热电池氧化物正极材料研究进展
|
摘要
传统热电池采用过渡金属硫化物作为正极材料,随着电池小型化的要求,对正极的要求越来越严,国内积极开展了氧化物正极在热电池中的应用研究。综述了国内外学者对MnO_2基氧化物、VO基氧化物、铬酸盐等氧化物正极材料的研究进展,并对各项正极材料存在的问题进行分析,提出了相关优化设计方案。
Transition-metal sulfides, as normal thermal battery cathode materials can't feed the demand of miniaturization for thermal battery. Considering the domestic research of oxides, this article reviews the research progress of manganese oxides, vandium oxides, chromates, etc. and summarizes the problem and optimization directon.
Transition-metal sulfides, as normal thermal battery cathode materials can't feed the demand of miniaturization for thermal battery. Considering the domestic research of oxides, this article reviews the research progress of manganese oxides, vandium oxides, chromates, etc. and summarizes the problem and optimization directon.
引文
[1] MASSET P, GUIDOTTI R A. Thermal activated(thermal)battery technology:PartⅢa:Fe S2cathode material[J]. Journal of Power Sources, 2008, 177:595-609.
[2]宋恒旭,牛永强,侯华,等.高温锂电池氧化物正极材料研究现状与展望[J].无机化学学报, 2017, 33(12):2155-2168.
[3]杨潇薇,杨兆堂,兰伟,等.热电池MnO2/石墨烯正极制备及电性能研究[J].人工晶体学报, 2017(1):74-78.
[4]杨潇薇,杨兆堂,兰伟,等.导电剂对热电池正极MnO2电性能影响[J].电源技术, 2018, 42(9):1345-1352.
[5] NIU Y Q, WU Z, DU J, et al. A new thermal battery for powering borehole equipment:the discharge performance of Li-Mg-B alloy/LiNO3-KNO3/MnO2cells at high temperatures[J]. Journal of Power Sources, 2014, 245:537-542.
[6] NIU Y Q, WU Z, DU J, et al. Characterization of Li-Mg-B alloy/LiNO3-KNO3-KNO2-Ca(NO3)2/MnO2system for potential use as geothermal and oil/gas borehole battery[J]. Solid State Ionics, 2014,255:80-83.
[7] NIU Y Q, WU Z, DU J, et al. Discharge behavior of Li-Mg-B alloy/Mn O2couples with LiNO3-KNO3-Mg(OH)NO3eutectic electrolyte[J]. Electrochimica Acta, 2014, 115:607-611.
[8] NIU Y Q, WU Z, DU J. Discharge characteristics of Li-Mg-B alloy/Mn O2couples in molten LiNO3-KNO3-Ca(NO3)2eutectic electrolyte[J]. Journal of the Electrochemical Society, 2013, 160(9):A1375-A1379.
[9]卢财财,曹晓晖,杨少华,等.热电池用LiMn2O4正极材料的制备及性能研究[J].电源技术, 2016, 40(11):2189-2191.
[10] WANG Z J, DU J L, DUAN W, et al. LiMn2-xNixO4spinel oxides as high-temperature lithium battery cathode materials for borehole applications[J]. Int J Electrochem Sci, 2013, 8:6231-6242.
[11] MASSET P, GUIDOTTI R A. Thermal activated(thermal)battery technology:PartⅢb:Sulfur and oxide-based cathode materials[J].Journal of power sources, 2008, 178:456-466.
[12] GUIDOTTI R A, REINHARDT F W. Characterization of high-voltage cathodes in Cs Br-LiBr-KBr eutectic electrolyte[R]. Albuquerque, US:Sandia National Labs, 2000.
[13] GUIDOTTI R A,REINHARDT F W.Evaluation of the Li(Al)/MnO2couple in LiNO3-KNO3eutectic electrolyte for borehole applications[C]//Proceedings of 41st Power Sources Conference. Philadelphia:41st Power Sources Conference, 2004.
[14] JIA X, ZHANG L, ZHANG R, et al. Carbon nanotube-penetrated mesoporous V2O5microspheres as high-performance cathode materials for lithium-ion batteries[J]. Rsc Advance, 2014, 4(40):21018-21022.
[15] DAI J, LAI M, MCKEE J. Evaluation of a LiSi/Cu3V2O8thermal battery[J]. ECS Transactions, 2012, 41(11):11-16.
