降低氰酸酯树脂热膨胀系数的研究进展
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摘要
综述了国内外关于降低氰酸酯(CE)树脂热膨胀系数的两大类主要方法:改善分子结构和加入低热膨胀系数添加物。而后者按添加物的种类进一步分为:纳米粒子填充改性、负热膨胀系数材料改性、空心玻璃微珠填充改性、石墨烯填充改性以及液晶环氧树脂改性等。对未来降低氰酸酯树脂热膨胀系数的发展方向进行了展望。
Main methods of decreasing the thermal expansion coefficient of cyanate ester( CE) resin at home and abroad were summarized,including the research on molecular structure and the addition of the additives with low thermal expansion coefficient. According to the types of additives, the latter could be divided into the following categories: nano-particles filling modification, materials with negative thermal expansion coefficient filling modification, hollow glass bead filling modification, graphene filling modification,liquid crystalline epoxy resin modification and so on. The future development trend of lowing the thermal expansion coefficient of cyanate ester resin was prospected.
Main methods of decreasing the thermal expansion coefficient of cyanate ester( CE) resin at home and abroad were summarized,including the research on molecular structure and the addition of the additives with low thermal expansion coefficient. According to the types of additives, the latter could be divided into the following categories: nano-particles filling modification, materials with negative thermal expansion coefficient filling modification, hollow glass bead filling modification, graphene filling modification,liquid crystalline epoxy resin modification and so on. The future development trend of lowing the thermal expansion coefficient of cyanate ester resin was prospected.
引文
[1]HAMERTON I,HAY J N.Recent developments in the chemistry ofcyanate esters[J].Polym Int,1998,47(4):465-473.
[2]HAMERTON I.Chemistry and technology of cyanate ester resins[M].Netherlands:Springer,1994:1-9.
[3]戴善凯,顾嫒娟,梁国正,等.氰酸酯树脂的固化催化研究新进展[J].材料导报,2009,23(9):57-60.
[4]江磊,沈烈,郑强.聚合物的热膨胀[J].功能材料,2004,35(2):142-144.
[5]江建第,张昆,刘重阳,等.脂肪族聚酰胺热膨胀行为的研究[J].高分子学报,2013(2):255-262.
[6]张毅.环氧填充取向碳纳米管束杂化微胶囊及其氰酸酯复合材料的研究[D].苏州:苏州大学,2016.
[7]刘伟帅,王建,苗瑞珍,等.TGDDM/DDS交联环氧树脂的分子动力学模拟[J].高分子材料科学与工程,2016(5):109-114.
[8]王汝敏,陈立新,张双存,等.双酚A二氰酸酯的固化与催化研究[J].塑料工业,2004,32(12):5-7.
[9]程邦仁.氰酸酯树脂的结构、固化与改性研究[D].西安:西北工业大学,2004.
[10]王君龙.纳米二氧化硅粒子改性氰酸酯树脂的研究[D].西安:西北工业大学,2007.
[11]马万翔,王薇薇,何其慧,等.E-51环氧树脂改性双酚A型氰酸酯树脂的研究[J].热固性树脂,2011(1):6-10.
[12]牛磊,朱光明,王坤.氰酸酯树脂增韧改性研究进展[J].中国胶粘剂,2011(11):49-53.
[13]吴金剑,谢佳武,王志娟,等.F-48环氧树脂改性双酚A型氰酸酯树脂的研究[J].材料导报,2014,28(14):91-94.
[14]李俊燕,陈平.可溶性PPESK/氰酸酯树脂体系的制备与性能[J].高分子材料科学与工程,2013(2):149-151.
[15]马鹏常,刘敬峰,范卫锋,等.长链双马来酰亚胺改性氰酸酯树脂及其复合材料[J].高等学校化学学报,2013,34(8):1979-1984.
[16]段秀红,姚海波,郭海泉.刚性聚酰亚胺的分子堆积和热膨胀性能研究[J].计算机与应用化学,2015,32(8):917-920.
[17]张小华,徐伟箭.无机纳米粒子在环氧树脂增韧改性中的应用[J].高分子通报,2005(6):100-104.
[18]GOERTZEN W K,KESSLER M R.Thermal expansion of fumed silica/cyanate ester nanocomposites[J].J Appl Polym Sci,2008,109(1):647-653.
