全氟离子交换树脂的研究进展
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摘要
介绍了国内外全氟离子树脂的研究进展,包括新结构的功能单体的合成、新结构树脂的制备及其发展方向,并对其研发与应用前景进行了展望。
The current progresses of perfluorinated ion exchange resin at home and abroad are reviewed.The preparation of new fluoromonomers and new fluoropolymeric resins and their development directions are introduced.The prospects of the research and application of perfluorinated ion exchange resin are proposed as well.
The current progresses of perfluorinated ion exchange resin at home and abroad are reviewed.The preparation of new fluoromonomers and new fluoropolymeric resins and their development directions are introduced.The prospects of the research and application of perfluorinated ion exchange resin are proposed as well.
引文
[1]张永明,李虹,张恒.含氟功能材料[M].北京:化学工业出版社,2008.
[2]Moukheiber E,De Moor G,Flandin L,et al.Investigation of ionomerstructure through its dependence on ion exchange capacity(IEC)[J].J Membr Sci,2012,389(1):294-304.
[3]Feiring A E,Chio S K,Doyle M,et al.Novel aromatic polymers withpendant lithium perfluoroalkylsulfonate or sulfonimide groups[J].Macromolecules,2000,33(25):9262-9271.
[4]DesMarteau D D.Novel Perfluorinated ionomers and ionenes[J].JFluorine Chem,1995,72(2):203-208.
[5]Yang Z Y.Fluorinated ionic polymers:PCT WO,00/77057[P].2000-12-21.
[6]Doyle C M,Feiring A E,Choi S K.Aromatic polymers with pendantfluorinated ionic groups:PCT WO,99/67304[P].1999-12-29.
[7]Moukheiber E,De Moor G,Flandin L,et al.Investigation of ionomerstructure through its dependence on ion exchange capacity(IEC)[J].J Membr Sci,2012,389(1):294-304.
[8]Arcella V,Ghielmi A,Tommasi G,et al.High performance perflu-oropolymer films and membranes[J].Ann N Y Acad Sci,2003,984:226-244.
[9]Feiring A E,Rozen S.Fluorinated ion-exchange polymers and inter-mediates therefor:US,5830962[P].1998-11-03.
[10]Farnham W B,Yang Z Y.Monomers,ionomers and polymers forelectrochemical uses:PCT,00/24709[P].2000-05-04.
[11]Choi S K,Doyle C M,Roelofs M G,et al.Ionomers and ionicallyconductive compositions:US,6100324[P].2000-04-16.
[12]陈焱锋,吴军辉,朱灵运.全氟羧酸单体合成的研究进展[J].有机氟工业,2011,(1):14-16.
[13]王婧,张恒,张永明.全氟羧酸树脂的加工流变性能研究[J].有机氟工业,2010,(4):3-6.
[14]Appleby A J,Velev O A,LeHelloco J G,et al.Polymeric perfluorobis-sulfoimides as possible fuel cell electrolytes[J].J ElectrochemSoc,1993,140(1):109-111.
[15]Sumner J J,Creager S E,Ma J J,et al.Proton conductivity in Na-tion117 and in a novel bis[(perfluoroalkyl)sulfonyl]imide ionomermembrane[J].J Electrochem Soc,1998,145(1):107-110.
[16]Xiao J,Zhang Z,Nie J.Preparation,characterization and catalyticactivity of polystyrene with pendent perfluoroalkylsulfonylimidegroups[J].J Mol Catal A,2005,236(1/2):119-124.
[17]Lei C,Bessarabov D,Ye S,et al.Low equivalent weight short-side-chain perfluorosulfonic acid ionomers in fuel cell cathode catalystlayers[J].J Power Sources,2011,196(15):6168-6176.
[18]肖川,李克,陈炜,等.短支链全氟磺酸膜在高温环境下的应用[J].电源技术,2011,35(5):612-614.
[19]Hubner G,Roduner E.EPR investigations of HO radical initiateddegradation reactions of sulfonated aromatics as model compoundsfor fuel cell proton conducting membranes[J].J Mater Chem,1999,9(2):409-418.
[20]Wei J,Stone C,Steck A E.Trifluorostyrene and substituted triflu-orostyrene copolymeric compositions and ion-exchange membraneformed therefor:US,5422411[P].1993-09-21.
[21]Beattie P D,Basura V I,Holdcroft S.Temperature and pressure de-pendence of O2 reduction at Pt/Nafion 117 and Pt/BAM 407 inter-faces[J].J Electroanal Chem,1999,468(2):180-192.
[22]Ni H B,Li Z H,Dou H Y,et al.Synthesis and characterization offluorinated ionomer p-perfluoro-[1-(2-sulfonic)ethoxy]ethylatedpolyacrylonitrile-styrene[J].J Fluorine Chem,2006,127(8):1036-1041.
[23]王永鹏,岳喜贵,庞金辉,等.侧链含有全氟磺酸的聚芳醚砜质子交换膜材料的制备及性能[J].高等学校化学学报,2012,33(5):1100-1105.
[24]Yamamoto H.New reaction and new catalyst a personal perspective[J].Tetrahedron,2007,63(35):8377-8412.
[25]Peron J,Edwards D,Haldane M,et al.Fuel cell catalyst layers con-taining short-side-chain perfluorosulfonic acid ionomers[J].J Pow-er Sources,2011,196(1):179-181.
[26]王学军,张永明,张恒,等.一种主链全氟离子聚合物及其作为质子交换纤维材料的应用:CN,200910230069.2[P].2009-11-13.
[27]张永明,张恒,秦胜,等.高交换容量全氟离子交换树脂及其制备方法和用途:CN,200910247016.1[P].2009-12-15.
