复合高分子絮凝剂的研究与应用进展
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摘要
复合高分子絮凝剂既克服了单一絮凝剂吸附效果差、不易降解等缺点,又实现了不同成分在性能上的互补,在水处理领域发挥着越来越重要的作用。本文对复合高分子絮凝剂进行了分类概述,综述了无机-无机复合高分子絮凝剂、无机-有机复合高分子絮凝剂、微生物复合絮凝剂等复合高分子絮凝剂的研究进展,并对未来复合高分子絮凝剂的发展趋势进行了展望。
Compound polymer flocculant is playing an increasingly important role in water treatment field as it not only overcomes the defects of poor adsorption of single flocculant and difficult degradation,etc.,but also realizes complementarity in property of different components.This paper classifies and summarizes compound polymer flocculant and overviews the research progress of such compound polymer flocculants as inorganic-inorganic compound polymer flocculant,inorganic-organic compound polymer flocculant and microbial compound flocculant and looks into the prospect for future development trend of compound polymer flocculant.
Compound polymer flocculant is playing an increasingly important role in water treatment field as it not only overcomes the defects of poor adsorption of single flocculant and difficult degradation,etc.,but also realizes complementarity in property of different components.This paper classifies and summarizes compound polymer flocculant and overviews the research progress of such compound polymer flocculants as inorganic-inorganic compound polymer flocculant,inorganic-organic compound polymer flocculant and microbial compound flocculant and looks into the prospect for future development trend of compound polymer flocculant.
引文
[1]王宝玉,岳钦艳,王燕,等.复合高分子絮凝剂[M].北京:化学工业出版社.2016.
[2]姚彬,张文存,张玉荣,朱瑞龙.无机-有机高分子复合絮凝剂的研究进展[J].石化技术与应用,2018,36(5):347-352.
[3]刘志远,李昱辰,王鹤立,居玉坤.复合絮凝剂的研究进展及应用[J].工业水处理,2011,31(5):5-8.
[4]唐晓东,邓杰义,李晶晶,等.复合高分子絮凝剂的制备及研究进展[J].工业水处理,2015,35(2):1-5.
[5]Liu Z,Duan X,Zhan P,et al.Coagulation performance and microstructural morphology of a novel magnetic composite coagulant for pre-treating landfill leachate[J].International Journal of Environmental Science and Technology, 2017, 14(11):2507-2518.
[6]刘睿,白红娟,程芳琴,杜志平.复合絮凝剂对焦化废水中苯酚强化混凝去除性能研究[J].无机盐工业,2018,50(5):63-67.
[7]常鼎伟,任壮,武文洁.PATS的制备表征及其处理低浊水效能与残留铝控制[J].环境工程学报,2017,11(8):4615-4620.
[8]Liu L,Wu C,Chen Y,et al.Preparation,characterization and coagulation behaviour of polyferric magnesium silicate(PFMSi)coagulant[J].Water Science and Technology,2017,75(8):1961-1970.
[9]孙树青,孙丰凯,梁爽,徐晓丽.一种无机复合絮凝剂的制备及其对染料废水的处理[J].山东大学学报(工学版),2018,48(2):128-133.
[10]Li J,Liu X,et al.Effect of silicon content on preparation and coagulation performance of poly-silicic-metal coagulants derived from coal gangue for coking wastewater treatment[J].Separation and Purification Technology,2018(202):149-156.
[11]Wang R M,Wang Y,He Y F,et al.Preparation of solid composite polyferric sulfate and its flocculation behavior for wastewater containing high concentration organic compounds[J]. Water Science and Technology, 2010, 61(11):2749-2757.
[12]李晓旭,段冲.有机高分子絮凝剂在处理炼油废水中的应用[J].当代化工研究,2018,(4):30-31.
[13]Xu K,Liu Y,Wang Y,et al.A novel wastewater treating material:cationic poly acrylamide/diatomite composite flocculant[J].Journal of Polymers and the Environment,2018:1-9.
[14]Quan X,Wang H.Preparation of a novel coal gangue-polyacrylamide hybrid flocculant and its flocculation performance[J].Chinese Journal of Chemical Engineering,2014,22(9):1055-1060.
[15]夏雄,刘威,许霞,邓妍.PSAF-CPAM高分子无机-有机复合絮凝剂表征及其对印染废水除磷效果分析[J].工业安全与环保,2018,44(3):82-85.
[16]Zou J,Zhu H,Wang F,et al.Preparation of a new inorganicorganic composite flocculant used in solid-liquid separation for waste drilling fluid[J].Chemical Engineering Journal,2011,171(1):350-356.
[17]Wang X,Jiang S,Tan S,et al.Preparation and coagulation performance of hybrid coagulant polyacrylamide-polymeric aluminum ferric chloride[J].Journal of Applied Polymer Science,2018,135(23):46355.
[18]王友,陈彩花.铁铝基淀粉复合絮凝剂的制备及性能研究[J].广州化工,2015,43(23):143-144,178.
[19]Wei H,Ren J,Li A,et al.Sludge dewaterability of a starchbased flocculant and its combined usage with ferric chloride[J].Chemical Engineering Journal,2018,349(5):737-747.