[19]张雪霞.纳米Ti O2改性氰酸酯复合材料及其抗真空电子辐照研究[D].哈尔滨:哈尔滨工业大学,2010.
[20]LUNA-XAVIER J L,GUYOT A,BOURGEAT-LAMI E.Synthesis and characterization of silica/poly(methyl methacrylate)nanocomposite latex particles through emulsion polymerization using a cationic azo initiator[J].J Colloid Interf Sci,2002,250(1):82-92.
[21]HUANG C J,FU S Y,ZHANG Y H,et al.Cryogenic properties of Si O2/epoxy nanocomposites[J].Cryogenics,2005,45(6):450-454.
[22]杨志伟.负热膨胀材料及其环氧复合材料的制备与性能[D].邯郸:河北工程大学,2012.
[23]EVANS J S O,MARY T A,VOGT T,et al.Negative Thermal Expansion in Zr W2O8and Hf W2O8[J].Chem Mater,2016,8(12):2809-2823.
[24]GOERTZEN W K,KESSLER M R.Three-phase cyanate ester composites with fumed silica and negative-CTE reinforcements[J].J Therm Anal Calorim,2008,93(1):87-93.
[25]BADRINARAYANAN P,ROGALSKI M K,KESSLER M R.Carbon fiber-reinforced cyanate ester/nano-Zr W2O8composites with tailored thermal expansion[J].Acs Appl Mater Interfaces,2011,4(2):510-517.
[26]CHANG L L Y,SCROGER M G,PHILLIPS B.Condensed phase relations in the systems Zr O2-WO2-WO3and Hf O2-WO2-WO3[J].J Am Ceramic Soc,2006,50(4):211-215.
[27]刘杰.氰酸酯树脂基新型人工介质材料的研究[D].苏州:苏州大学,2009.
[28]YOON D,SON Y W,CHEONG H.Negative thermal expansion coefficient of graphene measured by Raman spectroscopy[J].Nano Lett,2011,11(8):3227-3231.
[29]NOVOSELOV K S,JIANG D,SCHEDIN F,et al.Twodimensional atomic crystals[J].Proc Nat Acad Sci USA,2005,102(30):10451.
[30]孙再强.石墨烯改性氰酸酯基复合材料及其抗电子质子辐照研究[D].哈尔滨:哈尔滨工业大学,2015.
[31]潘阳阳.碳纤维增强石墨烯-Ti O2/氰酸酯复合材料及抗电子辐照研究[D].哈尔滨:哈尔滨工业大学,2013.
[32]张晓彦.高性能液晶环氧树脂改性热固性树脂的研究[D].苏州:苏州大学,2011.
[33]YU Y,GAN W,LIU X,et al.Liquid crystalline epoxy resin modified cyanate ester/epoxy resin systems[J].J Appl Polym Sci,2008,109(5):2964-2972.
[34]JAHROMI S,KUIPERS W A G,NORDER B,et al.Liquid crystalline epoxide thermosets.Dynamic mechanical and thermal properties[J].Macromolecules,2002,28(7):2201-2211.
[2]HAMERTON I.Chemistry and technology of cyanate ester resins[M].Netherlands:Springer,1994:1-9.
[3]戴善凯,顾嫒娟,梁国正,等.氰酸酯树脂的固化催化研究新进展[J].材料导报,2009,23(9):57-60.
[4]江磊,沈烈,郑强.聚合物的热膨胀[J].功能材料,2004,35(2):142-144.
[5]江建第,张昆,刘重阳,等.脂肪族聚酰胺热膨胀行为的研究[J].高分子学报,2013(2):255-262.
[6]张毅.环氧填充取向碳纳米管束杂化微胶囊及其氰酸酯复合材料的研究[D].苏州:苏州大学,2016.
[7]刘伟帅,王建,苗瑞珍,等.TGDDM/DDS交联环氧树脂的分子动力学模拟[J].高分子材料科学与工程,2016(5):109-114.
[8]王汝敏,陈立新,张双存,等.双酚A二氰酸酯的固化与催化研究[J].塑料工业,2004,32(12):5-7.
[9]程邦仁.氰酸酯树脂的结构、固化与改性研究[D].西安:西北工业大学,2004.
[10]王君龙.纳米二氧化硅粒子改性氰酸酯树脂的研究[D].西安:西北工业大学,2007.
