二元羧酸盐类聚丙烯β成核剂研究进展
|
摘要
概述了聚丙烯β成核剂的发展概况,重点介绍了脂肪族二元羧酸及其盐类聚丙烯β成核剂和芳香族二元羧酸及其盐类聚丙烯β成核剂的研究现状及其对聚丙烯性能的影响,简述了二元羧酸盐类β晶型成核剂在聚丙烯高性能化方面的应用情况,并对其发展前景作了展望。
General situation of polypropylene β-nucleating agents was reviewed.Research situation of aliphatic dicarboxylate and aromatic dicarboxylate and their influence on the properties of polypropylene were introduced.Application of dicarboxylate in the high-performance polypropylene was summarized.Finally,the development trend of β-nucleating agents was discussed.
General situation of polypropylene β-nucleating agents was reviewed.Research situation of aliphatic dicarboxylate and aromatic dicarboxylate and their influence on the properties of polypropylene were introduced.Application of dicarboxylate in the high-performance polypropylene was summarized.Finally,the development trend of β-nucleating agents was discussed.
引文
[1]刘晓霞,张普玉.β晶型成核剂对聚丙烯力学及结晶性能的影响[J].应用化学,2006,23(11):1269-1272.Liu Xiaoxia,Zhang Puyu.The Influence ofβ-Nucleating Agents on Mechanical Properties and Melting Crystallization Behavior of Polypropylene[J]Chinese Journal of Applied Chemistry,2006,23(11):1269-1272.
[2]何叶尔,李力.聚丙烯树脂的加工和应用[M].第二版.北京:中国石油化工出版社:1998:1-3.
[3]王坷,史贞,王建民.PP增韧技术的研究进展[J].合成树脂及塑料.1996,13(3):58-61.Wang Ke,Shi Zhen,Wang Jianmin.Progress of the Studyon the Toughening of Polypropylene[J].Synth Resin Plast,1996,13(3):58-61.
[4]Gadzinowska K,Piorkowska E.Influence of Sample Thickness and Surface Nucleation on i-PP Crystallization Kinetics in DSC Measurements[J].Polimery,2003,48(11/12):790-799.
[5]谢飞,张祥福,方舫,等.成核剂对增韧聚丙烯力学性能的影响[J].中国塑料,2000,14(11):76-80.Xie Fei,Zhang Xiangfu,Fang Fang,et al.Effect of Nucleating Agents on Mechanical Properties of Toughened PP[J].China Plastics,2000,14(11):76-80.
[6]杨军,李炳海,王进,等.聚丙烯结晶行为的控制因素[J].现代塑料加工应用,1998,10(4):60-64.Yang Jun,Li Binghai,Wang jin,et al.Control Factors of Polypropylene Crystallization Behaviors[J].Modern Plastics Processing and Applications,1998,10(4):60-64.
[7]洪定一.聚丙烯——原理、工艺与技术[M].北京:中国石化出版社,2002:2.
[8]Kotek J,Kelnar I,Baldrian J,et al.Tensile Behavior of Isotactic Polypropylene Modified by Specific Nucleation and Active Fillers[J].Eur Polym J,2004,40(4):679-684.
[9]窦强,任巨光,赵石林,等.β晶型成核剂在聚丙烯增韧体系中的应用[J].中国塑料,2000,14(1):38-41.Dou Qiang,Ren Juguang,Zhao Shilin,et al.Applications ofβ-crystalline Form Nucleation Agents in PP TougheningSystems[J].China Plastics,2000,14(1):38-41.
[10]王文治,胡红旗,冯嘉春,等.PP晶型及稀土类PP晶型改性剂[J].塑料,2004,33(2):29-34.Wang Wenzhi,Hu Hongqi,Feng Jiachun,et al.Rare Earth Containing Crystalline Phase Modifier for PP[J].Plastics,2004,33(2):29-34.
[11]秦亚伟,郭绍辉,冯嘉春,等.聚丙烯的β晶型及β成核剂的研究进展[J].中国塑料,2006,20(3):7-13.Qin Yawei,Guo Shaohui,Feng Jiachun,et al.Advances inβ-forms Polypropylene andβ-nucleating Agents[J].China Plastics,2006,20(3).7-13.
[12]王克智.新型功能塑料助剂[M].北京:化学工业出版社,2003:58.
