硝胺类复合固体推进剂用键合剂的研究进展
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摘要
总结了提高硝胺类复合固体推进剂力学性能的方法,认为键合剂的使用是提高推进剂力学性能经济、高效、便捷的技术途径,分析了键合剂的作用机理及其功能特点,综述了硝胺类复合固体推进剂用键合剂的种类及其研究进展,认为多功能聚合物键合剂("一剂多能")是键合剂的一个发展方向,应根据硝胺填料表面特性及不同粘合剂结构特点,通过分子设计,制备出适用于不同粘合剂-硝胺体系推进剂的通用键合剂,针对通用键合剂的设计提出了几点建议。
This review article summarizes the methods for improving mechanical properties of nitramine-based composite solid propellants. It has been considered that the use of bonding agents is an economic,effective and convenient way to enhance the mechanical properties of the solid propellants. The bonding mechanism and characteristics of bonding agents are analyzed. The overview on the types and development of bonding agents for composite solid propellants containing nitramine has been presented as well. It has been shown that the multifunctional polymer bonding agent is a research direction of bonding agents. According to the surface characteristics of nitramine fillers and the structure characteristics of different adhesive,a universal bonding agent suitable for different adhesive-nitramine systems should be prepared by molecular design. Some suggestions are put forward for the design of universal bonding agents.
This review article summarizes the methods for improving mechanical properties of nitramine-based composite solid propellants. It has been considered that the use of bonding agents is an economic,effective and convenient way to enhance the mechanical properties of the solid propellants. The bonding mechanism and characteristics of bonding agents are analyzed. The overview on the types and development of bonding agents for composite solid propellants containing nitramine has been presented as well. It has been shown that the multifunctional polymer bonding agent is a research direction of bonding agents. According to the surface characteristics of nitramine fillers and the structure characteristics of different adhesive,a universal bonding agent suitable for different adhesive-nitramine systems should be prepared by molecular design. Some suggestions are put forward for the design of universal bonding agents.
引文
[1]Chen Y,Liu Y,Shi L,et al.Study on the synthesis and interfacial interaction performance of novel dodecylamine-based bonding agents used of composite solid propellants[J].Propellants,Explosives,Pyrotechnics,2015,40(1):50-59.
[2]Oliveira J I S,Pires D C,Diniz M F,et al.Determination of primary amine content in bonding agent used in composite solid propellants[J].Propellants,Explosives,Pyrotechnics,2014,39(4):538-544.
[3]Zenin A A,Finjakov S V,Puchkov V M,et al.Temperature and pressure sensitivities of burning wave parameters of nitramine-containing propellants and HMX[J].Journal of Propulsion&Power,2015,15(6):753-758.
[4]Duterque J,Lengelle G.Combustion mechanisms of nitramine-based propellants with additives[J].Journal of Propulsion&Power,2015,6(6):718-726.
[5]Naya T,Kohga M.Thermal decomposition behaviors and burning characteristics of AN/nitramine-based composite propellant[J].Journal of Energetic Materials,2015,33(2):73-90.
[6]姚莹莹,张教强.硝胺推进剂用聚合物键合剂的研究进展[J].中国胶黏剂,2009,18(5):56-59.
[7]Oberth A E,Bruenner R S.Polyurethane-based propellants[M]//Edited by Robert F Gould.Advances in chemistry series 88-propellants manufacture,hazards and testing.ACSPublication,1969:84-121.
[8]彭网大,王春华,张仁.硼化物键合剂在硝胺推进剂中的应用研究[J].固体火箭技术,1990,13(4):43-49.
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[10]潘碧峰,张磊,罗运军.树形键合包覆RDX及其相互作用研究[J].推进技术,2003,24(5):470-473.
[11]白国强,李晓峰,陈洛亮.硼酸酯类键合剂研究进展[J].化学推进剂与高分子材料,2006,4(6):17-19.
[12]崔瑞禧,张炜,陈浪.AP/RDX/Al/HTPB推进剂用硼酸酯键合剂的合成与应用研究[J].固体火箭技术,2012,35(3):372-375.
[13]崔瑞禧,张炜.硼酸酯键合剂分子结构及其与RDX晶面相互作用的理论研究[J].含能材料,2012,20(4):459-464.
[14]崔瑞禧,张炜,邓剑如.硼酸酯键合剂在丁羟四组元推进剂中作用机理研究[J].推进技术,2010,31(4):448-451.
[15]李玉斌,李金山,黄辉,等.新型硼酸酯键合剂与HMX的键合作用[J].火炸药学报,2010,33(4):36-39.
[16]于海江,马军,高登攀,等.一种五元环硼酸酯键合剂的合成及其水解反应动力学[J].含能材料,2014,22(1):1-6.
[17]王祝愿,张习龙,邓剑如.系列环状螯合硼酸酯键合剂的合成及工艺优化[J].固体火箭技术,2016,39(2):231-235.
