赣南淘锡坑石英脉型钨矿床成矿机制探讨:来自流体包裹体的证据
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摘要
赣南地区淘锡坑钨矿床是典型的大型石英脉型钨锡多金属矿床。矿体赋存于震旦系浅变质砂(板)岩,并延伸至深部花岗岩内,按空间产出位置分为内带矿体和外带矿体,包括宝山、西山、烂埂子、枫岭坑4大脉组,矿体产出各不相同,矿物组合也具有明显分带特征。在详细的岩相学研究基础上,文章选择淘锡坑主成矿期石英为研究对象,并与共生黑钨矿作对比,从空间角度开展不同脉组、不同矿体或中段的流体包裹体的对比研究。根据流体包裹体岩相学,石英包裹体类型有H_2O-NaCl型包裹体(Ⅰ型)、H_2O-NaCl-CO_2型包裹体(Ⅱ型)和纯CO_2体系裹体(Ⅲ型)及少量含石盐子晶的多相包裹体,并同时捕获贫CO_2的盐水溶液包裹体和纯CO-2气相包裹体。包裹体显微测温结果显示:内、外带石英脉气液两相的包裹体均具有较宽温度和盐度范围,外带均一温度和盐度w(NaCl_(eq))分别集中于200～220℃、1%～6%,内带均一温度和盐度w(NaCleq)分别集中于100～220℃、3%～7%,流体为中-低盐度、富含CO_2的H_2O-CO_2-NaCl体系,不同脉组不同矿脉之间对比结果均显示出多期成矿的特征。在矿脉形成过程中,流体的成分和温度在内外接触带有明显变化,表明岩体与围岩接触界面是造成淘锡坑矿床内带矿体和外带矿体的成矿条件改变的转折位置,成矿流体在此附近发生CO_2逸失引起相分离的不混溶作用是成矿的主要因素。
The Taoxikeng is a large scale quartz vein type tungsten deposit in Chongyi County, southern Jiangxi Province. The quartz veins occur in shallow metasandstone of sinian system and extent to the deep granite, which respectively are outer orebody and inner orebody. The Baoshan, Xishan, Langengzi and Fenglinkeng are four vein groups. They are characterized by different occurrence and mineral assemblage. The main types of fluid inclusions: H_2O-NaCl type(Ⅰtype), H_2O-NaCl-CO_2type(Ⅱtype), pure CO_2(Ⅲtype) and minor daughter mineralbearing inclusions in all samples from quartz and intergrowth wolframite in main metallogenic period. The existence of capturing both aqueous salt inclusions with poor CO_2 and pure CO_2 inclusions is a typical feature of the Taoxikeng deposit. Experimental results show that the main homogenization temperature and salinity of inner and outer orebody are in a wide temperature range. The homogeneous temperatures and salinities w(NaCl_(eq)) of fluid inclusions in quartz of outer orebody vary from 200℃ to 220℃ and 1% to 6%, respectively. The homogeneous temperatures and salinities w(NaCl_(eq)) of fluid inclusions in quartz of inner orebody vary from 100℃ to 220℃ and3%～7%, respectively. According to the data above, it can be concluded that the ore-forming fluids generally belong to middle temperature, low salinity, rich CO_2, H_2O-CO_2-NaCl system. The temperature and composition show the significant changes in inner orebody and outer orebody. It is the main reason that fluid immiscibility caused by CO_2 escaping happened in contact interface between granite and surrounding rock possibly led to tungsten precipitation.
The Taoxikeng is a large scale quartz vein type tungsten deposit in Chongyi County, southern Jiangxi Province. The quartz veins occur in shallow metasandstone of sinian system and extent to the deep granite, which respectively are outer orebody and inner orebody. The Baoshan, Xishan, Langengzi and Fenglinkeng are four vein groups. They are characterized by different occurrence and mineral assemblage. The main types of fluid inclusions: H_2O-NaCl type(Ⅰtype), H_2O-NaCl-CO_2type(Ⅱtype), pure CO_2(Ⅲtype) and minor daughter mineralbearing inclusions in all samples from quartz and intergrowth wolframite in main metallogenic period. The existence of capturing both aqueous salt inclusions with poor CO_2 and pure CO_2 inclusions is a typical feature of the Taoxikeng deposit. Experimental results show that the main homogenization temperature and salinity of inner and outer orebody are in a wide temperature range. The homogeneous temperatures and salinities w(NaCl_(eq)) of fluid inclusions in quartz of outer orebody vary from 200℃ to 220℃ and 1% to 6%, respectively. The homogeneous temperatures and salinities w(NaCl_(eq)) of fluid inclusions in quartz of inner orebody vary from 100℃ to 220℃ and3%～7%, respectively. According to the data above, it can be concluded that the ore-forming fluids generally belong to middle temperature, low salinity, rich CO_2, H_2O-CO_2-NaCl system. The temperature and composition show the significant changes in inner orebody and outer orebody. It is the main reason that fluid immiscibility caused by CO_2 escaping happened in contact interface between granite and surrounding rock possibly led to tungsten precipitation.
引文
Burke E A J.2001.Raman microspectrometry of fluid inclusions[J].Lithos,55(1-4):139-158.
Cao X F,Lv X B,He M C,Niu H,Du B F and Mei H.2009.An infrared microscope investigation of fuid inclusions in coexisting quartz and wolframite:A case study of Yaogangxian quartz-vein wolframite deposit[J].Mineral Deposits,28(5):611-620(in Chinese with English abstract).
Chang H L,Wang X W,Wang X D,Liu J Q and Huang H L.2007.The composition of melt inclusions in beryl from wolframite-quartz veins in Xihuashan,Jiangxi Province[J].Acta Petrologica et Mineralogica,26(3):259-268(in Chinese with English abstract).
Chen Z H,Wang D H,Qu W J,Chen Y C,Wang P A,Xu J X,Zhang JJ and Xu M L.2006.Geological characteristics and mineralization age of the Taoxikeng tungsten deposit in Chongyi County,southern Jiangxi Province,China[J].Geological Bullentin of China,25(4):496-501(in Chinese with English abstract).