[28]张永明,高自宏,秦胜,等.一种全氟离子交换树脂及其制备方法和用途:CN,200910260161.3[P].2009-12-25.
[29]高自宏,王学军,张恒,等.氯碱用国产离子膜研发及应用[J].氯碱工业,2010,46(10):11-16.
[30]王学军,于昌国,王婧,等.国产氯碱离子膜的应用与研究进展[J].中国氯碱,2012,(6):1-4.
[2]Moukheiber E,De Moor G,Flandin L,et al.Investigation of ionomerstructure through its dependence on ion exchange capacity(IEC)[J].J Membr Sci,2012,389(1):294-304.
[3]Feiring A E,Chio S K,Doyle M,et al.Novel aromatic polymers withpendant lithium perfluoroalkylsulfonate or sulfonimide groups[J].Macromolecules,2000,33(25):9262-9271.
[4]DesMarteau D D.Novel Perfluorinated ionomers and ionenes[J].JFluorine Chem,1995,72(2):203-208.
[5]Yang Z Y.Fluorinated ionic polymers:PCT WO,00/77057[P].2000-12-21.
[6]Doyle C M,Feiring A E,Choi S K.Aromatic polymers with pendantfluorinated ionic groups:PCT WO,99/67304[P].1999-12-29.
[7]Moukheiber E,De Moor G,Flandin L,et al.Investigation of ionomerstructure through its dependence on ion exchange capacity(IEC)[J].J Membr Sci,2012,389(1):294-304.
[8]Arcella V,Ghielmi A,Tommasi G,et al.High performance perflu-oropolymer films and membranes[J].Ann N Y Acad Sci,2003,984:226-244.
[9]Feiring A E,Rozen S.Fluorinated ion-exchange polymers and inter-mediates therefor:US,5830962[P].1998-11-03.
[10]Farnham W B,Yang Z Y.Monomers,ionomers and polymers forelectrochemical uses:PCT,00/24709[P].2000-05-04.
[11]Choi S K,Doyle C M,Roelofs M G,et al.Ionomers and ionicallyconductive compositions:US,6100324[P].2000-04-16.
[12]陈焱锋,吴军辉,朱灵运.全氟羧酸单体合成的研究进展[J].有机氟工业,2011,(1):14-16.
[13]王婧,张恒,张永明.全氟羧酸树脂的加工流变性能研究[J].有机氟工业,2010,(4):3-6.
[14]Appleby A J,Velev O A,LeHelloco J G,et al.Polymeric perfluorobis-sulfoimides as possible fuel cell electrolytes[J].J ElectrochemSoc,1993,140(1):109-111.
[15]Sumner J J,Creager S E,Ma J J,et al.Proton conductivity in Na-tion117 and in a novel bis[(perfluoroalkyl)sulfonyl]imide ionomermembrane[J].J Electrochem Soc,1998,145(1):107-110.
[16]Xiao J,Zhang Z,Nie J.Preparation,characterization and catalyticactivity of polystyrene with pendent perfluoroalkylsulfonylimidegroups[J].J Mol Catal A,2005,236(1/2):119-124.
[17]Lei C,Bessarabov D,Ye S,et al.Low equivalent weight short-side-chain perfluorosulfonic acid ionomers in fuel cell cathode catalystlayers[J].J Power Sources,2011,196(15):6168-6176.
[18]肖川,李克,陈炜,等.短支链全氟磺酸膜在高温环境下的应用[J].电源技术,2011,35(5):612-614.
[19]Hubner G,Roduner E.EPR investigations of HO radical initiateddegradation reactions of sulfonated aromatics as model compoundsfor fuel cell proton conducting membranes[J].J Mater Chem,1999,9(2):409-418.
[20]Wei J,Stone C,Steck A E.Trifluorostyrene and substituted triflu-orostyrene copolymeric compositions and ion-exchange membraneformed therefor:US,5422411[P].1993-09-21.
[21]Beattie P D,Basura V I,Holdcroft S.Temperature and pressure de-pendence of O2 reduction at Pt/Nafion 117 and Pt/BAM 407 inter-faces[J].J Electroanal Chem,1999,468(2):180-192.
[22]Ni H B,Li Z H,Dou H Y,et al.Synthesis and characterization offluorinated ionomer p-perfluoro-[1-(2-sulfonic)ethoxy]ethylatedpolyacrylonitrile-styrene[J].J Fluorine Chem,2006,127(8):1036-1041.
[23]王永鹏,岳喜贵,庞金辉,等.侧链含有全氟磺酸的聚芳醚砜质子交换膜材料的制备及性能[J].高等学校化学学报,2012,33(5):1100-1105.
[24]Yamamoto H.New reaction and new catalyst a personal perspective[J].Tetrahedron,2007,63(35):8377-8412.
[25]Peron J,Edwards D,Haldane M,et al.Fuel cell catalyst layers con-taining short-side-chain perfluorosulfonic acid ionomers[J].J Pow-er Sources,2011,196(1):179-181.
[26]王学军,张永明,张恒,等.一种主链全氟离子聚合物及其作为质子交换纤维材料的应用:CN,200910230069.2[P].2009-11-13.
[27]张永明,张恒,秦胜,等.高交换容量全氟离子交换树脂及其制备方法和用途:CN,200910247016.1[P].2009-12-15.
[28]张永明,高自宏,秦胜,等.一种全氟离子交换树脂及其制备方法和用途:CN,200910260161.3[P].2009-12-25.
[29]高自宏,王学军,张恒,等.氯碱用国产离子膜研发及应用[J].氯碱工业,2010,46(10):11-16.
[30]王学军,于昌国,王婧,等.国产氯碱离子膜的应用与研究进展[J].中国氯碱,2012,(6):1-4.