高磁感取向硅钢研发现状与展望
|
摘要
阐述了近年来国内取向硅钢的生产现状和取向硅钢渗氮工艺的进展,分析概括了主要生产企业的技术特点与专利储备情况。随着市场需求的变化,中国取向硅钢产能中高磁感取向硅钢占比越来越高,生产企业的专利布局也转向高磁感取向硅钢的开发,环保型产品的开发也成为了新的热点。薄板坯连铸连轧和双辊薄带连铸工艺在高磁感取向硅钢上的开发已有很大进展,但商业应用仍有相当距离。同时,展望了高磁感取向硅钢未来的发展趋势。
The present production status including nitriding process development of high magnetic induction grainoriented silicon steel(Hi-B)in China are summarized,and the relevant technologies and the corresponding patent reserves in some major electrical steel producers are analyzed.With the change of market demand,the proportion of high permeability oriented silicon steel is getting higher.The patent layout of production enterprises has also turned to the development of Hi-B steel.The development of environmentally-friendly products has become a new focus.Although Hi-B production using the thin slab casting and direct rolling and the twin-roll strip casting processes has made great progress,there are still considerable distances for commercial applications.The future development of high permeability oriented silicon steel is discussed.
The present production status including nitriding process development of high magnetic induction grainoriented silicon steel(Hi-B)in China are summarized,and the relevant technologies and the corresponding patent reserves in some major electrical steel producers are analyzed.With the change of market demand,the proportion of high permeability oriented silicon steel is getting higher.The patent layout of production enterprises has also turned to the development of Hi-B steel.The development of environmentally-friendly products has become a new focus.Although Hi-B production using the thin slab casting and direct rolling and the twin-roll strip casting processes has made great progress,there are still considerable distances for commercial applications.The future development of high permeability oriented silicon steel is discussed.
引文
[1] Goss N P.New development in electrical strip steels characterized by fine grain structure approaching the properties of a single crystal[J].Trans Amer Soc Metals,1935,23(1):511.
[2]何忠治,赵宇,罗海文.电工钢[M].北京:冶金工业出版社,2012.
[3] WANG Y P,LIU H T,SONG H Y,et al.Ultra-thin grainoriented silicon steel sheet fabricated by a novel way:Twinroll strip casting and two-stage cold rolling[J].Journal of Magnetism and Magnetic Materials,2018,452:288.
[4] HUANG W,LI G,ZHANG X,et al.Fast-speed laser scoring method:US,Patent 9,604,312[P].2017-03-28.
[5] Maleki A,Taherizadeh A,Hosseini N,et al.Twin roll casting of steels:An overview[J].ISIJ International,2017,57(1):1.
[6]王若平,毛炯辉,方泽民,等.高磁感取向硅钢带的生产方法:中国,CN101775547A[P].2012-11-21.
[7]叶影萍,方泽民,郭小龙,等.一种高磁感取向硅钢及生产方法:中国,CN103695791A[P].2014-04-02.
[8]储双杰,吉亚明,孙业中,等.具有优异磁性能和良好底层的高磁感取向硅钢生产方法:中国,CN102758127A[P].2012-10-31.
[9]刘献东,孙焕德,张丕军,等.一种取向硅钢及其生产方法和装置:中国,CN100381598C[P].2006-07-05.
[10]倪献娟,夏兆所,周谊军,等.一种低温取向电工钢的生产方法:中国,CN101358273A[P].2009-02-04.
[11]夏兆所,倪献娟,许学勇,等.一种低温加热取向电工钢的生产方法:中国,CN101348854A[P].2009-01-21.
[12]冯莉莉,王全礼,许学勇,等.一种高磁感取向硅钢的生产方法:中国,CN102041440A[P].2011-05-04.
[13]蒋奇武,金文旭,庞树芳,等.一种低温加热生产高磁感取向硅钢的方法:中国,CN101748259A[P].2010-06-23.
[14] Takahashi N,Harase J.Recent development of technology of grain oriented silicon steel[J].Materials Science Forum Trans Tech Publications,1996(204/205/206):143.