[11]马万翔,王薇薇,何其慧,等.E-51环氧树脂改性双酚A型氰酸酯树脂的研究[J].热固性树脂,2011(1):6-10.
[12]牛磊,朱光明,王坤.氰酸酯树脂增韧改性研究进展[J].中国胶粘剂,2011(11):49-53.
[13]吴金剑,谢佳武,王志娟,等.F-48环氧树脂改性双酚A型氰酸酯树脂的研究[J].材料导报,2014,28(14):91-94.
[14]李俊燕,陈平.可溶性PPESK/氰酸酯树脂体系的制备与性能[J].高分子材料科学与工程,2013(2):149-151.
[15]马鹏常,刘敬峰,范卫锋,等.长链双马来酰亚胺改性氰酸酯树脂及其复合材料[J].高等学校化学学报,2013,34(8):1979-1984.
[16]段秀红,姚海波,郭海泉.刚性聚酰亚胺的分子堆积和热膨胀性能研究[J].计算机与应用化学,2015,32(8):917-920.
[17]张小华,徐伟箭.无机纳米粒子在环氧树脂增韧改性中的应用[J].高分子通报,2005(6):100-104.
[18]GOERTZEN W K,KESSLER M R.Thermal expansion of fumed silica/cyanate ester nanocomposites[J].J Appl Polym Sci,2008,109(1):647-653.
[19]张雪霞.纳米Ti O2改性氰酸酯复合材料及其抗真空电子辐照研究[D].哈尔滨:哈尔滨工业大学,2010.
[20]LUNA-XAVIER J L,GUYOT A,BOURGEAT-LAMI E.Synthesis and characterization of silica/poly(methyl methacrylate)nanocomposite latex particles through emulsion polymerization using a cationic azo initiator[J].J Colloid Interf Sci,2002,250(1):82-92.
[21]HUANG C J,FU S Y,ZHANG Y H,et al.Cryogenic properties of Si O2/epoxy nanocomposites[J].Cryogenics,2005,45(6):450-454.
[22]杨志伟.负热膨胀材料及其环氧复合材料的制备与性能[D].邯郸:河北工程大学,2012.
[23]EVANS J S O,MARY T A,VOGT T,et al.Negative Thermal Expansion in Zr W2O8and Hf W2O8[J].Chem Mater,2016,8(12):2809-2823.
[24]GOERTZEN W K,KESSLER M R.Three-phase cyanate ester composites with fumed silica and negative-CTE reinforcements[J].J Therm Anal Calorim,2008,93(1):87-93.
[25]BADRINARAYANAN P,ROGALSKI M K,KESSLER M R.Carbon fiber-reinforced cyanate ester/nano-Zr W2O8composites with tailored thermal expansion[J].Acs Appl Mater Interfaces,2011,4(2):510-517.
[26]CHANG L L Y,SCROGER M G,PHILLIPS B.Condensed phase relations in the systems Zr O2-WO2-WO3and Hf O2-WO2-WO3[J].J Am Ceramic Soc,2006,50(4):211-215.
[27]刘杰.氰酸酯树脂基新型人工介质材料的研究[D].苏州:苏州大学,2009.
[28]YOON D,SON Y W,CHEONG H.Negative thermal expansion coefficient of graphene measured by Raman spectroscopy[J].Nano Lett,2011,11(8):3227-3231.
[29]NOVOSELOV K S,JIANG D,SCHEDIN F,et al.Twodimensional atomic crystals[J].Proc Nat Acad Sci USA,2005,102(30):10451.
[30]孙再强.石墨烯改性氰酸酯基复合材料及其抗电子质子辐照研究[D].哈尔滨:哈尔滨工业大学,2015.
[31]潘阳阳.碳纤维增强石墨烯-Ti O2/氰酸酯复合材料及抗电子辐照研究[D].哈尔滨:哈尔滨工业大学,2013.
[32]张晓彦.高性能液晶环氧树脂改性热固性树脂的研究[D].苏州:苏州大学,2011.
[33]YU Y,GAN W,LIU X,et al.Liquid crystalline epoxy resin modified cyanate ester/epoxy resin systems[J].J Appl Polym Sci,2008,109(5):2964-2972.
[34]JAHROMI S,KUIPERS W A G,NORDER B,et al.Liquid crystalline epoxide thermosets.Dynamic mechanical and thermal properties[J].Macromolecules,2002,28(7):2201-2211.