C_f/SiC复合材料的氧化及抗氧化技术研究进展
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摘要
连续碳纤维增强碳化硅陶瓷基复合材料(C_f/SiC)因其具有高比强、高比模、耐磨损、良好热稳定性以及耐高温等突出性能,成为航空、航天、高性能武器装备等高尖端领域极具潜力的热结构材料。但高温氧化是其工程应用上的弱点,会造成C_f/SiC复合材料性能的下降,直接影响到材料的使用寿命和安全性。分析C_f/SiC复合材料的氧化影响因素,从界面相、基体和表面涂层3个方面综述C_f/SiC复合材料高温抗氧化技术的研究进展,结果表明:不同的温度区间内C_f/SiC复合材料的氧化行为不同,而界面改性、涂层抗氧化和基体改性相结合是实现材料抗氧化的关键。
Continuous carbon fibers reinforced silicon carbide ceramic composites( C_f/SiC) are a king of high-temperature structural material with great potential in aeronautics and astronautics due to their excellent properties such as high specific strength,high specific modulus,good abrasion resistance,good thermal stability and high temperature resistance. But high temperature oxidation is their weakness,which may lead to the decline of their properties,and directly affect the service life and safety. The influencing factors of oxidation of C_f/SiC composites were analyzed in this paper. And the research status of hightemperature oxidation resistance of C_f/SiC composites was summarized from the three aspects of interphase,matrix and surface coatings. The results show that the oxidation behavior of C_f/SiC composites differ with temperature range,and the combination of interfacial modification,coating oxidation resistance and matrix modification is the key to the oxidation resistance of materials.Finally,the development trend of C_f/SiC composites is forecasted.
Continuous carbon fibers reinforced silicon carbide ceramic composites( C_f/SiC) are a king of high-temperature structural material with great potential in aeronautics and astronautics due to their excellent properties such as high specific strength,high specific modulus,good abrasion resistance,good thermal stability and high temperature resistance. But high temperature oxidation is their weakness,which may lead to the decline of their properties,and directly affect the service life and safety. The influencing factors of oxidation of C_f/SiC composites were analyzed in this paper. And the research status of hightemperature oxidation resistance of C_f/SiC composites was summarized from the three aspects of interphase,matrix and surface coatings. The results show that the oxidation behavior of C_f/SiC composites differ with temperature range,and the combination of interfacial modification,coating oxidation resistance and matrix modification is the key to the oxidation resistance of materials.Finally,the development trend of C_f/SiC composites is forecasted.
引文
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[22]李思维,张立同,刘永胜,等.CVI B-C基体改性2DC/Si C在低温湿氧中的自愈合行为[J].无机材料学报,2010,25(11):1119-1203.
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[25]成来飞,左新章,刘永胜,等.自愈合C/Si C陶瓷基复合材料的制备工艺与性能[J].航空制造技术,2014(6):24-29.
[26]Quemard L,Rebillat F,Guette A,et al.Self-healing mechanisms of a Si C fiber reinforced multi-layered ceramic matrix composite in high pressure stem environments[J].Journal of the European Ceramic Society,2007,27(4):2085-2094.
[27]Tang S F,Hu C L.Design,Preparation and properties of carbon fiber reinforced ultra-high temperature ceramic composites for aerospace applications:A review[J].Journal of Materials Science and Technology,2016,33(2):117-130.
[28]孟祥利,崔红,闫联生,等.基体改性C/C-Hf C-Hf B2-Si C复合材料抗烧蚀性能研究[J].中国材料进展,2013,32(11):655-658.
[29]吴守军.CVD Si C涂层缺陷控制与C/Si C复合材料氧化行为研究[D].西安:西北工业大学,2004:45-60.
[30]陈志彦,向洁琼,邹世钦.3D-Cf/Si C复合材料抗高温氧化涂层设计与自愈合机理[J].功能材料,2014,17(45):17116-17119.
[31]Goujard S,Vandenbulcke L,Tawil H.The oxidation behaviour of two-and three-dimensional C/Si C thermostructural materials protected by chemical-vapour-depositon polylayers coatings[J].Journal of Materials Science,1994,29(23):6212-6220.
[32]张伟华,成来飞,张立同,等.C/Si C复合材料表面Si-C-B自愈合涂层的制备与抗氧化行为[J].无机材料学报,2008,23(4):774-778.