[13]菲利普·雅各比.含β球晶的挤出聚丙烯片材:中国,1697765A[P].2005-11-16.
[14]Garbarczyk J,Paukzta D.Influence of Additives on the Structure and Properties of Polymers:2.Polymorphic Transitions of Isotactic Polypropylene Caused by Aminosulphur Compounds[J].Polymer,1981,22(4):562-564.
[15]史建公,蒋绍洋,张敏宏,等.稀土β聚丙烯成核剂研究及应用进展[J].化工进展,2010,29(5):854-860.Shi Jiangong,Jiang Shaoyang,Zhang Minhong,et al.Advances in Research and Application of Rare Earthβ-nucleating Agents for Polypropylene[J].Chemical Industry and Engineering Process,2010,29(5):854-860.
[16]秦亚伟,冯嘉春,郭绍辉,等.稀土β晶型成核剂对聚丙烯性能的影响[J].化工新型材料,2007,35(6):56-58,76.Qin Yawei,Feng Jiachun,Guo Shaohui,et al.Effect of Rare EarthβNucleating Agent on the Properties of Polypropylene[J].New Chemical Materials,2007,35(6)":56-58,76.
[17]Turner Jones A,Aizlewood J M,Beckett DR.Crystalline Forms of Isotactic Polypropylene[J].Makromol Chem,1964,75(1):134-158.
[18]Gradys A,Sajkiewicz P,Minakov A A,et al.Crystallization of Polypropylene at Various Cooling Rates[J].Mater Sci Eng,2005,413/414:442-446.
[19]Lovinger A J,Chua J O,Gryte C C.Study on theαandβ-Forms of Isotactic Polypropylene by Crystallization inTemperature Gradient[J].J Polym Sci Polym Phys Edt.1977,15(4):641-656.
[20]Dragaun H,Hubeny H,Muschik H.Shear-inducedβ-Form Crystallization in Isotactic Polypropylene[J].J Polym Sci,Polym Phys,1977,15(10):1779-1789.
[21]冯嘉春,陈鸣才,黄志镗.硬脂酸镧复合物对聚丙烯β晶型的诱导作用[J].高等学校化学学报,2001,22(1):154-156.Feng Jiachun,Chen Mingcai,Huang Zhitang.Lanthanum Stearate Composite Act asβ-modification Nucleating Agent of Isotatic Polypropylene[J].Chemical Journal of Chinese Universities,2001,22(1):154-156.
[22]Lee Dongho,Yoon Keunbyoung.Effects of Polycycopentene on Crystallization of Isotactic Polypropylene[J].J Appl Polym Sci,1994,54(10),1507-1511.
[23]Leugering H.Einflu(1 Kristallstruktur and Deriiberstruktur auf Einige Eigenschaften von Polypropylen[J].Makromol Chem,1967,109(1):204-216.
[24]史观一,张景云.β晶型聚丙烯的研究[J].科学通报,1981,26(12):731-733.Shi Guanyi,Zhang Jingyun.Research ofβ-Crystalline Form Polypropylene[J].Chinese Science Bulletin,1981.26(12):731-733.
[25]New Japan Chemical Co Ltd.Manufacture of Aromatic Cyclic Imides with High Purity:JP 03014835[P].1991-01-23.
[26]Feng J C,Chen M C,Huang Z T,et al.Effects of Mineral Additives on theβ-Crystalline Form of Isotactic Polypropylene[J].J Appl Polym Sci,2002,85(8):1742-1748.
[27]Dou Qiang,Lu Quliang,Li Huaidong.Effect of Metallic Salts of Malonic Acid on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].J Macro Sci.Part B:Physics,2008,47(5):900-912.
[28]Dou Qiang,Lu Quliang.Effect of Calcium Malonate on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].Polym Adv Technol,2008,19(11):1522-1527.
[29]Dou Qiang,Lu Quliang,Li Huaidong.Effect of Metallic Salts of Glutaric Acid on the Formation ofβ-Crystalline Form in Isotactic Polypropylene[J].J Elastomers&Plastics,2009,41(6):509-522.
[30]何阳,黄锐,郑德.β晶型聚丙烯研究进展[J].高分子通报,2008,(1):24-32.He Yang,Huang Rui,Zheng De.Advances in|3-Forms Polypropylene[J].Chinese Polymer Bulletin,2008,(1):24-32.
