阳离子型双子表面活性剂在石油行业的应用进展
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摘要
针对用于缓蚀剂、杀菌剂、驱油剂、压裂液和防腐剂这5个方面对阳离子型双子表面活性剂的合成、使用条件、应用现状进行了综述,发现存在的问题有:缓蚀剂溶解性较差、对环境有污染;在高温、高浓度前提下防腐剂性能不强;杀菌剂稳定性较差、易产生抗药性;驱油剂的吸附量不够低、在地层介质中没有较大的扩散速度;压裂液的耐温性能较差、破胶不够快速、彻底。针对上述的不足之处提出了对于驱油剂应加强其对于超高温、高盐地层的适应性;提高压裂液的降滤失能力;发展有利于环境生产、无污染或低污染的缓蚀剂;提高防腐剂在高浓度条件下的防腐效果;制备稳定性强的杀菌剂等建议。
The synthesis,use conditions and application status of cationic gemini surfactants are reviewed from five aspects:corrosion inhibitors,fungicides,oil displacing agents,fracturing fluids,and preservatives.The problems found are:poor solubility of the corrosion inhibitors,pollution to the environment,and high temperature and high concentration conditions.The performance of preservatives is not strong;the stability of bactericides is poor,and drug resistance is easy;the adsorption capacity of the oil displacement agent is not low enough,and there is no large diffusion rate in the formation medium;the temperature resistance of the pressure fluid is poor and the rubber breaks.Not fast enough and thorough.In view of the above-mentioned deficiencies,it is proposed that the oil displacement agent should be enhanced in its adaptability to ultra-high temperature and high-salt formations;the fracturing fluid's ability to reduce fluid loss should be improved;and the development of environmentally friendly,pollution-free,or low-pollution corrosion protection should be promoted.Agents;improve the antiseptic effect of preservatives under high concentration conditions;prepare strong fungicides.
The synthesis,use conditions and application status of cationic gemini surfactants are reviewed from five aspects:corrosion inhibitors,fungicides,oil displacing agents,fracturing fluids,and preservatives.The problems found are:poor solubility of the corrosion inhibitors,pollution to the environment,and high temperature and high concentration conditions.The performance of preservatives is not strong;the stability of bactericides is poor,and drug resistance is easy;the adsorption capacity of the oil displacement agent is not low enough,and there is no large diffusion rate in the formation medium;the temperature resistance of the pressure fluid is poor and the rubber breaks.Not fast enough and thorough.In view of the above-mentioned deficiencies,it is proposed that the oil displacement agent should be enhanced in its adaptability to ultra-high temperature and high-salt formations;the fracturing fluid's ability to reduce fluid loss should be improved;and the development of environmentally friendly,pollution-free,or low-pollution corrosion protection should be promoted.Agents;improve the antiseptic effect of preservatives under high concentration conditions;prepare strong fungicides.
引文
[1]Vander P,Mathieu M.Synthesis of high quality MCM-48and MCM-41 by means of the Gemini surfactant method[J].The Journal of Physical Chemistry B,1998,102(44):8847-8851.
[2]Li Y,Li P,Dong C.Aggregation properties of cationic Gemini surfactants with partially fluorinated spacers in aqueous solution[J].Langmuir,2006,22(1):42-45.
[3]Wang X,Wang J,Wang Y,et al.Salt effect on the complex formation between cationic Gemini surfactant and anionic polyelectrolyte in aqueous solution[J].Langmuir,2004,20(21):9014-9018.
[4]田兴国.“三采后”进一步提高采收率的驱替剂---Genmini型表面活性剂[J].国外油田工程,2001,19(9):11-12.
[5]陈洪.油气开采用表面活性剂的合成及性能研究[D].成都:西南石油学院,2004:1-102.
[6]Rist,Rike A,Carlsen P H J,et al.Synthesis of novel diammonium Gemini surfactants[J].Molecules,2001,6:979-987.
[7]陈洪,韩利娟,罗平亚.可作为驱油剂的阳离子双子表面活性剂:CN,1528853A[P].2004-09-15.
[8]逯红艳.14-6-14型阳离子双子表面活性剂的合成和性能评价[J].科学技术与工程,2012,12(33):9002-9004.
[9]王龙飞.阳离子型双子表面活性剂的合成与性能评价[J].价值工程,2012,16(227):325-326.
[10]谢建波.新型双子表面活性剂的合成与性能测定[J].上海化工,2016,41(7):15-19.
[11]Lu T,Huang J.Synthesis and properties of novel Gemini surfactants with short spacer[J].Chinese Science Bulletin,2007,52(19):2618-2620.
