机动车尾气中挥发性羰基化合物分析研究进展
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摘要
挥发性羰基化合物是机动车尾气中主要成分之一,在大气化学过程中对人体健康危害极大,逐渐引起社会的关注。该研究介绍了机动车尾气挥发性羰基化合物的形成机理,综述了羰基化合物的检测、采集和分析方法的研究现状,最后展望了机动车尾气中羰基化合物检测分析方法的发展前景。
Volatile carbonyl compounds are important constituents of the motor vehicle exhaust and very harmful to human health in atmospheric chemical processes,which has attracted more and more attentions.This study described formation mechanism of volatile carbonyl compounds in vehicle exhaust,summarized the research status of detection,collection and analysis of carbonyl compounds.Finally,this study also provided the development of determination for carbonyl compounds.
Volatile carbonyl compounds are important constituents of the motor vehicle exhaust and very harmful to human health in atmospheric chemical processes,which has attracted more and more attentions.This study described formation mechanism of volatile carbonyl compounds in vehicle exhaust,summarized the research status of detection,collection and analysis of carbonyl compounds.Finally,this study also provided the development of determination for carbonyl compounds.
引文
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[2]Manoli E,Voutsa D,Samara C.Chemical characterization and source identification/apportionment of fine and coarse air particles in Thessaloniki,Greece[J].Atmospheric Environment,2002,36(6):949-961.
[3]Beer T,Grant T,Williams D,et al.Fuel-cycle greenhouse gas emissions from alternative fuels in Australian heavy vehicles[J].Atmospheric Environment,2002,36(4):753-763.
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[8]US.Environmental Protection Agency(EPA).Volatile Organic Compounds[DB/OL].http://www.epa.gov/cgi-bin/broker?service=data&debu g=0&program=dataprog.national1.sas&polchoice=VOC.2008.
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[14]Song C L,Zhao Z,Lv G,et al.Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend[J].Chemosphere,2010,79:1033-1039.
[15]Zhao H,Ge Y S,Tan J W,et al.Effects of different mixing ratios on emissions from passenger cars fueled with methanol/gasoline blends[J].Journal of Environmental Sciences,2011,23(11):1831-1838.
[16]Ho K F,Ho S S H,Cheng Y,et al.Real-world emission factors of fifteen carbonyl compounds measured in a Hong Kong tunnel[J].Atmospheric Environment,2007,41:1747-1758.
[17]Pierson W R,Gertler A W,Robinson N F,et al.Real-world automotive emissions-summary of studies in the Fort McHenry and Tuscarora Mountain tunnels[J].Atmospheric Environment,1996,30:2233-2256.
[18]Andrew J,Kean,Gresjean E,et al.On-Road Measurement of Carbonlyls in California Light-Duty Vehicle Emissions[J].Environmental Science&Technology,2001,35:4198-4204.
[19]Ameur-Bouddabbous I,Kasperel J,Barbier J,et al.Transverse approach between real world concentrations of SO2,NO2,BTEX,aldehyde emissions and corrosion in the Grand Mare tunnel[J].Journal of Environmental Sciences,2012,24(7):1240-1250.
[20]Karavalakis G,Durbin T D,Shrivastava M,et al.Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles[J].Fuel,2012,93:549-558.
[21]Adam T W,Astorga C,Clairotte M,et al.Chemical analysis and ozone formation potential of exhaust from dual-fuel(liquefied petroleum gas/gasoline)light duty vehicles[J].Atmospheric Environment,2011,45:2842-2848.
[22]Sawant A A,Shah S D,Zhu X N,et al.Real-world emissions of carbonyl compounds from in-use heavy-duty diesel trucks and diesel Back-Up Generators(BUGs)[J].Atmospheric Environment,2007,41:4535-4547.
[23]GB18285-2005,点燃式发动机排气污染排放限值及测量方法[S].
[24]GB3847-2005,车用压燃式发动机汽车排气烟度排放限值及测量方法[S].
[25]Chi Y,Feng Y,Wen S,et al.Determination of carbonyl compounds in the atmosphere by DNPH derivatization and LC–ESI-MS/MS detection[J].Talanta,2007,72:539-545.
[26]Feng Y L,Mu C C,Zhai J,et al.Characteristics and personal exposures of carbonyl compounds in the subway stations and in-subway trains of Shanghai,China[J].Journal of Hazardous Materials,2010,183(1-3):547-582.
[27]Pang X,Lewis A C,Hamilton J F.Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC–MS and its comparison with HPLC method[J].Talanta,2011,85(15):406-414.
[28]周咪.广州机动车尾气中挥发性羰基化合物检测及排放清单研究[D].广州:暨南大学,2012.
[2]Manoli E,Voutsa D,Samara C.Chemical characterization and source identification/apportionment of fine and coarse air particles in Thessaloniki,Greece[J].Atmospheric Environment,2002,36(6):949-961.
[3]Beer T,Grant T,Williams D,et al.Fuel-cycle greenhouse gas emissions from alternative fuels in Australian heavy vehicles[J].Atmospheric Environment,2002,36(4):753-763.