Chen Z H,Wang D H,Liu S B,Wang C H,Xu J X,Zeng Z L and Qu W J.2008.Neutron activion analysis study on quartz from the Taoxikeng tungsten deposit in southern Jiangxi,China[J].Acta Geologica Sinica,82(7):978-985(in Chinese with English abstract).
Chen Z H,Wang D H,Zeng Z L,Zhao B,Chen Y C,Fang G C.2013.Application of“Five levels+Basement”model for three-dimensional probe and prospecting deposits into depth in Yudu-Ganxian ore concentration of Nanling Region[J].Geological Review,4(Supp.59):591-592(in Chinese with English abstract).
Chi G X and Lu H Z.1991.Characteristics of fluid phase separation fields in a depth-temperature coordinate with emphasis on their significance in localization of hydrothermal deposits[J].Acta Mineralogica Sinica,(4):355-948(in Chinese with English abstract).
Craw D,Teagle D A H and Belocky R.1993.Fluid immiscibility in late-Alpine gold-bearing veins,Eastern and Northwestern European Alps[J].Mineralium Deposita,28(1):28-36.
Fang G C,Chen Z H,Chen Y C,Huang F and Zhao Z.2011.Characteristics of primary for quartz vein-typetungsten deposits and its implication in locating ore bodies at depth[J].Geotectonica et Metallogenia,36(3):406-412(in Chinese with English abstract).
Feng C Y,She H Q,Zhang D Q,Li D X,Dong Y J,Mao J R,Chen XY,Xu J X,Wu J S,Du H Y,Zeng Z L and Li J W.2009.Studies of metallogenic rules and assessment of ore prospecting in the conjunction area of Fujian,Guangdong and Jiangxi Province[M].Beijing:Geology Press.1-304(in Chinese).
Garba I and Akande S O.1992.The origin and significance of nonaqueous CO2,fluid inclusions in the auriferous veins of Bin Yauri,northwestern Nigeria[J].Mineralium Deposita,27(3):249-255.
Guo C L,Wang D H,Chen Y C,Wang Y B,Chen Z H and Liu S B.2007.Precise zircon SHRIMP U-Pb and quartz vein Rb-Sr dating of Mesozoic Taoxikeng tungsten polymetallic deposit in southern Jiangxi[J].Mineral Deposits,26(4):432-442(in Chinese with English abstract).
Guo C L,Lin Z Y,Wang D H,Chen W,Zhang Y,Feng C Y,Chen Z H,Zeng Z L and Cai R Q.2008.Petrologic characteristics of the granites and greisen and muscovite 40Ar/39Ar dating in the Taoxikeng tungsten polymetallic deposit,southern Jiangxi Province[J].Acta Geologica Sinica,82(9):1274-1284(in Chinese with English abstract).
Guo C L,Chen Y C,Li C B,Chen Z H and Lou F S.2011.Zircon SHRIMP U-Pb dating,geochemistry Sr-Nd isotopic analysis of the late Jurassic granitoids in the Jiulongnao W-Sn-Pb-Zn ore-concentrated areas in Jiangxi Province and their geological significance[J].Acta Geologica Sinica,85(7):1188-1205(in Chinese with English abstract).
Hall D L,Sterner S M and Bodnar R J.1988.Freezing point depression of NaCl-KCl-H2O solutions[J].Econ.Geol.,83(1):197-202.
Higgins N C and Kerrich R.1982.Progressive 18O depletion during CO2separation from a carbon dioxide-rich hydrothermal fluid:Evidence from the Grey River tungsten deposit,Newfoundland[J].Canadian Journal of Earth Sciences,1990(12):2247-2257.
Higgins N C.1985.Wolframite deposition in a hydrothermal vein system:The Grey River tungsten prospect,Newfoundland,Canada[J].Econ.Geol.,80(5):1297-1327.
Hollister L S,Burruss R C,Henry D L and Hendel E M.1979.Physical conditions during uplift of metamorphic terranes,as recorded by fluid inclusions[J].Bull Mineral,102:555-561.
Huang H L,Chang H L,Li F,Zhang C H,Tan J and Zhou Y.2012.Acomparative study of fluid inclustions from coexisting transparent minerals in Xihuashan tungsten deposit[J].Mineral Deposits,31(6):1171-1183(in Chinese with English abstract).
Huang H L,Chang H L,Tan J,Li F,Zhang C H and Zhou Y.2015.Contrasting infrared microthermometry study of fluid inclusions in coexisting quartz,wolframite and other minerals:A case study of Xihuashan quartz-vein tungsten deposit,China[J].Acta Petrologica Sinica,31(4):925-940(in Chinese with English abstract).
Huang P Z,Wang X,Chen J,Ren M H and Lai G B.2012.Morphological and geochemical studies of the cassiterite in Taoxikeng tin deposit,southern Jiangxi,China[J].Geological Review,58(5):987-1000(in Chinese with English abstract).
Li J M,Li Y M,Lou F S,Hu Z H,Zhong Q H,Xie M M,Tang F L,Sha M,Yang X H,Liu X Y,Yi Y Q,Hu W J,Zhu Q M,Nie L M,Zhu C J,Wen L X,Zeng Q Q,Huang J C,Lei T H,Xie R F,Gong L X and Li J.2016.A“Five-storey”style quartz vein wolframite deposit in northern Jiangxi Province:The discovery of the Dongping wolframite deposit and its geological significance[J].Acta Geoscientica Sinica,37(3):379-384(in Chinese with English abstract).
Liu Y J.1982.Tungsten metallogenic geochemistry[J].Geology and Exploration,(1):17-25(in Chinese).
Liu Z Q,Liu S B,Liang T,Wang D H,Pei R F,Liang L J,Zhang S D,Liu X L,Peng Y X and Zhong X Y.2016.Structural analysis of Jiulongnao orefield in Nanling area:A case study on Taoxikeng tungsten deposit[J].Earth Science Frontiers,23(4):148-165(in Chinese with English abstract).
