MBR在废水处理中的应用及生物强化研究进展
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摘要
针对日益严苛的废水排放标准,必须提高废水处理工艺脱氮除磷和对难降解有机物的去除性能。膜生物反应器(MBR)作为膜分离与生物技术有机结合的污水处理技术,具有系统处理效果好、容积负荷高、占地面积小,节省空间等优点。文章梳理了MBR在废水脱氮除磷及难降解有机物处理等方面的应用情况,介绍了MBR各种生物强化技术研究现状,为新型MBR技术的开发提供了支持。
In order to meet the increasingly strict wastewater discharge standards, it is necessary to improve the performance of wastewater treatment process for removal of nitrogen, phosphorus and refractory organics. Membrane bioreactor(MBR) is one of the wastewater treatment technologies combined with membrane separation and biological degradation. In comparison to the conventional activated sludge systems, MBR has such advantages as superior effluent quality, higher volume load rate, smaller volume and footprint, etc.. In this paper, the application of MBR in removal of nitrogen, phosphorus and refractory organic compounds is reviewed and the research status of MBR in various kinds of bioaugmentation technologies is introduced, providing support for the development of new MBR technologies.
In order to meet the increasingly strict wastewater discharge standards, it is necessary to improve the performance of wastewater treatment process for removal of nitrogen, phosphorus and refractory organics. Membrane bioreactor(MBR) is one of the wastewater treatment technologies combined with membrane separation and biological degradation. In comparison to the conventional activated sludge systems, MBR has such advantages as superior effluent quality, higher volume load rate, smaller volume and footprint, etc.. In this paper, the application of MBR in removal of nitrogen, phosphorus and refractory organic compounds is reviewed and the research status of MBR in various kinds of bioaugmentation technologies is introduced, providing support for the development of new MBR technologies.
引文
[1]邵嘉慧,何义亮,顾国维.膜生物反应器-在污水处理中的研究和应用(第2版)[M].北京:化学工业出版社,2012.
[2]Ishizaki S,Fukushima T,Ishii S,et al.Membrane fouling potentials and cellular properties of bacteria isolated from fouled membranes in a MBR treating municipal wastewater[J].Water Research,2016,100:448-457.
[3]杨帅.移动床膜生物反应器脱氮除磷性能的研究[D].大连:理工大学,2010.
[4]郑祥,刘俊新.影响MBR脱氮效率的因素研究[J].环境科学学报,2005,25(10):1325-1329.
[5]耿琰,周琪,屈计宁.SMSBR反应器去除焦化废水中的氨氮[J].中国给水排水,2002,18(7):8-11.
[6]李辰.一体式膜生物反应器系统优化及脱氮性能研究[D].西安:西安建筑科技大学,2010.
[7]Holakoo L,Nakhla G,Bassi A S,et al.Long term performance of MBR for biological nitrogen removal from synthetic municipal wastewater[J].Chemosphere,2007,66(5):849-857.
[8]He S B,Xue G,Wang B Z.Factors affecting simultaneous nitrification and de-nitrification(SND)and its kinetics model in membrane bioreactor[J].Journal of Hazardous Materials,2009,168(2-3):704-710.
[9]Baek S H,Kim H J.Mathematical model for simultaneous nitrification and denitrification(SND)in membrane bioreactor(MBR)under low dissolved oxygen(DO)concentrations[J].Biotechnology&Bioprocess Engineering,2013,18(1):104-110.
[10]赵冰怡,陈英文,沈树宝.C/N比和曝气量影响MBR同步硝化反硝化的研究[J].环境工程学报,2009,3(3):400-404.
[11]Sarioglu M,Insel G,Artan N,et al.Model evaluation of simultaneous nitrification and denitrification in a membrane bioreactor operated without an anoxic reactor[J].Journal of Membrane Science,2009,337(1-2):17-27.
[12]Zhu G B,Peng Y Z,Wu S Y,et al.Simultaneous nitrification and denitrification in step feeding biological nitrogen removal process[J].Journal of Environmental Sciences,2007,19(9):1043-1048.
[13]孙星凡,张言,李荣光,等.A/O-MBR工艺短程硝化处理高氨氮废水试验研究[J].供水技术,2012,6(1):24-27,31.
[14]胡君杰,夏俊方,方小琴,等.垃圾渗滤液短程硝化反硝化脱氮工艺的研究[J].工业水处理,2016,36(5):76-81.