[31]Dou Qiang.Effect of Metallic Salts of Pimelic Acid and Crystallization Temperatures on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].J Macro Sci,Part B:Physics,2007,46(6):1063-1080.
[32]Shi Guanyi,Zhang Jingyun.Beta-crystalline Isotactic Polypropylene,Process for the Preparation there of.and Articles Produced Therefrom:DE,3610644A1[P].1986-10-02.
[33]史观一,黄斌,张景云,等.聚丙烯β相结晶的研究[J].中国科学(B辑),1986,16(6):569-576.Shi Guanyi,Huang Bin,Zhang Jingyun,et al.Research of Melting Crystallization Behavior ofβ-Phase of Polypropylene[J].Science in China(Ser B),1986,16(6):569-576.
[34]张景云,史观一.曹友虹,等.β晶型聚丙烯的力学性质[J].高分子通讯.1986.(4):241-244.Zhang Jingyun,Shi Guanyi,Cao Youhong,et al.The Mechanical Behaviorofβ-form of Isotactic Polypropylene[J].Polymer Communication,1986,(4):241-244.
[35]张晓东.史观一.成核剂含量对β晶相聚丙烯结晶与熔融行为的影响[J].高分子学报.1992,(3):293-298.Zhang Xiaodong,Shi Guanyi.Effect ofβ-nucleator Content on the Crystallization and Melting Behavior ofβ-Phase Polypropylene[J].Acta Polymerica Sinica,1992,(3):293-298.
[36]Shi Guanyi,Zhang Xiaodong.Cao Youhong,et al.Melting Behavior and Crystalline Order ofβ-Crystalline Phase Poly propylene[J].Makromol Chera 1993,194(1):269-277.
[37]池圣贤,乐道进,龙林林.聚丙烯β晶成核剂的研究进展[J].现代塑料加工应用,2009.21(2):60-63.Chi Shengxian,Yue Daojin.Long Linlin.Research and Development ofβ-form Nucleating Agents for Polypropylene[J].Modern Plastics Processing and Applications,2009.21(2):60-63.
[38]Li J X,Cheung W L,Jia Demia A Study on the Heat of Fusion ofβ-polypropylene[J].Polymer,1999,40(5):1219-1222.
[39]Li J X.Cheung W L.Conversion of Growth and Recrystallization ofβ-phase in Doped IPP[J].Polymer.1999,40(8):2085-2088.
[40]Tjiong S C.Shen J S.Li R K Y.Morphological Behavior and Instrumented Dart Impact Properties ofβCrystalline Phase Polypropylene[J].Polymer.1996.37(12):2309-2316.
[41]Tomasz Sterzynski,Harryoysaed.Structure Modification of Isotactic Polypropylene by Bi-component Nucleating Systems[J].Poly Eng Sci.2004,44(2):352-361.
[42]Li J X,Cheung W L.Pimelic Acid-based Nucleating Agents for Hexagonal Crystalline of Polypropylene[J].J Vinyl&Additive Technology,1997,3(2):151-156.
[43]吴家伟,王玮.β成核剂对丙烯酸接枝聚丙烯结晶行为的影响[J].塑料,2008,37(4):34-36.Wu Jiawei.Wang Wei.Influence ofβNucleating Agents on Crystallization Behavior of Graft Copolymer of Polypropylene and Acrylic Acid[J].Plastics.2008.37(4):34-36.
[44]姚日远,刁国旺.刘子龙,等.一种制备β晶型聚丙烯的方法:中国.101768230A[P].2010-7-7.
[45]杨伟,王市伟,杨鸣波.等.纤维B成核剂的制备方法及其在改性聚丙烯中的应用:中国,10161914382[P].2011-4-13.
[46]程雷.郑玉婴.曾安然.等.β成核剂对等规聚丙烯结晶性能的影响[J].塑料,2011.40(1):29-31.Stearate on the Crystallization Behavior of Isotactic Polypropylene[J].Plastics,2011,40(1):29-31.
[47]Zhang X D,Shi G Y.Effect of Converting the Crystalline Form Fromαtoβon the Mechanical Properties of Ethylene/Propylene Random and Block Copolymers[J].Polymer,1994,35(23):5067-5072.