Lu H Z,Fan H R,Ni P,Ou X X,Shen K and Zhang W H.2004.Fluid inclusions[M].Beijing:Science Press.1-485(in Chinese).
Lu H Z.2011.Fluids immiscibility and fluid inclusions.Acta Petrologica Sinica,27(5):1253-1261(in Chinese with English abstract).
Ma D S.2009.Progress in research on geochemistry of tungsten[J].Geological Journal of China Universities,15(1):19-34(in Chinese with English abstract).
Ni P,Wang X D,Wang G G,Huang J B,Pan J Y and Wang T G.2015.An infrared microthermometric study of fluid inclusions in coexisting quartz and wolframite from Late Mesozoic tungsten deposits in the Gannan metallogenic belt,South China[J].Ore Geology Reviews,65:1062-1077.
Roedder E.1984.Fluid inclusions[M].Mineralogical Society of America,12:1-644.
Shan Q,Liao S P,Lu H Z,Li J K,Yang W B and Luo Y.2011.Fluid inclusion records from the magmatic to hydrothermal stage:A case study of Qitianling granite pluton[J].Acta Petrologica Sinica,27(5):1511-1520(in Chinese with English abstract).
Song S Q,Hu R Z,Bi X W,Wei W F and Shi S H.2011a.Fluid inclusion geochemistry of the Taoxikeng tungsten deposit in southern Jiangxi Province,China[J].Geochimica,40(3):237-248(in Chinese with English abstract).
Song S Q,Hu R Z,Bi X W,Wei W F and Shi S H.2011b.Hydrogen,oxygen and sulfur isotope geochemical characteristcs of Taoxikeng tungsten deposit in Chongyi County,southern Jiangxi Province.Mineral deposits,30(1):0-10(in Chinese with English abstract).
Wang D H,Tang J X,Ying L J,Chen Z H,Xu J X,Zhang J J,Li S Rand Zeng Z L.2010.Application of“Five levels+Basement”model for prospecting deposits into depth[J].Journal of Jilin University(Earth Science Edition),40(4):733-738(in Chinese with English abstract).
Wang D H,Liu L J,Hou J L,Dai H Z,Yu Y,Dai J J and Tian S H.2017.A preliminary review of the application of“Five levels+Basement”model for Jiajika-style rare metal deposits[J].Earth Science Frontiers,24(5):1-7(in Chinese with English abstract).
Wang G G,Ni P,Zhao K D,Liu J R,Xie G A,Xu J H and Zhang Z H.2011.Comparison of fluid inclusions in coexisting sphalerite quartz from Yinshan deposit,Dexing,northeast Jiangxi Province[J].Acta Petrologica Sinica,27(5):1387-1396(in Chinese with English abstract).
Wang Q Y,Lu Y F,Chen Z H,Peng X L and Xiong X F.2012.Fluid inclusion characteristic and its geological implication of the Taoxikeng tungsten deposit,southern Jiangxi Province[J].Geology and Mineral Resources of South China,28(1):35-44(in Chinese with English abstract).
Wang X D,Ni P,Zhang B S and Wang T G.2010.Fluid inclusion studies of the Pangushan quartz-vein type tungsten deposit in southern Jiangxi Province[J].Acta Petrologica et Mineralogica,29(5):539-550(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2012.Fluid inclusion studies of the Huangsha quartz-vein type tungsten deposit,Jiangxi Province[J].Acta Petrologica Sinica,28(1):122-132(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2013a.Fluid inclusion studies on coexiting cassiterite and quartz from the Piaotang tungsten deposit,Jiangxi Province,China[J].Acta Geologica Sinica,87(6):850-859(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2013b.Fluid inclusion studies of Dajishan tungsten deposit in Jiangxi Province[J].Mineral Deposit,32(2):308-322(in Chinese with English abstract).
Wei W F,Hu R Z,Bi X W,Peng J T,Su W C,Song S Q and Shi S H.2012.Infrared microthermometric and stable isotopic study of fluid inclusions in wolframite at the Xihuashan tungsten deposit,Jiangxi Province,China[J].Mineralium Deposita,47(6):589-605.
Wood S A and Samson I M.2000.The hydrothermal geochemistry of tungsten in granitoid environments:I.Relative solubilities of ferberite and scheelite as a function of T,P,pH,and mNaCl[J].Econ.Geol.,95(1):143-182.
Xu J X,Zeng Z L,Wang D H,Chen Z H,Liu S B,Wang C H and Ying L J.2008.A new type of tungsten deposit in southern Jiangxi and the new model of“Five Floors+Basement”for prospecting[J].Acta Geologica Sinica,82(7):880-887(in Chinese with English abstract).
Xu G and Pollard P J.1999.Origin of CO2-rich fluid inclusions in synorogenic veins from the eastern Mount Isa Fold Belt,NWQueensland,and their implications for mineralization[J].Mineralium Deposita,34:395-404.
Xu M L,Gao R G,Zou X P.The tungsten potential assessment report on Taoxikeng mining area,Chongyi County,Jiangxi Province.(Internal Data).
Yamamoto J J,Kagi H,Kaneoka I,Lai Y,Prikhod’ko V S and Arai S.2002.Fossil pressures of fluid inclusions in mantle xenoliths exhibiting rheology of mantle minerals:Implications for the geobarometry of mantle minerals using micro-Raman spectroscopy[J].Earth and Planetary Science Letters,198(3-4):511-519.
Yang S Y,Jiang S Y and Zhao K D.2015.Tourmaline as a recorder of magmatic-hydrothermal evolution:An in situ major and trace element analysis of tourmaline from the Qitianling batholith,South China[J].Contributions to Mineralogy and Petrology,170:42.
Yin X B,Zhang D H,Wang C S and Zhao G J.2011.Characteristics of fluid inclusion for typical tungsten,Stannary vein deposit and porphyry molybdenum deposit in China[J].Jounral of Guilin University of Technology,31(4):524-532(in Chinese with English abstract).
