多孔炭材料的制备及在废水处理中的应用研究进展
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摘要
以微孔炭、介孔炭及大孔炭为代表的多孔炭材料,因其三维多孔结构和良好的热稳定性而具有优异的吸附性能,其主要制备方法有活化法、软硬模板法等。在介绍了三种多孔炭材料制备方法与特点的基础上,综述了多孔炭材料作为吸附剂在重金属离子废水、染料废水和其他废水处理中的应用研究进展。
Porous carbon materials,including microporous carbon,mesoporous carbon and macroporous carbon materials,have excellent adsorbing capacity because of the three-dimensional multiple channel structure and good thermal stability.Porous carbon materials could be prepared by carbon activation method and hard/soft template method.Based on the introduction of the preparation and characteristics of the three kinds of porous carbon materials,the research progress in the application of porous carbon materials,as adsorbents,to the treatment of heavy metal ions wastewater,dyestuff wastewater and other kinds of wastewater are summarized.
Porous carbon materials,including microporous carbon,mesoporous carbon and macroporous carbon materials,have excellent adsorbing capacity because of the three-dimensional multiple channel structure and good thermal stability.Porous carbon materials could be prepared by carbon activation method and hard/soft template method.Based on the introduction of the preparation and characteristics of the three kinds of porous carbon materials,the research progress in the application of porous carbon materials,as adsorbents,to the treatment of heavy metal ions wastewater,dyestuff wastewater and other kinds of wastewater are summarized.
引文
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[18]梁向峰,郭晨,刘庆芬,等.PEO-PPO-PEO嵌段共聚物在水溶液中的自组装行为及其应用[J].化工学报,2010,61(7):1693-1712.
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[25]柯行飞,曹洁明,郑明波,等.双模板法合成介孔/大孔二级孔道炭材料[J].物理化学学报,2007,23(5):757-760.
[26]Veksha A,Sasaoka E,Uddin M A.The influence of porosity and surface oxygen groups of peat-based activated carbons on benzene adsorption from dry and humid air[J].Carbon,2009,47(10):2371-2378.
[27]殷俊,陈光辉,崔皓,等.单质硫改性介孔炭对水溶液中汞的吸附性能研究[J].环境工程学报,2009,3(12):2148-2152.
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[29]陈田,王涛,王道军,等.功能化有序介孔炭对重金属离Cu(Ⅱ)、Cr(Ⅵ)的选择性吸附行为[J].物理化学学报,2010,26(12):3249-3256.
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[31]Burke D M,Morris M A,Holmes J D.Chemical oxidation of mesoporous carbon foams for lead ion adsorption[J].Separation and Purification Technology,2013,104:150-159.
[32]Chen Tian,Wang Tao,Wang Daojun,et al.Synthesis of ordered large-pore mesoporous carbon for Cr(Ⅵ)adsorption[J].Materials Research Bulletin,2011,46(9):1424-1430.
[33]詹予忠,杨向东,张晓斌.多孔炭/硅胶复合吸附剂吸附除铬(Ⅵ)研究[J].环境科学与技术,2008,31(5):42-44.
[34]Mohammadi N,Khani H,Gupta V K,et al.Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies[J].Journal of Colloid and Interface Science,2011,362(2):457-462.
[35]He Chun,Hu Xijun.Anionic dye adsorption on chemically modified ordered mesoporous carbons[J].Industrial&Engineering Chemistry Research,2011,50(24):14070-14083.
[36]董艳萍,田喜强,乔秀丽,等.磁性粒子/介孔炭的合成及其吸附性能[J].化工环保,2012,32(1):94-97.
[37]B觟ke N,Godongwana Z G,Petrik L F.Synthesis of an ordered mesoporous carbon with graphitic characteristics and its application for dye adsorption[J].Journal of Porous Materials,2011,17(3):483-488.
[38]Zhuang X,Wan Y,Feng C M,et al.Highly efficient adsorption of bulky dye molecules in wastewater on ordered mesoporous carbons[J].Chemistry of Materials,2009,21(4):706-716.
[39]孙何,李群艳,韦奇,等.有序介孔炭对罗丹明B的吸附行为研究[J].化学反应工程与工艺,2012,28(3):225-231.
[40]Yan C X,Wang C Q,Yao J F,et al.Adsorption of methylene blue on mesoporous carbons prepared using acid-and alkaline-treated zeolite X as the template[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,333(1):115-119.