[48]Varga J,Schulek TothF.Crystallization,Melting and Spherulitic Structure ofβ-nucleated Random Propylene Copolymers[J].J Them Anal,1996,47(4):941-955.
[49]Bernreitner Klaus,Wolfschwenger Johannes Ing.Method for Increasing the Ratio of Beta-modification in Polypropylene:EP0682066[P].1995-11-15.
[50]谢克昌,赵彦生,卢建军,等.改性小本体聚丙烯组合物及其制备方法:中国,1254503C[P].2006-05-03.
[51]李仲尧,史观一,袁锦瑶,等.β晶型聚丙烯树脂材料的制备及其制品的组成:中国,85108716A[P].1988-01-20.
[52]章自寿,王春广,杨竹根,等.负载型β成核剂对PP结晶与熔融行为的影响[J].中山大学学报:自然科学版,2009,48(3):51-55.Zhang Zishou,Wang Chunguang,Yang Zhugen,et al.Influences of Supportedβ-nucleating Agent on Crystallization and Melting Behaviors of Polypropylene[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(3):51-55.
[53]Zhang Zishou,Wang Chunguang,Yang Zhugen,et al.Crystallization Behavior and Melting Characteristics of PP Nucleated by a Novel Supportβ-nucleating Agent[J].Polymer,2008,49(23):5137-5145.
[54]Zhang Zishou,Chen Chunyan,Wang Chunguang,et al.A Novel Highly Efficientβ-nucleating Agent for Polypropylene Using Nano-CaCO_3 as a Support[J].J Polym Int,2010,59(9):1199-1204.
[55]罗本抬,张军,王晓琳,等.纳米碳酸钙/庚二酸复合成核剂对热致相分离法制备聚丙烯微孔膜的影响[J].高分子学报,2006,(7):866-872.Luo Benzhe,Zhang Jun,Wang Xiaolin,et al.Effect of Nano CaCO_3/Pimelic Acid Compounds Nucleating Agents on Preparations of Polypropylene Microporous Filmby TIPS[J].Acta Polymerica Sinica,2006,(7):866-872.
[56]孟明锐,窦强.庚二酸处理硅灰石填充改性聚丙烯[J].高分子材料科学与工程,2008,24(11):153-156.Meng Mingrui,Dou Qiang.Modification of PP by Pimelic Acid Treated Wollastonite[J].Polymer Materials Science&Engineering,2008,24(11):153-156.
[57]孟明锐,窦强.PP/庚二酸表面处理云母复合材料的力学性能和结晶行为[J].中国塑料,2007,21(8):24-28.Meng Mingrui,Dou Qiang.Mechanical Properties and Crystallization Behavior of PP/Pimelic Acid Treated Mica Composites[J].China Plastics,2007,21(8):24-28.
[58]薛建峰,窦强.辛二酸盐成核剂改性等规聚丙烯的研究[J].塑料科技,2011,39(1):104-108.Xue Jianfeng,Dou Qiang.Study on Isotactic Polypropylene Nucleated by Suberates[J].Plastics Science and Technology,2011,39(1):104-108.
[59]Li Xiaojun,Hu Keliang.Ji Mingrong,et al.Calcium Dicarboxylates Nucleation of Beta-polypropylene[J].J Appl PolymSci,2002,86(3):633-638.
[60]陈彦,徐懋.聚丙烯成核剂成核效应及热稳定性研究[J].高分子学报,1998,(4):387-392.Chen Yan,Xu Mao.Studies on The Thermal Stability of The Nucleating Effect of Nucleating Agents in Polypropylene[J].Acta Polymerica Sinica,1998,(4):387-392.
[61]A L贝森.含有8状晶体的成核(作用)剂的聚丙烯组合物:中国,1210103A[P].1999-03-10.
[62]吕志平,王建国,王卫星.二元酸盐聚丙烯β晶型成核剂:中国,101418084A[P].2008-11-28.
[63]吕志平,王卫星,张友强,等.新型聚丙烯β晶型成核剂的制备及应用[J].中国塑料,2009,23(7):81-84.Lu Zhiping,Wang Weixing,Zhang Youqiang,et al.Preparation and Application of Newβ-nucleating Agent of Polypropylene[J].China Plastics,2009,23(7):81-84.
[64]辛忠,赵世成.β晶型聚丙烯成核剂及含有该成核剂的聚丙烯树脂组合物:中国,1966563B[P].2012-4-25.