Yu Z F,Xu H,Zhu X Y,Wang Y L and Cheng X Y.2015.Characteristics and evolution of ore forming fluids in Yaogangxian tungsten deposit,Hunan Province[J].Mineral Deposits,34(2):309-320(in Chinese with English abstract).
Zhang D Q,Feng C Y,Li D X,Chen Y C and Zeng Z L.2012.Fluid inclusions characteristics and ore genesis of Taoxikeng tungsten and tin deposit in Chongyi County,Jiangxi Province[J].Journal of Jilin University,42(2):374-383(in Chinese with English abstract).
Zhu Y N and Peng J T.2015.Infrared microthermometric and noble gas isotope study of fluid inclusions in ore minerals at the Woxi orogenic Au-Sb-W deposit,western Hunan,South China[J].Ore Geology Reviews,65:55-69.
曹晓峰,吕新彪,何谋春,牛宏,杜保峰,梅徽.2009.共生黑钨矿与石英中流体包裹体红外显微对比研究--以瑶岗仙石英脉型钨矿床为例[J].矿床地质,28(5):611-620.
常海亮,汪雄武,王晓地,刘家齐,黄惠兰.2007.西华山黑钨矿-石英脉绿柱石中熔融包裹体的成分[J].岩石矿物学杂志,26(3):259-268.
陈郑辉,王登红,屈文俊,陈毓川,王平安,许建祥,张家菁,许敏林.2006.赣南崇义地区淘锡坑钨矿的地质特征与成矿时代[J].地质通报,25(4):496-501.
陈郑辉,王登红,刘善宝,王成辉,许建祥,曾载淋,屈文俊.2008.赣南淘锡坑钨矿的石英中子活化分析研究[J].地质学报,82(7):978-985.
陈郑辉,王登红,曾载淋,赵斌,陈毓川,方贵聪.2013.“五层楼+地下室”模式在南岭于都-赣县矿集区立体探测与深部成矿预测中的实践[J].地质论评,4(59):591-592.
池国祥,卢焕章.1991.流体相分离的深度(压力)-温度场特征及其对热液矿床定位的意义[J].矿物学报,(4):355-948.
方贵聪,陈郑辉,陈毓川,黄凡,赵正.2012.石英脉型钨矿原生晕特征及深部成矿定位预测-以赣南淘锡坑钨矿11号脉为例[J].大地构造与成矿学,36(3):406-412.
丰成友,佘宏全,张德全,李大新,董英君,毛建仁,陈祥云,许建祥,吴建设,杜海燕,曾载淋,李进文.2009.闽粤赣邻接区主要金属矿床的成矿规律及找矿评价[M].北京:地质出版社.1-304.
郭春丽,王登红,陈毓川,王彦斌,陈郑辉,刘善宝.2007.赣南中生代淘锡坑钨矿区花岗岩锆石SHRIMP年龄及石英脉Rb-Sr年龄测定[J].矿床地质,26(4):432-442.
郭春丽,蔺志永,王登红,陈文,张彦,丰成友,陈郑辉,曾载淋,蔡汝青.2008.赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年[J].地质学报,82(9):1274-1284.
郭春丽,陈毓川,黎传标,陈郑辉,楼法生.2011.赣南晚侏罗世九龙脑钨锡铅锌矿集区不同成矿类型花岗岩年龄、地球化学特征对比及其地质意义[J].地质学报,85(7):1188-1205.
黄惠兰,常海亮,李芳,张春红,谭靖,周云.2012.西华山钨矿床共生透明矿物与不透明矿物中流体包裹体的对比研究[J].矿床地质,31(6):1171-1183.
黄惠兰,常海亮,谭靖,李芳,张春红,周云.2015.共生黑钨矿与石英等多种矿物中流体包裹体的红外显微测温对比研究--以江西西华山石英脉钨矿床为例[J].岩石学报,31(4):925-940.
黄品赟,汪相,陈洁,任名华,赖光兵.2012.赣南淘锡坑锡矿床中锡石晶体形态学和地球化学研究[J].地质论评,58(5):987-1000.
李吉明,李永明,楼法生,胡正华,钟起泓,谢明明,唐峰林,沙珉,杨细浩,刘细元,易永清,胡文洁,朱庆敏,聂龙敏,朱昌杰,文亮先,曾庆权,黄建村,雷天浩,谢瑞丰,龚良信,李倩.2016.赣北发现“五层楼”式石英脉型黑钨矿矿床--东坪黑钨矿矿床的发现及其地质意义[J].地球学报,37(3):379-384.
刘英俊.1982.论钨的成矿地球化学[J].地质与勘探,(1):17-25.
刘战庆,刘善宝,梁婷,王登红,裴荣富,梁力杰,张树德,刘小林,彭瑜勋,钟先源.2016.南岭九龙脑矿田典型矿床构造解析:以淘锡坑钨矿床为例[J].地学前缘,23(4):148-165.
卢焕章,范宏瑞,倪培,欧光习,沈昆,张文淮.2004.流体包裹体[M].北京:科学出版社.1-485.
卢焕章.2011.流体不混溶性和流体包裹体[J].岩石学报,27(5):1253-1261.
马东升.2009.钨的地球化学研究进展[J].高校地质学报,15(1):19-34.
单强,廖思平,卢焕章,李建康,杨武斌,罗勇.2011.岩浆到热液演化的包裹体记录--以骑田岭花岗岩体为例[J].岩石学报,27(5):1511-1520.
宋生琼,胡瑞忠,毕献武,魏文凤,石少华.2011a.赣南淘锡坑钨矿床流体包裹体地球化学研究[J].地球化学,40(3):237-248.
宋生琼,胡瑞忠,毕献武,魏文凤,石少华.2011b.赣南崇义淘锡坑钨矿床氢-氧-硫同位素地球化学研究[J].矿床地质,30(1):0-10.
