高分子基复合材料非线性导电行为和机理研究进展
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摘要
本文综述了金属填料型和导电非金属填料型两类高分子基复合材料非线性导电特性及其导电机理的国内外研究进展,分析了目前存在的问题,并展望了高分子基非线性导电复合材料的应用前景。
Research progress of nonlinear conductive behavior and mechanism of metal particle-filled and inorganic nonmetallic particle-filled composites were reviewed, the existing problems were analyzed, and the application prospects of polymer composites with nonlinear electrical conduction were forecasted.
Research progress of nonlinear conductive behavior and mechanism of metal particle-filled and inorganic nonmetallic particle-filled composites were reviewed, the existing problems were analyzed, and the application prospects of polymer composites with nonlinear electrical conduction were forecasted.
引文
[1] 王振清, 梁文彦, 吕庆红. 先进复合材料研究进展[M]. 第一版. 哈尔滨: 哈尔滨工程大学出版社, 2014: 2～4.
[2] Sun Y G, Xia Y N. Nanoparticles Shape-controlled Synthesis of Gold and Silver [J]. Science, 2002, 298: 2176～2179.
[3] 阳素玉. 多形貌纳米银的制备及其可控性研究[D]. 中南大学硕士学位论文, 尹荔松, 湖南长沙, 中南大学, 2010.5.
[4] 刘嘉玮,王建江,许宝才. 场致电阻材料在强电磁脉冲防护中的应用展望[J]. 功能材料, 2017, 48(10): 10029～10035.
[5] Pande S, Chaudhary A, Patel D, et al. Mechanical and Electrical Properties of Multiwall Carbon Nanotube/polycarbonate Composites for Electrostatic Discharge and Electromagnetic Interference Shielding Applications[J]. RSC Advances, 2014, 4(27): 13839～13849.
[6] Feng P A N, Chao C, Wang Z, et al. Nonvolatile Resistive Switching Memories-characteristics, Mechanisms and Challenges[J]. Progress in Natural Science: Materials International, 2010, 20: 1～15.
[7] 熊卓越, 张博媛, 汪唯佳, 等. 碳系导电填料混杂填充聚合物共混体系的导电逾渗模型[J]. 高等学校化学学报, 2015, 36(8): 1641～1647.
[8] 卢艳华, 王钧, 徐任信. 聚合物基 PTC 材料的研究进展[C]. 2007中国科协年会, 中国湖北武汉, 2007年9月. 节能环保和谐发展-2007中国科协年会文集 (一). 2007: 1～5.
[9] Kwan S H, Shin F G, Tsui W L. Direct Current Electrical Conductivity of Silver-thermosetting Polyester Composites[J]. Journal of Materials Science, 1980, 15(12): 2978～2984.
[10] 邹慰亲, 王春凤, 邹欣平, 等. 复合材料导电开关特性的研究[J]. 广东民族学院学报, 1997, (4): 36～40.
[11] Kiesow A, Morris J E, Radehaus C, et al. Switching Behavior of Plasma Polymer Films Containing Silver Nanoparticles[J]. Journal of Applied Physics, 2003, 94(10): 6988～6990.
[12] White S I, Mutiso R M, Vora P M, et al. Electrical Percolation Behavior in Silver Nanowire-polystyrene Composites: Simulation and Experiment[J]. Advanced Functional Materials, 2010, 20(16): 2709～2716.
[13] White S I, Vora P M, Kikkawa J M, et al. Resistive Switching in Bulk Silver Nanowire-polystyrene Composites[J]. Advanced Functional Materials, 2011, 21(2): 233～240.
[14] Stassi S, Canavese G. Spiky Nanostructured Metal Particles as Filler of Polymeric Composites Showing Tunable Electrical Conductivity [J]. Journal of Polymer Science Part B: Polymer Physics, 2012, 50(14): 984～992.
[15] Xu Z, Gao M, Yu L, et al. Co Nanoparticles Induced Resistive Switching and Magnetism for the Electrochemically Deposited Polypyrrole Composite films [J]. ACS applied materials & interfaces, 2014, 6(20): 17823～17830.
[16] 王长远. 研究氧化锌纳米材料的研究进展[J]. 中国西部科技, 2013, 12(9): 56～58.