[12]曾湘楚,李小瑞.双子季铵盐表面活性剂的制备及性能研究[J].应用化工,2017,46(2):221-229.
[13]刘鑫.阳离子双子表面活性剂的合成及性能研究[D].大庆:东北石油大学,2013:1-44.
[14]孙玉海.系列阳离子双子表面活性剂的合成及其表面活性的研究[J].化学学报,2006,64(18):1925-1928.
[15]罗儒显,胡宾.阳离子七甲基三硅氧烷双子表面活性剂的合成及性能研究[J].广东化工,2015,11(42):44-45.
[16]李小瑞,解颖,王海花,等.酯基型双子表面活性剂的合成及驱油性能[J].精细化工,2017,34(12):1370-1378.
[17]Samuel M M,Card R J,Nelson E B.Polymer-free fluid for fracturing applications[J].SPE59478-PA,1999:65-71.
[18]Raghavan S R,Kaler E W.Highly visco-elasic wormlike micellar solutions formed by cationic surfactants with long unsaturated tails[J].Langmuir,2001,17:300-306.
[19]卢拥军,方波,房鼎业,等.粘弹性表面活性剂胶束体系及其流变特性[J].油田化学,2003,20(3):291-294.
[20]Wang Xialan,Qu Qi.Development of a non-residue polymer-based fracturing fluid[R].SPE80277,2003.
[21]梁文利,赵林,辛素云,等.压裂液技术研究新进展[J].断块油气田,2009,16(1):95-98,117-121.
[22]杨振周,周广才,卢拥军,等.粘弹性清洁压裂液的作用机理和现场应用[J].钻井液与完井液,2005,22(1):48-50.
[23]娄平均,牛华,朱红军,等.新型吉米奇季铵盐在VES清洁压裂液中的应用研究[J].天然气与石油,2011,19(1):45-47.
[24]贾振福,钟静霞,牛红彬,等.新型清洁压裂液的实验室合成[J].钻井液与完井液,2006,23(6):42-46.
[25]朱红军,牛华,娄平均,等.含双子表面活性剂酸性清洁压裂液的合成与性能[J].精细石油化工进展,2011,12(10):5-7.
[26]钟静,王丽敏,冯跃,等.高温清洁压裂液体系室内研究[J].石油地质与工程,2013,27(2):98-100.
[27]杨珍.一种阳离子双子表面活性剂压裂液的研究及应用[J].钻井液与完井液,2013,30(6):64-67.
[28]曹书瑜,涂述培.QH-VES无聚合物压力液及其在七个泉油田的应用[C].中国西部科技进步与经济社会发展专家论坛(九).成都:四川科技出版社,2007:381-384.
[29]杨冠科,王成.一种阳离子表面活性剂类清洁压裂液配方设计与性能评价[J].采油工艺与油田化学,2011,13(10):28-34.
[30]任晓娟,刘树仁,李志航,等.FRC-1清洁压裂液体系的性能和应用[J].精细石油化工进展,2004,5(1):5-7.
[31]张福铭,李学军,陈小华,等.海水基清洁压裂液体系PA-VES90的制备及性能研究[J].科学技术与工程,2012,12(8):1760-1764.
[32]李天聪,李仕铭,谷同杰.文南油田油管断裂失效分析与预防措施探讨[J].石油工业技术监督,2011,27(3):5-7.
[33]Achouri M El,Kertit S.Synthesis of some cationic Gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium[J].Corrosion Sicence,2001,43(1):19-35.
[34]Qiu L G,Xie A J,Shen Y H.A novel triazole-based cationic Gemini surfactant:synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid[J].Materials Chemistry and Physics,2005,91(2/3):269-273.
[35]王军,栾立辉,杨许召,等.季铵盐Gemini表面活性剂的缓蚀性能研究[J].腐蚀科学与防护技术,2010,22(3):203-206.
[36]葛君,樊国栋,柴玲玲.咪唑啉基季铵盐型Gemini表面活性剂的合成与性能[J].精细化工,2011,28(5):447-450.
[37]张光华,王腾飞,董惟昕.硫脲基烷基咪唑啉季铵盐缓蚀剂在油水两相中的传质性能[J].化工进展,2010,29(12):2254-2259.
[38]宋伟伟,张静,杜敏.新型不对称双季铵盐缓蚀剂在HCl中对Q235钢的缓蚀行为[J].化学学报,2011,69(16):1851-1857.
[39]李俊.含羟基双子表面活性剂的合成及其缓蚀性能的研究[D].北京:北京化工大学,2012:1-72.