[18]李洪旭,邓剑如,唐汉祥.螯合型钛酸酯助剂用于新型聚醚推进剂[J].推进技术,2000,21(4):73-76.
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[20]易谋建.钛酸酯键合剂在硝铵改性双基推进剂中的应用[D].西安:西安现代化学研究所,1988.
[21]Kim C S,Youn H,Noble P N,et al.Development of neutral polymeric bonding agents for propellants with polar composites filled with organic nitramine crystals[J].Propellants,Explosives,Pyrotechnics,1992,17(1):38-42.
[22]赵庆华,乌日嘎,崔玉春,等.硝胺类推进剂用键合剂的研究进展[J].化学推进剂与高分子材料,2012,10(3):12-16.
[23]Kim C S.The mechanism of filler reinforcement from addition of neutral polymeric bonding agents to energetic polar propellants[J].Propellants,Explosives,Pyrotechnics,1992,17(1):51-58.
[24]王北海.中性聚合物键合剂的分子设计和合成[J].推进技术,1995,16(4):71-76.
[25]王北海.NEPE推进剂用中性聚合物键合剂的分子设计[J].固体火箭技术,1994,17(3):47-53.
[26]张习龙,张丽,邓剑如.中性聚合物键合剂的精确合成方法[J].固体火箭技术,2013,36(3):368-370.
[27]张林,曹一林,卢艳华,等.嵌段型中性键合剂的合成与表征[J].化工新型材料,2014,42(3):85-87.
[28]王北海.中性聚合物键合剂在NEPE推进剂中的应用[J].固体火箭技术,1994,17(4):59-65.
[29]Landsem E,Jensen T L,Hansen F K,et al.Neutral polymeric bonding agents(NPBA)and their use in smokeless composite rocket propellants based on HMX-GAP-Bu NENA[J].Propellants,Explosives,Pyrotechnics,2012,37(5):581-591.
[30]孟玲玲,谢五喜,蔚红建,等.键合剂对硝酸酯增塑BAMO-THF推进剂力学性能的影响[J].化学推进剂与高分子材料,2011,9(2):64-66.
[31]Gholamian F,Ansari M,Abdullah M,et al.Intermolecular interaction of a neutral polymeric bonding agent containing N-vinylpyrrolidone units with ammonium perchlorate and ketoRDX[J].Chinese Journal of Polymer Science,2013,31(10):1372-1381.
[32]姚维尚,吴文辉,戴健吾,等.硝胺推进剂界面键合的表征研究[J].推进技术,1995,6(3):57-62.
[33]王延铭,赵庆华,孙翔宇,等.新型高分子键合剂的合成及其性能的研究[J].内蒙古科技大学学报,2008,27(4):341-345.
[34]潘碧峰,罗运军,谭惠民.树形分子键合剂包覆AP及其相互作用研究[J].含能材料,2004,12(1):6-9.
[35]潘碧峰,罗运军,谭惠民.树形分子键合剂与HMX的相互作用[J].火炸药学报,2004,27(3):25-28.
[36]潘碧峰,张磊,罗运军,等.树形键合剂包覆RDX及其相互作用研究[J].推进技术,2003,24(5):470-473.
[37]潘碧峰,罗运军,姚维尚,等.树形分子键合剂在PET试片中的应用[J].含能材料,2004,12(5):277-281.
[38]潘碧峰,罗运军,谭惠民.CL-20与树形分子键合剂的粘附性能研究[J].含能材料,2004,12(4):199-202.
[2]Oliveira J I S,Pires D C,Diniz M F,et al.Determination of primary amine content in bonding agent used in composite solid propellants[J].Propellants,Explosives,Pyrotechnics,2014,39(4):538-544.
[3]Zenin A A,Finjakov S V,Puchkov V M,et al.Temperature and pressure sensitivities of burning wave parameters of nitramine-containing propellants and HMX[J].Journal of Propulsion&Power,2015,15(6):753-758.
[4]Duterque J,Lengelle G.Combustion mechanisms of nitramine-based propellants with additives[J].Journal of Propulsion&Power,2015,6(6):718-726.
[5]Naya T,Kohga M.Thermal decomposition behaviors and burning characteristics of AN/nitramine-based composite propellant[J].Journal of Energetic Materials,2015,33(2):73-90.
[6]姚莹莹,张教强.硝胺推进剂用聚合物键合剂的研究进展[J].中国胶黏剂,2009,18(5):56-59.
[7]Oberth A E,Bruenner R S.Polyurethane-based propellants[M]//Edited by Robert F Gould.Advances in chemistry series 88-propellants manufacture,hazards and testing.ACSPublication,1969:84-121.
[8]彭网大,王春华,张仁.硼化物键合剂在硝胺推进剂中的应用研究[J].固体火箭技术,1990,13(4):43-49.
[9]张斌,罗运军,谭惠民.多种键合剂与CL-20界面的相互作用机理[J].火炸药学报,2005,28(3):23-25.
