二苯甲酰甲烷Eu(Ⅲ)配合物的合成及结构
|
摘要
文章选用二苯甲酰甲烷(DBM)和EuCl_3·6H_2O合成了一种新的β-二酮稀土配合物,通过紫外光谱、红外光谱、元素分析、热重分析等方法对这种配合物进行了结构表征,得到了二苯甲酰甲烷Eu(Ⅲ)配合物的结构。
A new Eu(Ⅲ) complex has been synthesized and designed by reactions of Dibenzoylmethane and EuCl_3·6H_2O. The complex was characterized by a number of analytical techniques.
A new Eu(Ⅲ) complex has been synthesized and designed by reactions of Dibenzoylmethane and EuCl_3·6H_2O. The complex was characterized by a number of analytical techniques.
引文
[1]黄春辉,李富友,黄维,有机电致发光材料与器件导论[M].上海:复旦大学出版社,2005.
[2]Dong Y P,Yan P F,Li G M,et al.Exploiting single-molecule magnets of b-diketone dysprosium complexes with C3v symmetry:suppression of quantum tunneling of magnetization[J].J Mater Chem C,2015,3:4407-4415.
[3]Dong Y P,Yan P F,Li G M,et al.Azacyclo-auxiliary ligand-tuned SMMs of dibenzoylmethane Dy(III)complexes[J].Inorg Chem Front,2015,2:827-836.
[4]Coronado E,Day P.Magnetic Molecular Conductors[J].Chem Rev,2004,104:5419-5448.
[5]Dong Y P,Yan P F,Zou X Y,et al.Dalton Trans,2016,45:9148-9157.
[6]秦梅,费潇瑶,韩璐,等.新型稀土荧光材料的合成及性能研究[J].化学工程师,2011,8:16-18.
[7]江强明.新型稀土配合物发光材料的合成及性质研究[J].化学工程师,2008,3:9-11.
[8]Li J Y,Li H F,Yan P F,et al.Synthesis,Crystal Structure,and Luminescent Properties of 2-(2,2,2-Trifluoroethyl)-1-indone Lanthanide Complexes[J].Inorg Chem,2012,51:5050-5057.
[9]Zou X Y,Li M J,Yan P F,et al.Systematic study on the structures of salen type lanthanide complexes tuned by lanthanide contraction and corresponding luminescence[J].Dalton Trans,2013,42:9482-9489.
[10]李洪峰.芳环桥连双β-二酮稀土配合物的合成及光致发光性质研究[D].哈尔滨:黑龙江大学,2012.
[11]刘鸿,朱国柱,范开文.含偶氮苯8-羟基喹啉稀土配合物的合成与表征[J].应用化工,2012,41:1567-1574.
[12]王道永.双β-二酮金属配合物的合成、表征及性质研究[D].西安:西北大学,2005.
[13]李建宁.稀土发光材料及其应用[M].北京:化工工业出版社,2013.
[14]刘兴旺,高赛生态,王丽,等.新型β-二酮及其稀土配合物的合成、表征及荧光性能研究[J].有机化学,2010,30:1848-1853.
[2]Dong Y P,Yan P F,Li G M,et al.Exploiting single-molecule magnets of b-diketone dysprosium complexes with C3v symmetry:suppression of quantum tunneling of magnetization[J].J Mater Chem C,2015,3:4407-4415.
[3]Dong Y P,Yan P F,Li G M,et al.Azacyclo-auxiliary ligand-tuned SMMs of dibenzoylmethane Dy(III)complexes[J].Inorg Chem Front,2015,2:827-836.
[4]Coronado E,Day P.Magnetic Molecular Conductors[J].Chem Rev,2004,104:5419-5448.
[5]Dong Y P,Yan P F,Zou X Y,et al.Dalton Trans,2016,45:9148-9157.
[6]秦梅,费潇瑶,韩璐,等.新型稀土荧光材料的合成及性能研究[J].化学工程师,2011,8:16-18.
[7]江强明.新型稀土配合物发光材料的合成及性质研究[J].化学工程师,2008,3:9-11.
[8]Li J Y,Li H F,Yan P F,et al.Synthesis,Crystal Structure,and Luminescent Properties of 2-(2,2,2-Trifluoroethyl)-1-indone Lanthanide Complexes[J].Inorg Chem,2012,51:5050-5057.
[9]Zou X Y,Li M J,Yan P F,et al.Systematic study on the structures of salen type lanthanide complexes tuned by lanthanide contraction and corresponding luminescence[J].Dalton Trans,2013,42:9482-9489.
[10]李洪峰.芳环桥连双β-二酮稀土配合物的合成及光致发光性质研究[D].哈尔滨:黑龙江大学,2012.
[11]刘鸿,朱国柱,范开文.含偶氮苯8-羟基喹啉稀土配合物的合成与表征[J].应用化工,2012,41:1567-1574.
[12]王道永.双β-二酮金属配合物的合成、表征及性质研究[D].西安:西北大学,2005.
[13]李建宁.稀土发光材料及其应用[M].北京:化工工业出版社,2013.
[14]刘兴旺,高赛生态,王丽,等.新型β-二酮及其稀土配合物的合成、表征及荧光性能研究[J].有机化学,2010,30:1848-1853.