王登红,唐菊兴,应立娟,陈郑辉,许建祥,张家菁,李水如,曾载淋.2010.“五层楼+地下室”找矿模型的适用性及其对深部找矿的意义[J].吉林大学学报(地球科学版),40(4):733-738.
王登红,刘丽君,侯江龙,代鸿章,于扬,代晶晶,田世洪.2017.初论甲基卡式稀有金属矿床“五层楼+地下室”勘查模型[J].地学前缘,24(5):1-7.
王国光,倪培,赵葵东,刘家润,解国爱,徐积辉,张志辉.2011.江西银山铅锌矿床闪锌矿与石英流体包裹体的对比研究[J].岩石学报,27(5):1387-1396.
汪群英,路远发,陈郑辉,彭相林,雄险峰.2012.赣南淘锡坑钨矿床流体包裹体特征及其地质意义[J].华南地质与矿产,28(1):35-44.
王旭东,倪培,张伯声,王天刚.2010.江西盘古山石英脉型钨矿床流体包裹体研究[J].岩石矿物学杂志,29(5):539-550.
王旭东,倪培,袁顺达,吴胜华.2012.江西黄沙石英脉型钨矿床流体包裹体研究[J].岩石学报,28(1):122-132.
王旭东,倪培,袁顺达,吴胜华.2013a.赣南漂塘钨矿锡石及共生石英中流体包裹体研究[J].地质学报,87(6):850-859.
王旭东,倪培,袁顺达,吴胜华.2013b.江西大吉山钨多金属矿床流体包裹体研究[J].矿床地质,32(2):308-322.
许建祥,曾载淋,王登红,陈郑辉,刘善宝,王成辉,应丽娟.2008.赣南钨矿新类型及“五层楼+地下室”找矿模型[J].地质学报,82(7):880-887.
徐敏林,高贵荣,邹小平.2005.江西省崇义县淘锡坑矿区钨矿资源潜力评价报告.内部资料.
印贤波,张德会,王晨昇,赵关健.2011.中国典型脉型钨、锡矿床和斑岩钼矿流体包裹体特征[J].桂林理工大学学报,31(4):524-532.
于志峰,许虹,祝新友,王艳丽,程细音.2015.湖南瑶岗仙钨矿床成矿流体演化特征研究[J].矿床地质,34(2):309-320.
张大权,丰成友,李大新,陈毓川,曾载淋.2012.江西省崇义县淘锡坑钨锡矿床流体包裹体特征及矿床成因[J].吉林大学学报:地球科学版,42(2):374-383.
Cao X F,Lv X B,He M C,Niu H,Du B F and Mei H.2009.An infrared microscope investigation of fuid inclusions in coexisting quartz and wolframite:A case study of Yaogangxian quartz-vein wolframite deposit[J].Mineral Deposits,28(5):611-620(in Chinese with English abstract).
Chang H L,Wang X W,Wang X D,Liu J Q and Huang H L.2007.The composition of melt inclusions in beryl from wolframite-quartz veins in Xihuashan,Jiangxi Province[J].Acta Petrologica et Mineralogica,26(3):259-268(in Chinese with English abstract).
Chen Z H,Wang D H,Qu W J,Chen Y C,Wang P A,Xu J X,Zhang JJ and Xu M L.2006.Geological characteristics and mineralization age of the Taoxikeng tungsten deposit in Chongyi County,southern Jiangxi Province,China[J].Geological Bullentin of China,25(4):496-501(in Chinese with English abstract).
Chen Z H,Wang D H,Liu S B,Wang C H,Xu J X,Zeng Z L and Qu W J.2008.Neutron activion analysis study on quartz from the Taoxikeng tungsten deposit in southern Jiangxi,China[J].Acta Geologica Sinica,82(7):978-985(in Chinese with English abstract).
Chen Z H,Wang D H,Zeng Z L,Zhao B,Chen Y C,Fang G C.2013.Application of“Five levels+Basement”model for three-dimensional probe and prospecting deposits into depth in Yudu-Ganxian ore concentration of Nanling Region[J].Geological Review,4(Supp.59):591-592(in Chinese with English abstract).
Chi G X and Lu H Z.1991.Characteristics of fluid phase separation fields in a depth-temperature coordinate with emphasis on their significance in localization of hydrothermal deposits[J].Acta Mineralogica Sinica,(4):355-948(in Chinese with English abstract).
Craw D,Teagle D A H and Belocky R.1993.Fluid immiscibility in late-Alpine gold-bearing veins,Eastern and Northwestern European Alps[J].Mineralium Deposita,28(1):28-36.
Fang G C,Chen Z H,Chen Y C,Huang F and Zhao Z.2011.Characteristics of primary for quartz vein-typetungsten deposits and its implication in locating ore bodies at depth[J].Geotectonica et Metallogenia,36(3):406-412(in Chinese with English abstract).
Feng C Y,She H Q,Zhang D Q,Li D X,Dong Y J,Mao J R,Chen XY,Xu J X,Wu J S,Du H Y,Zeng Z L and Li J W.2009.Studies of metallogenic rules and assessment of ore prospecting in the conjunction area of Fujian,Guangdong and Jiangxi Province[M].Beijing:Geology Press.1-304(in Chinese).
Garba I and Akande S O.1992.The origin and significance of nonaqueous CO2,fluid inclusions in the auriferous veins of Bin Yauri,northwestern Nigeria[J].Mineralium Deposita,27(3):249-255.
Guo C L,Wang D H,Chen Y C,Wang Y B,Chen Z H and Liu S B.2007.Precise zircon SHRIMP U-Pb and quartz vein Rb-Sr dating of Mesozoic Taoxikeng tungsten polymetallic deposit in southern Jiangxi[J].Mineral Deposits,26(4):432-442(in Chinese with English abstract).