[17] 刘晨阳, 郑晓泉, 等. 掺杂ZnO/环氧树脂基体的制备及其非线性电导改性研究[J]. 电工技术学报, 2016, 31(12): 24～30.
[18] 郭文敏, 韩宝忠, 李忠华. 影响低密度聚乙烯/氧化锌复合材料场致电导因素的研究[J]. 功能材料, 2009, 40(6): 943～945.
[19] 郭文敏, 李忠华. 聚乙烯基非线性复合材料的电导特性及机理[C]. 第十三届全国工程电介质学术会议, 中国陕西西安, 2011年10月. 第十三届全国工程电介质学术会议论文集. 2011: 212～216.
[20] 郭文敏, 韩宝忠, 李忠华. 聚乙烯/碳化硅复合材料的非线性电导特性的研究[J]. 功能材料, 2010, 41(3): 436～438.
[21] 郭文敏, 韩宝忠, 李忠华. 电场处理对碳化硅/聚合物复合材料电导特性的影响[J]. 功能材料, 2009, 40 (10): 1650～1653.
[22] Zhaoming Qu, Pin Lu, Yang Yuan, Qingguo Wang. Voltage-induced Nonlinear Conduction Properties of Epoxy Resin/micron-silver Particles Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012013.
[23] LU Pin, QU Zhaoming, WANG Qingguo, ZHAO Shiyang and BAI Liyun. Nonlinear Conductive Behavior of Silver Nanowires/silicone Rubber Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012052.
[24] 韩宝忠, 郭文敏, 李忠华. 碳化硅/硅橡胶复合材料的非线性电导特性[J]. 功能材料, 2008, 39(9): 1490～1493.
[25] Wang Z, Nelson J K, Hillborg H, et al. Graphene Oxide Filled Nanocomposite with Novel Electrical and Dielectric Properties[J]. Advanced Materials, 2012, 24(23): 3134～3137.
[26] Aleshin A N, Krylov P S, BerestennikovA S, et al. The Redox Nature of the Resistive Switching in Nanocomposite Thin Films Based on Graphene (graphene oxide) Nanoparticles and Poly (9-vinylcarbazole)[J]. Synthetic Metals, 2016, 217: 7～13.
[27] Wang J, Yu S, Luo S, et al. Investigation of Nonlinear I-V Behavior of CNTs Filled Polymer Composites[J]. Materials Science and Engineering: B, 2016, 206: 55～60.
[28] WEI LU, HONGFEI LIN, GUOHUA CHEN. Voltage-Induced Resistivity Relaxation in a High-Density Polyethylene/Graphite Nanosheet Composite [J]. Journal of Polymer Science: Part B: Polymer Physics, 2007, 45: 860～863.
[29] Lichun Zhou, Jinshan Lin, Hongfei Lin, Guohua Chen. Electrical-thermal Switching Effect in High-density Polyethylene/graphite Nanosheets Conducting Composites [J]. Journal of Material Science, 2008, 43: 4886～4891.
[30] LICHUN ZHOU, JINGSHAN LIN, GUOHUA CHEN. Electrical Breakdown in High-Density Polyethylene/Graphite Nanosheets Conductive Composites [J]. Journal of Polymer Science: Part B: Polymer Physics, 2009, 47: 576～582.
[31] Xiaoxin Lu, Julien Yvonnet, et al. Multiscale Modeling of Nonlinear Electric Conductivity in Graphene-reinforced Nanocomposites Taking into Account Tunnelling Effect [J]. Journal of Computational Physics, 2017, 337: 116～131.
[32] He Li, Zihao Guo, et al. Nonlinear Conductive Behaviors of Multilayer Graphene Nanosheets/epoxy Composites Below the Percolation Threshold [C]. 2017 IEEE Conference on Electrical Insulation and Dielectric Phenomenon, 2017, 10: 453～456.
[33] Yang Yuan, Qingguo Wang, Zhaoming Qu. Nonlinear Conductive Behavior in Graphene Nanoplatets/Epoxy Resin Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012015.
[34] 贾向明, 杨其, 李光宪, 等. 填充型导电高分子复合材料的逾渗理论进展[J]. 中国塑料, 2003, 17(6): 9～14.
