静态高温高压cBN单晶合成与触媒相关性研究进展
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摘要
静态高温高压触媒法是工业生产立方氮化硼单晶的主要方法,其中触媒的选择至关重要。研究触媒与cBN的相关性对于探索立方氮化硼的合成机理,改进合成工艺,获得性能优良的氮化硼晶体有重要的意义。本文以工业生产中常用的锂、镁、钙基触媒立方氮化硼合成为主,阐述了触媒在立方氮化硼合成中的作用及近年来立方氮化硼的合成机理研究进展,并在此基础上提出了今后的研究方向。
Static high pressure and high temperature-catalysis method is the main method to grow cubic boron nitride single crystal,and the choice of catalyst is of great importance.Research on the correlation between catalyst and cBN is necessary for exploring the synthesis mechanism of cubic boron nitride,improving the synthesis process,and obtaining of excellent performance of cubic boron nitride.In this paper,based on the synthesis of cubic boron nitride with the catalyst of lithium,magnesium and calcium compound,the role of catalyst in the synthesis of cubic boron nitride as well as the research development of the synthesis mechanism was expounded,and the research direction in future was put forward.
Static high pressure and high temperature-catalysis method is the main method to grow cubic boron nitride single crystal,and the choice of catalyst is of great importance.Research on the correlation between catalyst and cBN is necessary for exploring the synthesis mechanism of cubic boron nitride,improving the synthesis process,and obtaining of excellent performance of cubic boron nitride.In this paper,based on the synthesis of cubic boron nitride with the catalyst of lithium,magnesium and calcium compound,the role of catalyst in the synthesis of cubic boron nitride as well as the research development of the synthesis mechanism was expounded,and the research direction in future was put forward.
引文
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[19]Fukunaga O,Nakano S,Maki J,et al.Kinetics of Phase Transformation from hBN to cBN in the Presence of Mg3BN3 Catalyst[J].High PressureResearch:An international Journal,1990,5(1):947-949.
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[21]Helmar Lorenz,Bernd Lorenz,Ulrich Kuhne.The Kinetics of Cubic Boron Nitride Formation in the System BN-Mg3N2[J].Journal of MaterialsScience,1988,23:3254-3257.
[22]张铁臣,马文骏,郭伟力,等.Ca3B2N4-hBN系中立方氮化硼的膜生长机制[J].高压物理学报,1992,6(4):273-378.Zhang T C,Ma W J,Guo W L,et al.Growth Mechanism of cBN by Metal Films[J].Chinese Journal of High Pressure Physics,1992,4(6):273-278.
[23]Ztrq V Turkevich.Thermodynamic and Kinetic Aspects of Spontaneous Crystallization of Diamond and Cubic Boron Nitride[A].InnovativeSuperhard Materials and Sustainable Coatings for Advanced Manufacturing[C].2005:17-30.
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[25]吉晓瑞,杨大鹏,杨晓红,等.高温高压合成立方氮化硼的热力学分析[J].高压物理学报,2009,23(6):467-470.Ji X R,Yang D P,Yang X H,et al.Thermodynamical Analysis of Synthesis of Cubic Boron Nitride at High Pressure and High Temperature[J].Chinese Journal of High Pressure Physics,2009,23(6):467-470.
[26]郭玮,郭伟力,王琰弟,等.细颗粒cBN的高温高压合成研究[J].超硬材料工程,2010,22(4):10-12.Guo W,Guo W L,Wang Y D,et al.Synthesis of fine cBN Single Crystal at HPHT[J].Superhard Material Engineering,2010,22(4):10-12.
[27]Du Y H,Ji X R,Yang X X,et al.The Influence of hBN Crystallinity and Additive Lithium Hydride on cBN Synthesis in Li3N-hBN system[J].Diamond and Related Materials,2007,16:1475-1478.
[28]Guo W,Jia X,Shang J,et al.Effect of Al Additive on the Formation of Cubic Boron Nitride in Li3N-hBN System under HPHT[J].Journal ofCrystal Growth,2010,312:3544-3548.
[29]张相法,张奎.粗粒度立方氮化硼的合成方法[P].CN:101062766A,2007-10-31.Zhang X F,Zhang K.Synthesis Method of Big Cubic Boron Nitride Crystal[P].CN:101062766A,2007-10-31.
[30]吉晓瑞,杨大鹏,杨晓红,等.hBN-LiH/hBN-Li3N-B体系合成cBN的赋色过程研究[J].高压物理学报,2010,24(3):231-236.Ji X R,Yang D P,Yang X H,et al.The Coloration Process Study on the Synthesis of cBN by hBN-LiH/hBN-Li3N-B System[J].ChineseJournal of high Pressure Physics,2010,24(3):231-236.