[65]辛忠,赵世成.新型羧酸金属盐类β晶型成核剂的研究进展:中国塑料技术产业化研讨会[C].浙江:中国塑料加工工业协会,2011:218-226.
[66]Zhao Shicheng,Cai Zhi,Xin Zhong.A Highly Active NovelβNucleating Agent for Isotactic Polypropylene[J].Polymer,2008,49(11):2745-2754.
[67]Liu Yimin.Tong Zaizai,Xu Junting,et al.A Highly Efficientβ-nucleating Agent for Impact-resistant Polypropylene Copolymer[J].J Appl Polym Sci,2014,131(18):40753.
[2]何叶尔,李力.聚丙烯树脂的加工和应用[M].第二版.北京:中国石油化工出版社:1998:1-3.
[3]王坷,史贞,王建民.PP增韧技术的研究进展[J].合成树脂及塑料.1996,13(3):58-61.Wang Ke,Shi Zhen,Wang Jianmin.Progress of the Studyon the Toughening of Polypropylene[J].Synth Resin Plast,1996,13(3):58-61.
[4]Gadzinowska K,Piorkowska E.Influence of Sample Thickness and Surface Nucleation on i-PP Crystallization Kinetics in DSC Measurements[J].Polimery,2003,48(11/12):790-799.
[5]谢飞,张祥福,方舫,等.成核剂对增韧聚丙烯力学性能的影响[J].中国塑料,2000,14(11):76-80.Xie Fei,Zhang Xiangfu,Fang Fang,et al.Effect of Nucleating Agents on Mechanical Properties of Toughened PP[J].China Plastics,2000,14(11):76-80.
[6]杨军,李炳海,王进,等.聚丙烯结晶行为的控制因素[J].现代塑料加工应用,1998,10(4):60-64.Yang Jun,Li Binghai,Wang jin,et al.Control Factors of Polypropylene Crystallization Behaviors[J].Modern Plastics Processing and Applications,1998,10(4):60-64.
[7]洪定一.聚丙烯——原理、工艺与技术[M].北京:中国石化出版社,2002:2.
[8]Kotek J,Kelnar I,Baldrian J,et al.Tensile Behavior of Isotactic Polypropylene Modified by Specific Nucleation and Active Fillers[J].Eur Polym J,2004,40(4):679-684.
[9]窦强,任巨光,赵石林,等.β晶型成核剂在聚丙烯增韧体系中的应用[J].中国塑料,2000,14(1):38-41.Dou Qiang,Ren Juguang,Zhao Shilin,et al.Applications ofβ-crystalline Form Nucleation Agents in PP TougheningSystems[J].China Plastics,2000,14(1):38-41.
[10]王文治,胡红旗,冯嘉春,等.PP晶型及稀土类PP晶型改性剂[J].塑料,2004,33(2):29-34.Wang Wenzhi,Hu Hongqi,Feng Jiachun,et al.Rare Earth Containing Crystalline Phase Modifier for PP[J].Plastics,2004,33(2):29-34.
[11]秦亚伟,郭绍辉,冯嘉春,等.聚丙烯的β晶型及β成核剂的研究进展[J].中国塑料,2006,20(3):7-13.Qin Yawei,Guo Shaohui,Feng Jiachun,et al.Advances inβ-forms Polypropylene andβ-nucleating Agents[J].China Plastics,2006,20(3).7-13.
[12]王克智.新型功能塑料助剂[M].北京:化学工业出版社,2003:58.
[13]菲利普·雅各比.含β球晶的挤出聚丙烯片材:中国,1697765A[P].2005-11-16.
[14]Garbarczyk J,Paukzta D.Influence of Additives on the Structure and Properties of Polymers:2.Polymorphic Transitions of Isotactic Polypropylene Caused by Aminosulphur Compounds[J].Polymer,1981,22(4):562-564.
[15]史建公,蒋绍洋,张敏宏,等.稀土β聚丙烯成核剂研究及应用进展[J].化工进展,2010,29(5):854-860.Shi Jiangong,Jiang Shaoyang,Zhang Minhong,et al.Advances in Research and Application of Rare Earthβ-nucleating Agents for Polypropylene[J].Chemical Industry and Engineering Process,2010,29(5):854-860.