[15] Yashiki H,Kaneko T.Secondary recrystallization behavior and magnetic properties of grain oriented 2.2%Si-1.5%Mn steel[J].Journal of Applied Physics,1993,73(10):6606.
[16] Takahashi N,Suga Y,Kobayashi H.Recent developments in grain-oriented silicon-steel[J].Journal of Magnetism and Magnetic Materials,1996,160(7):98.
[17]王瑞,杨平,刘恭涛.渗氮温度对获得抑制剂取向硅钢粒子析出及退火组织的影响[J].中国体视学与图像分析,2016(3):272.
[18] Takahashi N,Kuroki K,Suga Y,et al.Process for preparing unidirectional silicon steel sheet having high magnetic flux density:US,Patent 5049205[P].1991-09-17.
[19] Shingaki Y,Inoue H.Method for manufacturing grain-oriented electrical steel sheet,and nitriding apparatus:US,Patent Application 15/502,259[P].2017-08-10.
[20] Murakami K,Ushigami Y,Takahashi F.Manufacturing method of grain-oriented electrical steel sheet:US,Patent Application 14/414,845[P].2015-06-18.
[21] Iwanaga I,Ushigami Y,Fujii N,et al.Method of manufacturing grain-oriented electrical steel sheet:US,Patent Application 148/208,230[P].2014-07-15.
[22] Lee C S,Han C H,Woo J S,et al.Method for manufacturing high magnetic flux density grain oriented electrical steel sheet based on low temperature slab heating method:中国,CN1231001A[P].1999-10-06.
[23] Song D H.Oriented electrical steel sheet with excellent magnetic properties and method for manufacturing same:US,Patent Application 15/539,665[P].2017-12-28.
[24] Han K S,Joo H D,Park J T,et al.Grain-oriented electrical steel sheet and manufacturing method therefor:US,Patent Application 15/537,749[P].2018-01-04.
[25]路林林,李国保,孙焕德,等.一种具有良好底层的低温加热生产取向硅钢的方法:中国,CN1978707[P].2007-06-13.
[26]张丕军,刘献东,陈晓,等.一种取向硅钢及其生产方法和装置:中国,CN1796587A[P].2006-07-05.
[27]王若平,毛炯辉,方泽民,等.低渗氮量高磁感取向硅钢带的生产方法:中国,CN101775548A[P].2010-07-14.
[28] Boettcher A,Lahn L,Inden G,et al.Method for producing a grain-oriented electrical steel strip or sheet intended for electrotechnical applications:US,Patent Application 14/347,679[P].2014-08-21.
[29] LIAO C C,HOU C K.Effect of nitriding time on secondary recrystallization behaviors and magnetic properties of grainoriented electrical steel[J].Journal of Magnetism and Magnetic Materials,2010,322(4):434.
[30]张洁清,赵仁南.一种利用纳米复合电沉积技术对取向硅钢渗氮的方法:中国,CN103436943A[P].2013-12-11.
[31] Matsuda H,Takahashi H,Yamaguchi H,et al.Method and device for nitriding grain-oriented electrical steel sheet:US,Patent Application 14/764,650[P].2015-12-24.
[32]刘献东,吴培文,孙焕德,等.一种取向硅钢的渗氮方法:中国,CN101294268B[P].2008-10-29.
[33] Matsuda H,Takahashi H,Yamaguchi H,et al.Apparatus and method for nitriding grain-oriented electrical steel sheet:US,Patent Application 14/761,707[P].2015-12-17.
[34] Miller Jr C L.Use of nitrogen-bearing base coatings in the manufacture of high permeability silicon steel:US,Patent 4,171,994[P].1979-10-23.
[35] Choby Jr E G.Processing for aluminum nitride inhibited oriented silicon steel:US,Patent 4,010,050[P].1977-03-01.
[36] XU Q,SHEN K,LI G,et al.Method for manufacturing oriented silicon steel product with high magnetic-flux density:US,Patent Application 13/823,424[P].2013-09-12.
[37] Komatsu H,Tanino M,Suga Y,et al.Method for producing a grain-oriented electrical steel sheet:US,Patent 4,929,286[P].1990-05-29.
