C/C-ZrC-Cu复合材料等离子喷涂W组织结构
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摘要
在金属反应熔渗法(RMI)制备的C/C-ZrC-Cu复合材料上采用大气等离子喷涂法(APS)得到厚度为1.3 mm的W涂层。运用扫描电镜-能谱(SEM-EDS),X射线衍射(XRD)测试技术分析研究了等离子喷涂W与C/C-CuZr复合材料界面相组成。结果表明:C/C复合材料反应熔渗法采用Cu-48.9%Zr(摩尔分数)粉末制备出均匀的熔渗组织,这是因为Zr提高了Cu在1300℃的C/C复合材料中的润湿性,在熔渗过程中生成了正交晶系相Cu_(10)Zr_7。W涂层与C/C-ZrC-Cu复合材料的结合类型以扩散结合为主,其界面区内主要是W和C通过包晶反应生成WC扩散层,反应扩散层厚度约为10 um。
W coating with thickness of 1.3 mm was successfully deposited by the atmosphere plasma spray(APS) technology on C/C-ZrC-Cu composite which was fabricated by reactive metal infiltration(RMI).Phase composition of interface between W coating and C/C-ZrC-Cu composite was investigated using a combination of X-ray diffraction(XRD) and scanning electron microscopy with energy-dispersive X-ray analysis(SEM-EDS).The results show that good performances of C/C-ZrC-Cu composite are obtained by reactive infiltration method with using powders of Cu-48.9% Zr,and Zr element can increase the wettability of Cu in C/C composite at 1300 ℃,the orthorhombic phase Cu_(10)Zr_7 is found in the composite.The type of bonding between W coating and C/C-ZrC-Cu composite is diffusion bonding on the main area of the interface.The diffusion bonding of WC layer is produced by peritectic reaction of phase W and C,and the thickness of reaction-diffusion layer is about 10 μm.
W coating with thickness of 1.3 mm was successfully deposited by the atmosphere plasma spray(APS) technology on C/C-ZrC-Cu composite which was fabricated by reactive metal infiltration(RMI).Phase composition of interface between W coating and C/C-ZrC-Cu composite was investigated using a combination of X-ray diffraction(XRD) and scanning electron microscopy with energy-dispersive X-ray analysis(SEM-EDS).The results show that good performances of C/C-ZrC-Cu composite are obtained by reactive infiltration method with using powders of Cu-48.9% Zr,and Zr element can increase the wettability of Cu in C/C composite at 1300 ℃,the orthorhombic phase Cu_(10)Zr_7 is found in the composite.The type of bonding between W coating and C/C-ZrC-Cu composite is diffusion bonding on the main area of the interface.The diffusion bonding of WC layer is produced by peritectic reaction of phase W and C,and the thickness of reaction-diffusion layer is about 10 μm.
引文
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[37]WANG N,LI C R,DU Z M,WANG F M,ZHANG W J.The thermodynamic re-assessment of the Cu-Zr system[J].Calphad,2006,30(4):461-469.
[38]GUSTAFSON P.Thermodynamic evaluation of C-W system[J].Materials Science&Technology,2013,2(7):653-658.
[2]YIN J,XIONG X,ZHANG H B,HUANG B Y.Microstructure and ablation performances of dual-matrix carbon/carbon composites[J].Carbon,2006,44(9):1690-1694.
[3]成会朝,范景莲,李鹏飞,田家敏.难熔钼合金的高温抗氧化和烧蚀行为[J].中国有色金属学报,2011,21(3):570-576.CHENG Hui-zhao,FAN Jing-lian,LI Peng-fei,TIAN Jia-min.Oxidation resistance and ablation behavior of refractory alloy at high temperature[J].The Chinese Journal of Nonferrous Metals,2011,21(3):570-576.
[4]JACOBSON N S,CURRY D M.Oxidation microstructure studies of reinforced carbon/carbon[J].Carbon,2006,44(7):1142-1150.
[5]李军,杨鑫,刘红卫,黄启忠,苏哲安.耐烧蚀超高温陶瓷改性C/C复合材料的研究进展[J].中国有色金属学报,2015,25(7):1731-1743.LI Jun,YANG Xing,LIU Hong-wei,HUANG Qi-zhong,SUZhe-an.Research process of ultra high temperature ceramics modified carbon/carbon composites for ablation resistance[J].The Chinese Journal of Nonferrous Metals,2015,25(7):1731-1743.
