天然矿物质及工业农业固体废弃物合成ZSM-5技术与发展
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摘要
矿产资源的开采产生了大量的固体废弃物,这些固体废弃物因现阶段技术水平的限制,大部分不能得到资源化有效利用,给人们的生活及环境造成了一定的影响。以硅铝质成分的天然矿物质及工业农业固体废弃物为原料合成ZSM-5功能材料,可有效利用资源,降低纯化工原料合成ZSM-5的原料消耗,而且以富含硅铝质成分的工农业固体废弃物所得ZSM-5产物对固体废弃物中重金属进行富集,可以实现以废治废的绿色工艺。介绍了可以用来合成ZSM-5的天然矿物质及工农业固体废弃物种类,从原料的不同预处理方法、ZSM-5水热合成条件、后期所得产物在各种催化反应中的应用及合成中遇到的一些问题等方面,分别介绍了以黏土、岩石等天然硅酸盐矿物质及工农业固体废弃物为原料合成ZSM-5的研究现状,总结了以天然矿物质及工农业固体废弃物为原料合成ZSM-5的研究进展,并分析了存在的主要问题及解决思路,对利用其他可利用天然矿物质及固体废弃物等合成ZSM-5及应用提供了一定的借鉴经验,对以有色金属尾矿为原料合成ZSM-5进行了可行性分析及展望。
Exploiting of mineral resources leaves a lot of solid waste. Due to the limitations of the current technology level,most of these solid wastes can not be utilized effectively and have a certain impact on people's life and environment. Using natural minerals,industrial and agricultural solid waste with silicon-aluminum composition to synthesize function material such as ZSM-5 can effectively utilize these silicon-aluminum materials,reduce the consumption of chemical materials to synthesize ZSM-5. Using the obtained ZSM-5 to enrich the heavy metals in industrial and agricultural solid waste can realize the waste treatment waste green process. Firstly,introduce the types of natural minerals,industrial and agricultural solid waste can be used to synthesize ZSM-5,and then introduce the pretreatment methods,hydrothermal synthesis conditions,applications of the ZSM-5 product in catalytic reactions and problems encountered in synthesis process are expound from different types of clay and rock natural minerals,industrial and agricultural solid residue based on predecessor's work. Summarized the research progress of synthesis of ZSM-5 with natural minerals,industrial and agricultural solid waste,and analyzed the main existing problems and solutions. Therefore,some reference experiences for using the mineral materials with silicon-aluminum composition to synthesize ZSM-5 were provided. And last,the synthesis of ZSM-5 through using nonferrous metals solid waste was prospected.
Exploiting of mineral resources leaves a lot of solid waste. Due to the limitations of the current technology level,most of these solid wastes can not be utilized effectively and have a certain impact on people's life and environment. Using natural minerals,industrial and agricultural solid waste with silicon-aluminum composition to synthesize function material such as ZSM-5 can effectively utilize these silicon-aluminum materials,reduce the consumption of chemical materials to synthesize ZSM-5. Using the obtained ZSM-5 to enrich the heavy metals in industrial and agricultural solid waste can realize the waste treatment waste green process. Firstly,introduce the types of natural minerals,industrial and agricultural solid waste can be used to synthesize ZSM-5,and then introduce the pretreatment methods,hydrothermal synthesis conditions,applications of the ZSM-5 product in catalytic reactions and problems encountered in synthesis process are expound from different types of clay and rock natural minerals,industrial and agricultural solid residue based on predecessor's work. Summarized the research progress of synthesis of ZSM-5 with natural minerals,industrial and agricultural solid waste,and analyzed the main existing problems and solutions. Therefore,some reference experiences for using the mineral materials with silicon-aluminum composition to synthesize ZSM-5 were provided. And last,the synthesis of ZSM-5 through using nonferrous metals solid waste was prospected.
引文
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