[41]Zhang P,An Q,Guo J,et al.Synthesis of mesoporous magnetic CoNPs/carbon nanocomposites and their adsorption property for methyl orange from aqueous solution[J].Journal of Colloid and Interface Science,2013,389(1):10-15.
[42]郭卓,袁悦.介孔炭CMK-3对苯酚的吸附动力学和热力学研究[J].高等学校化学学报,2007,28(2):289-292.
[43]崔祥婷,闻振涛,万颖.有序介孔炭用于吸附水相中的氯代芳香族化合物[J].上海师范大学学报,2010,39(3):279-283.
[44]刘冬梅,黄碧纯,叶代启.有序介孔炭吸附萘的研究[J].化学与生物工程,2009,26(9):23-28.
[2]Liu Yan,Guo Yupeng,Gao Wei,et al.Simultaneous preparation of silica and activated carbon from rice husk ash[J].Journal of Cleaner Production,2012,32:204-209.
[3]Hayashi J,Horikawa T,Takeda I,et al.Preparing activated carbon from various nutshells by chemical activation with K2CO3[J].Carbon,2002,40(13):2381-2386.
[4]Foo K Y,Hameed B H.Mesoporous activated carbon from wood sawdust by K2CO3activation using microwave heating[J].Bioresource Technology,2012,111:425-432.
[5]Huang C H,Doong R A.Sugarcane bagasse as the scaffold for mass production of hierarchically porous carbon monoliths by surface selfassembly[J].Microporous and Mesoporous Materials,2012,147(1):47-52.
[6]Teng Minmin,Qiao Junlian,Li Fengting,et al.Electrospun mesoporous carbon nanofibers produced from phenolic resin and their use in the adsorption of large dye molecules[J].Carbon,2012,50(8):2877-2886.
[7]Tang Yubing,Liu Qiang,Chen Fangyan.Preparation and characterization of activated carbon from waste ramulus mori[J].Chemical Engineering Journal,2012,203(1):19-24.
[8]Xiang Xiaoxia,Liu Enhui,Huang Zhengzheng,et al.Microporous carbon derived from polyaniline base as anode material for lithium ion secondary battery[J].Materials Research Bulletin,2011,46(8):1266-1271.
[9]张进华,车永芳,李兰廷,等.煤基碳分子筛的制备及CH4/N2分离性能研究[J].洁净煤技术,2011,17(2):64-67.
[10]Berenguer R,Nishihara H,Itoi H,et al.Electrochemical generation of oxygen-containing groups in an ordered microporous zeolitetemplated carbon[J].Carbon,2013,54:94-104.
[11]Ma Zhixin,Kyotani T,Tomita A.Preparation of a high surface area microporous carbon having the structural regularity of Y zeolite[J].Chemical Communications,2000,23(2):2365-2366.
[12]Xia Kaisheng,Gao Qiuming,Jiang Jinhua,et al.An unusual method to prepare a highly microporous carbon for hydrogen storage application[J].Materials Letters,2013,100(1):227-229.
[13]Kim K S,Park S J.Synthesis of microporous carbon nanotubes by templating method and their high electrochemical performance[J].Electrochimica Acta,2012,78:146-153.
[14]Mohd Din A T,Ahmad M A,Hameed B H.Riboflavin adsorption onto multi-modal mesoporous carbon synthesized from polyethylene glycol 400[J].Chemical Engineering Journal,2013,215/216:297-305.
[15]Babic B,Kokunesoski M,Miljkovi C M,et al.New mesoporous carbon materials synthesized by a templating procedure[J].Ceramics International,2013,39(4):4035-4043.
[16]苏沙沙,顾金楼,李永生,等.介孔碳材料的制备及对胆红素的优越吸附特性[J].化工新型材料,2011,39(6):81-83.
[17]邱会华,刘应亮,曾江华,等.简易模板法制备有序介孔炭[J].无机化学学报,2010,26(1):101-105.
[18]梁向峰,郭晨,刘庆芬,等.PEO-PPO-PEO嵌段共聚物在水溶液中的自组装行为及其应用[J].化工学报,2010,61(7):1693-1712.
[19]Mitome T,Uchida Y,Egashira Y,et al.Adsorption of indole on KOH-activated mesoporous carbon[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,424:89-95.
[20]刘攀博,焦剑,黄英,等.以一种新碳前驱体制备有序介孔炭及其表征[J].材料导报B,2012,26(7):8-12.
[21]李健生,顾娟,凌晓凤,等.有序介孔碳负载Fe、CO、Ni纳米晶的软模板合成及其表征[J].物理化学学报,2011,27(7):1772-1776.
