锂离子电池三元正极材料的研究进展
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摘要
随着不可再生能源储量的减少及环保政策的加强,传统能源受到了一定的影响,新能源受到了世界各国的重视。锂离子作为新能源领域中的一种,具有电池能量密度高、工作电压高、循环寿命长、无记忆效应、绿色环保等优点,引起了广大科研人员的关注。目前,影响锂离子电池性能的关键是正极材料,因此对三元正极材料镍钴锰研究进展做了综述,讨论了三元正极材料的不同制备方法及改性包覆方法,并对三元正极材料目前存在的问题及未来的发展方向做了探讨。
With the reduction of non-renewable energy reserves and the reinforcement of environmental protection policies,traditional energy has been affected and the new energy has attracted the attentions of all countries in the world.Lithium ion battery as one of the new energy fields,has caught the attentions of researchers due to its advantages,such as high energy density,high working voltage,long cycle life,no memory effect and pollution-free etc..At present,the key to improve performance of lithium ion battery is the cathode electrode material.The research progress of ternary cathode material of nickel,cobalt and manganese was reviewed.The different preparation and modification methods of ternary materials were also discussed.Finally,present problems and future development direction of ternary materials were pointed out.
With the reduction of non-renewable energy reserves and the reinforcement of environmental protection policies,traditional energy has been affected and the new energy has attracted the attentions of all countries in the world.Lithium ion battery as one of the new energy fields,has caught the attentions of researchers due to its advantages,such as high energy density,high working voltage,long cycle life,no memory effect and pollution-free etc..At present,the key to improve performance of lithium ion battery is the cathode electrode material.The research progress of ternary cathode material of nickel,cobalt and manganese was reviewed.The different preparation and modification methods of ternary materials were also discussed.Finally,present problems and future development direction of ternary materials were pointed out.
引文
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[22]国海鹏,贾梦秋,廖煜炤,等.锂离子电池正极材料Li Ni1/2Co1/6Mn1/3O2的制备与性能[J].过程工程学报,2008,8(4):808-813.
[23]杨祖光,滑纬博,张军,等.锆掺杂以提升Li Ni0.5Co0.2Mn0.3O2正极材料的高温电化学性能[J].物理化学学报,2016,32(5):1056-1061.
[24]Wolff-Goodrich S,Lin F,Markus I M,et al.Tailoring the surface properties of Li Ni0.4Mn0.4Co0.2O2by titanium substitution for improved high voltage cycling performance[J].Physical Chemistry Chemical Physics,2015,17(34):21778-21781.
[25]Lee Y J,Choi H Y,Ha C W,et al.Cycle life modeling and the capacity fading mechanisms in a graphite/Li Ni0.6Co0.2Mn0.2O2cell[J].Journal of Applied Electrochemistry,2015,45(5):419-426.
[26]Xiong X H,Ding D,Wang Z X,et al.Surface modification of Li Ni0.8Co0.1Mn0.1O2with conducting polypyrrole[J].Journal of Solid State Electrochemistry.2014,18(9):2619-2624.
[27]Li J,Petibon R,Glazier S,et al.In-situ neutron diffraction study of a high voltage Li(Ni0.42Mn0.42Co0.16)O2/graphite pouch cell[J].Electrochimica Acta,2015,180(3):234-240.
[2]陈鹏,肖冠,廖世军.具有不同组成的镍钴锰三元材料的最新研究进展[J].化工进展,2016,35(1):166-174.
[3]孙玉城.镍钴锰酸锂三元正极材料的研究与应用[J].无机盐工业,2014,46(1):1-3.
[4]郭红霞,乔月纯,穆培振.锂离子电池正极材料研究与应用进展[J].无机盐工业,2016,48(3):5-8.
[5]俞会根,王恒,盛军.三元正极材料Li[Ni-Co-Mn]O2的研究进展[J].电源技术,2014,38(9):1749-1752.
[6]Longo R C,Kong F T,Liang C P,et al.Transition metal ordering optimization for high-reversible capacity positive electrode materials in the Li-Ni-Co-Mn pseudoquaternary system[J].The Journal of Physical Chemistry C,2016,120(16):8540-8549.
[7]He Y S,Ma Z F,Liao X Z,et al.Synthesis and characterization of submicron-sized Li Ni1/3Co1/3Mn1/3O2by a simple self-propagating solldstate metathesis method[J].Journal of Power Sources,2007,163:1053-1058.
[8]Hu C Y,Guo J,Du Y,et al.Effects of synthesis conditions on layered Li[Ni1/3Co1/3Mn1/3]O2positive-electrode via hydroxide co-precipitation method for lithium-ion batteries[J].Transactions of Nonferrous Metals Society of China,2011,21(1):114-120.