[33]Liu Y S,Cheng L F,Zhang L T,et al.Oxidation protection of multilayer CVD Si C/B/Si C coatings for 3D C/Si C composite[J].Materials Science and Engineering A,2007,466(1-2):172-177.
[34]Zuo X Z,Zhang L T,Liu Y S,et al.Oxidation behaviour of two-dimensional C/Si C modified with self-healing Si-B-C coating in static air[J].Corrosion Science,2012,65:87-93.
[35]Liu Y S,Wan J J,Zuo X Z,et al.Oxidation behavior of 2D C/Si C composites coated with multi-layer Si C/Si C-B-C/Si C coatings under wet oxygen atmosphere[J].Applied Surface Science,2015,353:214-223.
[36]綦育仕,王艳艳,周长灵,等.Cf/Si C复合材料的Zr B2-Si C/Si C超高温陶瓷涂层的研究[J].现代技术陶瓷,2016,37(2):119-125.
[37]Verdon C,Szwedek O,Jacques S,et al.Hafnium and silicon carbide multilayer coatings for the protection of carbon composites[J].Surface and Coatings Technology,2013,230:124-129.
[38]Liu Q M,Zhang L T,Liu J,et al.The oxidation behavior of Si C-Zr C-Si C coated C/Si C minicomposites at ultra high temperatures[J].The American Ceramic Society,2010,93(12):3390-3392.
[2]张立同,成来飞.连续纤维增韧陶瓷基复合材料可持续发展战略探讨[J].复合材料学报,2007,24(2):1-6.
[3]王鸣,董志国,张晓越,等.连续纤维增强碳化硅陶瓷基复合材料在航空发动机上的应用[J].航空制造技术,2014(6):10-13.
[4]Christin F A.A global approach to fiber n-D architectures and self-sealing matrices:From research to production[J].International Journal of Applied Ceramic Technology,2005,2(2):97-104.
[5]Schmidt S,Beyer S,Immich H,et al.Ceramic matrix composites:A challenge in space-propulsion technology application[J].International Journal of Applied Ceramic Technology,2005,2(2):85-96.
[6]Zhang L,Cheng L,Xu Y.Progress in research work of new CMC-Si C[J].Aeronautical Manufacturing Technology,2003,1:24-32.
[7]Opila E J,Serra J L.Oxidation of C/Si C composites at reduced oxygen partial pressures[R].NASA,2007.
[8]Lamouroux F,Camus G,Thébault J.Kinetics and mechanisms of oxidation of 2D wove C/Si C composites:I,Experimental approach[J].Journal of the American Ceramic Society,1997,77(8):2049-2057.
[9]Lamouroux F,Naslain R,Jouin J M.Kinetics and mechanisms of oxidation of 2D wove C/Si C composites:II,Theoretical approach[J].Journal of American Ceramic Society,2010,77(8):2049-2057.
[10]Lamouroux F,Bourrat X,Naslain R,et al.Structure/oxidation behavior relationship in the carbonaceous constituents of 2D-C/Py C/Si C composites[J].Carbon,1993,31(8):1273-1288.
[11]潘牧,南策文.碳化硅(Si C)基材料的高温氧化和腐蚀[J].腐蚀科学与防护技术,2000,12(2):109-113.
[12]Charpentier L,Balat-Pichelin M,Glénat H,et al.High temperature oxidation of Si C under helium with low-pressure oxygen.Part 2:CVDβ-Si C[J].Journal of the European Ceramic Society,2010,30(12):2661-2670.
[13]Opila E J.Oxidation kinetics of chemically vapor-deposited silicon carbide in wet oxygen[J].Journal of the American Ceramic Society,1994,77(3):730-736.
[14]Liu Y S,Zhang L T,Cheng L F,et al.Effect of water on oxidation behavior of 3D C/Si C composites coated with Si C/aBCx/Si C coatings[J].Advanced Composite Materials,2010,19:185-196.
[15]Lamouroux F,Bourrat X,Naslain R.Silicon carbide infiltration of porpus C-C composites forimproving oxidation resistance[J].Carbon,1995,33(4):525-535.
[16]魏玺.3DC/Si C复合材料氧化机理分析及氧化动力学[D].西安:西北工业大学,2004:35-41.
[17]殷小玮.3DC/Si C复合材料的环境氧化行为[D].西安:西北工业大学,2001:29-43.