[35] 刘生丽, 冯辉霞, 张建强, 等. 逾渗理论的研究及应用进展[J]. 应用化工, 2010, 39(7): 1074～1078.
[36] Nan C W, Shen Y, Ma J. Physical Properties of Composites Near Percolation [J]. Annual Review of Materials Research, 2010, 40: 131～151.
[37] Polley M H, Boonstra B. Carbon Blacks for Highly Conductive Rubber [J]. Rubber Chemistry and Technology, 1957, 30(1): 170～179.
[38] Simmons. J G. Generalized Formula for the Electric tunnel Effect Between Similar Electrodes Separated by a Thin Insulating Film [J]. J. Appl. Phys, 1963, 34(6): 1793～1803.
[39] Sheng P, Sichel E K, Gittleman J I. Fluctuation-induced Tunneling Conduction in Carbon-polyvinylchloride Composites [J]. Physical Review Letters, 1978, 40(18): 1197～1200.
[40] Sheng P. Fluctuation-induced Tunneling Conduction in Disordered Materials [J]. Physical Review B, 1980, 21(6): 2180～2195.
[41] Medalia A I. Electrical Conduction in Carbon Black Composites [J]. Rubber Chemistry and Technology, 1986, 59(3): 432～454.
[42] Ezquerra T A, Kulescza M, Cruz C S, et al. Charge Transport in Polyethylene-graphite Composite Materials[J]. Advanced Materials, 1990, 2(12): 597～600.
[43] Kaiser A B, Park Y W. Current-voltage Characteristics of Conducting Polymers and Carbon Nanotubes [J]. Synthetic metals, 2005, 152(1): 181～184.
[44] Van Beek L K H, Van Pul B. Internal Field Emission in Carbon black-loaded Natural Rubber Vulcanizates [J]. Journal of Applied Polymer Science, 1962, 6(24): 651～655.
[45] Landauer R. Electrical Conductivity in Inhomogeneous Media [C]. Electrical Transport and Optical Properties of Inhomogeneous Media. AIP Publishing, 1978, 40(1): 2～45.
[46] McLachlan D S, Blaszkiewicz M, Newnham R E. Electrical Resistivity of Composites [J]. Journal of the American Ceramic Society, 1990, 73(8): 2187～2203.
[47] 朱栋培. 量子力学基础[M]. 第一版. 合肥:中国科学技术大学出版社, 2012: 52～53.
[48] 张雄伟, 黄锐. LDPE/炭黑复合导电材料性能的研究[J]. 中国塑料, 1994, 8(3): 26～34.
[2] Sun Y G, Xia Y N. Nanoparticles Shape-controlled Synthesis of Gold and Silver [J]. Science, 2002, 298: 2176～2179.
[3] 阳素玉. 多形貌纳米银的制备及其可控性研究[D]. 中南大学硕士学位论文, 尹荔松, 湖南长沙, 中南大学, 2010.5.
[4] 刘嘉玮,王建江,许宝才. 场致电阻材料在强电磁脉冲防护中的应用展望[J]. 功能材料, 2017, 48(10): 10029～10035.
[5] Pande S, Chaudhary A, Patel D, et al. Mechanical and Electrical Properties of Multiwall Carbon Nanotube/polycarbonate Composites for Electrostatic Discharge and Electromagnetic Interference Shielding Applications[J]. RSC Advances, 2014, 4(27): 13839～13849.
[6] Feng P A N, Chao C, Wang Z, et al. Nonvolatile Resistive Switching Memories-characteristics, Mechanisms and Challenges[J]. Progress in Natural Science: Materials International, 2010, 20: 1～15.
[7] 熊卓越, 张博媛, 汪唯佳, 等. 碳系导电填料混杂填充聚合物共混体系的导电逾渗模型[J]. 高等学校化学学报, 2015, 36(8): 1641～1647.
[8] 卢艳华, 王钧, 徐任信. 聚合物基 PTC 材料的研究进展[C]. 2007中国科协年会, 中国湖北武汉, 2007年9月. 节能环保和谐发展-2007中国科协年会文集 (一). 2007: 1～5.
[9] Kwan S H, Shin F G, Tsui W L. Direct Current Electrical Conductivity of Silver-thermosetting Polyester Composites[J]. Journal of Materials Science, 1980, 15(12): 2978～2984.