[15]Zhang X,Li D,Liang Y,et al.Autotrophic nitrogen removal from domestic sewage in MBR-CANON system and the biodiversity of functional microbes[J].Bioresource Technology,2013,150:113-120.
[16]Wang Z,Qu F,Liang H,et al.Effect of low temperature on the performance of a gravity flow CANON-like pilot plant MBR treating surface water[J].Desalination&Water Treatment,2015,56(11):2856-2866.
[17]Yoon S H,Kim H S,Park J K,et al.Influence of important operational parameters on performance of a membrane biological reactor[J].Water Science and Technology,2000,41(10-11):235-242.
[18]迟军.应用淹没式膜生物反应器处理含磷污水[J].大庆石油学院学报,2003,27(2):40-55.
[19]Lesjean B,Gnirss R,Adam C.Process configurations adapted to membrane bioreactors for enhanced biological phosphorous and nitrogen removal[J].Desalination,2002,149(l-3):217-224.
[20]Hasar H,Kinaci C.Comparison of a s MBR and a CASP system for wastewater reclamation and reuse[J].Filtration&Separation,2004,41(1):35-39.
[21]Zhang H M,Xiao J N,Cheng Y J,et al.Comparison between a sequencing batch membrane bioreactor and a conventional membrane bioreactor[J].Process Biochemistry,2006,41(1):87-95.
[22]Bae T H,Han S S,Tak T M.Membrane sequencing batch reactor system for the treatment of dairy industry wastewater[J].Process Biochemistry,2003,39(2):221-231.
[23]迟军,王宝贞,吕斯壕.一体化复合式膜生物反应器除磷研究[J].水处理技术,2003,29(1):47-49.
[24]Ahn K H,Song K G,Choa E,et al.Enhanced biological phosphorus and nitrogen removal using a sequencing anoxic/anaerobic membrane bioreactor(SAM)process[J].Desalination,2003,157(1-3):345-352.
[25]丁安,梁恒,郭五珍,等.回流对间歇式A/O-MBR脱氮除磷影响的中试研究[J].哈尔滨工业大学学报,2013,45(4):33-37.
[26]Ballesteros M M M,Garrido L,Casas Lopez J L,et al.An analysis of the bacterial community in a membrane bioreactor fed with photo-Fenton pre-treated toxic water[J].Journal of Industrial Microbiology&Biotechnology,2011,38(9):1171-1178.
[27]韩卫清,薛红民,陈勇,等.微电解、A/O和膜生物反应器组合工艺处理高浓度有机氮废水[J].环境工程,2011,29(7):45-47.
[28]Estrada-Arriaga E B,Mijaylova P N.Influence of operational parameters(sludge retention time and hydraulic residence time)on the removal of estrogens by membrane bioreactor[J].Environmental Science and Pollution Research,2011,18(7):1121-1128.
[29]靖丹枫,贾仁勇,白新征.固定化膜生物反应器处理含抗生素污水[J].环境工程学报,2012,6(5):1495-1499.
[30]Dialynas E,Diamadopoulos E.The effect of biomass adsorption on the removal of selected pharmaceutical compounds in an immersed membrane bioreactor system[J].Journal of Chemical Technology and Biotechnology,2012,87(2):232-237.
[31]Boonyaroj V,Chiemchaisri C,Chiemchaisri W,et al.Toxic organic micro-pollutants removal mechanisms in long-term operated membrane bioreactor treating municipal solid waste leachate[J].Bioresource Technology,2012,113:174-180.
[32]Ahmed F N,Lan C Q.Treatment of landfill leachate using membrane bioreactors:A review[J].Desalination,2012,287:41-54.
[33]刘建森,刘恩华,吴兆飞,等.兼氧+管式膜MBR工艺在垃圾渗滤液处理中的应用[J].天津工业大学学报,2011,30(2):16-18,22.
[34]孙华伟,张朝晖,余小双,等.管式膜MBR在印染废水处理工艺中的运行规律研究[J].水处理技术,2010,36(1):95-97.
[35]王尧,戴海平,吴杨超.MBR工艺在炼油废水生化处理中的应用[J].天津工业大学学报,2013,32(1):14-17.
