基于P3HT空穴传输层的钙钛矿太阳能电池性能仿真研究
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摘要
利用AMPS-1D软件对钙钛矿太阳能电池性能进行仿真。研究发现,当P3HT厚度500 nm时,钙钛矿太阳能电池的短路电流密度J_(sc)=18. 995 m A/cm~2,光电转换效率E_(ff)=17. 425%,填充因数FF=0. 824,开路电压V_(oc)=1. 113 V。钙钛矿太阳能电池的光吸收层厚度为400 nm时,钙钛矿太阳能的光电转化效率最大。钙钛矿太阳能电池开路电压、短路电流密度、填充因数和光电转化效率等性能随着阴极材料功函数的增大而减。通过理论计算对制备高性能的太阳能电池具有指导性作用。
The performance of perovskite solar cell was simulated by the AMPS-1D software. The results were showed that performance of perovskite solar cell were Jsc= 18. 995 m A/cm~2,E_(ff)= 17. 425%,FF =0. 824 and V_(oc)= 1. 113 V,when the P3HT thickness was 500 nm. The thickness of light absorption layer of perovskite solar cell was 400 nm,the photoelectric conversion efficiency of perovskite solar cell was the highest. The opening voltage,short circuit current density,filling factor and photoelectric conversion efficiency of perovskite solar cell decreased with the increasing of cathode material work function. It has instructive significance to prepare high-performance perovskite solar cell.
The performance of perovskite solar cell was simulated by the AMPS-1D software. The results were showed that performance of perovskite solar cell were Jsc= 18. 995 m A/cm~2,E_(ff)= 17. 425%,FF =0. 824 and V_(oc)= 1. 113 V,when the P3HT thickness was 500 nm. The thickness of light absorption layer of perovskite solar cell was 400 nm,the photoelectric conversion efficiency of perovskite solar cell was the highest. The opening voltage,short circuit current density,filling factor and photoelectric conversion efficiency of perovskite solar cell decreased with the increasing of cathode material work function. It has instructive significance to prepare high-performance perovskite solar cell.
引文
[1]Jeon N J,Na H,Jung E H,et al.A Fluorene-terminated Fole-transporting Material for Highly Efficient and Etable Eerovskite Eolar Cells[J].Nature Energy,2018,3(8):682-689.
[2]Kumar M H,Yantara N,Dharani S,et al.Flexible,Low-temperature,Solution Srocessed ZnO-based Perovskite Solid State Solar Cells[J].Chemical Communications,2013,49(94):11089-11091.
[3]Leijtens T,Eperon G E,Pathak S,et al.Overcoming Ultraviolet Light Instability of Sensitized Ti O2with Meso-superstructured Organometal Trihalide Perovskite Solar Cells[J].Nature Communications,2013,4:2885.
[4]Cao J,Wu B,Chen R,et al.Efficient,Hysteresis-Free,and Stable Perovskite Solar Cells with ZnO as Electron-Transport Layer:Effect of Surface Passivation[J].Advanced Materials,2018,30(11):1705596.
[5]Chen W,Wu Y,Yue Y,et al.Efficient and Stable Large-area Perovskite Solar Cells withInorganic Charge Extraction Layers[J].Science,2015:aad1015.
[6]Hou F,Su Z,Jin F,et al.Efficient and Stable Planar Heterojunction Perovskite Solar Cells with an Mo O3/PEDOT:PSS Hole TransportingLayer[J].Nanoscale,2015,7(21):9427-9432.
[7]Zhu Z,Bai Y,Zhang T,et al.High-performance Hole-extraction Layer of Sol-gel-processed Ni O Nanocrystals for Inverted Planar Perovskite Solar Cells[J].Angewandte Chemie,2014,126(46):12779-12783.
[8]Ogomi Y,Morita A,Tsukamoto S,et al.CH3NH3SnxPb(1-x)I3Perovskite Solar Cells Covering up to 1060 nm[J].The Journal of Physical Chemistry Letters,2014,5(6):1004-1011.