[40]郑乐驰.双子表面活性剂及其防腐性能研究[D].武汉:武汉工程大学,2016:1-81.
[41]魏晓晓.含氮杂环季铵盐Gemini表面活性剂的合成及性能研究[D].西安:陕西科技大学,2017:1-58.
[42]吕志凤,张倩,战风涛,等.环境友好型咪唑啉缓蚀剂的合成及性能研究[J].精细与专用化学品,2018,26(1):28-32.
[43]Qiu L G,Xie A J,Sn Y.The adsorption and corrosion inhibition of some cationic Gemini surfactants on carbon steel surface in hydrochloric acid[J].Corrosion Science,2005,47(5):273-278.
[44]Salah M Tawfik,Ali A Abd-Elaal1,Ismail Aiad1,et al.Three Gemini cationic surfactants as biodegradable corrosion inhibitors for carbon steel in HCl solution[J].Res Chem Intermed,2016,42(6):1101-1123.
[45]Labena A,Hegazy M A,Horn H,et al.The biocidal effect of a novel synthesized Gemini surfactant on environmental sulfidogenic bacteria:planktonic cells and biofilms[J].Materials Science and Engineering C,2015,47:367-375.
[46]朱瑞龙,孙玉鹏,苏建军,等.聚季铵盐杀菌剂的合成[J].现代化工,2016,36(12):67-69.
[47]孟琳,周丽萍,葛双启,等.双季铵盐杀菌剂的合成及其杀菌性能研究[J].化学工程师,2005,115(4):59-60.
[2]Li Y,Li P,Dong C.Aggregation properties of cationic Gemini surfactants with partially fluorinated spacers in aqueous solution[J].Langmuir,2006,22(1):42-45.
[3]Wang X,Wang J,Wang Y,et al.Salt effect on the complex formation between cationic Gemini surfactant and anionic polyelectrolyte in aqueous solution[J].Langmuir,2004,20(21):9014-9018.
[4]田兴国.“三采后”进一步提高采收率的驱替剂---Genmini型表面活性剂[J].国外油田工程,2001,19(9):11-12.
[5]陈洪.油气开采用表面活性剂的合成及性能研究[D].成都:西南石油学院,2004:1-102.
[6]Rist,Rike A,Carlsen P H J,et al.Synthesis of novel diammonium Gemini surfactants[J].Molecules,2001,6:979-987.
[7]陈洪,韩利娟,罗平亚.可作为驱油剂的阳离子双子表面活性剂:CN,1528853A[P].2004-09-15.
[8]逯红艳.14-6-14型阳离子双子表面活性剂的合成和性能评价[J].科学技术与工程,2012,12(33):9002-9004.
[9]王龙飞.阳离子型双子表面活性剂的合成与性能评价[J].价值工程,2012,16(227):325-326.
[10]谢建波.新型双子表面活性剂的合成与性能测定[J].上海化工,2016,41(7):15-19.
[11]Lu T,Huang J.Synthesis and properties of novel Gemini surfactants with short spacer[J].Chinese Science Bulletin,2007,52(19):2618-2620.
[12]曾湘楚,李小瑞.双子季铵盐表面活性剂的制备及性能研究[J].应用化工,2017,46(2):221-229.
[13]刘鑫.阳离子双子表面活性剂的合成及性能研究[D].大庆:东北石油大学,2013:1-44.
[14]孙玉海.系列阳离子双子表面活性剂的合成及其表面活性的研究[J].化学学报,2006,64(18):1925-1928.
[15]罗儒显,胡宾.阳离子七甲基三硅氧烷双子表面活性剂的合成及性能研究[J].广东化工,2015,11(42):44-45.
[16]李小瑞,解颖,王海花,等.酯基型双子表面活性剂的合成及驱油性能[J].精细化工,2017,34(12):1370-1378.
[17]Samuel M M,Card R J,Nelson E B.Polymer-free fluid for fracturing applications[J].SPE59478-PA,1999:65-71.
[18]Raghavan S R,Kaler E W.Highly visco-elasic wormlike micellar solutions formed by cationic surfactants with long unsaturated tails[J].Langmuir,2001,17:300-306.
[19]卢拥军,方波,房鼎业,等.粘弹性表面活性剂胶束体系及其流变特性[J].油田化学,2003,20(3):291-294.
[20]Wang Xialan,Qu Qi.Development of a non-residue polymer-based fracturing fluid[R].SPE80277,2003.
[21]梁文利,赵林,辛素云,等.压裂液技术研究新进展[J].断块油气田,2009,16(1):95-98,117-121.