[9]Zhang S,Deng C,Fu B L,et al.Synthetic optimization of spherical Li[Ni1/3Mn1/3Co1/3]O2prepared by a carbonate co-precipitation method[J].Powder Technology,2010,198:373-380.
[10]Kuthanapillil M S,Bruce P G.Macroporous Li(Ni1/3Co1/3Mn1/3)O2:A highpower and high-energy cathode for rechargeable lithium batteries[J].Advanced Materials,2006,18(17):2330-2334.
[11]Kong J Z,Zhai H F,Ren C,et al.Synthesis and electrochemical performance of macroporous Li Ni0.5Co0.2Mn0.3O2by a modified solgel method[J].Journal of Alloys and Compounds,2013,577:507-510.
[12]Oljaca M,Blizanac B,Pasquier A D,et al.Novel Li Ni1/3Co1/3Mn1/3O2cathode morphologies for high power Li-ion batteries[J].Journal of Power Sources,2014,248(15):729-738.
[13]Lee K S,Myung S T,Prakash J,et al.Optimizationg of microwave synthesis of Li[Ni0.4Co0.2Mn0.4]O2as a positive electrode material for lithium batteries[J].Electrochimica Acta,2008,53(7):3065-3074.
[14]Zhang H L,Liu S X.Synthesis and characterization of Li Ni1/3Co1/3Mn1/3O2-xClxas cathode materials for lithium ion batteries at 55℃[J].Advances in Materials Science and Engineering,2013,5:1-6.
[15]Fu C Y,Zhou Z L,Liu Y H,et al.Synthesis and electrochemical properties of Mg-doped Li Ni0.6Co0.2Mn0.2O2cathode materials for Li-ion battery[J].Journal of Wuhan University of Technology:Materials Science Edition,2011,26(2):211-215.
[16]Araki K,Taguchi N,Sakaebe H K,et al.Electrochemical properties of Li Ni1/3Co1/3Mn1/3O2cathode material modified by coating with Al2O3nanoparticles[J].Journal of Power sources,2014,269:236-243.
[17]Hsieh C T,Hsu H H,Mo C Y,et al.Medium-frequency induction sintering of lithium nickel cobalt manganese oxide cathode materials for lithium ion batteries[J].Solid State Ionics,2015,270:39-46.
[18]Yoo G W,Jang B C,Son J T.Novel design of core shell structure by NCA modification on NCM cathode material to enhance capacity and cycle life for lithium secondary battery[J].Ceramics International,2015,41(1):1913-1916.
[19]Sun Y K,Kim D H,Jung H G,et al.High-voltage performance of concentration-gradient Li[Ni0.67Co0.15Mn0.18]O2cathode material for lithium-ion batteries[J].Electrochimica Acta,2010,55(28):8621-8627.
[20]Sun Y K,Chen Z,Noh H J,et al.Nanostructured high-energy cathode materials for advanced lithium batteries[J].Nature Materials,2012,11(11):942-947.
[21]Xiong W,Jiang Y,Yang Z,et al.High-performance hierarchical Li Ni1/3Co1/3Mn1/3O2microspheres synthesized via a facile templatesacrificial route[J].Journal of Alloys and Compounds,2014,589:615-621.
[22]国海鹏,贾梦秋,廖煜炤,等.锂离子电池正极材料Li Ni1/2Co1/6Mn1/3O2的制备与性能[J].过程工程学报,2008,8(4):808-813.
[23]杨祖光,滑纬博,张军,等.锆掺杂以提升Li Ni0.5Co0.2Mn0.3O2正极材料的高温电化学性能[J].物理化学学报,2016,32(5):1056-1061.
[24]Wolff-Goodrich S,Lin F,Markus I M,et al.Tailoring the surface properties of Li Ni0.4Mn0.4Co0.2O2by titanium substitution for improved high voltage cycling performance[J].Physical Chemistry Chemical Physics,2015,17(34):21778-21781.
[25]Lee Y J,Choi H Y,Ha C W,et al.Cycle life modeling and the capacity fading mechanisms in a graphite/Li Ni0.6Co0.2Mn0.2O2cell[J].Journal of Applied Electrochemistry,2015,45(5):419-426.
[26]Xiong X H,Ding D,Wang Z X,et al.Surface modification of Li Ni0.8Co0.1Mn0.1O2with conducting polypyrrole[J].Journal of Solid State Electrochemistry.2014,18(9):2619-2624.
[27]Li J,Petibon R,Glazier S,et al.In-situ neutron diffraction study of a high voltage Li(Ni0.42Mn0.42Co0.16)O2/graphite pouch cell[J].Electrochimica Acta,2015,180(3):234-240.