[9]Deng Q,Li Y,Chen L,et al.The Effects of Electron and Hole TransportLayer with the Electrode Work Function on Perovskite SolarCells[J].Modern Physics Letters B,2016,30(27):1650341-1-10.
[10]Adhikari K R,Gurung S,Bhattarai B K,et al.Comparative Study on MAPb I3Based Solar Cells Using Different Electron Transporting Materials[J].Physica Status Solidi(c),2016,13(1):13-17.
[11]Karimi E,Ghorashi S M B.Simulation of Perovskite Solar Cell with P3HT hole-transporting Materials[J].Journal of Nanophotonics,2017,11(3):032510.
[12]Lin L,Jiang L,Qiu Y,et al.Modeling and Analysis of HTM-free Perovskite Solar Cells Based on ZnO Electron Transport Layer[J].Superlattices and Microstructures,2017,104:167-177.
[13]Lee M M,Teuscher J,Miyasaka T,et al.Efficient Hybrid Solar Cells Based on meso-superstructured Organometal Halide Perovskites[J].Science,2012:1228604.
[2]Kumar M H,Yantara N,Dharani S,et al.Flexible,Low-temperature,Solution Srocessed ZnO-based Perovskite Solid State Solar Cells[J].Chemical Communications,2013,49(94):11089-11091.
[3]Leijtens T,Eperon G E,Pathak S,et al.Overcoming Ultraviolet Light Instability of Sensitized Ti O2with Meso-superstructured Organometal Trihalide Perovskite Solar Cells[J].Nature Communications,2013,4:2885.
[4]Cao J,Wu B,Chen R,et al.Efficient,Hysteresis-Free,and Stable Perovskite Solar Cells with ZnO as Electron-Transport Layer:Effect of Surface Passivation[J].Advanced Materials,2018,30(11):1705596.
[5]Chen W,Wu Y,Yue Y,et al.Efficient and Stable Large-area Perovskite Solar Cells withInorganic Charge Extraction Layers[J].Science,2015:aad1015.
[6]Hou F,Su Z,Jin F,et al.Efficient and Stable Planar Heterojunction Perovskite Solar Cells with an Mo O3/PEDOT:PSS Hole TransportingLayer[J].Nanoscale,2015,7(21):9427-9432.
[7]Zhu Z,Bai Y,Zhang T,et al.High-performance Hole-extraction Layer of Sol-gel-processed Ni O Nanocrystals for Inverted Planar Perovskite Solar Cells[J].Angewandte Chemie,2014,126(46):12779-12783.
[8]Ogomi Y,Morita A,Tsukamoto S,et al.CH3NH3SnxPb(1-x)I3Perovskite Solar Cells Covering up to 1060 nm[J].The Journal of Physical Chemistry Letters,2014,5(6):1004-1011.
[9]Deng Q,Li Y,Chen L,et al.The Effects of Electron and Hole TransportLayer with the Electrode Work Function on Perovskite SolarCells[J].Modern Physics Letters B,2016,30(27):1650341-1-10.
[10]Adhikari K R,Gurung S,Bhattarai B K,et al.Comparative Study on MAPb I3Based Solar Cells Using Different Electron Transporting Materials[J].Physica Status Solidi(c),2016,13(1):13-17.
[11]Karimi E,Ghorashi S M B.Simulation of Perovskite Solar Cell with P3HT hole-transporting Materials[J].Journal of Nanophotonics,2017,11(3):032510.
[12]Lin L,Jiang L,Qiu Y,et al.Modeling and Analysis of HTM-free Perovskite Solar Cells Based on ZnO Electron Transport Layer[J].Superlattices and Microstructures,2017,104:167-177.
[13]Lee M M,Teuscher J,Miyasaka T,et al.Efficient Hybrid Solar Cells Based on meso-superstructured Organometal Halide Perovskites[J].Science,2012:1228604.