Guo C L,Lin Z Y,Wang D H,Chen W,Zhang Y,Feng C Y,Chen Z H,Zeng Z L and Cai R Q.2008.Petrologic characteristics of the granites and greisen and muscovite 40Ar/39Ar dating in the Taoxikeng tungsten polymetallic deposit,southern Jiangxi Province[J].Acta Geologica Sinica,82(9):1274-1284(in Chinese with English abstract).
Guo C L,Chen Y C,Li C B,Chen Z H and Lou F S.2011.Zircon SHRIMP U-Pb dating,geochemistry Sr-Nd isotopic analysis of the late Jurassic granitoids in the Jiulongnao W-Sn-Pb-Zn ore-concentrated areas in Jiangxi Province and their geological significance[J].Acta Geologica Sinica,85(7):1188-1205(in Chinese with English abstract).
Hall D L,Sterner S M and Bodnar R J.1988.Freezing point depression of NaCl-KCl-H2O solutions[J].Econ.Geol.,83(1):197-202.
Higgins N C and Kerrich R.1982.Progressive 18O depletion during CO2separation from a carbon dioxide-rich hydrothermal fluid:Evidence from the Grey River tungsten deposit,Newfoundland[J].Canadian Journal of Earth Sciences,1990(12):2247-2257.
Higgins N C.1985.Wolframite deposition in a hydrothermal vein system:The Grey River tungsten prospect,Newfoundland,Canada[J].Econ.Geol.,80(5):1297-1327.
Hollister L S,Burruss R C,Henry D L and Hendel E M.1979.Physical conditions during uplift of metamorphic terranes,as recorded by fluid inclusions[J].Bull Mineral,102:555-561.
Huang H L,Chang H L,Li F,Zhang C H,Tan J and Zhou Y.2012.Acomparative study of fluid inclustions from coexisting transparent minerals in Xihuashan tungsten deposit[J].Mineral Deposits,31(6):1171-1183(in Chinese with English abstract).
Huang H L,Chang H L,Tan J,Li F,Zhang C H and Zhou Y.2015.Contrasting infrared microthermometry study of fluid inclusions in coexisting quartz,wolframite and other minerals:A case study of Xihuashan quartz-vein tungsten deposit,China[J].Acta Petrologica Sinica,31(4):925-940(in Chinese with English abstract).
Huang P Z,Wang X,Chen J,Ren M H and Lai G B.2012.Morphological and geochemical studies of the cassiterite in Taoxikeng tin deposit,southern Jiangxi,China[J].Geological Review,58(5):987-1000(in Chinese with English abstract).
Li J M,Li Y M,Lou F S,Hu Z H,Zhong Q H,Xie M M,Tang F L,Sha M,Yang X H,Liu X Y,Yi Y Q,Hu W J,Zhu Q M,Nie L M,Zhu C J,Wen L X,Zeng Q Q,Huang J C,Lei T H,Xie R F,Gong L X and Li J.2016.A“Five-storey”style quartz vein wolframite deposit in northern Jiangxi Province:The discovery of the Dongping wolframite deposit and its geological significance[J].Acta Geoscientica Sinica,37(3):379-384(in Chinese with English abstract).
Liu Y J.1982.Tungsten metallogenic geochemistry[J].Geology and Exploration,(1):17-25(in Chinese).
Liu Z Q,Liu S B,Liang T,Wang D H,Pei R F,Liang L J,Zhang S D,Liu X L,Peng Y X and Zhong X Y.2016.Structural analysis of Jiulongnao orefield in Nanling area:A case study on Taoxikeng tungsten deposit[J].Earth Science Frontiers,23(4):148-165(in Chinese with English abstract).
Lu H Z,Fan H R,Ni P,Ou X X,Shen K and Zhang W H.2004.Fluid inclusions[M].Beijing:Science Press.1-485(in Chinese).
Lu H Z.2011.Fluids immiscibility and fluid inclusions.Acta Petrologica Sinica,27(5):1253-1261(in Chinese with English abstract).
Ma D S.2009.Progress in research on geochemistry of tungsten[J].Geological Journal of China Universities,15(1):19-34(in Chinese with English abstract).
Ni P,Wang X D,Wang G G,Huang J B,Pan J Y and Wang T G.2015.An infrared microthermometric study of fluid inclusions in coexisting quartz and wolframite from Late Mesozoic tungsten deposits in the Gannan metallogenic belt,South China[J].Ore Geology Reviews,65:1062-1077.
Roedder E.1984.Fluid inclusions[M].Mineralogical Society of America,12:1-644.
Shan Q,Liao S P,Lu H Z,Li J K,Yang W B and Luo Y.2011.Fluid inclusion records from the magmatic to hydrothermal stage:A case study of Qitianling granite pluton[J].Acta Petrologica Sinica,27(5):1511-1520(in Chinese with English abstract).
Song S Q,Hu R Z,Bi X W,Wei W F and Shi S H.2011a.Fluid inclusion geochemistry of the Taoxikeng tungsten deposit in southern Jiangxi Province,China[J].Geochimica,40(3):237-248(in Chinese with English abstract).
Song S Q,Hu R Z,Bi X W,Wei W F and Shi S H.2011b.Hydrogen,oxygen and sulfur isotope geochemical characteristcs of Taoxikeng tungsten deposit in Chongyi County,southern Jiangxi Province.Mineral deposits,30(1):0-10(in Chinese with English abstract).
Wang D H,Tang J X,Ying L J,Chen Z H,Xu J X,Zhang J J,Li S Rand Zeng Z L.2010.Application of“Five levels+Basement”model for prospecting deposits into depth[J].Journal of Jilin University(Earth Science Edition),40(4):733-738(in Chinese with English abstract).
Wang D H,Liu L J,Hou J L,Dai H Z,Yu Y,Dai J J and Tian S H.2017.A preliminary review of the application of“Five levels+Basement”model for Jiajika-style rare metal deposits[J].Earth Science Frontiers,24(5):1-7(in Chinese with English abstract).