[38] Günther K,Schrapers H.Process for the coating of electrical steel strips with an annealing separator:US,Patent 6,423,156[P].2002-07-23.
[39]胡守天,孔祥华,李平和,等.取向硅钢绝缘涂层结构及其对铁芯损耗的影响[J].工程科学学报,2009,31(10):1277.
[40] Sundermeier U,Wark R,Hochstrate R.Chromium-free coating for the electrical insulation of grain-oriented electrical steel strip:US,Patent Application 14/936,175[P].2016-03-03.
[41] Han M S,Kim J W,Kwon M S,et al.Non-chromium coating agent for a grain-oriented electrical steel sheet,preparation method thereof,electrical steel sheet using the same,and manufacturing method thereof:WO,2010016658A3[P].2010-02-11.
[42] Inokuti Y,Suzuki K,Kobayashi Y.Effect of difference in ion plating method on the magnetic properties of TiN-coated grain oriented silicon steel sheet[J].Materials Transactions,JIM,2007,36(8):1081.
[43] Günther K,Abbruzzese G,Fortunati S,et al.Recent technology developments in the production of grain oriented electrical steel[J].Steel Research International,2005,76(6):413.
[44] K·京特,L·拉恩,A·普洛赫,等.生产晶粒取向的电工带钢的方法:中国,CN101238226[P].2008-08-06.
[45]陈圣林,方泽民,骆忠汉,等.一种用薄板坯连铸连轧生产高磁感取向硅钢的方法:中国,CN102517429A[P].2012-06-27.
[46]仇圣桃,周明伟,贾友生,等.一种薄板坯连铸连轧高磁感取向硅钢及其制备方法:中国,CN103774042A[P].2014-05-07.
[47] Sosinsky D J,Campbell P,Mahapatra R,et al.The CASTRIP?process-recent developments at nucor steel′s commercial strip casting plant[J].Metallurgist,2008,52(11/12):691.
[48] LIU H T,LIU Z Y,QIU Y Q,et al.Characterization of the solidification structure and texture development of ferritic stainless steel produced by twin-roll strip casting[J].Materials characterization,2009,60(1):79.
[49] LIU H,LIU Z,CAO G,et al.Microstructure and texture evolution of strip casting 3wt%Si non-oriented silicon steel with columnar structure[J].Journal of Magnetism and Magnetic Materials,2011,323(21):2648.
[50] WANG X,LI H,LIU Z,et al.Effect of cooling rate on bending behavior of 6.5wt.%Si electrical steel thin sheets fabricated by strip casting and rolling[J].Materials Characterization,2016,111:67.
[51] SONG H Y,LIU H T,LIU W Q,et al.Effects of two-stage cold rolling schedule on microstructure and texture evolution of strip casting grain-oriented silicon steel with extra-low carbon[J].Metallurgical and Materials Transactions A,2012,47(4):1.
[52] SONG H Y,LIU H T,LU H H,et al.Fabrication of grainoriented silicon steel by a novel way:Strip casting process[J].Materials Letters,2014,137:475.
[2]何忠治,赵宇,罗海文.电工钢[M].北京:冶金工业出版社,2012.
[3] WANG Y P,LIU H T,SONG H Y,et al.Ultra-thin grainoriented silicon steel sheet fabricated by a novel way:Twinroll strip casting and two-stage cold rolling[J].Journal of Magnetism and Magnetic Materials,2018,452:288.
[4] HUANG W,LI G,ZHANG X,et al.Fast-speed laser scoring method:US,Patent 9,604,312[P].2017-03-28.
[5] Maleki A,Taherizadeh A,Hosseini N,et al.Twin roll casting of steels:An overview[J].ISIJ International,2017,57(1):1.
[6]王若平,毛炯辉,方泽民,等.高磁感取向硅钢带的生产方法:中国,CN101775547A[P].2012-11-21.
[7]叶影萍,方泽民,郭小龙,等.一种高磁感取向硅钢及生产方法:中国,CN103695791A[P].2014-04-02.
