微反应器技术在聚合中的应用研究进展
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摘要
微反应器因其优良的传热、传质性能在聚合反应中的研究方兴未艾。与传统釜式聚合相比,微反应器聚合能够更好地调控聚合物分子量分布,提高聚合反应速率,控制聚合物分子结构和产物形貌。本文综述了微反应器技术在配位聚合、开环聚合和光诱导可控自由基聚合中的研究进展,并简要介绍了微反应器聚合技术的放大实验。最后,对微反应器技术在聚合物合成中的发展方向提出展望。
The research of microreactor in the field of polymerization reactions is booming due to its excellent heat and mass transfer performance. Compared with the conventional tank reactor, microreactor technology can regulate the polymer molecular weight distribution and improve the polymerization rate better, as well as control the polymer molecular structures and product morphologies. In this short review, the research progress of microreactor technology in coordination polymerization, ring-opening polymerization and photoinduced controlled radical polymerization are summarized, and the scale-up of the microreactor polymerization technology is briefly introduced. Finally, the development trend of the microreactor technology in polymerization is prospected.
The research of microreactor in the field of polymerization reactions is booming due to its excellent heat and mass transfer performance. Compared with the conventional tank reactor, microreactor technology can regulate the polymer molecular weight distribution and improve the polymerization rate better, as well as control the polymer molecular structures and product morphologies. In this short review, the research progress of microreactor technology in coordination polymerization, ring-opening polymerization and photoinduced controlled radical polymerization are summarized, and the scale-up of the microreactor polymerization technology is briefly introduced. Finally, the development trend of the microreactor technology in polymerization is prospected.
引文
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[39] Cai Z, Zhang Y, Li J, et al. J Appl Polym Sci, 2013, 128(1): 628～635.