烟用接装纸中非挥发性物质总迁移量测定方法的改进
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摘要
目的提高烟用接装纸中非挥发性物质总迁移量的测试效率。方法对标准GB 31604.8-2016中测试方法进行改进,通过考察接装纸迁移前后的质量变化,从而得出接装纸中非挥发性物资总迁移量,建立一种新的烟用接装纸中非挥发性物质总迁移量的测试方法,并采用该方法测定15个样品的含量。结果样品的检测时间由原来10 h缩短至6 h。一次检测样品数量由1个增加至5个,减少了分析设备,降低了能耗。改进后方法的相对标准偏差小于10.0%。结论标准与建立的方法的测试结果无显著性差异,改进后的方法完全适用于烟用接装纸中非挥发性物质总迁移量的快速测定。
Objective To improve of standard method for determination of overall migration of nonvolatile substances in tipping paper for cigarette. Methods The GB 31604.8-2016 method was improved. By investigating the quality changes of the tipping paper for cigarette before and after migration, overall migration of nonvolatile substances was obtained. A new method of determination of overall migration of nonvolatile substances in tipping paper for cigarette was developed. Then 15 samples were determined by the established method. Results The testing time was shortened from 10 h to 6 h. The number of samples increased from 1 to 5 in a set of equipment, and the analysis equipment and power consumption were reduced significantly. The relative standard deviations of improved method were below 10.0%. Conclusion There is no significant difference in the test results between the established method and GB 31604.8-2016 standard method. It is suitable for the rapid analysis of overall migration amount of nonvolatile substances in tipping paper for cigarette.
Objective To improve of standard method for determination of overall migration of nonvolatile substances in tipping paper for cigarette. Methods The GB 31604.8-2016 method was improved. By investigating the quality changes of the tipping paper for cigarette before and after migration, overall migration of nonvolatile substances was obtained. A new method of determination of overall migration of nonvolatile substances in tipping paper for cigarette was developed. Then 15 samples were determined by the established method. Results The testing time was shortened from 10 h to 6 h. The number of samples increased from 1 to 5 in a set of equipment, and the analysis equipment and power consumption were reduced significantly. The relative standard deviations of improved method were below 10.0%. Conclusion There is no significant difference in the test results between the established method and GB 31604.8-2016 standard method. It is suitable for the rapid analysis of overall migration amount of nonvolatile substances in tipping paper for cigarette.
引文
[1]周国泰.危险化学品安全技术全书[M].北京:化学工业出版社,1997.Zhou GT.Encyclopedia of hazardous chemicals safety technology[M].Beijing:Chemical Industry Press,1997.
[2]何凤生.中华职业医学[M].北京:人民卫生出版社,1999.He FS.Chinese Occupational Medicine[M].Beijing:People's Medical Publishing House,1999.
[3]庞永强,李雪,罗彦波,等.接装纸和成型纸透气度对卷烟中元素迁移行为的影响[J].烟草科技,2015(6):64-67,72.Pang YQ,Li X,Luo YB,et al.Influence of filler and molding paper on the migration of elements in cigarettes[J].Tobacco Sci Technol,2015(6):64-67,72.
[4]李韵,汪宏毅,廖晓玲,等.LC-MS/MS法测定烟用接装纸中18种邻苯二甲酸酯[J].烟草科技,2013,(12):31-35.Li Y,Wang HY,Liao XL,et al.LC-MS/MS determination of 18 kinds of phthalate two formic acid esters in tobacco filled paper[J].Tobacco Sci Technol,2013,(12):31-35.
[5]Regulation(EC)No 1935/2004 of the European parliament and of the council of 27 October 2004-On materials and articles intended to come into contact with food and repealing Directives 80/590/EEC and89/109/EEC[S].
[6]Commission Directive 2002/72/EC of 6 August 2002 relating to plastic materials and articles in tended to come into contact with foodstuffs[S].
[7]Commission Regulation(EU)No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food[S].
[8]21 CFR 176.170:Components of paper and paperboard in contact with aqueous and fatty foods[S].
[9]GB 9687-1988食品包装用聚乙烯成型品卫生标准[S].GB 9687-1988 Hygienic Standard for polyethylene moldings for food packaging[S].
[10]GB/T 27589-2011纸餐盒[S].GB/T 27589-2011 Paper lunch boxes[S].
[11]GB/T 27590-2011纸杯[S].GB/T 27590-2011 Paper cups[S].