[31]Takashi Taniguchi,Shinobu Yamaoka.Spontaneous Nucleation of Cubic Boron Nitride Single Crystal by Temperature Gradient Method under HighPressure[J].Journal of Crystal Growth,2001,222:549-557.
[32]Fukunaga O,Takeuchi S,Taniguchi T.High-pressure Synthesis of Cubic BN Using Fe-Mo-Al and Co-Mo-Al Alloy Solvents[J].Diamond andRelated Materials,2011,20:752-755.
[2]Bhaskar Pal,Chattopadhyay A K,Chattopadhyay A B.Development and performance Evaluation of Monolayer Brazed cBN Grinding Wheel onBearing Steel[J].The International Journal of Advanced Manufacturing Technology,2010,48:935-944.
[3]张旺玺,卢金斌.立方氮化硼材料的制备、性能及应用[J].中原工学院学报,2011,22(2):25-28.Zhang W Xi,Lu J B.Review on Synthesis,Properties and Application of cBN Based Materials[J].Journal of Zhongyuan University ofTechnology,2011,22(2):25-28.
[4]王光祖.立方氮化硼(cBN)特性综述[J].超硬材料工程,2005,(5):41-45.Wang G Z.Summarization about the Peculiarities of cBN[J].Superhard material engineering,2005,17(63):41-45.
[5]李志宏,赵博.2010年超硬材料行业经济运行情况简析[A].2011中国(郑州)国际磨料磨具磨削技术发展论坛超硬材料论坛论文集[C].2011,1-9.
[6]Devries R C,Fleischer J F.The System Li3BN2 at High Pressures and Temperatures[J].MaterialsResearch bulletin,1969,4:433-442.
[7]王光祖.在不同触媒-hBN体系中cBN的合成[J].超硬材料工程,2005,64(17):44-47.Wang G Z.Synthesis of cBN with Various Catalyst and hBN System[J].Superhard Material Engineering,2005,64(17):44-47.
[8]张铁臣.立方氮化硼触媒多样性及生长特性研究[J].金刚石与磨料磨具工程.2004,139(1):27-30.Zhang T C.Study of the Various Kinds of Catalyst and Growing Character in Synthesis Cubic Boron Nitride[J].Diamond and abrasivesengineering,2004,(1):27-30.
[9]徐晓伟,赵红梅,范慧俐,等.用hBN合成cBN[J].北京科技大学学报,2001,23(4):337-339.Xu X W,Zhao H M,Fan H L,et al.Synthesis of cBN with hBN[J].Journal of University of Science and Technology Beijing,2001,23(4):337-339.
[10]Takashi Taniguchi,Shinobu Yamaoka.Spontaneous Nucleation of Cubic Boron Nitride Single Crystal by Temperature Gradient Method under highpressure[J].Journal of Crystal Growth,2001,222:539-557.
[11]Guo W,Jia X,Guo W L,et al.Effects of Additive LiF on the Synthesis of cBN in the System of Li3N-hBN at HPHT[J].Diamond and RelatedMaterials,2010,312:3544-3548.
[12]Wang X C,Jia X P,Zhang T C,et al.cBN Synthesis in the System of hBN-Mg and Bonded Water[J].Diamond and Related Materials,2003,12:57-60.
[13]张铁臣,望贤成,杜勇慧,等.在Mg-hBN体系中水对cBN晶体合成的影响[J].高压物理学报,2004,18(1):17-20.Zhang T C,Wang X C,Du Y H,et al.The Effect of Water on the Synthesis of Cubic Boron Nitride Crystal in the System of Mg-hBN[J].ChineseJournal of High Pressure Physics,2004,18(1):17-20.
[14]Devries R C,Fleische J F.Phase Equlibria Pertinent to the Growth of Cubic Boron Nitride[J].Journal of Crystal Growth,1979,13:88-92.
[15]Vladimir L Solozhenko,Vladimir Z Turkevich.High Pressure Phase Equilibria in the Li3N-BN System:in Situ Studies[J].Materials letters,1997,32:179-184.
[16]Bocouillon G,Loriers-Susse C,Loriers J.Synthesis of Cubic Boron Nitride Using Mg and Pure or M-doped Li3N,Ca3N2and Mg3N2 with M=Al,B,Si,Ti[J].Journal of Materials Science,1993,28:3547-3556.