[36]Friha I,Karray F,Feki F,et al.Treatment of cosmetic industry wastewater by submerged membrane bioreactor with consideration of microbial community dynamics[J].International Biodeterioration&Biodegradation,2014,88:125-133.
[37]Akgul D,Aktan C K,Yapsakli K,et al.Treatment of landfill leachate using UASB-MBR-SHARON-Anammox configuration[J].Biodegradation,2013,24(3):399-412.
[38]夏本立,刘渊,王煊军,等.MBR处理偏二甲肼废水效果的影响因素[J].火炸药学报,2011,34(1):73-76.
[39]肖蓉蓉,杨皓洁,唐奕,等.焦化废水MBR深度处理试验研究[J].水处理技术,2011,37(7):72-76.
[40]靖丹枫,贾仁勇,白新征.固定化膜生物反应器处理含抗生素污水[J].环境工程学报,2012,6(5):1495-1499.
[41]Li C,Zhang Z,Li Y,et al.Study on dyeing wastewater treatment at high temperature by MBBR and the thermotolerant mechanism based on its microbial analysis[J].Process Biochemistry,2015,50(11):1934-1941.
[42]Yang X L,Song H L,Lu J L,et al.Influence of diatomite addition on membrane fouling and performance in a submerged membrane bioreactor[J].Bioresource Technology,2010,101(23):9178-9184.
[43]高春梅,冀世锋,储鸣,等.生物促生剂强化膜生物反应器处理印染废水的研究[J].净水技术,2010,29(2):32-35,61.
[44]Qin L,Zhang G L,Meng Q,et al.Enhanced submerged membrane bioreactor combined with biosurfactant rhamnolipids:Performance for frying oil degradation and membrane fouling reduction[J].Bioresource Technology,2012,126:314-320.
[45]冀世锋,高春梅,杨红,等.生物铁强化膜生物反应器处理印染废水的研究[J].环境科学与技术,2012,35(1):84-88.
[46]Tian J Y,Liang H,Li X,et al.Membrane coagulation bioreactor(MCBR)for drinking water treatment[J].Water Research,2008,42(14):3910-3920.
[47]Bani-Melhem K,Smith E.Grey water treatment by a continuous process of an electrocoagulation unit and a submerged membrane bioreactor system[J].Chemical Engineering Journal,2012,198-199:201-210.
[48]李亮,阮晓磊,陈军.电絮凝-MBR组合工艺深度处理石化工业废水的研究[J].工业水处理,2010,30(4):59-62.
[49]王旭.膜电生物反应器降解苯酚废水的研究[D].天津:天津工业大学,2008.
[50]杨丽,刘恩华.膜电生物反应器深度处理垃圾渗滤液研究[J].水处理技术,2010,36(2):68-71.
[51]王韬,杜启云.MBER法处理高浓度苯酚废水的动力学研究[J].天津工业大学学报,2008,27(3):19-21.
[52]崔志广,李舒渊,夏俊林,等.电絮凝强化膜生物反应器除磷研究[J].中国给水排水,2009,25(7):1-4.
[53]Khalid B M,Maria E.Development of a novel submerged membrane electrobioreactor(SMEBR):performance for fouling reduction[J].Environmental Science&Technology,2010,44(9):3298-3304.
[2]Ishizaki S,Fukushima T,Ishii S,et al.Membrane fouling potentials and cellular properties of bacteria isolated from fouled membranes in a MBR treating municipal wastewater[J].Water Research,2016,100:448-457.
[3]杨帅.移动床膜生物反应器脱氮除磷性能的研究[D].大连:理工大学,2010.
[4]郑祥,刘俊新.影响MBR脱氮效率的因素研究[J].环境科学学报,2005,25(10):1325-1329.
[5]耿琰,周琪,屈计宁.SMSBR反应器去除焦化废水中的氨氮[J].中国给水排水,2002,18(7):8-11.
[6]李辰.一体式膜生物反应器系统优化及脱氮性能研究[D].西安:西安建筑科技大学,2010.
[7]Holakoo L,Nakhla G,Bassi A S,et al.Long term performance of MBR for biological nitrogen removal from synthetic municipal wastewater[J].Chemosphere,2007,66(5):849-857.
[8]He S B,Xue G,Wang B Z.Factors affecting simultaneous nitrification and de-nitrification(SND)and its kinetics model in membrane bioreactor[J].Journal of Hazardous Materials,2009,168(2-3):704-710.