[22]杨振周,周广才,卢拥军,等.粘弹性清洁压裂液的作用机理和现场应用[J].钻井液与完井液,2005,22(1):48-50.
[23]娄平均,牛华,朱红军,等.新型吉米奇季铵盐在VES清洁压裂液中的应用研究[J].天然气与石油,2011,19(1):45-47.
[24]贾振福,钟静霞,牛红彬,等.新型清洁压裂液的实验室合成[J].钻井液与完井液,2006,23(6):42-46.
[25]朱红军,牛华,娄平均,等.含双子表面活性剂酸性清洁压裂液的合成与性能[J].精细石油化工进展,2011,12(10):5-7.
[26]钟静,王丽敏,冯跃,等.高温清洁压裂液体系室内研究[J].石油地质与工程,2013,27(2):98-100.
[27]杨珍.一种阳离子双子表面活性剂压裂液的研究及应用[J].钻井液与完井液,2013,30(6):64-67.
[28]曹书瑜,涂述培.QH-VES无聚合物压力液及其在七个泉油田的应用[C].中国西部科技进步与经济社会发展专家论坛(九).成都:四川科技出版社,2007:381-384.
[29]杨冠科,王成.一种阳离子表面活性剂类清洁压裂液配方设计与性能评价[J].采油工艺与油田化学,2011,13(10):28-34.
[30]任晓娟,刘树仁,李志航,等.FRC-1清洁压裂液体系的性能和应用[J].精细石油化工进展,2004,5(1):5-7.
[31]张福铭,李学军,陈小华,等.海水基清洁压裂液体系PA-VES90的制备及性能研究[J].科学技术与工程,2012,12(8):1760-1764.
[32]李天聪,李仕铭,谷同杰.文南油田油管断裂失效分析与预防措施探讨[J].石油工业技术监督,2011,27(3):5-7.
[33]Achouri M El,Kertit S.Synthesis of some cationic Gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium[J].Corrosion Sicence,2001,43(1):19-35.
[34]Qiu L G,Xie A J,Shen Y H.A novel triazole-based cationic Gemini surfactant:synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid[J].Materials Chemistry and Physics,2005,91(2/3):269-273.
[35]王军,栾立辉,杨许召,等.季铵盐Gemini表面活性剂的缓蚀性能研究[J].腐蚀科学与防护技术,2010,22(3):203-206.
[36]葛君,樊国栋,柴玲玲.咪唑啉基季铵盐型Gemini表面活性剂的合成与性能[J].精细化工,2011,28(5):447-450.
[37]张光华,王腾飞,董惟昕.硫脲基烷基咪唑啉季铵盐缓蚀剂在油水两相中的传质性能[J].化工进展,2010,29(12):2254-2259.
[38]宋伟伟,张静,杜敏.新型不对称双季铵盐缓蚀剂在HCl中对Q235钢的缓蚀行为[J].化学学报,2011,69(16):1851-1857.
[39]李俊.含羟基双子表面活性剂的合成及其缓蚀性能的研究[D].北京:北京化工大学,2012:1-72.
[40]郑乐驰.双子表面活性剂及其防腐性能研究[D].武汉:武汉工程大学,2016:1-81.
[41]魏晓晓.含氮杂环季铵盐Gemini表面活性剂的合成及性能研究[D].西安:陕西科技大学,2017:1-58.
[42]吕志凤,张倩,战风涛,等.环境友好型咪唑啉缓蚀剂的合成及性能研究[J].精细与专用化学品,2018,26(1):28-32.
[43]Qiu L G,Xie A J,Sn Y.The adsorption and corrosion inhibition of some cationic Gemini surfactants on carbon steel surface in hydrochloric acid[J].Corrosion Science,2005,47(5):273-278.
[44]Salah M Tawfik,Ali A Abd-Elaal1,Ismail Aiad1,et al.Three Gemini cationic surfactants as biodegradable corrosion inhibitors for carbon steel in HCl solution[J].Res Chem Intermed,2016,42(6):1101-1123.
[45]Labena A,Hegazy M A,Horn H,et al.The biocidal effect of a novel synthesized Gemini surfactant on environmental sulfidogenic bacteria:planktonic cells and biofilms[J].Materials Science and Engineering C,2015,47:367-375.
[46]朱瑞龙,孙玉鹏,苏建军,等.聚季铵盐杀菌剂的合成[J].现代化工,2016,36(12):67-69.
[47]孟琳,周丽萍,葛双启,等.双季铵盐杀菌剂的合成及其杀菌性能研究[J].化学工程师,2005,115(4):59-60.