[16]秦亚伟,冯嘉春,郭绍辉,等.稀土β晶型成核剂对聚丙烯性能的影响[J].化工新型材料,2007,35(6):56-58,76.Qin Yawei,Feng Jiachun,Guo Shaohui,et al.Effect of Rare EarthβNucleating Agent on the Properties of Polypropylene[J].New Chemical Materials,2007,35(6)":56-58,76.
[17]Turner Jones A,Aizlewood J M,Beckett DR.Crystalline Forms of Isotactic Polypropylene[J].Makromol Chem,1964,75(1):134-158.
[18]Gradys A,Sajkiewicz P,Minakov A A,et al.Crystallization of Polypropylene at Various Cooling Rates[J].Mater Sci Eng,2005,413/414:442-446.
[19]Lovinger A J,Chua J O,Gryte C C.Study on theαandβ-Forms of Isotactic Polypropylene by Crystallization inTemperature Gradient[J].J Polym Sci Polym Phys Edt.1977,15(4):641-656.
[20]Dragaun H,Hubeny H,Muschik H.Shear-inducedβ-Form Crystallization in Isotactic Polypropylene[J].J Polym Sci,Polym Phys,1977,15(10):1779-1789.
[21]冯嘉春,陈鸣才,黄志镗.硬脂酸镧复合物对聚丙烯β晶型的诱导作用[J].高等学校化学学报,2001,22(1):154-156.Feng Jiachun,Chen Mingcai,Huang Zhitang.Lanthanum Stearate Composite Act asβ-modification Nucleating Agent of Isotatic Polypropylene[J].Chemical Journal of Chinese Universities,2001,22(1):154-156.
[22]Lee Dongho,Yoon Keunbyoung.Effects of Polycycopentene on Crystallization of Isotactic Polypropylene[J].J Appl Polym Sci,1994,54(10),1507-1511.
[23]Leugering H.Einflu(1 Kristallstruktur and Deriiberstruktur auf Einige Eigenschaften von Polypropylen[J].Makromol Chem,1967,109(1):204-216.
[24]史观一,张景云.β晶型聚丙烯的研究[J].科学通报,1981,26(12):731-733.Shi Guanyi,Zhang Jingyun.Research ofβ-Crystalline Form Polypropylene[J].Chinese Science Bulletin,1981.26(12):731-733.
[25]New Japan Chemical Co Ltd.Manufacture of Aromatic Cyclic Imides with High Purity:JP 03014835[P].1991-01-23.
[26]Feng J C,Chen M C,Huang Z T,et al.Effects of Mineral Additives on theβ-Crystalline Form of Isotactic Polypropylene[J].J Appl Polym Sci,2002,85(8):1742-1748.
[27]Dou Qiang,Lu Quliang,Li Huaidong.Effect of Metallic Salts of Malonic Acid on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].J Macro Sci.Part B:Physics,2008,47(5):900-912.
[28]Dou Qiang,Lu Quliang.Effect of Calcium Malonate on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].Polym Adv Technol,2008,19(11):1522-1527.
[29]Dou Qiang,Lu Quliang,Li Huaidong.Effect of Metallic Salts of Glutaric Acid on the Formation ofβ-Crystalline Form in Isotactic Polypropylene[J].J Elastomers&Plastics,2009,41(6):509-522.
[30]何阳,黄锐,郑德.β晶型聚丙烯研究进展[J].高分子通报,2008,(1):24-32.He Yang,Huang Rui,Zheng De.Advances in|3-Forms Polypropylene[J].Chinese Polymer Bulletin,2008,(1):24-32.
[31]Dou Qiang.Effect of Metallic Salts of Pimelic Acid and Crystallization Temperatures on the Formation ofβCrystalline Form in Isotactic Polypropylene[J].J Macro Sci,Part B:Physics,2007,46(6):1063-1080.
[32]Shi Guanyi,Zhang Jingyun.Beta-crystalline Isotactic Polypropylene,Process for the Preparation there of.and Articles Produced Therefrom:DE,3610644A1[P].1986-10-02.
[33]史观一,黄斌,张景云,等.聚丙烯β相结晶的研究[J].中国科学(B辑),1986,16(6):569-576.Shi Guanyi,Huang Bin,Zhang Jingyun,et al.Research of Melting Crystallization Behavior ofβ-Phase of Polypropylene[J].Science in China(Ser B),1986,16(6):569-576.