[9]Baek S H,Kim H J.Mathematical model for simultaneous nitrification and denitrification(SND)in membrane bioreactor(MBR)under low dissolved oxygen(DO)concentrations[J].Biotechnology&Bioprocess Engineering,2013,18(1):104-110.
[10]赵冰怡,陈英文,沈树宝.C/N比和曝气量影响MBR同步硝化反硝化的研究[J].环境工程学报,2009,3(3):400-404.
[11]Sarioglu M,Insel G,Artan N,et al.Model evaluation of simultaneous nitrification and denitrification in a membrane bioreactor operated without an anoxic reactor[J].Journal of Membrane Science,2009,337(1-2):17-27.
[12]Zhu G B,Peng Y Z,Wu S Y,et al.Simultaneous nitrification and denitrification in step feeding biological nitrogen removal process[J].Journal of Environmental Sciences,2007,19(9):1043-1048.
[13]孙星凡,张言,李荣光,等.A/O-MBR工艺短程硝化处理高氨氮废水试验研究[J].供水技术,2012,6(1):24-27,31.
[14]胡君杰,夏俊方,方小琴,等.垃圾渗滤液短程硝化反硝化脱氮工艺的研究[J].工业水处理,2016,36(5):76-81.
[15]Zhang X,Li D,Liang Y,et al.Autotrophic nitrogen removal from domestic sewage in MBR-CANON system and the biodiversity of functional microbes[J].Bioresource Technology,2013,150:113-120.
[16]Wang Z,Qu F,Liang H,et al.Effect of low temperature on the performance of a gravity flow CANON-like pilot plant MBR treating surface water[J].Desalination&Water Treatment,2015,56(11):2856-2866.
[17]Yoon S H,Kim H S,Park J K,et al.Influence of important operational parameters on performance of a membrane biological reactor[J].Water Science and Technology,2000,41(10-11):235-242.
[18]迟军.应用淹没式膜生物反应器处理含磷污水[J].大庆石油学院学报,2003,27(2):40-55.
[19]Lesjean B,Gnirss R,Adam C.Process configurations adapted to membrane bioreactors for enhanced biological phosphorous and nitrogen removal[J].Desalination,2002,149(l-3):217-224.
[20]Hasar H,Kinaci C.Comparison of a s MBR and a CASP system for wastewater reclamation and reuse[J].Filtration&Separation,2004,41(1):35-39.
[21]Zhang H M,Xiao J N,Cheng Y J,et al.Comparison between a sequencing batch membrane bioreactor and a conventional membrane bioreactor[J].Process Biochemistry,2006,41(1):87-95.
[22]Bae T H,Han S S,Tak T M.Membrane sequencing batch reactor system for the treatment of dairy industry wastewater[J].Process Biochemistry,2003,39(2):221-231.
[23]迟军,王宝贞,吕斯壕.一体化复合式膜生物反应器除磷研究[J].水处理技术,2003,29(1):47-49.
[24]Ahn K H,Song K G,Choa E,et al.Enhanced biological phosphorus and nitrogen removal using a sequencing anoxic/anaerobic membrane bioreactor(SAM)process[J].Desalination,2003,157(1-3):345-352.
[25]丁安,梁恒,郭五珍,等.回流对间歇式A/O-MBR脱氮除磷影响的中试研究[J].哈尔滨工业大学学报,2013,45(4):33-37.
[26]Ballesteros M M M,Garrido L,Casas Lopez J L,et al.An analysis of the bacterial community in a membrane bioreactor fed with photo-Fenton pre-treated toxic water[J].Journal of Industrial Microbiology&Biotechnology,2011,38(9):1171-1178.
[27]韩卫清,薛红民,陈勇,等.微电解、A/O和膜生物反应器组合工艺处理高浓度有机氮废水[J].环境工程,2011,29(7):45-47.
[28]Estrada-Arriaga E B,Mijaylova P N.Influence of operational parameters(sludge retention time and hydraulic residence time)on the removal of estrogens by membrane bioreactor[J].Environmental Science and Pollution Research,2011,18(7):1121-1128.
[29]靖丹枫,贾仁勇,白新征.固定化膜生物反应器处理含抗生素污水[J].环境工程学报,2012,6(5):1495-1499.