[16] SAKURAI Y, OHTSUKA H, YAMAKI J. Rechargeable copper vanadate cathodes for lithium cell[J]. Journal of the Electrochemical Society, 1988, 135(1):32-36.
[17]闫妍,杨少华,赵彦龙.高电位CuV2O6正极材料在热电池中的应用[J].沈阳理工大学学报, 2014, 33(2):6-8.
[18]骆柬氽,杨少华,白银祥,等.热电池用高电位Cu3V2O8的性能研究[J].电源技术, 2014, 38(8):1516-1518.
[19]袁朝军,杨少华,曹晓晖.钻井用Li-Si/LiNO3-KNO3-Ca(NO3)2/Cu3V2O8热电池放电性能的研究[J].电源技术,2015, 39(11):2450-2452.
[20]孙榕,杨少华.热电池钒酸铜正极性能影响因素的研究[J].电源技术, 2017, 41(2):270-271.
[21]袁朝军,杨少华,曹晓晖.导电剂对低温高电位热电池正极Cu3-V2O8性能的影响[J].功能材料, 2015, 46(17):17046-17048.
[22] SAKURAI Y, YAMAKI J. Correlation between microstructure and electrochemical behavior of amorphous V2O5-P2O5in lithium cells[J]. Journal of the Electrochemical Society, 1988, 135(4):791-796.
[23] EGUCHI M, KOMAMURA A, MIURA T, et al. Lithiation characteristics of Cu5V2O10[J]. Electrochimica Acta, 1996, 41(6):857-861.
[24] HILLEL T, EIN-ELI Y. Copper vanadate as promising high voltage cathodes for Li thermal batteries[J]. Journal of Power Sources,2013, 229:112-116.
[25]石奎,冯玉才,周爱.热电池正极材料钒氧碳的性能研究[J].电源技术, 2016, 40(9):1833-1862.
[26] ZHONG C R, SU X, HOU G, et al. Effect of different treatment methods on the electrochemical properties of LiV3O8at elevated temperatures[J]. Ceramics International, 2017, 43(1):414-419.
[27]方文利.锂热电池阴极材料钒氧化物的制备及改性研究[D].哈尔滨:哈尔滨工业大学,2017.
[28]倪祖君.热电池正极材料Co S2及Co S2-LVO复合材料性能研究[D].哈尔滨:哈尔滨工业大学,2017.
[29] VIJAYAKUMAR M. Transport properties of LixV2O5(x=0.6~1.6)electrode material[J]. Materials Research Bulletin, 2003(13):1735-1743.
[30]苑晓宇,马伟民,闻雷,等.热电池正极材料的研究进展[J].陶瓷学报, 2010, 31(4):663-668.
[2]宋恒旭,牛永强,侯华,等.高温锂电池氧化物正极材料研究现状与展望[J].无机化学学报, 2017, 33(12):2155-2168.
[3]杨潇薇,杨兆堂,兰伟,等.热电池MnO2/石墨烯正极制备及电性能研究[J].人工晶体学报, 2017(1):74-78.
[4]杨潇薇,杨兆堂,兰伟,等.导电剂对热电池正极MnO2电性能影响[J].电源技术, 2018, 42(9):1345-1352.
[5] NIU Y Q, WU Z, DU J, et al. A new thermal battery for powering borehole equipment:the discharge performance of Li-Mg-B alloy/LiNO3-KNO3/MnO2cells at high temperatures[J]. Journal of Power Sources, 2014, 245:537-542.
[6] NIU Y Q, WU Z, DU J, et al. Characterization of Li-Mg-B alloy/LiNO3-KNO3-KNO2-Ca(NO3)2/MnO2system for potential use as geothermal and oil/gas borehole battery[J]. Solid State Ionics, 2014,255:80-83.
[7] NIU Y Q, WU Z, DU J, et al. Discharge behavior of Li-Mg-B alloy/Mn O2couples with LiNO3-KNO3-Mg(OH)NO3eutectic electrolyte[J]. Electrochimica Acta, 2014, 115:607-611.
[8] NIU Y Q, WU Z, DU J. Discharge characteristics of Li-Mg-B alloy/Mn O2couples in molten LiNO3-KNO3-Ca(NO3)2eutectic electrolyte[J]. Journal of the Electrochemical Society, 2013, 160(9):A1375-A1379.