[10]潘碧峰,张磊,罗运军.树形键合包覆RDX及其相互作用研究[J].推进技术,2003,24(5):470-473.
[11]白国强,李晓峰,陈洛亮.硼酸酯类键合剂研究进展[J].化学推进剂与高分子材料,2006,4(6):17-19.
[12]崔瑞禧,张炜,陈浪.AP/RDX/Al/HTPB推进剂用硼酸酯键合剂的合成与应用研究[J].固体火箭技术,2012,35(3):372-375.
[13]崔瑞禧,张炜.硼酸酯键合剂分子结构及其与RDX晶面相互作用的理论研究[J].含能材料,2012,20(4):459-464.
[14]崔瑞禧,张炜,邓剑如.硼酸酯键合剂在丁羟四组元推进剂中作用机理研究[J].推进技术,2010,31(4):448-451.
[15]李玉斌,李金山,黄辉,等.新型硼酸酯键合剂与HMX的键合作用[J].火炸药学报,2010,33(4):36-39.
[16]于海江,马军,高登攀,等.一种五元环硼酸酯键合剂的合成及其水解反应动力学[J].含能材料,2014,22(1):1-6.
[17]王祝愿,张习龙,邓剑如.系列环状螯合硼酸酯键合剂的合成及工艺优化[J].固体火箭技术,2016,39(2):231-235.
[18]李洪旭,邓剑如,唐汉祥.螯合型钛酸酯助剂用于新型聚醚推进剂[J].推进技术,2000,21(4):73-76.
[19]Monte S J.The potential of titanate agents in solid rocket fuel systems[R].AD-P004454.
[20]易谋建.钛酸酯键合剂在硝铵改性双基推进剂中的应用[D].西安:西安现代化学研究所,1988.
[21]Kim C S,Youn H,Noble P N,et al.Development of neutral polymeric bonding agents for propellants with polar composites filled with organic nitramine crystals[J].Propellants,Explosives,Pyrotechnics,1992,17(1):38-42.
[22]赵庆华,乌日嘎,崔玉春,等.硝胺类推进剂用键合剂的研究进展[J].化学推进剂与高分子材料,2012,10(3):12-16.
[23]Kim C S.The mechanism of filler reinforcement from addition of neutral polymeric bonding agents to energetic polar propellants[J].Propellants,Explosives,Pyrotechnics,1992,17(1):51-58.
[24]王北海.中性聚合物键合剂的分子设计和合成[J].推进技术,1995,16(4):71-76.
[25]王北海.NEPE推进剂用中性聚合物键合剂的分子设计[J].固体火箭技术,1994,17(3):47-53.
[26]张习龙,张丽,邓剑如.中性聚合物键合剂的精确合成方法[J].固体火箭技术,2013,36(3):368-370.
[27]张林,曹一林,卢艳华,等.嵌段型中性键合剂的合成与表征[J].化工新型材料,2014,42(3):85-87.
[28]王北海.中性聚合物键合剂在NEPE推进剂中的应用[J].固体火箭技术,1994,17(4):59-65.
[29]Landsem E,Jensen T L,Hansen F K,et al.Neutral polymeric bonding agents(NPBA)and their use in smokeless composite rocket propellants based on HMX-GAP-Bu NENA[J].Propellants,Explosives,Pyrotechnics,2012,37(5):581-591.
[30]孟玲玲,谢五喜,蔚红建,等.键合剂对硝酸酯增塑BAMO-THF推进剂力学性能的影响[J].化学推进剂与高分子材料,2011,9(2):64-66.
[31]Gholamian F,Ansari M,Abdullah M,et al.Intermolecular interaction of a neutral polymeric bonding agent containing N-vinylpyrrolidone units with ammonium perchlorate and ketoRDX[J].Chinese Journal of Polymer Science,2013,31(10):1372-1381.
[32]姚维尚,吴文辉,戴健吾,等.硝胺推进剂界面键合的表征研究[J].推进技术,1995,6(3):57-62.
[33]王延铭,赵庆华,孙翔宇,等.新型高分子键合剂的合成及其性能的研究[J].内蒙古科技大学学报,2008,27(4):341-345.
[34]潘碧峰,罗运军,谭惠民.树形分子键合剂包覆AP及其相互作用研究[J].含能材料,2004,12(1):6-9.
[35]潘碧峰,罗运军,谭惠民.树形分子键合剂与HMX的相互作用[J].火炸药学报,2004,27(3):25-28.
[36]潘碧峰,张磊,罗运军,等.树形键合剂包覆RDX及其相互作用研究[J].推进技术,2003,24(5):470-473.
[37]潘碧峰,罗运军,姚维尚,等.树形分子键合剂在PET试片中的应用[J].含能材料,2004,12(5):277-281.
[38]潘碧峰,罗运军,谭惠民.CL-20与树形分子键合剂的粘附性能研究[J].含能材料,2004,12(4):199-202.