[20]Lin Q,Peng H,Zhong S,et al.Synthesis,characterization,and secondary sludge dewatering performance of a novel combined silicon-aluminum-iron-starch flocculant[J].Journal of Hazardous Materials,2015(285):199-206.
[21]周云,刘英,张志强,夏四清.微生物絮凝剂制备的研究新进展[J].环境污染与防治,2014,36(4):80-85,91.
[22]Huang J,Yang Z H,Zeng G M,et al.Influence of composite flocculant of PAC and MBFGA1on residual aluminum species distribution[J].Chemical Engineering Journal,2012(191):269-277.
[23]Xia X,Lan S,Li X,et al.Characterization and coagulationflocculation performance of a composite flocculant in high-turbidity drinking water treatment[J].Chemosphere,2018(206):701-708.
[2]姚彬,张文存,张玉荣,朱瑞龙.无机-有机高分子复合絮凝剂的研究进展[J].石化技术与应用,2018,36(5):347-352.
[3]刘志远,李昱辰,王鹤立,居玉坤.复合絮凝剂的研究进展及应用[J].工业水处理,2011,31(5):5-8.
[4]唐晓东,邓杰义,李晶晶,等.复合高分子絮凝剂的制备及研究进展[J].工业水处理,2015,35(2):1-5.
[5]Liu Z,Duan X,Zhan P,et al.Coagulation performance and microstructural morphology of a novel magnetic composite coagulant for pre-treating landfill leachate[J].International Journal of Environmental Science and Technology, 2017, 14(11):2507-2518.
[6]刘睿,白红娟,程芳琴,杜志平.复合絮凝剂对焦化废水中苯酚强化混凝去除性能研究[J].无机盐工业,2018,50(5):63-67.
[7]常鼎伟,任壮,武文洁.PATS的制备表征及其处理低浊水效能与残留铝控制[J].环境工程学报,2017,11(8):4615-4620.
[8]Liu L,Wu C,Chen Y,et al.Preparation,characterization and coagulation behaviour of polyferric magnesium silicate(PFMSi)coagulant[J].Water Science and Technology,2017,75(8):1961-1970.
[9]孙树青,孙丰凯,梁爽,徐晓丽.一种无机复合絮凝剂的制备及其对染料废水的处理[J].山东大学学报(工学版),2018,48(2):128-133.
[10]Li J,Liu X,et al.Effect of silicon content on preparation and coagulation performance of poly-silicic-metal coagulants derived from coal gangue for coking wastewater treatment[J].Separation and Purification Technology,2018(202):149-156.
[11]Wang R M,Wang Y,He Y F,et al.Preparation of solid composite polyferric sulfate and its flocculation behavior for wastewater containing high concentration organic compounds[J]. Water Science and Technology, 2010, 61(11):2749-2757.
[12]李晓旭,段冲.有机高分子絮凝剂在处理炼油废水中的应用[J].当代化工研究,2018,(4):30-31.
[13]Xu K,Liu Y,Wang Y,et al.A novel wastewater treating material:cationic poly acrylamide/diatomite composite flocculant[J].Journal of Polymers and the Environment,2018:1-9.
[14]Quan X,Wang H.Preparation of a novel coal gangue-polyacrylamide hybrid flocculant and its flocculation performance[J].Chinese Journal of Chemical Engineering,2014,22(9):1055-1060.
[15]夏雄,刘威,许霞,邓妍.PSAF-CPAM高分子无机-有机复合絮凝剂表征及其对印染废水除磷效果分析[J].工业安全与环保,2018,44(3):82-85.
[16]Zou J,Zhu H,Wang F,et al.Preparation of a new inorganicorganic composite flocculant used in solid-liquid separation for waste drilling fluid[J].Chemical Engineering Journal,2011,171(1):350-356.
[17]Wang X,Jiang S,Tan S,et al.Preparation and coagulation performance of hybrid coagulant polyacrylamide-polymeric aluminum ferric chloride[J].Journal of Applied Polymer Science,2018,135(23):46355.
[18]王友,陈彩花.铁铝基淀粉复合絮凝剂的制备及性能研究[J].广州化工,2015,43(23):143-144,178.
[19]Wei H,Ren J,Li A,et al.Sludge dewaterability of a starchbased flocculant and its combined usage with ferric chloride[J].Chemical Engineering Journal,2018,349(5):737-747.
[20]Lin Q,Peng H,Zhong S,et al.Synthesis,characterization,and secondary sludge dewatering performance of a novel combined silicon-aluminum-iron-starch flocculant[J].Journal of Hazardous Materials,2015(285):199-206.
[21]周云,刘英,张志强,夏四清.微生物絮凝剂制备的研究新进展[J].环境污染与防治,2014,36(4):80-85,91.
[22]Huang J,Yang Z H,Zeng G M,et al.Influence of composite flocculant of PAC and MBFGA1on residual aluminum species distribution[J].Chemical Engineering Journal,2012(191):269-277.
[23]Xia X,Lan S,Li X,et al.Characterization and coagulationflocculation performance of a composite flocculant in high-turbidity drinking water treatment[J].Chemosphere,2018(206):701-708.