[4]Cardone M,Mazzoncini M,Seggiani M,et al.Brassica carinata as an alternative oil crop for the production of biodiesel in Italy:engine performance and regulated and unregulated exhaust emission[J].Environmental Science and Technology,2003,36(6):4656-4662.
[5]Georgios K,Vasiliki B,Stamoulis S,et al.Biodiesel emissions profile in modern diesel vehicles.Part 2:Effect of biodiesel origin on carbonyl,PAH,nitro-PAH and oxy-PAH emissions[J].Science of the Total Environment,2011,409:738-747.
[6]Chao H R,Lin T C,Chao M R,et al.Effect of methanol-containing additive on the emission of carbonyl compounds from a heavy-duty diesel engine[J].Journal of Hazardous Materials B73,2000:39-54.
[7]Payri F,Bermu′dez V R,Tormos B,et al.Hydrocarbon emissions speciation in diesel and biodiesel exhausts[J].Atmospheric Environment,2009,43(6):1273-1279.
[8]US.Environmental Protection Agency(EPA).Volatile Organic Compounds[DB/OL].http://www.epa.gov/cgi-bin/broker?service=data&debu g=0&program=dataprog.national1.sas&polchoice=VOC.2008.
[9]Bakeas E B,Argyris D I,Siskos P A,et al.Carbonyl compounds in the urban environment of Athens,Greece[J].Chemosphere,2003,52(5):805-13.
[10]Geller M D,Ntziachristos L,Mamakos A,et al.Physicochemical and redox characteristics of particulate matter(PM)emitted from gasoline and diesel passenger cars[J].Atmospheric Environment,2006,40(36):6988-7004.
[11]Grosjean D,Grosjean E,Gertler A W.On-road emissions of carbonyls from light-duty and heavy-duty vehicles[J].Environmental Science and Technology,2001,35:45-53.
[12]Ballesteros R,Hernández J J,Guillén-Flores J.Carbonyls speciation in a typical European automotive diesel engine using bioethanol/butanol-diesel blends[J].Fuel,2012,95:136-145.
[13]Guarieiro L L N,Souza A F,Torres E A,et al.Emission profile of 18carbonyl compounds,CO,CO2,and NOx emitted by a diesel engine fuelled with diesel and ternary blends containing diesel,ethanol and biodiesel or vegetable oils[J].Atmospheric Environment,2009,43:2754-2761.
[14]Song C L,Zhao Z,Lv G,et al.Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend[J].Chemosphere,2010,79:1033-1039.
[15]Zhao H,Ge Y S,Tan J W,et al.Effects of different mixing ratios on emissions from passenger cars fueled with methanol/gasoline blends[J].Journal of Environmental Sciences,2011,23(11):1831-1838.
[16]Ho K F,Ho S S H,Cheng Y,et al.Real-world emission factors of fifteen carbonyl compounds measured in a Hong Kong tunnel[J].Atmospheric Environment,2007,41:1747-1758.
[17]Pierson W R,Gertler A W,Robinson N F,et al.Real-world automotive emissions-summary of studies in the Fort McHenry and Tuscarora Mountain tunnels[J].Atmospheric Environment,1996,30:2233-2256.
[18]Andrew J,Kean,Gresjean E,et al.On-Road Measurement of Carbonlyls in California Light-Duty Vehicle Emissions[J].Environmental Science&Technology,2001,35:4198-4204.
[19]Ameur-Bouddabbous I,Kasperel J,Barbier J,et al.Transverse approach between real world concentrations of SO2,NO2,BTEX,aldehyde emissions and corrosion in the Grand Mare tunnel[J].Journal of Environmental Sciences,2012,24(7):1240-1250.
[20]Karavalakis G,Durbin T D,Shrivastava M,et al.Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles[J].Fuel,2012,93:549-558.
[21]Adam T W,Astorga C,Clairotte M,et al.Chemical analysis and ozone formation potential of exhaust from dual-fuel(liquefied petroleum gas/gasoline)light duty vehicles[J].Atmospheric Environment,2011,45:2842-2848.
[22]Sawant A A,Shah S D,Zhu X N,et al.Real-world emissions of carbonyl compounds from in-use heavy-duty diesel trucks and diesel Back-Up Generators(BUGs)[J].Atmospheric Environment,2007,41:4535-4547.
[23]GB18285-2005,点燃式发动机排气污染排放限值及测量方法[S].
[24]GB3847-2005,车用压燃式发动机汽车排气烟度排放限值及测量方法[S].
[25]Chi Y,Feng Y,Wen S,et al.Determination of carbonyl compounds in the atmosphere by DNPH derivatization and LC–ESI-MS/MS detection[J].Talanta,2007,72:539-545.
[26]Feng Y L,Mu C C,Zhai J,et al.Characteristics and personal exposures of carbonyl compounds in the subway stations and in-subway trains of Shanghai,China[J].Journal of Hazardous Materials,2010,183(1-3):547-582.
[27]Pang X,Lewis A C,Hamilton J F.Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC–MS and its comparison with HPLC method[J].Talanta,2011,85(15):406-414.
[28]周咪.广州机动车尾气中挥发性羰基化合物检测及排放清单研究[D].广州:暨南大学,2012.