[34]张景云,史观一.曹友虹,等.β晶型聚丙烯的力学性质[J].高分子通讯.1986.(4):241-244.Zhang Jingyun,Shi Guanyi,Cao Youhong,et al.The Mechanical Behaviorofβ-form of Isotactic Polypropylene[J].Polymer Communication,1986,(4):241-244.
[35]张晓东.史观一.成核剂含量对β晶相聚丙烯结晶与熔融行为的影响[J].高分子学报.1992,(3):293-298.Zhang Xiaodong,Shi Guanyi.Effect ofβ-nucleator Content on the Crystallization and Melting Behavior ofβ-Phase Polypropylene[J].Acta Polymerica Sinica,1992,(3):293-298.
[36]Shi Guanyi,Zhang Xiaodong.Cao Youhong,et al.Melting Behavior and Crystalline Order ofβ-Crystalline Phase Poly propylene[J].Makromol Chera 1993,194(1):269-277.
[37]池圣贤,乐道进,龙林林.聚丙烯β晶成核剂的研究进展[J].现代塑料加工应用,2009.21(2):60-63.Chi Shengxian,Yue Daojin.Long Linlin.Research and Development ofβ-form Nucleating Agents for Polypropylene[J].Modern Plastics Processing and Applications,2009.21(2):60-63.
[38]Li J X,Cheung W L,Jia Demia A Study on the Heat of Fusion ofβ-polypropylene[J].Polymer,1999,40(5):1219-1222.
[39]Li J X.Cheung W L.Conversion of Growth and Recrystallization ofβ-phase in Doped IPP[J].Polymer.1999,40(8):2085-2088.
[40]Tjiong S C.Shen J S.Li R K Y.Morphological Behavior and Instrumented Dart Impact Properties ofβCrystalline Phase Polypropylene[J].Polymer.1996.37(12):2309-2316.
[41]Tomasz Sterzynski,Harryoysaed.Structure Modification of Isotactic Polypropylene by Bi-component Nucleating Systems[J].Poly Eng Sci.2004,44(2):352-361.
[42]Li J X,Cheung W L.Pimelic Acid-based Nucleating Agents for Hexagonal Crystalline of Polypropylene[J].J Vinyl&Additive Technology,1997,3(2):151-156.
[43]吴家伟,王玮.β成核剂对丙烯酸接枝聚丙烯结晶行为的影响[J].塑料,2008,37(4):34-36.Wu Jiawei.Wang Wei.Influence ofβNucleating Agents on Crystallization Behavior of Graft Copolymer of Polypropylene and Acrylic Acid[J].Plastics.2008.37(4):34-36.
[44]姚日远,刁国旺.刘子龙,等.一种制备β晶型聚丙烯的方法:中国.101768230A[P].2010-7-7.
[45]杨伟,王市伟,杨鸣波.等.纤维B成核剂的制备方法及其在改性聚丙烯中的应用:中国,10161914382[P].2011-4-13.
[46]程雷.郑玉婴.曾安然.等.β成核剂对等规聚丙烯结晶性能的影响[J].塑料,2011.40(1):29-31.Stearate on the Crystallization Behavior of Isotactic Polypropylene[J].Plastics,2011,40(1):29-31.
[47]Zhang X D,Shi G Y.Effect of Converting the Crystalline Form Fromαtoβon the Mechanical Properties of Ethylene/Propylene Random and Block Copolymers[J].Polymer,1994,35(23):5067-5072.
[48]Varga J,Schulek TothF.Crystallization,Melting and Spherulitic Structure ofβ-nucleated Random Propylene Copolymers[J].J Them Anal,1996,47(4):941-955.
[49]Bernreitner Klaus,Wolfschwenger Johannes Ing.Method for Increasing the Ratio of Beta-modification in Polypropylene:EP0682066[P].1995-11-15.
[50]谢克昌,赵彦生,卢建军,等.改性小本体聚丙烯组合物及其制备方法:中国,1254503C[P].2006-05-03.
[51]李仲尧,史观一,袁锦瑶,等.β晶型聚丙烯树脂材料的制备及其制品的组成:中国,85108716A[P].1988-01-20.
