琥珀酸酯磺酸盐不对称双子表面活性剂的表面性能研究
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摘要
用Wilhelmy板法和最大泡压法分别测定了1,4-丁二醇双琥珀酸聚醚(3)仲辛基混合双酯磺酸钠(GSS4AEO3-71)和1,4-丁二醇双琥珀酸聚醚(7)仲辛基混合双酯磺酸钠(GSS4AEO7-71)水溶液在不同浓度下的静态表面张力和动态表面张力,并结合数学模型对两者的表面性能做进一步的分析和比较。结果表明;该不对称双子表面活性剂的临界胶束浓度(cmc)达到10~(-5) mol/L数量级,且随聚氧乙烯链长度增加,cmc减小;此外,GSS4AEO7-71的动态表面活性最好,且浓度高更显著。
The static surface tension and dynamic surface tension(DST)of 1,4-butanediol bis succinic acid polyether(3)secondary octyl mixed sodium sulfonate(GSS4 AEO3-71)and 1,4-butanediol bis succinic acid polyether(7)secondary octyl mixed sodium sulfonate(GSS4 AEO7-71)aqueous solutions at different concentrations were measured respectively by the Wilhelmy plate method and the maximum bubble pressure method,and their surface properties were further analyzed and compared with the mathematical model.The results showed that the critical micelle concentration of the asymmetric Gemini surfactant reached 10-5 mol/L,and with the polyoxyethylene chain length increases,CMC decreases;in addition,the dynamic surface activity of GSS4 AEO7-71 was the best,and the concentration was higher.
The static surface tension and dynamic surface tension(DST)of 1,4-butanediol bis succinic acid polyether(3)secondary octyl mixed sodium sulfonate(GSS4 AEO3-71)and 1,4-butanediol bis succinic acid polyether(7)secondary octyl mixed sodium sulfonate(GSS4 AEO7-71)aqueous solutions at different concentrations were measured respectively by the Wilhelmy plate method and the maximum bubble pressure method,and their surface properties were further analyzed and compared with the mathematical model.The results showed that the critical micelle concentration of the asymmetric Gemini surfactant reached 10-5 mol/L,and with the polyoxyethylene chain length increases,CMC decreases;in addition,the dynamic surface activity of GSS4 AEO7-71 was the best,and the concentration was higher.
引文
[1]喻红梅,李建华,华平,等.1,4-丁二醇双子琥珀酸聚醚(3)异辛基混合双酯磺酸钠的合成[J].精细化工,2013,30(11):1217-1222.
[2]Tang X L,Dong J F,Li X F.A comparison of spreading behaviors of Silwet L-77on dry and wet lotus leaves[J].Journal of Colloid&Interface Science,2008,325(1):223-227.
[3]姚志刚,胡艾希,黎小武,等.ELENMOL JS-2水溶液的动态表面张力及吸附动力学[J].华南理工大学学报:自然科学版,2007,35(7):82-87.
[4]张殿龙,屈文山,李哲.几种聚氧乙烯醚型表面活性剂的表面活性比较研究[J].印染助剂,2015,32(9):22-27.
[5]Lai L,Mei P,Wu X M,et al.Interfacial dynamic properties and dilational rheology of mixed anionic and cationic Gemini surfactant systems at air-water interface[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2016,509:341-350.
[6]王泓棣.不对称磺基琥珀酸酯盐Gemini表面活性剂的合成、性能与应用[D].陕西科技大学,2016.
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[8]刘胜伟.不对称双子表面活性剂的性质研究及其应用[D].宁波大学,2015.
[9]任昊.羧酸盐型Gemini表面活性剂制备及性能研究[D].西南石油大学,2015.
[10]董乐.m-n-m型Gemini双季铵盐表面活性剂的合成及性能研究[D].太原理工大学,2015.
[1]于艳春,肖鹤鸣.琥珀酸二油脂磺酸钠的合成、结构及水合作用[J].物理化学学报,2009,25(1):30-34.
[12]凌锦龙,曹枫,徐敏虹,等.C16mimBr/Triton X-100混合体系的表面性质和胶团化行为[J].化学学报,2011,69(22):2658-2664.
[13]喻红梅,李建华,华平,等.1,4-丁二醇双子琥珀酸聚醚(3)异辛基混合双酯磺酸钠的合成与性能[J].精细化工,2013,30(11):1217-1222.
[14]赵国玺,朱王步瑶.表面活性剂作用原理[M].北京:中国轻工业出版社,2003,270-272.
[15]Rosen M J,Song L D.Dynamic surface tension of aqueous surfactant solutions 8.Effect of spacer on dynamic properties of Gemini surfactant solutions[J].Journal of Colloid&Interface Science,1996,179(1):261-268.
[16]Fatma N,Panda M,Kabir-ud-Din.Mixed micellization of novel cationic ester-bonded gemini surfactants:Investigations by conductometric and tensiometric measurements[J].Journal of Molecular Liquids,2016,219:959-966.
[17]Jin Y,Wang L,Wang T,et al.Aggregation behavior of dodecylsulfonate-based surface active ionic liquids in water[J].Journal of Molecular Liquids,2015,212(6):23-29.
[18]Qu W,Gao Z,Zhang D,et al.Tetramethyl-6-decyne-5,8-diol polyoxyethylene:Their dynamic surface activity and dynamic spreading behavior in solutions[J].Journal of Molecular Liquids,2017,232:265-268.