[8]储双杰,吉亚明,孙业中,等.具有优异磁性能和良好底层的高磁感取向硅钢生产方法:中国,CN102758127A[P].2012-10-31.
[9]刘献东,孙焕德,张丕军,等.一种取向硅钢及其生产方法和装置:中国,CN100381598C[P].2006-07-05.
[10]倪献娟,夏兆所,周谊军,等.一种低温取向电工钢的生产方法:中国,CN101358273A[P].2009-02-04.
[11]夏兆所,倪献娟,许学勇,等.一种低温加热取向电工钢的生产方法:中国,CN101348854A[P].2009-01-21.
[12]冯莉莉,王全礼,许学勇,等.一种高磁感取向硅钢的生产方法:中国,CN102041440A[P].2011-05-04.
[13]蒋奇武,金文旭,庞树芳,等.一种低温加热生产高磁感取向硅钢的方法:中国,CN101748259A[P].2010-06-23.
[14] Takahashi N,Harase J.Recent development of technology of grain oriented silicon steel[J].Materials Science Forum Trans Tech Publications,1996(204/205/206):143.
[15] Yashiki H,Kaneko T.Secondary recrystallization behavior and magnetic properties of grain oriented 2.2%Si-1.5%Mn steel[J].Journal of Applied Physics,1993,73(10):6606.
[16] Takahashi N,Suga Y,Kobayashi H.Recent developments in grain-oriented silicon-steel[J].Journal of Magnetism and Magnetic Materials,1996,160(7):98.
[17]王瑞,杨平,刘恭涛.渗氮温度对获得抑制剂取向硅钢粒子析出及退火组织的影响[J].中国体视学与图像分析,2016(3):272.
[18] Takahashi N,Kuroki K,Suga Y,et al.Process for preparing unidirectional silicon steel sheet having high magnetic flux density:US,Patent 5049205[P].1991-09-17.
[19] Shingaki Y,Inoue H.Method for manufacturing grain-oriented electrical steel sheet,and nitriding apparatus:US,Patent Application 15/502,259[P].2017-08-10.
[20] Murakami K,Ushigami Y,Takahashi F.Manufacturing method of grain-oriented electrical steel sheet:US,Patent Application 14/414,845[P].2015-06-18.
[21] Iwanaga I,Ushigami Y,Fujii N,et al.Method of manufacturing grain-oriented electrical steel sheet:US,Patent Application 148/208,230[P].2014-07-15.
[22] Lee C S,Han C H,Woo J S,et al.Method for manufacturing high magnetic flux density grain oriented electrical steel sheet based on low temperature slab heating method:中国,CN1231001A[P].1999-10-06.
[23] Song D H.Oriented electrical steel sheet with excellent magnetic properties and method for manufacturing same:US,Patent Application 15/539,665[P].2017-12-28.
[24] Han K S,Joo H D,Park J T,et al.Grain-oriented electrical steel sheet and manufacturing method therefor:US,Patent Application 15/537,749[P].2018-01-04.
[25]路林林,李国保,孙焕德,等.一种具有良好底层的低温加热生产取向硅钢的方法:中国,CN1978707[P].2007-06-13.
[26]张丕军,刘献东,陈晓,等.一种取向硅钢及其生产方法和装置:中国,CN1796587A[P].2006-07-05.
[27]王若平,毛炯辉,方泽民,等.低渗氮量高磁感取向硅钢带的生产方法:中国,CN101775548A[P].2010-07-14.
[28] Boettcher A,Lahn L,Inden G,et al.Method for producing a grain-oriented electrical steel strip or sheet intended for electrotechnical applications:US,Patent Application 14/347,679[P].2014-08-21.
[29] LIAO C C,HOU C K.Effect of nitriding time on secondary recrystallization behaviors and magnetic properties of grainoriented electrical steel[J].Journal of Magnetism and Magnetic Materials,2010,322(4):434.
[30]张洁清,赵仁南.一种利用纳米复合电沉积技术对取向硅钢渗氮的方法:中国,CN103436943A[P].2013-12-11.
[31] Matsuda H,Takahashi H,Yamaguchi H,et al.Method and device for nitriding grain-oriented electrical steel sheet:US,Patent Application 14/764,650[P].2015-12-24.