Wang G G,Ni P,Zhao K D,Liu J R,Xie G A,Xu J H and Zhang Z H.2011.Comparison of fluid inclusions in coexisting sphalerite quartz from Yinshan deposit,Dexing,northeast Jiangxi Province[J].Acta Petrologica Sinica,27(5):1387-1396(in Chinese with English abstract).
Wang Q Y,Lu Y F,Chen Z H,Peng X L and Xiong X F.2012.Fluid inclusion characteristic and its geological implication of the Taoxikeng tungsten deposit,southern Jiangxi Province[J].Geology and Mineral Resources of South China,28(1):35-44(in Chinese with English abstract).
Wang X D,Ni P,Zhang B S and Wang T G.2010.Fluid inclusion studies of the Pangushan quartz-vein type tungsten deposit in southern Jiangxi Province[J].Acta Petrologica et Mineralogica,29(5):539-550(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2012.Fluid inclusion studies of the Huangsha quartz-vein type tungsten deposit,Jiangxi Province[J].Acta Petrologica Sinica,28(1):122-132(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2013a.Fluid inclusion studies on coexiting cassiterite and quartz from the Piaotang tungsten deposit,Jiangxi Province,China[J].Acta Geologica Sinica,87(6):850-859(in Chinese with English abstract).
Wang X D,Ni P,Yuan S D and Wu S H.2013b.Fluid inclusion studies of Dajishan tungsten deposit in Jiangxi Province[J].Mineral Deposit,32(2):308-322(in Chinese with English abstract).
Wei W F,Hu R Z,Bi X W,Peng J T,Su W C,Song S Q and Shi S H.2012.Infrared microthermometric and stable isotopic study of fluid inclusions in wolframite at the Xihuashan tungsten deposit,Jiangxi Province,China[J].Mineralium Deposita,47(6):589-605.
Wood S A and Samson I M.2000.The hydrothermal geochemistry of tungsten in granitoid environments:I.Relative solubilities of ferberite and scheelite as a function of T,P,pH,and mNaCl[J].Econ.Geol.,95(1):143-182.
Xu J X,Zeng Z L,Wang D H,Chen Z H,Liu S B,Wang C H and Ying L J.2008.A new type of tungsten deposit in southern Jiangxi and the new model of“Five Floors+Basement”for prospecting[J].Acta Geologica Sinica,82(7):880-887(in Chinese with English abstract).
Xu G and Pollard P J.1999.Origin of CO2-rich fluid inclusions in synorogenic veins from the eastern Mount Isa Fold Belt,NWQueensland,and their implications for mineralization[J].Mineralium Deposita,34:395-404.
Xu M L,Gao R G,Zou X P.The tungsten potential assessment report on Taoxikeng mining area,Chongyi County,Jiangxi Province.(Internal Data).
Yamamoto J J,Kagi H,Kaneoka I,Lai Y,Prikhod’ko V S and Arai S.2002.Fossil pressures of fluid inclusions in mantle xenoliths exhibiting rheology of mantle minerals:Implications for the geobarometry of mantle minerals using micro-Raman spectroscopy[J].Earth and Planetary Science Letters,198(3-4):511-519.
Yang S Y,Jiang S Y and Zhao K D.2015.Tourmaline as a recorder of magmatic-hydrothermal evolution:An in situ major and trace element analysis of tourmaline from the Qitianling batholith,South China[J].Contributions to Mineralogy and Petrology,170:42.
Yin X B,Zhang D H,Wang C S and Zhao G J.2011.Characteristics of fluid inclusion for typical tungsten,Stannary vein deposit and porphyry molybdenum deposit in China[J].Jounral of Guilin University of Technology,31(4):524-532(in Chinese with English abstract).
Yu Z F,Xu H,Zhu X Y,Wang Y L and Cheng X Y.2015.Characteristics and evolution of ore forming fluids in Yaogangxian tungsten deposit,Hunan Province[J].Mineral Deposits,34(2):309-320(in Chinese with English abstract).
Zhang D Q,Feng C Y,Li D X,Chen Y C and Zeng Z L.2012.Fluid inclusions characteristics and ore genesis of Taoxikeng tungsten and tin deposit in Chongyi County,Jiangxi Province[J].Journal of Jilin University,42(2):374-383(in Chinese with English abstract).
Zhu Y N and Peng J T.2015.Infrared microthermometric and noble gas isotope study of fluid inclusions in ore minerals at the Woxi orogenic Au-Sb-W deposit,western Hunan,South China[J].Ore Geology Reviews,65:55-69.
曹晓峰,吕新彪,何谋春,牛宏,杜保峰,梅徽.2009.共生黑钨矿与石英中流体包裹体红外显微对比研究--以瑶岗仙石英脉型钨矿床为例[J].矿床地质,28(5):611-620.
常海亮,汪雄武,王晓地,刘家齐,黄惠兰.2007.西华山黑钨矿-石英脉绿柱石中熔融包裹体的成分[J].岩石矿物学杂志,26(3):259-268.
陈郑辉,王登红,屈文俊,陈毓川,王平安,许建祥,张家菁,许敏林.2006.赣南崇义地区淘锡坑钨矿的地质特征与成矿时代[J].地质通报,25(4):496-501.
陈郑辉,王登红,刘善宝,王成辉,许建祥,曾载淋,屈文俊.2008.赣南淘锡坑钨矿的石英中子活化分析研究[J].地质学报,82(7):978-985.
陈郑辉,王登红,曾载淋,赵斌,陈毓川,方贵聪.2013.“五层楼+地下室”模式在南岭于都-赣县矿集区立体探测与深部成矿预测中的实践[J].地质论评,4(59):591-592.
池国祥,卢焕章.1991.流体相分离的深度(压力)-温度场特征及其对热液矿床定位的意义[J].矿物学报,(4):355-948.
方贵聪,陈郑辉,陈毓川,黄凡,赵正.2012.石英脉型钨矿原生晕特征及深部成矿定位预测-以赣南淘锡坑钨矿11号脉为例[J].大地构造与成矿学,36(3):406-412.