[19]李鹏飞,胡志勇,曹端林.带支链疏水基的阴离子双子表面活性剂的合成及其胶束化热力学研究[J].日用化学工业,2012,42(1):10-14.
[20]卜芳,王栋,闫杰,等.阳离子表面活性剂聚集行为的热力学研究[J].环境科学与技术,2010,33(6):21-24.
[21]金柱,张军,周媛,等.烷基糖苷柠檬酸单酯盐水溶液表面张力研究[J].应用化工,2016,45(9):1614-1618.
[22]王军,陈玉菲,李妮妮,等.糖基双子阳离子表面活性剂的表面活性[J].日用化学工业,2015,45(10):541-545.
[23]Qu W S,Gao Z X,Zhang D L,et al.Tetramethyl-6-decyne-5,8-diol polyoxyethylene:Their dynamic surface activity and dynamic spreading behavior in solutions[J].Journal of Molecular Liquids,2017:265-268.
[24]Ju H B,Jiang Y J,Geng T,et al.Equilibrium and dynamic surface tension of quaternary ammonium salts with different hydrocarbon chain length of counterions[J].Journal of Molecular Liquids,2017,225:606-612.
[2]Tang X L,Dong J F,Li X F.A comparison of spreading behaviors of Silwet L-77on dry and wet lotus leaves[J].Journal of Colloid&Interface Science,2008,325(1):223-227.
[3]姚志刚,胡艾希,黎小武,等.ELENMOL JS-2水溶液的动态表面张力及吸附动力学[J].华南理工大学学报:自然科学版,2007,35(7):82-87.
[4]张殿龙,屈文山,李哲.几种聚氧乙烯醚型表面活性剂的表面活性比较研究[J].印染助剂,2015,32(9):22-27.
[5]Lai L,Mei P,Wu X M,et al.Interfacial dynamic properties and dilational rheology of mixed anionic and cationic Gemini surfactant systems at air-water interface[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2016,509:341-350.
[6]王泓棣.不对称磺基琥珀酸酯盐Gemini表面活性剂的合成、性能与应用[D].陕西科技大学,2016.
[7]秦松.反应型阳离子Gemini表面活性剂的合成与性能研究[D].陕西科技大学,2016.
[8]刘胜伟.不对称双子表面活性剂的性质研究及其应用[D].宁波大学,2015.
[9]任昊.羧酸盐型Gemini表面活性剂制备及性能研究[D].西南石油大学,2015.
[10]董乐.m-n-m型Gemini双季铵盐表面活性剂的合成及性能研究[D].太原理工大学,2015.
[1]于艳春,肖鹤鸣.琥珀酸二油脂磺酸钠的合成、结构及水合作用[J].物理化学学报,2009,25(1):30-34.
[12]凌锦龙,曹枫,徐敏虹,等.C16mimBr/Triton X-100混合体系的表面性质和胶团化行为[J].化学学报,2011,69(22):2658-2664.
[13]喻红梅,李建华,华平,等.1,4-丁二醇双子琥珀酸聚醚(3)异辛基混合双酯磺酸钠的合成与性能[J].精细化工,2013,30(11):1217-1222.
[14]赵国玺,朱王步瑶.表面活性剂作用原理[M].北京:中国轻工业出版社,2003,270-272.
[15]Rosen M J,Song L D.Dynamic surface tension of aqueous surfactant solutions 8.Effect of spacer on dynamic properties of Gemini surfactant solutions[J].Journal of Colloid&Interface Science,1996,179(1):261-268.
[16]Fatma N,Panda M,Kabir-ud-Din.Mixed micellization of novel cationic ester-bonded gemini surfactants:Investigations by conductometric and tensiometric measurements[J].Journal of Molecular Liquids,2016,219:959-966.
[17]Jin Y,Wang L,Wang T,et al.Aggregation behavior of dodecylsulfonate-based surface active ionic liquids in water[J].Journal of Molecular Liquids,2015,212(6):23-29.
[18]Qu W,Gao Z,Zhang D,et al.Tetramethyl-6-decyne-5,8-diol polyoxyethylene:Their dynamic surface activity and dynamic spreading behavior in solutions[J].Journal of Molecular Liquids,2017,232:265-268.
[19]李鹏飞,胡志勇,曹端林.带支链疏水基的阴离子双子表面活性剂的合成及其胶束化热力学研究[J].日用化学工业,2012,42(1):10-14.
[20]卜芳,王栋,闫杰,等.阳离子表面活性剂聚集行为的热力学研究[J].环境科学与技术,2010,33(6):21-24.
[21]金柱,张军,周媛,等.烷基糖苷柠檬酸单酯盐水溶液表面张力研究[J].应用化工,2016,45(9):1614-1618.
[22]王军,陈玉菲,李妮妮,等.糖基双子阳离子表面活性剂的表面活性[J].日用化学工业,2015,45(10):541-545.
[23]Qu W S,Gao Z X,Zhang D L,et al.Tetramethyl-6-decyne-5,8-diol polyoxyethylene:Their dynamic surface activity and dynamic spreading behavior in solutions[J].Journal of Molecular Liquids,2017:265-268.
[24]Ju H B,Jiang Y J,Geng T,et al.Equilibrium and dynamic surface tension of quaternary ammonium salts with different hydrocarbon chain length of counterions[J].Journal of Molecular Liquids,2017,225:606-612.