[10] 邹慰亲, 王春凤, 邹欣平, 等. 复合材料导电开关特性的研究[J]. 广东民族学院学报, 1997, (4): 36～40.
[11] Kiesow A, Morris J E, Radehaus C, et al. Switching Behavior of Plasma Polymer Films Containing Silver Nanoparticles[J]. Journal of Applied Physics, 2003, 94(10): 6988～6990.
[12] White S I, Mutiso R M, Vora P M, et al. Electrical Percolation Behavior in Silver Nanowire-polystyrene Composites: Simulation and Experiment[J]. Advanced Functional Materials, 2010, 20(16): 2709～2716.
[13] White S I, Vora P M, Kikkawa J M, et al. Resistive Switching in Bulk Silver Nanowire-polystyrene Composites[J]. Advanced Functional Materials, 2011, 21(2): 233～240.
[14] Stassi S, Canavese G. Spiky Nanostructured Metal Particles as Filler of Polymeric Composites Showing Tunable Electrical Conductivity [J]. Journal of Polymer Science Part B: Polymer Physics, 2012, 50(14): 984～992.
[15] Xu Z, Gao M, Yu L, et al. Co Nanoparticles Induced Resistive Switching and Magnetism for the Electrochemically Deposited Polypyrrole Composite films [J]. ACS applied materials & interfaces, 2014, 6(20): 17823～17830.
[16] 王长远. 研究氧化锌纳米材料的研究进展[J]. 中国西部科技, 2013, 12(9): 56～58.
[17] 刘晨阳, 郑晓泉, 等. 掺杂ZnO/环氧树脂基体的制备及其非线性电导改性研究[J]. 电工技术学报, 2016, 31(12): 24～30.
[18] 郭文敏, 韩宝忠, 李忠华. 影响低密度聚乙烯/氧化锌复合材料场致电导因素的研究[J]. 功能材料, 2009, 40(6): 943～945.
[19] 郭文敏, 李忠华. 聚乙烯基非线性复合材料的电导特性及机理[C]. 第十三届全国工程电介质学术会议, 中国陕西西安, 2011年10月. 第十三届全国工程电介质学术会议论文集. 2011: 212～216.
[20] 郭文敏, 韩宝忠, 李忠华. 聚乙烯/碳化硅复合材料的非线性电导特性的研究[J]. 功能材料, 2010, 41(3): 436～438.
[21] 郭文敏, 韩宝忠, 李忠华. 电场处理对碳化硅/聚合物复合材料电导特性的影响[J]. 功能材料, 2009, 40 (10): 1650～1653.
[22] Zhaoming Qu, Pin Lu, Yang Yuan, Qingguo Wang. Voltage-induced Nonlinear Conduction Properties of Epoxy Resin/micron-silver Particles Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012013.
[23] LU Pin, QU Zhaoming, WANG Qingguo, ZHAO Shiyang and BAI Liyun. Nonlinear Conductive Behavior of Silver Nanowires/silicone Rubber Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012052.
[24] 韩宝忠, 郭文敏, 李忠华. 碳化硅/硅橡胶复合材料的非线性电导特性[J]. 功能材料, 2008, 39(9): 1490～1493.
[25] Wang Z, Nelson J K, Hillborg H, et al. Graphene Oxide Filled Nanocomposite with Novel Electrical and Dielectric Properties[J]. Advanced Materials, 2012, 24(23): 3134～3137.
[26] Aleshin A N, Krylov P S, BerestennikovA S, et al. The Redox Nature of the Resistive Switching in Nanocomposite Thin Films Based on Graphene (graphene oxide) Nanoparticles and Poly (9-vinylcarbazole)[J]. Synthetic Metals, 2016, 217: 7～13.
[27] Wang J, Yu S, Luo S, et al. Investigation of Nonlinear I-V Behavior of CNTs Filled Polymer Composites[J]. Materials Science and Engineering: B, 2016, 206: 55～60.
[28] WEI LU, HONGFEI LIN, GUOHUA CHEN. Voltage-Induced Resistivity Relaxation in a High-Density Polyethylene/Graphite Nanosheet Composite [J]. Journal of Polymer Science: Part B: Polymer Physics, 2007, 45: 860～863.