丰成友,佘宏全,张德全,李大新,董英君,毛建仁,陈祥云,许建祥,吴建设,杜海燕,曾载淋,李进文.2009.闽粤赣邻接区主要金属矿床的成矿规律及找矿评价[M].北京:地质出版社.1-304.
郭春丽,王登红,陈毓川,王彦斌,陈郑辉,刘善宝.2007.赣南中生代淘锡坑钨矿区花岗岩锆石SHRIMP年龄及石英脉Rb-Sr年龄测定[J].矿床地质,26(4):432-442.
郭春丽,蔺志永,王登红,陈文,张彦,丰成友,陈郑辉,曾载淋,蔡汝青.2008.赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年[J].地质学报,82(9):1274-1284.
郭春丽,陈毓川,黎传标,陈郑辉,楼法生.2011.赣南晚侏罗世九龙脑钨锡铅锌矿集区不同成矿类型花岗岩年龄、地球化学特征对比及其地质意义[J].地质学报,85(7):1188-1205.
黄惠兰,常海亮,李芳,张春红,谭靖,周云.2012.西华山钨矿床共生透明矿物与不透明矿物中流体包裹体的对比研究[J].矿床地质,31(6):1171-1183.
黄惠兰,常海亮,谭靖,李芳,张春红,周云.2015.共生黑钨矿与石英等多种矿物中流体包裹体的红外显微测温对比研究--以江西西华山石英脉钨矿床为例[J].岩石学报,31(4):925-940.
黄品赟,汪相,陈洁,任名华,赖光兵.2012.赣南淘锡坑锡矿床中锡石晶体形态学和地球化学研究[J].地质论评,58(5):987-1000.
李吉明,李永明,楼法生,胡正华,钟起泓,谢明明,唐峰林,沙珉,杨细浩,刘细元,易永清,胡文洁,朱庆敏,聂龙敏,朱昌杰,文亮先,曾庆权,黄建村,雷天浩,谢瑞丰,龚良信,李倩.2016.赣北发现“五层楼”式石英脉型黑钨矿矿床--东坪黑钨矿矿床的发现及其地质意义[J].地球学报,37(3):379-384.
刘英俊.1982.论钨的成矿地球化学[J].地质与勘探,(1):17-25.
刘战庆,刘善宝,梁婷,王登红,裴荣富,梁力杰,张树德,刘小林,彭瑜勋,钟先源.2016.南岭九龙脑矿田典型矿床构造解析:以淘锡坑钨矿床为例[J].地学前缘,23(4):148-165.
卢焕章,范宏瑞,倪培,欧光习,沈昆,张文淮.2004.流体包裹体[M].北京:科学出版社.1-485.
卢焕章.2011.流体不混溶性和流体包裹体[J].岩石学报,27(5):1253-1261.
马东升.2009.钨的地球化学研究进展[J].高校地质学报,15(1):19-34.
单强,廖思平,卢焕章,李建康,杨武斌,罗勇.2011.岩浆到热液演化的包裹体记录--以骑田岭花岗岩体为例[J].岩石学报,27(5):1511-1520.
宋生琼,胡瑞忠,毕献武,魏文凤,石少华.2011a.赣南淘锡坑钨矿床流体包裹体地球化学研究[J].地球化学,40(3):237-248.
宋生琼,胡瑞忠,毕献武,魏文凤,石少华.2011b.赣南崇义淘锡坑钨矿床氢-氧-硫同位素地球化学研究[J].矿床地质,30(1):0-10.
王登红,唐菊兴,应立娟,陈郑辉,许建祥,张家菁,李水如,曾载淋.2010.“五层楼+地下室”找矿模型的适用性及其对深部找矿的意义[J].吉林大学学报(地球科学版),40(4):733-738.
王登红,刘丽君,侯江龙,代鸿章,于扬,代晶晶,田世洪.2017.初论甲基卡式稀有金属矿床“五层楼+地下室”勘查模型[J].地学前缘,24(5):1-7.
王国光,倪培,赵葵东,刘家润,解国爱,徐积辉,张志辉.2011.江西银山铅锌矿床闪锌矿与石英流体包裹体的对比研究[J].岩石学报,27(5):1387-1396.
汪群英,路远发,陈郑辉,彭相林,雄险峰.2012.赣南淘锡坑钨矿床流体包裹体特征及其地质意义[J].华南地质与矿产,28(1):35-44.
王旭东,倪培,张伯声,王天刚.2010.江西盘古山石英脉型钨矿床流体包裹体研究[J].岩石矿物学杂志,29(5):539-550.
王旭东,倪培,袁顺达,吴胜华.2012.江西黄沙石英脉型钨矿床流体包裹体研究[J].岩石学报,28(1):122-132.
王旭东,倪培,袁顺达,吴胜华.2013a.赣南漂塘钨矿锡石及共生石英中流体包裹体研究[J].地质学报,87(6):850-859.
王旭东,倪培,袁顺达,吴胜华.2013b.江西大吉山钨多金属矿床流体包裹体研究[J].矿床地质,32(2):308-322.
许建祥,曾载淋,王登红,陈郑辉,刘善宝,王成辉,应丽娟.2008.赣南钨矿新类型及“五层楼+地下室”找矿模型[J].地质学报,82(7):880-887.
徐敏林,高贵荣,邹小平.2005.江西省崇义县淘锡坑矿区钨矿资源潜力评价报告.内部资料.
印贤波,张德会,王晨昇,赵关健.2011.中国典型脉型钨、锡矿床和斑岩钼矿流体包裹体特征[J].桂林理工大学学报,31(4):524-532.
于志峰,许虹,祝新友,王艳丽,程细音.2015.湖南瑶岗仙钨矿床成矿流体演化特征研究[J].矿床地质,34(2):309-320.
张大权,丰成友,李大新,陈毓川,曾载淋.2012.江西省崇义县淘锡坑钨锡矿床流体包裹体特征及矿床成因[J].吉林大学学报:地球科学版,42(2):374-383.