含氰废水的电化学处理技术研究进展
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摘要
介绍了含氰废水的电化学处理技术及其研究进展,重点对电解氧化、电解沉积、电吸附、电渗析和电凝絮等方法的工艺流程、反应原理及工艺特点进行了阐述,在对近年来国内外采用电化学技术处理含氰废水的最新成果与研究进展进行综述的基础上,展望了电化学处理技术的应用前景及研究发展方向。
The progress in the study for the process of treatment cyanide wastewater by electrochemistry methods were introduced,the basic principle,characteristics and applications of electrolytic oxidation,electrolytic deposition,electric adsorption,electrodialysis and electrolytic flocculation were mainly introduced.Based on the review of latest research progress of treatment cyanide wastewater by electrochemistry technology both at home and abroad in recent years,prospects of the cyanide wastewater treatment technology were proposed.
The progress in the study for the process of treatment cyanide wastewater by electrochemistry methods were introduced,the basic principle,characteristics and applications of electrolytic oxidation,electrolytic deposition,electric adsorption,electrodialysis and electrolytic flocculation were mainly introduced.Based on the review of latest research progress of treatment cyanide wastewater by electrochemistry technology both at home and abroad in recent years,prospects of the cyanide wastewater treatment technology were proposed.
引文
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[27]雷兆武.电化学技术在重金属废水处理中应用[J].中国环境管理干部学院学报,2008,18(4):15-17.
[28]王海东,陈发源,杨春风,等.电混凝处理电镀综合废水[J].环境工程学报,2013,7(10):3833-3838.
[29]何晓莉,王志盈,袁林江,等.管式电凝聚法处理印染废水COD的特性研究[J].给水排水,2000,26(5):33-35.
[30]朱小梅,赵娜,刘晓星,等.高压脉冲电絮凝法处理电镀废水[J].河北大学学报(自然科学版),2007,27(增):94-97.
[31]江学,梅凯,刘玲,等.微电解芬顿预处理高浓度含氰废水[J].能源环境保护,2013,27(4):30-33.
[32]李仕雄,李勇,徐忠敏,等.焦亚硫酸钠破氰—电絮凝法处理黄金生产废水[J].黄金科学技术,2012,20(3):66-69.
[33]Agarwal B,Thakur P K,Balomajuder C.Use of iron-impregnated granular activated carbon for co-adsorptive removal of phenol and cyanide:Insight into equilibrium and kinetics[J].Fe-Impregnated Granular Activated Carbon,2013,200(9):1278-1292.
[34]范丽,周艳伟,杨卫身,等.炭材料用作电吸附剂的研究与进展[J].新型炭材料,2004,19(2):145-149.
[35]罗斌.电激发羟基自由基处理含氰废水的中试应用[J].广东化工,2014,41(16):253-254.
[36]Hijosa-Valsero M,Molina R,Schikora H,et al.Removal of cyanide from water by means of plasma discharge technology[J].Water Research,2013,47(4):1701-1707.
[37]冯求宝,杨怀远,杜建敏,等.脉冲电晕放电去除废水中氰化物的研究[J].工业安全与环保,2010,36(2):11-13.
[38]龙淼,李胜利,章英慧,等.高压脉冲放电处理含氰废水的影响因素探究[J].工业安全与环保,2005,31(3):7-10.
[2]兰新哲,张聪慧,党晓娥,等.提金氰化物回收循环再用技术新进展[J].黄金科学技术,1999,7(3):40-45.
[3]马红周,杨明,兰新哲.活性炭吸附酸化后的含氰废水试验研究[J].黄金,2007,28(9):56-57.
[4]宋永辉,兰新哲,李秀玲.D301树脂对铁氰溶液中Fe(Ш)及CN-的吸附行为及机理[J].中国有色金属学报,2008,18(1):160-165.
[5]宋永辉,李秀玲,兰新哲.201×7树脂负载Fe(CN)63-的解吸[J].黄金,2008,29(11):43-46.
[6]冯玉杰,李晓岩,尤宏.电化学技术在环境工程中的应用[M].北京:化学工业出版社,2002:94-96.
[7]姜力强,郑精武,刘昊,等.电解法处理含氰含铜废水工艺研究[J].水处理技术,2004,30(3):153-156.
[8]李慧婷.电化学氧化法在工业废水处理中的应用研究[D].长春:吉林大学,2011.
[9]胡湖生,杨明德,党杰,等.从含氰废水中回收铜以及相应的废水处置方法:中国,200610169698.5[P].2007-08-01.
[10]王碧侠,兰新哲,宋永辉.用电积法从氰化提金尾液中回收铜的工艺实验研究[J].黄金,2008,29(6):45-48.