[6]ZHAO D,ZHANG C R,HU H F,ZHANG Y D.Ablation behavior and mechanism of 3D C/ZrC composite in oxyacetylene torch environment[J].Composites Science and Technology,2011,71(11):1392-1396.
[7]WANG D N,ZENG Y,XIONG X,LI G D,CHEN Z K,SUN W,WANG Y L.Ablation behavior of Zr B2-SiC protective coating for carbon/carbon composites[J].Ceramics International,2015,41(6):7677-7686.
[8]ZHOU W Y,YI M Y,PENG K,RAN L P,GE Y C.Preparation of a C/C-Cu composite with Mo2C coatings as a modification interlayer[J].Materials Letters,2015,145:264-268.
[9]ZHOU W Y,RAN L P,PENG K,GE Y C,WU H,YI M Z.Effect of Carbon/Carbon Preform density on the microstructure and properties of Mo2C interlayer-modified carbon/carbon-copper composites for sliding contact materials[J].Advanced Engineering Materials,2016,18(2):277-283.
[10]YANG X,SU Z A,HUANG Q Z,CHAI L Y.Preparation and oxidation resistance of mullite/SiC coating for carbon materials at 1150℃[J].Transactions of Nonferrous Metals Society of China,2012,22(12):2997-3002.
[11]CHEN Z F,WU W P,CHENG H,LIU Y,WANG S M,XUE RJ.Microstructure and evolution of iridium coating on the C/Ccomposites ablated by oxyacetylene torch[J].Acta Astronautica,2010,66(5/6):682-687.
[12]MUMTAZ K,ECHIGOYA J,HIRAI T,SHINDO Y.Iridium coatings on carbon-carbon composites produced by two different sputtering methods:a comparative study[J].Journal of Materials Science Letters,1993,12(12):1411-1412.
[13]WANG Y G,LIU Q M,LIU J L,ZHANG L T,CHENG L F.Deposition mechanism for chemical vapor deposition of zirconium carbide coatings[J].Journal of the American Ceramic Society,2008,91(4):1249-1252.
[14]WANG Y J,LI H J,FU Q G,WU H,YAO D J,LI H L.SiC/HfC/SiC ablation resistant coating for carbon/carbon composites[J].Surface and Coatings Technology,2012,206(19/20):3883-3887.
[15]WANG Y L,XIONG X,LI G D,ZHANG H B,CHEN Z K,SUN W,ZHAO X J.Microstructure and ablation behavior of hafnium carbide coating for carbon/carbon composites[J].Surface and Coatings Technology,2012,206(11/12):2825-2832.
[16]YAO X Y,LI H J,ZHANG Y L,REN J J,YAO D J,TAO J.ASi C/Zr B2-SiC/SiC oxidation resistance multilayer coating for carbon/carbon composites[J].Corrosion Science,2012,57:148-153.
[17]ZHOU H J,GAO L,WANG Z,DONG S M.ZrB2-SiC oxidation protective coating on C/C composites prepared by vapor silicon infiltration process[J].Journal of the American Ceramic Society,2010,93(4):915-919.
[18]BARTULIA C,VALENTEA T,TULUIB M.Plasma spray deposition and high temperature characterization of Zr B2-Si Cprotective coatings[J].Surface and Coatings Technology,2002,155(2/3):260-273.
[19]徐玄,王跃明,熊翔,解路,闵小兵.等离子喷涂成形钨喉衬的烧蚀性能[J].中国有色金属学报,2011,21(6):1435-1443.XU Xuan,WANG Yue-ming,XIONG Xiang,JIE Lu,MINXiao-bing.Ablation property of tungsten nozzle produced by plasma spray forming[J].2011,21(6):1435-1443.
[20]周哲,葛毅成,汪沅,龚洁明,易茂中.炭/炭复合材料耐烧蚀W涂层[J].中国有色金属学报,2016,26(6):1272-1280.ZHOU Zhe,GE Yi-cheng,WANG Yuan,GONG Jie-ming,YIMao-zhong.Ablation performances of carbon/carbon composites with W coatings[J].2016,26(6):1272-1280.
[21]舒武炳,郭海明,乔生儒,孟国文,田长生.化学气相沉积法制备Ti C涂层的相组成和表面形貌[J].西北工业大学学报,2000,18(2):229-232.WU Bing-shu,GUO Hai-ming,QIAO Sheng-ru,MENGGuo-wen,TIAN Chang-sheng.Phase composition and surface morphology of TiC coating by chemical vapor deposition[J].Journal of North western Polytechnical University,2000,18(2):229-232.
