肟菌酯的应用与开发进展
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摘要
肟菌酯是甲氧基丙烯酸酯类杀菌剂,杀菌谱广,活性高。自上市后,肟菌酯成为拜耳公司重要杀菌剂品种之一,占据大豆、谷物用杀菌剂市场重要地位。重点介绍了肟菌酯的应用、市场、开发进展、合成化学,并对其应用前景进行了展望。
Trifloxystrobin is belong to strobilurin fungicide, and has broad spectrum, high activity. Since its introduction,trifloxystrobin has been one of Bayer's largest selling fungicides, and has established as one of the leading products for use in disease control in soybean, cereal. The application, global market, development progress, synthetic method were introduced in this paper. Future development was also forecasted.
Trifloxystrobin is belong to strobilurin fungicide, and has broad spectrum, high activity. Since its introduction,trifloxystrobin has been one of Bayer's largest selling fungicides, and has established as one of the leading products for use in disease control in soybean, cereal. The application, global market, development progress, synthetic method were introduced in this paper. Future development was also forecasted.
引文
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[2]柏亚罗,张晓进,顾群,等.专利农药新品种手册[M].北京:化学工业出版社, 2011:202-209.
[3]刘长令.世界农药大全:杀菌剂卷[M].北京:化学工业出版社,2012:143-145.
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[6]柏亚罗,万红梅.甲氧基丙烯酸酯类杀菌剂的抗性剖析[J].农药,2009, 48(2):88-94.
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[11] Phillips Mc Dougall. Global Crop Protection and Seed Database[DB/OL].[2018-06-01]. http://www.agraspire.com/searchByProduct.asp.
[12] European Commission. EU Pesticides Database[EB/OL].[2017-10-04]. http://ec.europa.eu/food/plant/pesticides/eu-pesticidesdatabase/public/?event=activesubstance.detail&language=EN&selectedID=1991.
[13] US EPA. Chemical Name:Trifloxystrobin[EB/OL].[2018-06-01].https://iaspub.epa.gov/apex/pesticides/f?p=113:6:::NO::P6_XCHEMICAL_ID:4149.
[14] Phillips Mc Dougall-AgriService. Corps Section—2016 Market[R].Phillips Mc Dougall-AgriService, 2017.
[15]于春睿,孙克,张敏恒.肟菌酯合成方法述评[J].农药, 2014, 53(10):773-775.
[16]张荣华,李倩,朱志良.肟菌酯合成工艺[J].农药, 2007, 46(1):29-30.
[17]陈伟,方晓敏,杨莉,等.杀菌剂肟菌酯的合成工艺[J].化学研究,2014, 25(1):16-19.
[18]柴兵,闻冲,陈晓东,等.肟菌酯合成新工艺[J].农药, 2013, 52(4):258-259.
[19] Wingert H, Wolf B, Benoit R, et al. Preparation of E-Oxime Ethers of Phenylglyoxylic Esters:US, 5221762[P]. 1993-06-22.
[20]陆翠军,刘建华,杜晓华.肟菌酯的合成工艺[J].农药, 2011, 50(3):187-191.
[2]柏亚罗,张晓进,顾群,等.专利农药新品种手册[M].北京:化学工业出版社, 2011:202-209.
[3]刘长令.世界农药大全:杀菌剂卷[M].北京:化学工业出版社,2012:143-145.
[4]柏亚罗. Strobilurins类杀菌剂研究开发进展[J].农药, 2007, 46(5):289-295.
[5]周权康.甲氧基丙烯酸酯类杀菌剂不同产品特点与技术定位区别[DB/OL].(2017-03-15)[2017-09-21]. http://www.agroinfo.com.cn/other_detail_3848.html.
[6]柏亚罗,万红梅.甲氧基丙烯酸酯类杀菌剂的抗性剖析[J].农药,2009, 48(2):88-94.
[7]中华人民共和国农业农村部农药检定所.农药登记数据[DB/OL].[2018-08-26]. http://www.chinapestidide.gov.cn/hysj/index.jhtml.
[8] Phillips Mc Dougall-AgriService. Products Section—2016 Market[R]. Phillips Mc Dougall-AgriService, 2017.
[9] Phillips Mc Dougall-AgriService. Products Section—2015 Market[R]. Phillips Mc Dougall-AgriService, 2016.
[10]柏亚罗.肟菌酯行政保护期满获首登[DB/OL].[2018-06-01].http://www.agroinfo.com.cn/other_detail_1382.html.
[11] Phillips Mc Dougall. Global Crop Protection and Seed Database[DB/OL].[2018-06-01]. http://www.agraspire.com/searchByProduct.asp.
[12] European Commission. EU Pesticides Database[EB/OL].[2017-10-04]. http://ec.europa.eu/food/plant/pesticides/eu-pesticidesdatabase/public/?event=activesubstance.detail&language=EN&selectedID=1991.
[13] US EPA. Chemical Name:Trifloxystrobin[EB/OL].[2018-06-01].https://iaspub.epa.gov/apex/pesticides/f?p=113:6:::NO::P6_XCHEMICAL_ID:4149.
[14] Phillips Mc Dougall-AgriService. Corps Section—2016 Market[R].Phillips Mc Dougall-AgriService, 2017.
[15]于春睿,孙克,张敏恒.肟菌酯合成方法述评[J].农药, 2014, 53(10):773-775.
[16]张荣华,李倩,朱志良.肟菌酯合成工艺[J].农药, 2007, 46(1):29-30.
[17]陈伟,方晓敏,杨莉,等.杀菌剂肟菌酯的合成工艺[J].化学研究,2014, 25(1):16-19.
[18]柴兵,闻冲,陈晓东,等.肟菌酯合成新工艺[J].农药, 2013, 52(4):258-259.
[19] Wingert H, Wolf B, Benoit R, et al. Preparation of E-Oxime Ethers of Phenylglyoxylic Esters:US, 5221762[P]. 1993-06-22.
[20]陆翠军,刘建华,杜晓华.肟菌酯的合成工艺[J].农药, 2011, 50(3):187-191.