[52]章自寿,王春广,杨竹根,等.负载型β成核剂对PP结晶与熔融行为的影响[J].中山大学学报:自然科学版,2009,48(3):51-55.Zhang Zishou,Wang Chunguang,Yang Zhugen,et al.Influences of Supportedβ-nucleating Agent on Crystallization and Melting Behaviors of Polypropylene[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(3):51-55.
[53]Zhang Zishou,Wang Chunguang,Yang Zhugen,et al.Crystallization Behavior and Melting Characteristics of PP Nucleated by a Novel Supportβ-nucleating Agent[J].Polymer,2008,49(23):5137-5145.
[54]Zhang Zishou,Chen Chunyan,Wang Chunguang,et al.A Novel Highly Efficientβ-nucleating Agent for Polypropylene Using Nano-CaCO_3 as a Support[J].J Polym Int,2010,59(9):1199-1204.
[55]罗本抬,张军,王晓琳,等.纳米碳酸钙/庚二酸复合成核剂对热致相分离法制备聚丙烯微孔膜的影响[J].高分子学报,2006,(7):866-872.Luo Benzhe,Zhang Jun,Wang Xiaolin,et al.Effect of Nano CaCO_3/Pimelic Acid Compounds Nucleating Agents on Preparations of Polypropylene Microporous Filmby TIPS[J].Acta Polymerica Sinica,2006,(7):866-872.
[56]孟明锐,窦强.庚二酸处理硅灰石填充改性聚丙烯[J].高分子材料科学与工程,2008,24(11):153-156.Meng Mingrui,Dou Qiang.Modification of PP by Pimelic Acid Treated Wollastonite[J].Polymer Materials Science&Engineering,2008,24(11):153-156.
[57]孟明锐,窦强.PP/庚二酸表面处理云母复合材料的力学性能和结晶行为[J].中国塑料,2007,21(8):24-28.Meng Mingrui,Dou Qiang.Mechanical Properties and Crystallization Behavior of PP/Pimelic Acid Treated Mica Composites[J].China Plastics,2007,21(8):24-28.
[58]薛建峰,窦强.辛二酸盐成核剂改性等规聚丙烯的研究[J].塑料科技,2011,39(1):104-108.Xue Jianfeng,Dou Qiang.Study on Isotactic Polypropylene Nucleated by Suberates[J].Plastics Science and Technology,2011,39(1):104-108.
[59]Li Xiaojun,Hu Keliang.Ji Mingrong,et al.Calcium Dicarboxylates Nucleation of Beta-polypropylene[J].J Appl PolymSci,2002,86(3):633-638.
[60]陈彦,徐懋.聚丙烯成核剂成核效应及热稳定性研究[J].高分子学报,1998,(4):387-392.Chen Yan,Xu Mao.Studies on The Thermal Stability of The Nucleating Effect of Nucleating Agents in Polypropylene[J].Acta Polymerica Sinica,1998,(4):387-392.
[61]A L贝森.含有8状晶体的成核(作用)剂的聚丙烯组合物:中国,1210103A[P].1999-03-10.
[62]吕志平,王建国,王卫星.二元酸盐聚丙烯β晶型成核剂:中国,101418084A[P].2008-11-28.
[63]吕志平,王卫星,张友强,等.新型聚丙烯β晶型成核剂的制备及应用[J].中国塑料,2009,23(7):81-84.Lu Zhiping,Wang Weixing,Zhang Youqiang,et al.Preparation and Application of Newβ-nucleating Agent of Polypropylene[J].China Plastics,2009,23(7):81-84.
[64]辛忠,赵世成.β晶型聚丙烯成核剂及含有该成核剂的聚丙烯树脂组合物:中国,1966563B[P].2012-4-25.
[65]辛忠,赵世成.新型羧酸金属盐类β晶型成核剂的研究进展:中国塑料技术产业化研讨会[C].浙江:中国塑料加工工业协会,2011:218-226.
[66]Zhao Shicheng,Cai Zhi,Xin Zhong.A Highly Active NovelβNucleating Agent for Isotactic Polypropylene[J].Polymer,2008,49(11):2745-2754.
[67]Liu Yimin.Tong Zaizai,Xu Junting,et al.A Highly Efficientβ-nucleating Agent for Impact-resistant Polypropylene Copolymer[J].J Appl Polym Sci,2014,131(18):40753.