[18]Naslain R R.The design of the fiber-matrix interfacial zone in ceramic matrix composites[J].Composites Part A:Applied Science and Manufacturing,1998,29(9-10):1145-1155.
[19]Rebillat F,Guette A,Espitalier L,et al.Oxidation resistance of Si C/Si C micro and minicomposites with a highly crystallised BN interphase[J].Journal of the European Ceramic Society,1998,18(13):1809-1819.
[20]欧阳海波,李贺军,齐乐华,等.Si C/Py C复合涂层碳纤维微观结构及氧化行为研究[J].无机材料学报,2009,24(1):103-106.
[21]Naslain R.Boron-bearing species in ceramic matrix composites for long-term aerospace applicaions[J].Journal of Solid State Chemistry,2004,177(2):449-456.
[22]李思维,张立同,刘永胜,等.CVI B-C基体改性2DC/Si C在低温湿氧中的自愈合行为[J].无机材料学报,2010,25(11):1119-1203.
[23]Lamouroux F,Bertrand S,Pailler R,et al.Oxidation-resistant carbon-fiber-reinforced ceramic-matrix composites[J].Composites Science and Technology,1999,59(7):1073-1085.
[24]童长青,成来飞,殷小玮,等.C/Si C-Si B4复合材料的制备及氧化行为[J].功能材料,2008,39(12):1982-1988.
[25]成来飞,左新章,刘永胜,等.自愈合C/Si C陶瓷基复合材料的制备工艺与性能[J].航空制造技术,2014(6):24-29.
[26]Quemard L,Rebillat F,Guette A,et al.Self-healing mechanisms of a Si C fiber reinforced multi-layered ceramic matrix composite in high pressure stem environments[J].Journal of the European Ceramic Society,2007,27(4):2085-2094.
[27]Tang S F,Hu C L.Design,Preparation and properties of carbon fiber reinforced ultra-high temperature ceramic composites for aerospace applications:A review[J].Journal of Materials Science and Technology,2016,33(2):117-130.
[28]孟祥利,崔红,闫联生,等.基体改性C/C-Hf C-Hf B2-Si C复合材料抗烧蚀性能研究[J].中国材料进展,2013,32(11):655-658.
[29]吴守军.CVD Si C涂层缺陷控制与C/Si C复合材料氧化行为研究[D].西安:西北工业大学,2004:45-60.
[30]陈志彦,向洁琼,邹世钦.3D-Cf/Si C复合材料抗高温氧化涂层设计与自愈合机理[J].功能材料,2014,17(45):17116-17119.
[31]Goujard S,Vandenbulcke L,Tawil H.The oxidation behaviour of two-and three-dimensional C/Si C thermostructural materials protected by chemical-vapour-depositon polylayers coatings[J].Journal of Materials Science,1994,29(23):6212-6220.
[32]张伟华,成来飞,张立同,等.C/Si C复合材料表面Si-C-B自愈合涂层的制备与抗氧化行为[J].无机材料学报,2008,23(4):774-778.
[33]Liu Y S,Cheng L F,Zhang L T,et al.Oxidation protection of multilayer CVD Si C/B/Si C coatings for 3D C/Si C composite[J].Materials Science and Engineering A,2007,466(1-2):172-177.
[34]Zuo X Z,Zhang L T,Liu Y S,et al.Oxidation behaviour of two-dimensional C/Si C modified with self-healing Si-B-C coating in static air[J].Corrosion Science,2012,65:87-93.
[35]Liu Y S,Wan J J,Zuo X Z,et al.Oxidation behavior of 2D C/Si C composites coated with multi-layer Si C/Si C-B-C/Si C coatings under wet oxygen atmosphere[J].Applied Surface Science,2015,353:214-223.
[36]綦育仕,王艳艳,周长灵,等.Cf/Si C复合材料的Zr B2-Si C/Si C超高温陶瓷涂层的研究[J].现代技术陶瓷,2016,37(2):119-125.
[37]Verdon C,Szwedek O,Jacques S,et al.Hafnium and silicon carbide multilayer coatings for the protection of carbon composites[J].Surface and Coatings Technology,2013,230:124-129.
[38]Liu Q M,Zhang L T,Liu J,et al.The oxidation behavior of Si C-Zr C-Si C coated C/Si C minicomposites at ultra high temperatures[J].The American Ceramic Society,2010,93(12):3390-3392.