[11]高腾跃,刘奎仁,韩庆,等.电沉积回收氰化尾液中铜和氰化物的研究[J].东北大学学报(自然科学版),2015,36(1):81-85.
[12]张成光,缪娟,符德学,等.电化学法处理废水的研究进展[J].河南化工,2006,23(6):1-4.
[13]范树军,张焕彬,付建军.铁炭微电解/Fenton氧化预处理高浓度煤化工废水的研究[J].工业水处理,2010,30(8):93-95.
[14]李定龙,申晶晶,姜晟,等.电吸附除盐技术进展及其应用[J].水资源保护,2008,24(4):63-64.
[15]Song Y H,Lei S M,Zhou J,et al.Removal of heavy metals and cyanide from gold mine wastewater by adsorption and electric adsorption[J].Journal of Chemical Technology and Biotechnology,2016,91(9):2539-2544.
[16]Song Y H,Lei S M,Wu C C,et al.Treatment cyanideextracting gold wastewater by adsorption and electric adsorption[C].Sheng Zhen:DEStech Publications,2015:894-902.
[17]宋永辉,雷思明,吴春辰,等.一种采用电吸附技术深度处理氰化提金废水的方法:中国,ZL2014100143147[P].2014-04-30.
[18]宋永辉,吴春辰,田慧,等.高浓度氰化提金废水的电吸附处理实验研究[J].稀有金属,2016,40(5):492-498.
[19]Schoeman J J.Evaluation of electrodialysis for the treatment of a hazardous leachate[J].Desalination,2008,224(1/3):178-182.
[20]周军,叶长明,徐驷蛟,等.电渗析技术在工业废水处理中应用的研究[J].节能与环保,2007(7):33-37.
[21]李海波,李东梧,郑洪君,等.电渗析法处理含金贵液的研究[J].化学工程,2003,31(2):46-52.
[22]Zheng Y,Li Z H,Wang X Y,et al.The treatment of cyanide from gold mine effluent by a novel five-compartment electrodialysis[J].Electrochimica ACTA,2015,169:150-158.
[23]Zheng Y,Gao X L,Wang X Y,et al.Application of electrod ialysis to remove copper and cyanide from simul ated and real gold mine effluent[J].RSC Advances,2015,5:19807-19817.
[24]吴振杰.应用均相离子交换膜电渗析技术处理含氰化物工业废水[J].化学学报,1980,34(2):19-25.
[25]哈尔滨建筑工程学院.电渗析技术资料选编:氰化镀镉废水实验[M].北京:中国建筑工业出版社,1997.
[26]林海波,伍振毅,黄卫民,等.工业废水电化学处理技术的进展及其发展方向[J].化工进展,2008,27(2):223-230.
[27]雷兆武.电化学技术在重金属废水处理中应用[J].中国环境管理干部学院学报,2008,18(4):15-17.
[28]王海东,陈发源,杨春风,等.电混凝处理电镀综合废水[J].环境工程学报,2013,7(10):3833-3838.
[29]何晓莉,王志盈,袁林江,等.管式电凝聚法处理印染废水COD的特性研究[J].给水排水,2000,26(5):33-35.
[30]朱小梅,赵娜,刘晓星,等.高压脉冲电絮凝法处理电镀废水[J].河北大学学报(自然科学版),2007,27(增):94-97.
[31]江学,梅凯,刘玲,等.微电解芬顿预处理高浓度含氰废水[J].能源环境保护,2013,27(4):30-33.
[32]李仕雄,李勇,徐忠敏,等.焦亚硫酸钠破氰—电絮凝法处理黄金生产废水[J].黄金科学技术,2012,20(3):66-69.
[33]Agarwal B,Thakur P K,Balomajuder C.Use of iron-impregnated granular activated carbon for co-adsorptive removal of phenol and cyanide:Insight into equilibrium and kinetics[J].Fe-Impregnated Granular Activated Carbon,2013,200(9):1278-1292.
[34]范丽,周艳伟,杨卫身,等.炭材料用作电吸附剂的研究与进展[J].新型炭材料,2004,19(2):145-149.
[35]罗斌.电激发羟基自由基处理含氰废水的中试应用[J].广东化工,2014,41(16):253-254.
[36]Hijosa-Valsero M,Molina R,Schikora H,et al.Removal of cyanide from water by means of plasma discharge technology[J].Water Research,2013,47(4):1701-1707.
[37]冯求宝,杨怀远,杜建敏,等.脉冲电晕放电去除废水中氰化物的研究[J].工业安全与环保,2010,36(2):11-13.
[38]龙淼,李胜利,章英慧,等.高压脉冲放电处理含氰废水的影响因素探究[J].工业安全与环保,2005,31(3):7-10.