[32]刘献东,吴培文,孙焕德,等.一种取向硅钢的渗氮方法:中国,CN101294268B[P].2008-10-29.
[33] Matsuda H,Takahashi H,Yamaguchi H,et al.Apparatus and method for nitriding grain-oriented electrical steel sheet:US,Patent Application 14/761,707[P].2015-12-17.
[34] Miller Jr C L.Use of nitrogen-bearing base coatings in the manufacture of high permeability silicon steel:US,Patent 4,171,994[P].1979-10-23.
[35] Choby Jr E G.Processing for aluminum nitride inhibited oriented silicon steel:US,Patent 4,010,050[P].1977-03-01.
[36] XU Q,SHEN K,LI G,et al.Method for manufacturing oriented silicon steel product with high magnetic-flux density:US,Patent Application 13/823,424[P].2013-09-12.
[37] Komatsu H,Tanino M,Suga Y,et al.Method for producing a grain-oriented electrical steel sheet:US,Patent 4,929,286[P].1990-05-29.
[38] Günther K,Schrapers H.Process for the coating of electrical steel strips with an annealing separator:US,Patent 6,423,156[P].2002-07-23.
[39]胡守天,孔祥华,李平和,等.取向硅钢绝缘涂层结构及其对铁芯损耗的影响[J].工程科学学报,2009,31(10):1277.
[40] Sundermeier U,Wark R,Hochstrate R.Chromium-free coating for the electrical insulation of grain-oriented electrical steel strip:US,Patent Application 14/936,175[P].2016-03-03.
[41] Han M S,Kim J W,Kwon M S,et al.Non-chromium coating agent for a grain-oriented electrical steel sheet,preparation method thereof,electrical steel sheet using the same,and manufacturing method thereof:WO,2010016658A3[P].2010-02-11.
[42] Inokuti Y,Suzuki K,Kobayashi Y.Effect of difference in ion plating method on the magnetic properties of TiN-coated grain oriented silicon steel sheet[J].Materials Transactions,JIM,2007,36(8):1081.
[43] Günther K,Abbruzzese G,Fortunati S,et al.Recent technology developments in the production of grain oriented electrical steel[J].Steel Research International,2005,76(6):413.
[44] K·京特,L·拉恩,A·普洛赫,等.生产晶粒取向的电工带钢的方法:中国,CN101238226[P].2008-08-06.
[45]陈圣林,方泽民,骆忠汉,等.一种用薄板坯连铸连轧生产高磁感取向硅钢的方法:中国,CN102517429A[P].2012-06-27.
[46]仇圣桃,周明伟,贾友生,等.一种薄板坯连铸连轧高磁感取向硅钢及其制备方法:中国,CN103774042A[P].2014-05-07.
[47] Sosinsky D J,Campbell P,Mahapatra R,et al.The CASTRIP?process-recent developments at nucor steel′s commercial strip casting plant[J].Metallurgist,2008,52(11/12):691.
[48] LIU H T,LIU Z Y,QIU Y Q,et al.Characterization of the solidification structure and texture development of ferritic stainless steel produced by twin-roll strip casting[J].Materials characterization,2009,60(1):79.
[49] LIU H,LIU Z,CAO G,et al.Microstructure and texture evolution of strip casting 3wt%Si non-oriented silicon steel with columnar structure[J].Journal of Magnetism and Magnetic Materials,2011,323(21):2648.
[50] WANG X,LI H,LIU Z,et al.Effect of cooling rate on bending behavior of 6.5wt.%Si electrical steel thin sheets fabricated by strip casting and rolling[J].Materials Characterization,2016,111:67.
[51] SONG H Y,LIU H T,LIU W Q,et al.Effects of two-stage cold rolling schedule on microstructure and texture evolution of strip casting grain-oriented silicon steel with extra-low carbon[J].Metallurgical and Materials Transactions A,2012,47(4):1.
[52] SONG H Y,LIU H T,LU H H,et al.Fabrication of grainoriented silicon steel by a novel way:Strip casting process[J].Materials Letters,2014,137:475.