[30]Dialynas E,Diamadopoulos E.The effect of biomass adsorption on the removal of selected pharmaceutical compounds in an immersed membrane bioreactor system[J].Journal of Chemical Technology and Biotechnology,2012,87(2):232-237.
[31]Boonyaroj V,Chiemchaisri C,Chiemchaisri W,et al.Toxic organic micro-pollutants removal mechanisms in long-term operated membrane bioreactor treating municipal solid waste leachate[J].Bioresource Technology,2012,113:174-180.
[32]Ahmed F N,Lan C Q.Treatment of landfill leachate using membrane bioreactors:A review[J].Desalination,2012,287:41-54.
[33]刘建森,刘恩华,吴兆飞,等.兼氧+管式膜MBR工艺在垃圾渗滤液处理中的应用[J].天津工业大学学报,2011,30(2):16-18,22.
[34]孙华伟,张朝晖,余小双,等.管式膜MBR在印染废水处理工艺中的运行规律研究[J].水处理技术,2010,36(1):95-97.
[35]王尧,戴海平,吴杨超.MBR工艺在炼油废水生化处理中的应用[J].天津工业大学学报,2013,32(1):14-17.
[36]Friha I,Karray F,Feki F,et al.Treatment of cosmetic industry wastewater by submerged membrane bioreactor with consideration of microbial community dynamics[J].International Biodeterioration&Biodegradation,2014,88:125-133.
[37]Akgul D,Aktan C K,Yapsakli K,et al.Treatment of landfill leachate using UASB-MBR-SHARON-Anammox configuration[J].Biodegradation,2013,24(3):399-412.
[38]夏本立,刘渊,王煊军,等.MBR处理偏二甲肼废水效果的影响因素[J].火炸药学报,2011,34(1):73-76.
[39]肖蓉蓉,杨皓洁,唐奕,等.焦化废水MBR深度处理试验研究[J].水处理技术,2011,37(7):72-76.
[40]靖丹枫,贾仁勇,白新征.固定化膜生物反应器处理含抗生素污水[J].环境工程学报,2012,6(5):1495-1499.
[41]Li C,Zhang Z,Li Y,et al.Study on dyeing wastewater treatment at high temperature by MBBR and the thermotolerant mechanism based on its microbial analysis[J].Process Biochemistry,2015,50(11):1934-1941.
[42]Yang X L,Song H L,Lu J L,et al.Influence of diatomite addition on membrane fouling and performance in a submerged membrane bioreactor[J].Bioresource Technology,2010,101(23):9178-9184.
[43]高春梅,冀世锋,储鸣,等.生物促生剂强化膜生物反应器处理印染废水的研究[J].净水技术,2010,29(2):32-35,61.
[44]Qin L,Zhang G L,Meng Q,et al.Enhanced submerged membrane bioreactor combined with biosurfactant rhamnolipids:Performance for frying oil degradation and membrane fouling reduction[J].Bioresource Technology,2012,126:314-320.
[45]冀世锋,高春梅,杨红,等.生物铁强化膜生物反应器处理印染废水的研究[J].环境科学与技术,2012,35(1):84-88.
[46]Tian J Y,Liang H,Li X,et al.Membrane coagulation bioreactor(MCBR)for drinking water treatment[J].Water Research,2008,42(14):3910-3920.
[47]Bani-Melhem K,Smith E.Grey water treatment by a continuous process of an electrocoagulation unit and a submerged membrane bioreactor system[J].Chemical Engineering Journal,2012,198-199:201-210.
[48]李亮,阮晓磊,陈军.电絮凝-MBR组合工艺深度处理石化工业废水的研究[J].工业水处理,2010,30(4):59-62.
[49]王旭.膜电生物反应器降解苯酚废水的研究[D].天津:天津工业大学,2008.
[50]杨丽,刘恩华.膜电生物反应器深度处理垃圾渗滤液研究[J].水处理技术,2010,36(2):68-71.
[51]王韬,杜启云.MBER法处理高浓度苯酚废水的动力学研究[J].天津工业大学学报,2008,27(3):19-21.
[52]崔志广,李舒渊,夏俊林,等.电絮凝强化膜生物反应器除磷研究[J].中国给水排水,2009,25(7):1-4.
[53]Khalid B M,Maria E.Development of a novel submerged membrane electrobioreactor(SMEBR):performance for fouling reduction[J].Environmental Science&Technology,2010,44(9):3298-3304.