[17]周艳平,阎学伟,马贤峰,等.高温高压下立方氮化硼晶体的生长机制[J].无机材料学报,1995,10(4):391-398.Zhou Y P,Yan X W,Ma X F,et al.Growth Mechanism of cubic Boron Nitride at High Pressure and High Temperature[J].Journal of InorganicMaterials,1995,10(4):391-398.
[18]Bogdanov S P.Influence of Superstoichiometric Boron on the Synthesis of Cubic Boron Nitride[J].Glass Physics and Chemistry,2008,34(3):336-339.
[19]Fukunaga O,Nakano S,Maki J,et al.Kinetics of Phase Transformation from hBN to cBN in the Presence of Mg3BN3 Catalyst[J].High PressureResearch:An international Journal,1990,5(1):947-949.
[20]Lorenz H,Orgzall I,Hinze E.Rapid Formation of Cubic Boron Nitride in System Mg3N2-hBN[J].Diamond and Related Materials,1995,4:1050-1055.
[21]Helmar Lorenz,Bernd Lorenz,Ulrich Kuhne.The Kinetics of Cubic Boron Nitride Formation in the System BN-Mg3N2[J].Journal of MaterialsScience,1988,23:3254-3257.
[22]张铁臣,马文骏,郭伟力,等.Ca3B2N4-hBN系中立方氮化硼的膜生长机制[J].高压物理学报,1992,6(4):273-378.Zhang T C,Ma W J,Guo W L,et al.Growth Mechanism of cBN by Metal Films[J].Chinese Journal of High Pressure Physics,1992,4(6):273-278.
[23]Ztrq V Turkevich.Thermodynamic and Kinetic Aspects of Spontaneous Crystallization of Diamond and Cubic Boron Nitride[A].InnovativeSuperhard Materials and Sustainable Coatings for Advanced Manufacturing[C].2005:17-30.
[24]徐晓伟,李玉萍,李湘瑶,等.用分段-慢超压方法合成立方氮化硼[J].人工晶体学报,1996,25(4):335-338.Xu X W,Li Y P,Li X Y,et al.Synthesizing cBN by Stepped and Slow Elevating Pressure Method[J].Journal of Synthetic Crystals,1996,25(4):335-338.
[25]吉晓瑞,杨大鹏,杨晓红,等.高温高压合成立方氮化硼的热力学分析[J].高压物理学报,2009,23(6):467-470.Ji X R,Yang D P,Yang X H,et al.Thermodynamical Analysis of Synthesis of Cubic Boron Nitride at High Pressure and High Temperature[J].Chinese Journal of High Pressure Physics,2009,23(6):467-470.
[26]郭玮,郭伟力,王琰弟,等.细颗粒cBN的高温高压合成研究[J].超硬材料工程,2010,22(4):10-12.Guo W,Guo W L,Wang Y D,et al.Synthesis of fine cBN Single Crystal at HPHT[J].Superhard Material Engineering,2010,22(4):10-12.
[27]Du Y H,Ji X R,Yang X X,et al.The Influence of hBN Crystallinity and Additive Lithium Hydride on cBN Synthesis in Li3N-hBN system[J].Diamond and Related Materials,2007,16:1475-1478.
[28]Guo W,Jia X,Shang J,et al.Effect of Al Additive on the Formation of Cubic Boron Nitride in Li3N-hBN System under HPHT[J].Journal ofCrystal Growth,2010,312:3544-3548.
[29]张相法,张奎.粗粒度立方氮化硼的合成方法[P].CN:101062766A,2007-10-31.Zhang X F,Zhang K.Synthesis Method of Big Cubic Boron Nitride Crystal[P].CN:101062766A,2007-10-31.
[30]吉晓瑞,杨大鹏,杨晓红,等.hBN-LiH/hBN-Li3N-B体系合成cBN的赋色过程研究[J].高压物理学报,2010,24(3):231-236.Ji X R,Yang D P,Yang X H,et al.The Coloration Process Study on the Synthesis of cBN by hBN-LiH/hBN-Li3N-B System[J].ChineseJournal of high Pressure Physics,2010,24(3):231-236.
[31]Takashi Taniguchi,Shinobu Yamaoka.Spontaneous Nucleation of Cubic Boron Nitride Single Crystal by Temperature Gradient Method under HighPressure[J].Journal of Crystal Growth,2001,222:549-557.
[32]Fukunaga O,Takeuchi S,Taniguchi T.High-pressure Synthesis of Cubic BN Using Fe-Mo-Al and Co-Mo-Al Alloy Solvents[J].Diamond andRelated Materials,2011,20:752-755.