[22]孙何,韦奇,李群艳,等.一步法合成含Co磁性有序介孔炭[J].人工晶体学报,2012,s1:391-396.
[23]Holmes S M,Graniel-Garcia B E,Foran P,et al.A novel porous carbon based on diatomaceous earth[J].Chemical Communications,2006(25):2662-2663.
[24]Liu Dong,Yuan Peng,Tan Daoyong,et al.Facile preparation of hierarchically porous carbon using diatomite as both template and catalyst and methylene blue adsorption of carbon products[J].Journal of Colloid and Interface Science,2012,388(1):176-184.
[25]柯行飞,曹洁明,郑明波,等.双模板法合成介孔/大孔二级孔道炭材料[J].物理化学学报,2007,23(5):757-760.
[26]Veksha A,Sasaoka E,Uddin M A.The influence of porosity and surface oxygen groups of peat-based activated carbons on benzene adsorption from dry and humid air[J].Carbon,2009,47(10):2371-2378.
[27]殷俊,陈光辉,崔皓,等.单质硫改性介孔炭对水溶液中汞的吸附性能研究[J].环境工程学报,2009,3(12):2148-2152.
[28]祝建中,杨嘉,Deng B L.有序介孔炭合成、改性及其对汞离子的吸附性能[J].新型炭材料,2008,23(3):221-227.
[29]陈田,王涛,王道军,等.功能化有序介孔炭对重金属离Cu(Ⅱ)、Cr(Ⅵ)的选择性吸附行为[J].物理化学学报,2010,26(12):3249-3256.
[30]Gu Zhimang,Deng Baolin,Yang J.Synthesis and evaluation of iron-containing ordered mesoporous carbon(Fe OMC)for arsenic adsorption[J].Microporous and Mesoporous Materials,2007,102(1/2/3):265-273.
[31]Burke D M,Morris M A,Holmes J D.Chemical oxidation of mesoporous carbon foams for lead ion adsorption[J].Separation and Purification Technology,2013,104:150-159.
[32]Chen Tian,Wang Tao,Wang Daojun,et al.Synthesis of ordered large-pore mesoporous carbon for Cr(Ⅵ)adsorption[J].Materials Research Bulletin,2011,46(9):1424-1430.
[33]詹予忠,杨向东,张晓斌.多孔炭/硅胶复合吸附剂吸附除铬(Ⅵ)研究[J].环境科学与技术,2008,31(5):42-44.
[34]Mohammadi N,Khani H,Gupta V K,et al.Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies[J].Journal of Colloid and Interface Science,2011,362(2):457-462.
[35]He Chun,Hu Xijun.Anionic dye adsorption on chemically modified ordered mesoporous carbons[J].Industrial&Engineering Chemistry Research,2011,50(24):14070-14083.
[36]董艳萍,田喜强,乔秀丽,等.磁性粒子/介孔炭的合成及其吸附性能[J].化工环保,2012,32(1):94-97.
[37]B觟ke N,Godongwana Z G,Petrik L F.Synthesis of an ordered mesoporous carbon with graphitic characteristics and its application for dye adsorption[J].Journal of Porous Materials,2011,17(3):483-488.
[38]Zhuang X,Wan Y,Feng C M,et al.Highly efficient adsorption of bulky dye molecules in wastewater on ordered mesoporous carbons[J].Chemistry of Materials,2009,21(4):706-716.
[39]孙何,李群艳,韦奇,等.有序介孔炭对罗丹明B的吸附行为研究[J].化学反应工程与工艺,2012,28(3):225-231.
[40]Yan C X,Wang C Q,Yao J F,et al.Adsorption of methylene blue on mesoporous carbons prepared using acid-and alkaline-treated zeolite X as the template[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,333(1):115-119.
[41]Zhang P,An Q,Guo J,et al.Synthesis of mesoporous magnetic CoNPs/carbon nanocomposites and their adsorption property for methyl orange from aqueous solution[J].Journal of Colloid and Interface Science,2013,389(1):10-15.
[42]郭卓,袁悦.介孔炭CMK-3对苯酚的吸附动力学和热力学研究[J].高等学校化学学报,2007,28(2):289-292.
[43]崔祥婷,闻振涛,万颖.有序介孔炭用于吸附水相中的氯代芳香族化合物[J].上海师范大学学报,2010,39(3):279-283.
[44]刘冬梅,黄碧纯,叶代启.有序介孔炭吸附萘的研究[J].化学与生物工程,2009,26(9):23-28.