[22]王坤杰,郭全贵,史景利,刘朗.在位反应制备TiC涂层的动力学研究[J].材料工程,2007(s1):169-171.WANG Kun-jie,GUO Quan-gui,SHI Jing-li,LIU Lang.Study on kinetic properties of TiC coatings prepared by in-situ reaction[J].Journal of Materials Engineering,2007(s1):169-171.
[23]SUN W,XIONG X,HUANG B Y,LI G D,ZHANG H B,CHEN Z K,ZHENG X L.Zr C ablation protective coating for carbon/carbon composites[J].Carbon,2009,47(14):3368-3371.
[24]LIU Q M,ZHANG L T,CHENG L F,WANG Y G.Chemical vapour deposition of zirconium carbide and silicon carbide hybrid whiskers[J].Materials Letters,2010,64(4):552-554.
[25]LIU Q M,ZHANG L T,JIANG F R,LIU J,CHENG L F,LI H,WANG Y G.Laser ablation behaviors of SiC-ZrC coated carbon/carbon composites[J].Surface and Coatings Technology,2011,205(17/18):4299-4303.
[26]WANG Y J,LI H J,FU Q G,WU H,LIU L,SUN C.Ablation behaviour of a Ta C coating on SiC coated C/C composites at different temperatures[J].Ceramics International,2013,39(1):359-365.
[27]WANG Y L,XIONG X,ZHAO X J,LI G D,CHEN Z K,SUNW.Structural evolution and ablation mechanism of a hafnium carbide coating on a C/C composite in an oxyacetylene torch environment[J].Corrosion Science,2012,61:156-161.
[28]张仲灵,易茂中,周文艳,吴皇,庞伟林,葛毅成,冉丽萍.粉末熔渗制备C/C-ZrC-Cu复合材料的组织结构[J].粉末冶金材料科学与工程,2016,21(2):311-316.ZHANG Zhong-ling,YI Mao-zhong,ZHOU Wen-yan,WUHuang,PANG Wei-lin,GE Yi-cheng,RAN Li-ping.Microstructure of C/C-ZrC-Cu composite fabricated by reactive melt infiltration[J].Materials Science and Engineering of Powder Metallurgy,2016,21(2):311-316.
[29]LEJAEGHERE K,VAN S V,VAN O G,COTTENIER S.Error estimates for solid-state density-functional theory predictions:an overview by means of the ground-state elemental crystals[J].Critical Reviews in Solid State and Materials Sciences,2014,39(1):1-24.
[30]BINDZUS N,STRAAS?T,WAHLBERG N,BECKER J,BJERG L,LOCK N,DIPPEL A C,IVERSEN B B.Experimental determination of core electron deformation in diamond[J].Acta Crystallographica,2014,70(Pt 1):39-48.
[31]YANG Xiao,TAKEICHI N,SHIDA K,TANAKA H,KURIYAMA N,SAKAI T.Novel Mg-Zr-A-H(A=Li,Na)hydrides synthesized by a high pressure technique and their hydrogen storage properties[J].Journal of Alloys and Compounds,2011,509(4):1211-1216.
[32]LV Z T,HU H Q,WU C,CUI S X,ZHANG G Q,FENG W X.First-principles study of structural stability,electronic and elastic properties of ZrC compounds[J].Physica B:Condensed Matter,2011,406(14):2750-2754.
[33]DING H P,VIRKAR A V,LIU F.Defect configuration and phase stability of cubic versus tetragonal yttria-stabilized zirconia[J].Solid State Ionics,2012,215:16-23.
[34]ABDULLAEVA Z,OMURZAK E,IWAMOTO C,OKUDERAH,KOINUMA M,TAKEBE S.High temperature stable WC1-x@C and TiC@C core-shell nanoparticles by pulsed plasma in liquid[J].Rsc Advances,2012,3(2):513-519.
[35]ALBISETTI A F,BIFFI C A,TUISSI A.Synthesis and structural analysis of Cu10Zr7[J].Journal of Alloys and Compounds,2012,544(24):42-45.
[36]HYDE A R.Ceramic matrix composites[J].Elsevier Applied Science,1990,11(1):30-36.
[37]WANG N,LI C R,DU Z M,WANG F M,ZHANG W J.The thermodynamic re-assessment of the Cu-Zr system[J].Calphad,2006,30(4):461-469.
[38]GUSTAFSON P.Thermodynamic evaluation of C-W system[J].Materials Science&Technology,2013,2(7):653-658.