[12]GB/T 27591-2011纸碗[S].GB/T 27591-2011 Paper bowl[S].
[13]EN 1186-3:2002与食品接触的材料和物品-塑料[S].EN-1186-3:2002 Materials and articles in contact with foodstuffs-Plastics[S].
[14]GB/T 5009.60-2003食品包装用聚乙烯、聚苯乙烯、聚丙烯成型品卫生标准的分析方法[S].GB/T 5009.60-2003 Analytical methods for hygienic standard for polyethylene,polystyrene and polypropylene moldings used in food packaging[S].
[15]SN/T 2335-2009食品接触材料高分子材料水性食品模拟物中总迁移量的试验方法全浸没法[S].SN/T 2335-2009 Standard test method for total migration of food contact materials,polymers,aquatic food stimulants-Full immersion[S].
[16]GB 31604.8-2016食品安全国家标准食品接触材料及制品[S].GB 31604.8-2016 Food Safety National Standards-Food contact materials and products[S].
[17]GB/T 6682-2008分析实验室用水国家标准[S].GB/T 6682-2008 National standard of water in analysis laboratory[S].
[18]方萍,何延.试验设计与统计[M].杭州:浙江大学出版社,2003.Fang P,He Y.Experimental design and statistics[M].Hangzhou:Zhejiang University Press,2003.
[2]何凤生.中华职业医学[M].北京:人民卫生出版社,1999.He FS.Chinese Occupational Medicine[M].Beijing:People's Medical Publishing House,1999.
[3]庞永强,李雪,罗彦波,等.接装纸和成型纸透气度对卷烟中元素迁移行为的影响[J].烟草科技,2015(6):64-67,72.Pang YQ,Li X,Luo YB,et al.Influence of filler and molding paper on the migration of elements in cigarettes[J].Tobacco Sci Technol,2015(6):64-67,72.
[4]李韵,汪宏毅,廖晓玲,等.LC-MS/MS法测定烟用接装纸中18种邻苯二甲酸酯[J].烟草科技,2013,(12):31-35.Li Y,Wang HY,Liao XL,et al.LC-MS/MS determination of 18 kinds of phthalate two formic acid esters in tobacco filled paper[J].Tobacco Sci Technol,2013,(12):31-35.
[5]Regulation(EC)No 1935/2004 of the European parliament and of the council of 27 October 2004-On materials and articles intended to come into contact with food and repealing Directives 80/590/EEC and89/109/EEC[S].
[6]Commission Directive 2002/72/EC of 6 August 2002 relating to plastic materials and articles in tended to come into contact with foodstuffs[S].
[7]Commission Regulation(EU)No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food[S].
[8]21 CFR 176.170:Components of paper and paperboard in contact with aqueous and fatty foods[S].
[9]GB 9687-1988食品包装用聚乙烯成型品卫生标准[S].GB 9687-1988 Hygienic Standard for polyethylene moldings for food packaging[S].
[10]GB/T 27589-2011纸餐盒[S].GB/T 27589-2011 Paper lunch boxes[S].
[11]GB/T 27590-2011纸杯[S].GB/T 27590-2011 Paper cups[S].
[12]GB/T 27591-2011纸碗[S].GB/T 27591-2011 Paper bowl[S].
[13]EN 1186-3:2002与食品接触的材料和物品-塑料[S].EN-1186-3:2002 Materials and articles in contact with foodstuffs-Plastics[S].
[14]GB/T 5009.60-2003食品包装用聚乙烯、聚苯乙烯、聚丙烯成型品卫生标准的分析方法[S].GB/T 5009.60-2003 Analytical methods for hygienic standard for polyethylene,polystyrene and polypropylene moldings used in food packaging[S].
[15]SN/T 2335-2009食品接触材料高分子材料水性食品模拟物中总迁移量的试验方法全浸没法[S].SN/T 2335-2009 Standard test method for total migration of food contact materials,polymers,aquatic food stimulants-Full immersion[S].
[16]GB 31604.8-2016食品安全国家标准食品接触材料及制品[S].GB 31604.8-2016 Food Safety National Standards-Food contact materials and products[S].
[17]GB/T 6682-2008分析实验室用水国家标准[S].GB/T 6682-2008 National standard of water in analysis laboratory[S].
[18]方萍,何延.试验设计与统计[M].杭州:浙江大学出版社,2003.Fang P,He Y.Experimental design and statistics[M].Hangzhou:Zhejiang University Press,2003.