[9]卢财财,曹晓晖,杨少华,等.热电池用LiMn2O4正极材料的制备及性能研究[J].电源技术, 2016, 40(11):2189-2191.
[10] WANG Z J, DU J L, DUAN W, et al. LiMn2-xNixO4spinel oxides as high-temperature lithium battery cathode materials for borehole applications[J]. Int J Electrochem Sci, 2013, 8:6231-6242.
[11] MASSET P, GUIDOTTI R A. Thermal activated(thermal)battery technology:PartⅢb:Sulfur and oxide-based cathode materials[J].Journal of power sources, 2008, 178:456-466.
[12] GUIDOTTI R A, REINHARDT F W. Characterization of high-voltage cathodes in Cs Br-LiBr-KBr eutectic electrolyte[R]. Albuquerque, US:Sandia National Labs, 2000.
[13] GUIDOTTI R A,REINHARDT F W.Evaluation of the Li(Al)/MnO2couple in LiNO3-KNO3eutectic electrolyte for borehole applications[C]//Proceedings of 41st Power Sources Conference. Philadelphia:41st Power Sources Conference, 2004.
[14] JIA X, ZHANG L, ZHANG R, et al. Carbon nanotube-penetrated mesoporous V2O5microspheres as high-performance cathode materials for lithium-ion batteries[J]. Rsc Advance, 2014, 4(40):21018-21022.
[15] DAI J, LAI M, MCKEE J. Evaluation of a LiSi/Cu3V2O8thermal battery[J]. ECS Transactions, 2012, 41(11):11-16.
[16] SAKURAI Y, OHTSUKA H, YAMAKI J. Rechargeable copper vanadate cathodes for lithium cell[J]. Journal of the Electrochemical Society, 1988, 135(1):32-36.
[17]闫妍,杨少华,赵彦龙.高电位CuV2O6正极材料在热电池中的应用[J].沈阳理工大学学报, 2014, 33(2):6-8.
[18]骆柬氽,杨少华,白银祥,等.热电池用高电位Cu3V2O8的性能研究[J].电源技术, 2014, 38(8):1516-1518.
[19]袁朝军,杨少华,曹晓晖.钻井用Li-Si/LiNO3-KNO3-Ca(NO3)2/Cu3V2O8热电池放电性能的研究[J].电源技术,2015, 39(11):2450-2452.
[20]孙榕,杨少华.热电池钒酸铜正极性能影响因素的研究[J].电源技术, 2017, 41(2):270-271.
[21]袁朝军,杨少华,曹晓晖.导电剂对低温高电位热电池正极Cu3-V2O8性能的影响[J].功能材料, 2015, 46(17):17046-17048.
[22] SAKURAI Y, YAMAKI J. Correlation between microstructure and electrochemical behavior of amorphous V2O5-P2O5in lithium cells[J]. Journal of the Electrochemical Society, 1988, 135(4):791-796.
[23] EGUCHI M, KOMAMURA A, MIURA T, et al. Lithiation characteristics of Cu5V2O10[J]. Electrochimica Acta, 1996, 41(6):857-861.
[24] HILLEL T, EIN-ELI Y. Copper vanadate as promising high voltage cathodes for Li thermal batteries[J]. Journal of Power Sources,2013, 229:112-116.
[25]石奎,冯玉才,周爱.热电池正极材料钒氧碳的性能研究[J].电源技术, 2016, 40(9):1833-1862.
[26] ZHONG C R, SU X, HOU G, et al. Effect of different treatment methods on the electrochemical properties of LiV3O8at elevated temperatures[J]. Ceramics International, 2017, 43(1):414-419.
[27]方文利.锂热电池阴极材料钒氧化物的制备及改性研究[D].哈尔滨:哈尔滨工业大学,2017.
[28]倪祖君.热电池正极材料Co S2及Co S2-LVO复合材料性能研究[D].哈尔滨:哈尔滨工业大学,2017.
[29] VIJAYAKUMAR M. Transport properties of LixV2O5(x=0.6~1.6)electrode material[J]. Materials Research Bulletin, 2003(13):1735-1743.
[30]苑晓宇,马伟民,闻雷,等.热电池正极材料的研究进展[J].陶瓷学报, 2010, 31(4):663-668.