[29] Lichun Zhou, Jinshan Lin, Hongfei Lin, Guohua Chen. Electrical-thermal Switching Effect in High-density Polyethylene/graphite Nanosheets Conducting Composites [J]. Journal of Material Science, 2008, 43: 4886～4891.
[30] LICHUN ZHOU, JINGSHAN LIN, GUOHUA CHEN. Electrical Breakdown in High-Density Polyethylene/Graphite Nanosheets Conductive Composites [J]. Journal of Polymer Science: Part B: Polymer Physics, 2009, 47: 576～582.
[31] Xiaoxin Lu, Julien Yvonnet, et al. Multiscale Modeling of Nonlinear Electric Conductivity in Graphene-reinforced Nanocomposites Taking into Account Tunnelling Effect [J]. Journal of Computational Physics, 2017, 337: 116～131.
[32] He Li, Zihao Guo, et al. Nonlinear Conductive Behaviors of Multilayer Graphene Nanosheets/epoxy Composites Below the Percolation Threshold [C]. 2017 IEEE Conference on Electrical Insulation and Dielectric Phenomenon, 2017, 10: 453～456.
[33] Yang Yuan, Qingguo Wang, Zhaoming Qu. Nonlinear Conductive Behavior in Graphene Nanoplatets/Epoxy Resin Composites [J]. IOP Conference Series: Materials Science and Engineering, 2018, 301: 012015.
[34] 贾向明, 杨其, 李光宪, 等. 填充型导电高分子复合材料的逾渗理论进展[J]. 中国塑料, 2003, 17(6): 9～14.
[35] 刘生丽, 冯辉霞, 张建强, 等. 逾渗理论的研究及应用进展[J]. 应用化工, 2010, 39(7): 1074～1078.
[36] Nan C W, Shen Y, Ma J. Physical Properties of Composites Near Percolation [J]. Annual Review of Materials Research, 2010, 40: 131～151.
[37] Polley M H, Boonstra B. Carbon Blacks for Highly Conductive Rubber [J]. Rubber Chemistry and Technology, 1957, 30(1): 170～179.
[38] Simmons. J G. Generalized Formula for the Electric tunnel Effect Between Similar Electrodes Separated by a Thin Insulating Film [J]. J. Appl. Phys, 1963, 34(6): 1793～1803.
[39] Sheng P, Sichel E K, Gittleman J I. Fluctuation-induced Tunneling Conduction in Carbon-polyvinylchloride Composites [J]. Physical Review Letters, 1978, 40(18): 1197～1200.
[40] Sheng P. Fluctuation-induced Tunneling Conduction in Disordered Materials [J]. Physical Review B, 1980, 21(6): 2180～2195.
[41] Medalia A I. Electrical Conduction in Carbon Black Composites [J]. Rubber Chemistry and Technology, 1986, 59(3): 432～454.
[42] Ezquerra T A, Kulescza M, Cruz C S, et al. Charge Transport in Polyethylene-graphite Composite Materials[J]. Advanced Materials, 1990, 2(12): 597～600.
[43] Kaiser A B, Park Y W. Current-voltage Characteristics of Conducting Polymers and Carbon Nanotubes [J]. Synthetic metals, 2005, 152(1): 181～184.
[44] Van Beek L K H, Van Pul B. Internal Field Emission in Carbon black-loaded Natural Rubber Vulcanizates [J]. Journal of Applied Polymer Science, 1962, 6(24): 651～655.
[45] Landauer R. Electrical Conductivity in Inhomogeneous Media [C]. Electrical Transport and Optical Properties of Inhomogeneous Media. AIP Publishing, 1978, 40(1): 2～45.
[46] McLachlan D S, Blaszkiewicz M, Newnham R E. Electrical Resistivity of Composites [J]. Journal of the American Ceramic Society, 1990, 73(8): 2187～2203.
[47] 朱栋培. 量子力学基础[M]. 第一版. 合肥:中国科学技术大学出版社, 2012: 52～53.
[48] 张雄伟, 黄锐. LDPE/炭黑复合导电材料性能的研究[J]. 中国塑料, 1994, 8(3): 26～34.