,2004,18(2):231-236.
[7] 杨振强,谢文磊,左玉.固体碱催化剂在油脂酯交换反应中的应用[J].粮食与油脂,2006.7:13-15.
[8] 张高勇,李天栋.脂肪酸烷基酯的生产方法:CN,1810761[P].2006-08-02.
[9] Stern R,Hillion G,Gateau P,et al.Process for manufacturing a composition of fatty acid esters useful as gas oil substitute motor fuel with hydrated ethyl alcoholand the resultant esters composition:US,4695411[P].1987-09-22.
[10] 岳娟,王兴国,金青哲,等.固体酸性催化剂催化生物柴油合成反应性能的比较[J].中国油脂,2006,31(7):63-65.
[11] Martin M,Claudia R.Biodiesel:the comprehensive handbook[M].Graz (Austria):Karl-Franzens University,2004.