喷气燃料热氧化安定性的研究综述
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摘要
喷气燃料是一种十分重要的燃料,不仅为飞机飞行提供动力,而且对燃油系统部件的润滑和冷却也収挥着重要作用。热氧化安定性是喷气燃料最重要的性能指标之一,提高热氧化安定性是喷气燃料使用过程中面临的重大技术难题之一。文章综述了喷气燃料的结构/组成、氧化安定性的评定方法和原理以及改善措施的研究现状,提出为提高喷气燃料热的氧化安定性应加强热氧化衰变过程的特征分析和抗氧剂作用机理的研究。
Jet fuel is a very important fuel as the power source of jet engine and also is the coolant of lubricating system and internal combustion system.Thermal oxidation stability is one of the major technical problems in the use of jet fuel.Therefore,thermal oxidation stability is one of the important performance indexes of jet fuel.In this paper,the composition of jet fuel,evaluation method and principle of oxidation stability and improvement measures were reviewed.It's suggested that the characteristics of thermal oxidation and the mechanism of antioxidant action should be studied in the future.
Jet fuel is a very important fuel as the power source of jet engine and also is the coolant of lubricating system and internal combustion system.Thermal oxidation stability is one of the major technical problems in the use of jet fuel.Therefore,thermal oxidation stability is one of the important performance indexes of jet fuel.In this paper,the composition of jet fuel,evaluation method and principle of oxidation stability and improvement measures were reviewed.It's suggested that the characteristics of thermal oxidation and the mechanism of antioxidant action should be studied in the future.
引文
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[33]Judit Z,Klippenstein S,Miller J.Pressure-Dependent OH Yields in Alkene+HO2 Reactions:A Theoretical Study[J].The Journal of Physical Chemistry A,2011,115(36):10218-10225.
[34]Miyoshi A.Systematic Computational Study on the Unimolecular Reactions of Alkylperoxy(RO2),Hydroperoxyalkyl(QOOH),and Hydroperoxyalkylperoxy(O2QOOH)Radicals[J].The Journal of Physical Chemistry A,2011,115(15):3301-3325.
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[37]Jalan A,Alecu M,Meana R,et al.New Pathways for Formation of Acids and Carbonyl Products in Low-Temperature Oxidation:The Korcek Decomposition ofγ-Ketohydroperoxides[J].Journal of the American Chemical Society,2013,135(30):11100-11114.
[38]Katta V,Jones E,Roquemore W.Modeling of Deposition Process in Liquid Fuels[J].Combustion Scienceand Technology,1998,139(1):75-111.
[39]Bugler J,Rodriguez A,et al.An experimental and modelling study of n-pentane oxidation in two jet-stirred reactors:The importance of pressure-dependent kinetics and new reaction pathways[J].Proceedings of the Combustion Institute,2017,36(1):441-448.
[40]Ranzi E,Cavallotti C,Cuoci A,et al.New reaction classes in the kinetic modeling of low temperature oxidation of n-alkanes[J].Combustion and Flame,2015,162(5):1679-1691.
[41]Marin-Flores O,Turba T,Breit J,et al.Thermodynamic and experimental study of the partial oxidation of a Jet A fuel surrogate over molybdenum dioxide[J].Applied Catalysis A:General,2010,381(1-2):18-25.
[42]Rawson P,Stansfield C,Creek J,et al.Suitability of a radical based method for assessment of jet fuel antioxidant capacity and projected storage stability[J].Fuel,2017,199:497-503.
[43]韦献雅,殷丼琴,钟成,等.DPPH法评价抗氧化活性研究迚展[J].食品科学,2014(09):317-322.
[44]蔺建民,张永光,李率.生物柴油调合燃料氧化安定性标准测试方法的现状和趋势[J].生物质化学工程,2008(02):33-40.
[45]Liu X,Zhan J,Lai D,et al.Initial Pyrolysis Mechanism of Oil Shale Kerogen with Reactive Molecular Dynamics Simulation[J].Energy&Fuels,2015,29(5):2987-2997.
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